Abstract: The invention provides ammonia gas sensor and its manufacturing method. Said ammonia gas sensor comprises a piezoelectric substrate, a surface acoustic wave sensor, and a L-glutamic acid hydrochloride coating; said surface acoustic wave sensor and said L-glutamic acid hydrochloride coating are on the said piezoelectric substrate.

Abstract: A gas-concentration measuring apparatus for measuring the concentration variation of gas residing in a target region. The gas-concentration measuring apparatus comprises an ultrasound-transmitter adapted to transmit an ultrasound in response to an ultrasound-generating signal having a rate of voltage change equal to or greater than a slew rate of an operational amplifier, and further adapted to output the ultrasound-generating signal. An ultrasound-receiver adapted to receive the ultrasound wave passed through the gas residing in the target region, and further adapted to convert the received ultrasound into an electrical signal serving as a received ultrasound signal is provided. A gas-concentration determiner adapted to input the ultrasound-generating signal and the received ultrasound wave signal into the operational amplifier to generate an amplified transmitting-side chopping wave and an amplified receiving-side chopping wave is further provided.

Abstract: An acoustic gas monitor has a measurement chamber into which a reference gas of known composition is received and is provided with a wall section for the selective transmission of a gaseous substance to be monitored between the reference gas internal the chamber and a host gas externally of the chamber. An acoustic velocity meter is arranged to supply to an analyzer a signal indicative of an acoustic velocity within the mixture of reference gas and gaseous substance in the chamber. The analyzer being programmed to derive, from the velocity measurement made within the single chamber, information relating to the level of the gaseous substance to be monitored.

Abstract: An acoustic gas analyzer for gas mixture has an acoustic velocity meter that provides a first output dependent on a detected transmission of acoustic energy through a gas to be analyzed, a temperature probe having a probe time constant that provides a second output indicative of a measured temperature of the gas, and a calculation unit that receives the first and the second outputs and determines compositional information of the gas therefrom. A signal processor is connected between the acoustic velocity meter and the calculation unit and temporally adapts the amplitude of the first output from the meter in a manner dependent on the probe time constant and provides a temporally adapted first output for use as the first output within the calculation unit.

Abstract: An apparatus and method for sensing chemical and/or biological analytes in a gaseous or liquid medium by monitoring the changes in impedance and thickness of a sensing element in the presence of the analyte is provided. Detecting means are provided to measure the change in the physical property of the sensing material to determine the presence and/or the amount of analyte present. An array of hybrid sensors dedicated to detecting a particular analyte which may be included in the medium, is also provided.

Abstract: 22A temperature and/or pressure compensated microbalance is disclosed. Temperature compensation is achieved by applying heat to at least a part of the microbalance, measuring a temperature-dependent variable, and controlling the amount of heat applied to the microbalance to keep the temperature-dependent variable substantially constant. In one embodiment, the heat is applied to the microbalance by passing electrical current through a resistive element provided on or embedded in the oscillating element of the microbalance. Pressure compensation is achieved by taking into account the variation in the mass or density of fluid passing through the microbalance. Various materials and methods of construction are also disclosed, including micro-machining and electroforming.

Abstract: An apparatus to normalize a flow rate of a fluid in a main flow channel is provided. The apparatus uses a movable member, such as a flexible membrane disposed for reciprocating displacement, to produce a constant dither flow of the fluid that is independent of fluid composition. This dither flow generates a signal output from a normalizing flow sensor that both represents a characteristic property of the fluid and a flow rate calibration factor. A similar apparatus to determine the characteristic property or flow rate calibration factor is also provided. The devices disclosed may be used in numerous industrial, process, and medical flow system applications for normalization of flow sensors and to derive other properties of a fluid.

Abstract: A vibration testing device includes a computer system having: a measurement processing block for inputting an output of the monitoring sensor and processing the output; a model substituting block for modeling characteristics of the test piece, calculating a response quantity corresponding to a drive condition of an actuator, and inputting the calculation result to a numerical simulation block and the parameter changing block; the parameter changing block for comparing the calculation result of the model substituting block with the processing result of the measurement processing block, and changing the parameter; the numerical simulation block for calculating a vibration response in accordance with a previously input structure numerical model; and a waveform generating block for calculating a time function of a deformation to be applied to the test piece, and outputting the time block to the actuator controlling device.

Abstract: A sensor for the measurement of carbon dioxide concentration within an air flow being input to a measuring cell (1) connected to at least one electroacoustic element (2, 3) for transmitting and receiving airborne acoustic waves within the measuring cell (1). The output signal of the sensor corresponds to the propagation velocity of these waves and an indirect measure of carbon dioxide concentration, with an automatic offset correction functionality for compensation of undesired offset variations of the signal, caused by temperature or humidity variations. Preferably, an accumulating function for minimizing the influence of the offset variations is included, which for humidity variations may consist of a material with high porosity and surface density of polar molecular groups. Temperature control of the inner sheath (4) is effected by a temperature sensor (11), a resistive heating element (12) in good thermal contact with the inner sheath (4), and a control circuit (13).

Abstract: A controller for a quartz crystal microbalance (QCM) sensor system and method for detecting mass deposition on a QCM sensor. The controller controls a QCM using temperature-, voltage- and current-regulating circuits, a microcontroller, an oscillator, heating and cooling devices and circuits, high voltage grids, digital-to-analog and analog-to-digital converters, data telemetry and uplink circuits, and a remote user. The remote user may be a person, computer, network or data logger. The remote user allows the controller to be reconfigurable during operation. The controller samples and reports data faster and is more reliable over extended periods of operation. Further, the controller is assembled using innovative techniques making it smaller and thus more transportable, easier to incorporate into existing facilities and less expensive to construct and operate. The apparatus may also be assembled in a modular fashion that allows for customization.

Abstract: An acoustic monitoring method and system in laser-induced optical breakdown (LIOB) provides information which characterize material which is broken down, microbubbles in the material, and/or the microenvironment of the microbubbles. In one embodiment of the invention, femtosecond laser pulses are focused just inside the surface of a volume of aqueous solution which may include dendrimer nanocomposite (DNC) particles. A tightly focused, high frequency, single-element ultrasonic transducer is positioned such that its focus coincides axially and laterally with this laser focus. When optical breakdown occurs, a microbubble forms and a shock or pressure wave is emitted (i.e., acoustic emission). In addition to this acoustic signal, the microbubble may be actively probed with pulse-echo measurements from the same transducer. After the microbubble forms, received pulse-echo signals have an extra pulse, describing the microbubble location and providing a measure of axial microbubble size.

Abstract: The contents of a container 1 are non-intrusively monitored by probing the container with an ultrasonic signal, and measuring changes in the ultrasound signature of the received signal after the signal has passed through the contents of the container.

Abstract: In the prevent invention a controllable acoustic source (14) in connection with the process fluid (10) emits a signal (18) into the fluid (10), consisting of a suspension of particles (12), being volumes of gas, liquid or solid phase. The controllable acoustic signal (18) is allowed to interact with the particles (12), and the acoustic (pressure) signals (22) resulting from such an interaction is measured preferably via a sensor (24). A spectrum is measured. The spectrum is used to predict properties, content and/or size of the particles (12) and/or used to control a process in which the process fluid (10) participates. The prediction is performed in the view of the control of the acoustic source (14). The used acoustic signal has preferably a frequency below 20 kHz.

Abstract: A programmable device for analyzing mixtures of suspended vapors and air by pinging particles making up the vapors at their mechanical resonant frequencies and detecting the resultant rings.

Abstract: Systems and methods of monitoring thin film deposition are described. In one aspect, a thin film deposition sensor includes an acoustical resonator (e.g., a thin film bulk acoustical resonator) that has an exposed surface and is responsive to thin film material deposits on the exposed surface. A substrate clip may be configured to attach the thin film deposition sensor to a substrate. A transceiver circuit may be configured to enable the thin film deposition sensor to be interrogated wirelessly. A method of monitoring a thin film deposition on a substrate also is described.

Abstract: In a method for producing surface wave sensors on the basis of a surface wave building component a polymer parylene film with a thickness of 20 to 200 nm is applied to a hydrophilic sensor surface of the surface wave building component by deposition from the gas phase, whereby the hydrophilic sensor surface becomes hydrophobic, the surface is then subjected to plasma activation to render it hydrophilic and a hydrophilic sorption polymer layer is then applied to the parylene film so as to provide a surface wave sensor with a homogenous sorption polymer layer.

Abstract: An acoustic gas monitor has a measurement chamber into which a reference gas of known composition is received and is provided with a wall section for the selective transmission of a gaseous substance to be monitored between the reference gas internal the chamber and a host gas externally of the chamber. An acoustic velocity meter is arranged to supply to an analyzer a signal indicative of an acoustic velocity within the mixture of reference gas and gaseous substance in the chamber. The analyzer being programmed to derive, from the velocity measurement made within the single chamber, information relating to the level of the gaseous substance to be monitored.

Abstract: An apparatus that is configured to sense the presence of gases, vapors and liquids using acoustic waves. The apparatus comprises a first part that is configured to generate acoustic waves. The apparatus further comprises a second part having a sensing and acoustic wave guiding device, which is configured to sense the presence of such substances and propagate acoustic waves. The first part is removably fixable to the second part of the apparatus. When the first part is fixed to the second part, the acoustic waves propagate in the second part.

Abstract: A gas sensor (10) including a measurement chamber (28) into which a gas GS is flown and a detection element main body (40) facing the measurement chamber (28). The detection element main body (40) includes an element case 42, and a protective film (48) is adhered to a bottom surface thereof. An acoustic matching plate (50) and a piezoelectric element (51) of a substantially columnar shape and a tube body (52) provided in a position surrounding the acoustic matching plate 50 and the piezoelectric element 51 are housed in the element case (42). A filler is then introduced into the element case (42), whereby the acoustic matching plate (50), the piezoelectric element (51), and the tube body (52) are sealed by a filled layer (99).

Abstract: Volume measuring apparatus is used in a closed space as in the case of volume measurement of liquid in a container placed on an orbit of an artificial satellite and permits the volume measurement in a state without mixture with gas, liquid, or solid. A volume measuring apparatus is an apparatus for measuring the volume of liquid or solid under microgravity, which has two or more containers coupled to each other by a pipe, a device for separating or fixing a gas phase, a liquid phase, or a solid phase, a pressure fluctuation source, a pressure signal receiver, a pressure gage, and a thermometer, wherein the separating or fixing device, the pressure fluctuation source, the pressure signal receiver, the pressure gage, and the thermometer are placed in the containers and wherein the pressure fluctuation source, the pressure signal receiver, the pressure gage, and the thermometer are connected to a signal analyzing unit.

Abstract: The invention relates to a method and to apparatus for thermodynamic analysis of a mixture of fluids, in which the volume of a sample of a given quantity of said mixture is caused to vary step by step and in monotonic manner, and the pressure of the sample is read at each step, the sample being stirred at each step so as to hasten the mixture reaching thermodynamic equilibrium. According to the invention, the sample is stirred by applying ultrasound to said sample by means of transducer (20). The sample can be contained in a bag (19) of flexible material immersed together with the transducer in a control fluid inside a rigid container (10). The invention can be used to determine the bubble point of a mixture of hydrocarbons.

Abstract: An apparatus to normalize a flow rate of a fluid in a main flow channel is provided. The apparatus uses a moveable member, such as a flexible membrane disposed for reciprocating displacement, to produce a constant dither flow of the fluid that is independent of fluid composition. This dither flow generates a signal output from a normalizing flow sensor that both represents a characteristic property of the fluid and a flow rate calibration factor. A similar apparatus to determine the characteristic property or flow rate calibration factor is also provided. The devices disclosed may be used in numerous industrial, process, and medical flow system applications for normalization of flow sensors and to derive other properties of a fluid.

Abstract: A piezoelectric crystal element and a sensor utilizing the same are presented for use in a sensor device for identifying at least one foreign material from environment. The crystal element comprises at least one crystal resonator in the form of an inverted mesa structure, which has a membrane-like region and is characterized by a certain resonance frequency value. A surface region of the crystal resonator is modified by reactive molecules of a kind capable of interacting with the foreign material to yield a reaction product that effects a change in the resonance frequency of the crystal resonator from said certain resonance frequency value. This change is indicative of the identity and quantity of the foreign material.

Abstract: An apparatus and method for sensing chemical and/or biological analytes includes a deflectable arm of a microcantilever formed over and contacting a sensing element. A gaseous or liquid medium which may include the analyte being detected, is introduced to the sensing element. The sensing element undergoes volumetric expansion or contraction in the presence of the analyte sought to be detected, typically by adsorbing the analyte. The volumetric change of the sensing element causes the deflectable arm to deflect. The deflectable arm includes at least one measurable physical property which changes when the arm deflects. Detecting means are provided to measure the change in the physical property to determine the presence and amount of analyte present. An array of microcantilevers in which each microcantilever is dedicated to detecting a particular analyte which may be included in the medium, is also provided.

Abstract: An energy meter which measures a volume of gas supplied, which measures a calorific value of the gas supplied, and which calculates an energy value corresponding to the measured volume of gas supplied and the calorific value. The structure to measure the volume of the gas supplied and to calculate the energy value may be provided in a single unit. The structure to measure the calorific value of the gas supplied preferably includes a structure to measure the speed of sound in the gas and further preferably measures a first thermal conductivity of the gas at a first temperature and measures a second thermal conductivity of the gas at a second temperature which differs from the first temperature, and is arranged to produce the calorific value of the gas corresponding to the measured speed of sound in the first and second thermal conductivities.

Abstract: A controller for a quartz crystal microbalance (QCM) sensor system and method for detecting mass deposition on a QCM sensor. The controller controls a QCM using temperature-, voltage- and current-regulating circuits, a microcontroller, an oscillator, heating and cooling devices and circuits, high voltage grids, digital-to-analog and analog-to-digital converters, data telemetry and uplink circuits, and a remote user. The remote user may be a person, computer, network or data logger. The remote user allows the controller to be reconfigurable during operation. The controller samples and reports data faster and is more reliable over extended periods of operation. Further, the controller is assembled using innovative techniques making it smaller and thus more transportable, easier to incorporate into existing facilities and less expensive to construct and operate. The apparatus may also be assembled in a modular fashion that allows for customization.

Abstract: A method and apparatus for measuring properties of a liquid composition includes a mechanical resonator, such as a thickness shear mode resonator or a tuning fork resonator, connected to a measurement circuit. The measurement circuit provides a variable frequency input signal to the tuning fork, causing the mechanical resonator to oscillate. To test the properties of a liquid composition, the mechanical resonator is placed inside a sample well containing a small amount of the liquid. The input signal is then sent to the mechanical resonator and swept over a selected frequency range, preferably less than 1 MHz to prevent the liquid being tested from exhibiting gel-like characteristics and causing false readings. The mechanical resonator's response over the frequency range depends on various characteristics of the liquid being tested, such as the temperature, viscosity, and other physical properties.

Abstract: A method and apparatus for measuring the relative density of a gas, for example natural gas. The gas is supplied through an inlet to a chamber and is output through an outlet. Using a control and an ultra-sonic transducer emitter and an ultra-sonic transducer receiver, the speed of sound in the gas corrected to standard conditions is calculated. Then, the control operates to measure the relative density RD of the gas using the formula RD=a×SoSsc+b, where SoSsc is the speed of sound in the gas corrected to standard conditions, and a and b are constants.

Abstract: A system for determining the composition of a multiple-component fluid and for determining linear flow comprising at least one sing-around circuit that determines the velocity of a signal in the multiple-component fluid and that is correlatable to a database for the multiple-component fluid. A system for determining flow uses two of the inventive circuits, one of which is set at an angle that is not perpendicular to the direction of flow.

Abstract: In a surface acoustic wave sensor mounted within a body, the sensor having a surface acoustic wave array detector and a micro-fabricated sample preconcentrator exposed on a surface of the body, an apparatus for collecting air for the sensor, comprising a housing operatively arranged to mount atop the body, the housing including a multi-stage channel having an inlet and an outlet, the channel having a first stage having a first height and width proximate the inlet, a second stage having a second lower height and width proximate the micro-fabricated sample preconcentrator, a third stage having a still lower third height and width proximate the surface acoustic wave array detector, and a fourth stage having a fourth height and width proximate the outlet, where the fourth height and width are substantially the same as the first height and width.

Abstract: A method and apparatus for measuring the calorific value of a gas. The apparatus includes a chamber to which a gas in question, for example natural gas, is supplied through an inlet and leaves through an outlet. The speed of sound SoS at ambient temperature is measured using any suitable method such as electronic control and a calculating device and an ultra-sound emitter and an ultra-sound receiver. The ambient temperatures Ta, is observed by a temperature sensor, and a thermal conductivity sensor measures the thermal conductivity of the gas at two different temperatures above the ambient temperature. One value ThCH, of the thermal conductivity is measured at 70° C. above ambient and the other value ThCL of the thermal conductivity is measured at 50° C. above ambient. The control calculates the calorific value CV of the gas according to the formula: CV=a·ThCH+b·ThCL+C·SoS+d·Ta+e·Ta2 +f, where a, b, c, d, e and f are constants.

Abstract: When a sensor has deteriorated, the propagation time T1′ of a first reflection wave becomes greater than the propagation time T1 of a first reflection wave as measured in a new sensor. If measurement of the concentration of a specific gas is based on the propagation time T1 of the first reflection wave as measured in the new sensor, gas concentration cannot be determined accurately. By contrast, a reflection wave other than the first reflection wave (for example, a second reflection wave) is merely reflected off the surface of the ultrasonic element and is not affected by the internal structure of the ultrasonic element. Therefore, even when the sensor is deteriorated, the propagation time T2, T2′ of the second reflection wave exhibits less variation and is less susceptible to deterioration of the sensor.

Abstract: A device that measures the concentration of a particular gas within a sample of gas includes a housing having a gas flow path with a gas inlet port designed to receive the sample of gas, a gas outlet port, and a chamber extending between the gas inlet and outlet ports. The sample of gas flows into the inlet port, proceeds through the chamber and exits the housing through the outlet port. The device further includes a first ultrasonic transmitter positioned within the chamber near the inlet port capable of transmitting an ultrasonic pulse into the chamber in a direction with the flow of gas, and a second ultrasonic transmitter positioned within the chamber near the outlet port capable of transmitting an ultrasonic pulse into the chamber in a direction against the flow of gas.

Abstract: An acoustic device for continuously or intermittently determining the composition of gas mixtures. The acoustic device has an acoustic resonator with input and output transducers arranged to minimize the effect of external conditions. The device normally operates as a feedback oscillator with the oscillation frequency determined by the gas-filled resonator's natural frequency, providing a speed of sound measurement. The device is configured as two open ended parallel side by side adjacent one half wavelength tubes, each with sending and receiving transducers inserted through a tube wall at the midpoint of that tube. This forms a symmetric quarter wave resonator from each tube. The two sending transducers are operated out of phase, as are the two receiving transducers. The causes cancellation of external sounds, and of their influence on measurements. A small pressure relieved cap is preferably placed over the external surface of each transducer.

Abstract: A method for determining the endpoint of a plasma etch process is disclosed. The endpoint of the plasma etch process is determined using an acoustic cell attached to an exhaust port on a reaction chamber of a plasma reactor. The gas from the reaction chamber flows into the acoustic cell during the plasma etch process. Acoustic signals are periodically transmitted through the gas flowing in the acoustic cell and a first velocity for the acoustic signals associated with etching a first material layer formed on a substrate is determined. Thereafter, the endpoint of the plasma etch step is determined when the first velocity changes to a second velocity associated with etching the first material layer through its thickness to its interface with an underlying material layer. The gas from the reaction chamber flows through a compressor prior to flowing into the acoustic cell to increase the gas pressure in the acoustic cell.

Abstract: A system and method that allows for early detection of biological conditions, such as a disease, through analysis of appropriate gaseous samples. The system and method are particularly amenable to the early screening for diseases, such as lung cancer, through the detection of specific biomarkers when present in exhaled breath from an individual. A preferred system implements a CO overtone laser that generates radiation and directs it through a photoacoustic cell. The absorption of the radiation is detected acoustically, and the absorption characteristics are utilized in determining the presence of a specific biological condition.

Abstract: A sensor comprises a substrate and a polymeric film disposed on the substrate. The polymeric film comprises at least one hardblock component and at least one softblock component. The invention also sets forth a method for enhancing detection of a target compound by a sensor. The method comprises disposing a polymeric film on a surface of the sensor, in which the polymeric film enhances detection of target compounds not normally sensed by a sensor without the polymeric film. The polymeric film comprises at least one hardblock component and at least one softblock component.

Abstract: An apparatus that is configured to sense the presence of gases, vapors and liquids using acoustic waves. The apparatus comprises a first part that is configured to generate acoustic waves. The apparatus further comprises a second part having a sensing and acoustic wave guiding device, which is configured to sense the presence of such substances and propagate acoustic waves. The first part is removably fixable to the second part of the apparatus. When the first part is fixed to the second part, the acoustic waves propagate in the second part.

Abstract: A device for detecting chemical substances includes a plurality of sensors arranged in an array. The sensors are connected to respective oscillator circuits which drive the sensors, and the oscillator circuits are coupled to a power multiplexer which provides the circuits with power according to a timing pattern such that not all of the oscillator circuits are activated at any one time. Preferably, only one oscillator circuit is activated at any given time. This multiplexing arrangement saves power and substantially eliminates cross talk between the oscillator circuits. The oscillator circuits are preferably application specific integrated circuits (ASICs), and the sensors are preferably surface acoustic wave (SAW) devices. In use, the SAW sensors are exposed to a gas, such as air, containing the chemical substance to be detected. Signals from the SAW sensors are analyzed to identify the chemical substance.

Abstract: A gas concentration sensor comprises an ultrasonic element 33 opposite a reflection surface 34. A depression 34a is formed on an edge portion of a reflection surface 34 which is in contact with a side wall of a measurement chamber 32 such that a bottom surface of the depression 34a is substantially in parallel with the reflection surface 34. The distance between the ultrasonic element 33 and the edge portion of the reflection surface 34 becomes greater than the distance between the ultrasonic element 33 and a central portion of the reflection surface 34. As a result, an indirect wave, which impinges obliquely on the side wall of the measurement chamber 32 and propagates along the side wall, is reflected from the bottom surface of the depression 34a and propagates.

Abstract: A method and apparatus for real time gas analysis involving determining individual concentrations of fluid constituents in a mixture of known constituents by measuring properties of the mixture and solving a set of equations, which relate the individual gas concentrations to the measured properties of the mixture, for the unknown individual gas concentrations. The individual concentrations of four gasses in a mixture are determined by: passing the mixture through a flowmeter, a capillary, an orifice, and a sonic oscillator; transducing temperature, pressure and acoustic frequency measurements taken from the sensors; determining the density, viscosity, and the specific heat of the mixture; forming three equations which respectively relate these three properties to individual gas concentrations; and solving the three equations and the constitutive equation which requires that the sum of the concentrations equal unity, for the four unknown individual gas concentrations.

Abstract: A gas analyzer (10) integrated into the main passageway (11) of a breathing circuit includes pressure-drop flow element (12) that measures a pressure drop across an orifice, an acoustic flowmeter (14) measures the speed of sound in the gas mixture, and a SAW device (20) from which the viscosity of the gas mixture is determined. The dielectric constant of the gas mixture is determined from the capacitance of spaced-apart charged plates of a capacitor (22) through which the mixture passes. The gas mixture density is determined from the measured pressure drop and flow rate, while the gas mixture specific heat is determined from the density and speed of sound in accordance with known relationships. The individual concentrations of five constituents of a mixture of gasses can be determined by solving five equations relating the independently measured properties of the gas mixture to the individual constituent concentrations.

Abstract: An ultrasonic gas analyzer includes an acoustic cavity through which an air sample is drawn by a low speed air pump or other mechanism. The cavity has a pair of ultrasonic wave transmitters/receivers on opposite sides of the acoustic cavity. An electronic circuit controls the transmitters/receivers so that a high frequency ultrasonic wave is propagated across the cavity and thereby through the gas flowing through the cavity. This ultrasonic wave reflects back and forward across the acoustic cavity and the transmitters/receivers receive this wave and supply a signal indicative of the wave to an electronic circuit. Based on the time of flight data for the ultrasonic wave being reflected in a gas/air mixture and in air and the amplitude of those reflected ultrasonic waves, a determination is made as to the gases within the gas/air mixture. This determination then can be displayed and an audio signal can be generated depending on the amount of detected gases.

Abstract: Apparatus (15, 30) and methods for performing acoustical measurements are provided having some and preferably all of the following features: (A) the system (15, 30) is operated under near-field conditions; (B) the piezoelement (40) or piezoelements (40, 48) used in the system are (i) mechanically (41, 49) and electrically (13, 16) damped and (ii) efficiently electrically coupled to the signal processing components of the system; (C) each piezoelement (40, 48) used in the system includes an acoustical transformer (42, 50) for coupling the element to a gaseous test medium (9); (D) speed of sound is determined from the time difference between two detections of an acoustical pulse (81, 82) at a receiver (40, FIG. 3; 48, FIG.

Abstract: A method and device for determining concentration and rate of change of concentration of a gas having ability to act as crystal etchant, such as hydrofluoric acid (HF) or deuterium fluoric acid (DF) gas. A crystal 22 is placed in a chamber and subjected to erosion by the gas. The crystal resonant frequency, changeable during the crystal erosion, is determined and a crystal resonant frequency change is calculated to determine the concentration of the gas. The crystal 22 is preferably an AT-cut quartz crystal. The step of obtaining the crystal resonant frequency is preferably performed in a Colpitts oscillator. The step of calculating the gas concentration, proportional to the change in the crystal resonant frequency, may also encompass calculating a change and rate of change in the gas concentration, and averaging the calculated gas concentration. The crystal 22 is preferably inserted in a crystal holder 20, and mounted on an electronic box 34 which holds the oscillator board.

Abstract: A method and apparatus for measuring surface changes, such as mass uptake at various pressures, in a thin-film material, in particular porous membranes, using multiple differently-configured acoustic sensors.

Abstract: The present invention relates to a method of determining the relative proportions of gases in a mixture, such that the relative proportions of N gases are determined using N-1 sensors, not all of which are specific to a particular gas. In the preferred embodiment, oxygen and carbon dioxide are measured in the presence of nitrogen by measuring magnetic susceptibility and speed of sound. The described method of gas analysis leads to very fast response times and exceptional stability, making the technology suitable for breath-by-breath analysis of respired air. Notably, the method does not require high-temperature components, electrochemical cells, or consumable components.

Abstract: A system and method are set forth for photoacoustical analysis of isotope and other compounds having telltale absorption wavelengths between 1700-2500 nm. The system and method includes a Co:Mg F2, an optical parametric oscillator (OPO), or a diode laser tunable between 1700-2500 nm which is directed into a sample at energies sufficient to generate detectable acoustical emissions. A microphone detects the emissions for processing and analysis. The system and method is adapted to detect stable isotope compounds such as 13CO2 as well as other chemical compounds. For non-gaseous compounds, a CO2 or diode laser is used to photoablate the gaseous sample containing the suspected compound.

Abstract: Apparatus and methods for performing acoustical measurements are provided having some and preferably all of the following features: (1) the system is operated under near-field conditions; (2) the piezoelement or piezoelements used in the system are (a) mechanically and electrically damped and (b) efficiently electrically coupled to the signal processing components of the system; (3) each piezoelement used in the system includes an acoustical transformer for coupling the element to a gaseous test medium; (4) speed of sound is determined from the time difference between two detections of an acoustical pulse at a receiver; (5) cross-correlation techniques are employed to detect the acoustical pulse at the receiver; (6) fast Fourier transform techniques are used to implement the cross-correlation techniques; and (7) stray path signals through the body of the acoustic sensor are removed from detected signals prior to signal analysis.

Abstract: The invention relates to a sensor comprising a piezoelectric crystal with a polyarylene thioether-containing coating, the coating containing at least one polyarylene system having repeating units of the formula I, —[(Ar1)n—X]m—[(Ar2)i—Y]j—[(Ar3)k—Z]l—[(Ar4)o—W]p—  (I) which contain at least one thioether group, in which Ar1, Ar2, Ar3 and Ar4 are identical or different aryl systems having from 6 to 18 carbon atoms, W, X, Y and Z are identical or different linking groups, selected from the group comprising —SO2—, —S—, —SO—, —O—, —CO—, —CO2—, alkylene or alkylidene having from 1 to 6 carbon atoms and —NR1—, where R1 is an alkyl or alkylide group having from 1 to 6 carbon atoms and at least one linking group must be —S—, n, m, i, j, k, l, o, p are, equal or different, integers zero, 1, 2, 3 or 4, their sum havin