With Hydrocarbon Liquid Or Gas Present Patents (Class 75/529)
  • Patent number: 7959708
    Abstract: A method and apparatus for forming internally shrouded supersonic coherent jets comprising an inert gas, such as pure argon and argon/oxygen mixtures. This method and apparatus can be employed to produce low-carbon steels with a top lance in basic oxygen steelmaking.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: June 14, 2011
    Assignee: Praxair Technology, Inc.
    Inventors: William John Mahoney, Gary Thomas Vardian
  • Publication number: 20110126672
    Abstract: A method for the continuous production of steel using metal charge material that is preheated in an upper part of a melting vessel, is then melted in a lower part of the melting vessel with fossil fuels and the molten material is continuously discharged into a treatment vessel in which the desired steel quality is adjusted while gases are introduced into the melting vessel from the exterior to afterburn the melting exhaust gases. The process gases are step-wise afterburned when ascending in the melting vessel by introducing the afterburn gases into the interior of the charge material column by way of an interior shaft that projects into the material column and in whose walls inlet openings for the gases are disposed and form afterburn planes arranged one on top of the other.
    Type: Application
    Filed: February 11, 2011
    Publication date: June 2, 2011
    Applicant: SMS SIEMAG AKTIENGESELLSCHAFT
    Inventors: Peter Monheim, Wolfgang Reichelt, Walter Weischedel
  • Patent number: 7452401
    Abstract: A method of injecting oxygen into a melt located within a metallurgical furnace having a heated furnace atmosphere in which oxygen and fuel is injected into 1 or more nozzles having passageways of converging-diverging configuration under choked flow conditions to produce supersonic jet or jets discharged from the passageways. Fuel is injected into internal circumferential locations of the passageways so as to impart a structure to the jets being discharged that have an outer circumferential region containing a mixture of fuel and oxygen and a central region containing essentially oxygen. Such a structured jet upon discharge interacts with the furnace atmosphere to create an outer shear-mixing zone in which the outer circumferential layer mixes with the heated furnace atmosphere and auto-ignites to produce a flame envelope surrounding a supersonic jet of oxygen. The jet of oxygen and flame envelope can be directed against a melt contained within the metallurgical furnace for injection of oxygen into the melt.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: November 18, 2008
    Assignee: Praxair Technology, Inc.
    Inventors: William John Mahoney, Michael Francis Riley, Adrian Christian Deneys, Gary Thomas Vardian, Stephen A. Manley
  • Patent number: 6749661
    Abstract: A method and an apparatus for advantageously introducing a flame and a high velocity oxidizing gas into a furnace for metal melting, refining and processing, particularly steel making in an electric arc furnace. The steel making process of an electric arc furnace is made more efficient by shortening the time of the scrap melting phase and introducing an effective high velocity oxidizing gas stream into the process sooner to decarburize the melted metal. In one implementation of an apparatus, improved efficiency is obtained by mounting a fixed burner/lance closer to the hot face of the furnace refractory at an effective injection angle. This mounting technique shortens the distance that the flame of the burner has to melt through the scrap to clear a path to the molten metal and shortens the distance the high velocity oxygen from the lance travels to the slag-metal interface thereby increasing its penetrating power.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: June 15, 2004
    Assignee: Process Technology International, Inc.
    Inventor: Valery G. Shver
  • Publication number: 20030172777
    Abstract: According to the invention, oil-charged mill-scale is treated such that the oil is encapsulated or bound therein. An escape of oil on use in a shaft oven first occurs when the ignition point is reached, thus guaranteeing combustion. Agglomeration of said mixture is by pelleting. A mixture comprising the following is preferably used for encapsulation and chemical binding of the oil: A zinc salt and a calcium salt of a saturated or unsaturated fatty acid, a hydrophobic inducing agent, an amino alcohol and ammonia. The abstract of the disclosure is submitted herewith as required by 37 C.F.R. §1.72(b). As stated in 37 C.F.R. §1.72(b), “A brief abstract of the technical disclosure in the specification must commence on a separate sheet, preferably following the claims, under the heading “Abstract of the Disclosure.
    Type: Application
    Filed: February 3, 2003
    Publication date: September 18, 2003
    Inventor: Wolfgang Schwetlick
  • Patent number: 6432165
    Abstract: A blowing lance for treating molten metals which are situated in vacuum-treatment vessels, in particular steel in RH vessels, having a central pipe and an encasing pipe which is arranged coaxially with respect to the central pipe and can be cooled by a cooling medium. The central pipe and the encasing pipe are connected to supply lines, which in turn can be connected to an oxygen station, a fuel-gas station and an inert-gas station and to a solids-feed device. In this lance, the cooled encasing pipe is arranged at a distance from the central pipe over its entire length. The free annular area (AR) between the two pipes satisfying the following statement AR=0.8 to 1.2×AZ where AZ=free cross-sectional area of the central pipe. The end of the central pipe is designed in the form of a Laval nozzle. The nozzle opening of the central pipe is being arranged at a distance (a) inside the encasing tube, where a=0.5 to 0.8×d where d=clear diameter of the central pipe.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: August 13, 2002
    Assignee: SMS Demag AG
    Inventors: Rainer Dittrich, Horst-Dieter Schöler, Andreas Ploch, Manfred Zeimes
  • Patent number: 6379425
    Abstract: Desulfurization is carried out by blowing CaO into molten iron, and a gas mixture of an inert gas and a hydrocarbon gas is used as a carrier. The ratio of the hydrocarbon gas to the desulfurizing agent is maintained in the range of from about 2.0 to about 50 Nl/kg. This desulfurizing method improves the desulfurization efficiency of the desulfurizing agent, increases the productivity of the desulfurizing process, and reduces the amount of slag generated in the desulfurizing process. Alternatively, a desulfurizing flux is blown into the molten iron together with a carrier gas comprising a gas mixture of an inert gas and a hydrocarbon gas or an inert gas alone at the start of desulfurization. The hydrocarbon gas in the carrier gas is increased, is added, or the unit gas is replaced by the hydrocarbon gas at adequate timing, whereby the desulfurization efficiency is improved.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: April 30, 2002
    Assignee: Kawasaki Steel Coporation
    Inventors: Naoki Kikuchi, Shuji Takeuchi, Akiharu Takao, Mototatsu Sugizawa, Shigeru Ogura
  • Patent number: 6328784
    Abstract: A process for desulfurizing a molten iron alloy in which a desulfurizing agent is applied to the molten iron alloy under agitation. Concurrently, a gas containing a hydrocarbon gas is blown onto the bath surface of the molten iron alloy, or a substance generating a hydrocarbon gas is added to the bath surface.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: December 11, 2001
    Assignee: Kawasaki Corporation
    Inventors: Naoki Kikuchi, Shuji Takeuchi, Mototatsu Sugizawa, Shigeru Ogura
  • Patent number: 6254652
    Abstract: Sequential processing of hydrogen rich and hydrogen deficient feeds (14 and 16) in a heat balanced, single molten metal bath (40) to produce both 90+ mole % hydrogen (90) and one or more lower purity vapor streams (140) is disclosed. The molten metal bath is heated by oxygen addition (18) to burn dissolved carbon from the bath and then cooled by sequential addition of two feeds with differing hydrogen contents. Preferably a 98% hydrogen product with a pressure of at least 2 atm., absolute is obtained, along with a lower purity hydrogen containing stream and a separate carbon oxides flue gas stream.
    Type: Grant
    Filed: May 18, 1999
    Date of Patent: July 3, 2001
    Assignee: Marathon Ashland Petroleum LLC
    Inventor: Donald P. Malone
  • Patent number: 6214084
    Abstract: Iron ore is reduced to molten iron by introducing the ore into a reactor while combusting coal with pure oxygen in the reactor. The molten iron phase, which forms at the bottom of the reactor, is stirred by injecting carbon monoxide into the molten iron. In a preferred embodiment, finely pulverized iron ore is injected with pure oxygen tangentially into a cyclone section of the furnace situated on top of a converter section, thereby causing melting and preliminary reduction of the ore to take place in the cyclone section. Primary reduction of the iron oxide occurs in the converter section of the furnace.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: April 10, 2001
    Assignee: The BOC Group, Inc.
    Inventors: Neeraj Saxena, Paul Alfred Sweeney, Akhilesh Kapoor
  • Patent number: 5931985
    Abstract: A process for blowing oxygen-containing gas, with and without solid material, on a metal melt in a metallurgical vessel, a process for generating a burner flame and corresponding devices. The inventive process and lance suitable for such process provides, without structural conversion and by a simple design, various different process steps in the treatment of metal melts in a metallurgical vessel while increasing the insertion rates of the individual media. This is accomplished using a multifunctional lance in which the process of blowing oxygen with and without solids, and the generation of a burner flame may be performed independently from one another. The individual supply lines are connected in a corresponding manner depending on the respective process step. In the process for blowing oxygen-containing gas, vibrations are excited in the gas flow in a relatively simple manner.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: August 3, 1999
    Assignee: Mannesmann Aktiengesellschaft
    Inventors: Horst-Dieter Schoeler, Ulrich Meyer, Anatoly Sizov
  • Patent number: 5417740
    Abstract: A method of steelmaking in an at least partially refractory lined furnace. The process includes the steps of retaining a portion of a hot liquid slag from a previous heat, and altering the retained slag with basic slag forming material to increase its basicity, melting temperature, and viscosity, and to reduce its melting temperature below the melting point. The altering step is performed before charging ferrous materials for a new heat. Altered slag is then positioned on the bottom of the furnace, or on the furnace walls, or both, using a slag coating technique. Ferrous metal is then charged, after which a second charge of basic slag forming materials may be added prior to and/or during the first controllable oxygen blow. A slagging off step is conducted after less than one-half of the oxygen is introduced into the heat and when the mass of oxygen already introduced is sufficient to oxidize approximately all of the silicon introduced with hot liquid metal charged into the furnace.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: May 23, 1995
    Assignee: ZapTech Corporation
    Inventors: Grigori Galperin, Anatoli Boutchenkov, Gregory M. Gitman, Rafik Aizatulov
  • Patent number: 5084093
    Abstract: A method for manufacturing molten pig iron is disclosed which comprises:forming a packed bed of coke in a vertical furnace having a charging port in an upper portion thereof for charging raw materials and discharging gases, one or more primary tuyeres in its lower portion, and one or more secondary tuyeres in a wall of the furnace at a level above the primary tuyere, the packed bed of coke extending higher than the level of the primary tuyere;forming a packed bed of scrap and iron ore atop the packed bed of coke to a level which extends above the secondary tuyere; andblowing an oxidizing gas through the primary tuyere and the secondary tuyere to melt and reduce the scrap iron and iron ore.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: January 28, 1992
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Hideyuki Yamaoka, Takaiku Yamamoto, Hiroaki Ishida, Hiroyuki Ikemiya
  • Patent number: 5049185
    Abstract: The disclosure relates to a method for supplying, with a lance (11), a liquid to a heat treatment oven, the liquid being vaporized by the oven heat and being introduced into the oven with the aid of a carrier gas, and a lance (11) for carrying the method into effect.According to the method, the liquid is, with a carrier gas, atomized in an end of the lance (11) facing away from the interior of the oven, the atomized liquid and the carrier gas being supplied to a vaporization chamber (12) with an outlet aperture (14) directed towards the interior of the oven, in which chamber (12) the atomized liquid is vaporized by the oven heat during simultaneous cooling of the chamber (12), and the thus formed vapor and carrier gas are caused to depart from the vaporization chamber (12) of the lance (11) through the aperture designed as a nozzle (22).
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: September 17, 1991
    Assignee: AGA Aktiebolag
    Inventor: Rolf Andersson
  • Patent number: 4957546
    Abstract: The present invention relates to a new steelmaking process and apparatus which operates on an intermittent basis where several cycles composed of reducing and oxidizing periods are performed to create sufficient energy for melting of solid metallic charge, i.e., sponge iron, scrap, iron ore. During the reducing period, oxygen and carbonaceous material are injected through the vessel bottom thus attaining both carburization of a steam of the melt and generation of CO+H.sub.2 rich gas, and when the dissolved carbon of the melt is in the range of 3%-4%, conditions are then changed to the oxidizing period where solid metallic charge is added initially while oxygen injection is maintained, and until the solid charge has been melted, thus generating a stream of CO+CO.sub.2 gas rich in CO. In addition, other fluids and solids participate in the process, i.e., nitrogen, hydrocarbons, fluxes, and are used according to the appropriate period of the process.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: September 18, 1990
    Assignee: Instituto Mexicano de Investigaciones Siderurgicas
    Inventor: Arturo Lazcano-Navarro
  • Patent number: 4919714
    Abstract: Disclosed are an improved method of refining steel and an apparatus for practicing the method.The refining method comprises, basically, carrying out the refining, particularly, decarburization, while stirring molten steel in the refining furnace by injecting gas thereinto, while supplying heat with a burner installed at the top of the furnace to the molten steel. According to this method, it is possible to start at an initial carbon content of the moltend steel lower than that of known AOD process, and complete the refining in a curtailed period of time and with a decreased oxidation loss of Cr. Thus, damage of refractory materials of the furnace is reduced, and the amount of Si necessary for reducing Cr-oxides in the latter stage of the refining is also reduced.Oxygen for the decarburization is supplied usually in the form of gas, but can be supplied from a solid oxygen source.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: April 24, 1990
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventors: Saburo Sugiura, Senji Fujita, Hiroya Nakata, Tetsuo Okamoto, Yoshio Inagaki, Keiichi Mizuguchi, Atsushi Ishii