Abstract: Methods for fabricating triazene-based graphitic carbon nitride films are provided. A substrate can be coated with silk fibroin, submerged in the central zone of plasma, and provided with microwave power. The substrate can then be dried to give a triazene-based graphitic carbon nitride film. Methods of the subject invention can be easily scaled up to industrial levels and produce triazene-based graphitic carbon nitride films that show excellent electrical properties as anodes in lithium-ion batteries.

Abstract: The present invention relates to methods of making articles, and systems for providing wool articles having self-cleaning properties. The self-cleaning properties are brought about coating the wool articles with a photocatalyst formulation. The formulation contains titanium compounds, stabilizers, catalysts, and water.

Abstract: A polymerizable composition that comprises a first component comprising a (meth)acrylate and an organic peroxide as an oxidizing agent and a second component comprising a (meth)acrylate and a cysteine as a reducing agent which has a partial structure represented by the following structural formula, the first component and/or the second component further comprising a polymerization promoter:

Abstract: A process obtains an aged or faded effect on garments made of protein fibers such as wool, cashmere and silk. Granules of inert materials, which are particularly light in order not to damage very fine fibers, are introduced into a tumbler. The garments were previously treated with a chemical product commonly referred to as “dye retardant” for inhibiting dyeing of the fabric. The tumbler is pre-arranged so that the chemical product does not migrate through holes or openings. Raw confectioned garments that are to be treated, such as jerseys or outerwear, are introduced into the tumbler. The garments are extracted from the tumbler at the end of migration of the chemical product for inhibiting dyeing of the outer surface of the garments by the granules and steamed in an autoclave to fix the chemical process of the product for inhibiting dyeing of the outer surface of the garments. The garments are then dyed with a specific selection of dyes that must be defined each time according to the desired result.

Abstract: Described are compositions and methods relating to the treatment of keratinous fibers and textiles comprising such fibers with enzymatically-generated peracids in aqueous media. The treatment has beneficial effects, including reducing felting, increasing dye uptake, and reducing prickling tendency.

Abstract: Disclosed is a method for producing a modified animal fiber, the method includes step 1 (31, 32) of pre-oxidizing a cystine bond (—S—S— bond) present in an epidermal cell of an animal fiber to bring the cystine bond into a low oxidation state, step 2 (33) of oxidizing with ozone the pre-oxidized —S—S— bond to bring the —S—S— bond into at least one high oxidation state selected from di-, tri-, and tetra-oxidation states, and step 3 (34) of reductively cleaving the —S—S— bond in a high oxidation state. The method imparts shrink resistance and pilling resistance to an animal fiber. In the step 2 (33) ozone is microdispersed in an aqueous solution comprising an anionic surfactant having a C8-24 alkyl group, and the animal fiber is contacted with the ozone.

Abstract: The present invention relates to a method of treating fabric conditioner for washable silk products, which can provide smoothness to silk products since fabric conditioners of different kinds are mixed and treated together and decrease whiteness or prevent yellowing.

Abstract: Useful materials are produced from keratin containing raw materials by a process that includes gentle lanthionization of cystine disulfide bonds. Hydratable materials are produced for use in medical and cosmetic applications.

Abstract: Disclosed is a method for producing a modified animal fiber, the method includes step 1 (31, 32) of pre-oxidizing a cystine bond (—S—S— bond) present in an epidermal cell of an animal fiber to bring the cystine bond into a low oxidation state, step 2 (33) of oxidizing with ozone the pre-oxidized —S—S— bond to bring the —S—S— bond into at least one high oxidation state selected from di-, tri-, and tetra-oxidation states, and step 3 (34) of reductively cleaving the —S—S— bond in a high oxidation state. The method imparts shrink resistance and pilling resistance to an animal fiber. In the step 2 (33) ozone is microdispersed in an aqueous solution comprising an anionic surfactant having a C8-24 alkyl group, and the animal fiber is contacted with the ozone.

Abstract: The present invention relates a method of making a coated cellulosic textile, whereby a silk peptide is polymerized with a building block to develop a silk peptide/building block nanoparticle, said nanoparticle then being used to coat the textile. The resultant textile exhibits a high level of wrinkle recovery angle and/or tear strength, all without the use of N-methylol compounds, including ureas and formaldehydes.

Abstract: An article is provided that includes a polymeric fiber that has an excess number of surface active reactive moieties relative to the number of surface reactive moieties found on the fiber in a native state. A particle is bonded covalently to the fiber through an intermediate coupling agent. Multiple particles can be covalently bonded to the fiber, the multiple particles can be bonded uniformly or asymmetrically around the fiber diameter. A process for modifying a fiber includes creating surface activated reactive moieties thereon. The activated fiber is then exposed to a liquid solution containing a coupling agent to form a covalent bond. The coupling agent is also reacted with a particle in a liquid solution to form a covalent bond between the coupling agent and the particle. The coupling agent is covalently bonded to either a particle and then bonded to the fiber, or vice versa.

Abstract: A process for pretreatment of wool, silk or blends thereof rendering it receptive for the subsequent step of indigo dyeing. The pretreatment steps comprise in the step of cationization for imparting cationic charge and generating other dye combining sites.

Abstract: Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates.

Abstract: A method of treating a wool material, the method comprising the steps of: (a) contacting the wool material with a cationic surfactant; and (b) contacting the wool material with a nucleophile.

Abstract: A polymer adapted for the Shrink resist treatment of textile materials imparting water, stain and/or oil repellency. The polymer includes a fluorinated polyether.

Abstract: The present invention relates to a specific process in which wool is initially subjected to a plasma treatment and then to a wet chemical treatment with a finishing agent, which provides nonfelting wool in a technically simple and easily handleable manner.

Abstract: Methods of improving shrink-resistance of natural fibers (e.g., wool, wool fibers, animal hair, cotton), synthetic fibers (e.g., acetate, nylon, polyester, viscose rayon), or blends thereof (e.g., wool/cotton blends), or fabrics or yarns composed of natural fibers, synthetic fibers, or blends thereof, involving contacting the fibers (or fabric or yarn) with NaOH, H2O2, gluconic acid, dicyandiamide, and non-ionic surfactant (e.g., Triton X surfactant such as Triton X-100 and preferably Triton X-114), and optionally subsequently contacting the fibers (or fabric or yarn) with protease and non-ionic surfactant and optionally sodium sulfite and optionally triethanolamine and optionally polyacrylamide polymer. The methods do not utilize dichloroisocyanuric acid, chloroamines, peroxymonosulfuric acid, monoperoxyphthalic acid, permanganate, chlorine gas, sodium hypochlorite, or aminoplast resins.

Abstract: The present invention provides an animal fibers having improved shrink proofing and pilling resistance properties and method for preparation thereof. An animal fiber having excellent shrink proofing and pilling resistance and retaining its original water repellency is also provided. A method of treating animal fiber in which a surface layer part of animal fiber is primary-oxidized in advance with an oxidizer, and aqueous treatment liquid containing ozone in the form of ultrafine bubbles of 5? or less is allowed to collide against the fiber by blowing the liquid on the fiber in the aqueous treatment solution, and then, the fiber is treated with a reducing agent. Particularly, the above-mentioned method for treating animal fiber in which ultrafine bubbles of ozone are formed by using a line mixer. The method in which an apparatus which collects the ultrafine ozone bubbles in aqueous treatment liquid on the fiber is used so that the bubbles are not scattered out of a treatment reaction bowl.

Abstract: The present invention provides durable and regenerable antimicrobial fibers and methods for preparing the same. These fibers have excellent colorfastness and washfastness, and are environmentally friendly. The antimicrobial fibers of this invention are suitable for a variety of purposes, including medical uses, sportswear, and uniforms.

Abstract: A process for treating a textile fabric to impart or enhance at least one property of the fabric comprising: introducing the fabric into an aqueous formaldehyde containing solution to provide a wet pickup of an effective amount of the solution by the fabric, applying to the fabric an effective amount of a catalyst for catalyzing a reaction between formaldehyde and the fabric; thereafter exposing the wet fabric to a temperature of at least about 300° F. to react the formaldehyde with the fabric to impart or enhance the property of the fabric before there is a substantial loss of formaldehyde from the exposed fabric.

Abstract: A slenderized crimped animal fiber with a fixed slenderized form having a lowering rate of tensile strength for undyed spun yarn of no less than 10%, fiber contraction in boiling water of no more than 1%, an alkali solubility of no more than 22% by weight and a UB solubility of no more than 35% by weight, wherein the slenderized crimped animal fiber is prepared by being drawn by practically 1.20 to 1.60 times after an anisotropic swelling is given to the animal fiber consisting of bilateral structure using swelling plasticization with base.

Abstract: The present invention provides a fiber product-treating agent which can impart an excellent wrinkle-resistant effect and an excellent durable press effect to the fiber product capable of being heated and being hardly effected with not only during wearing but also after washing. That is, the present invention provides the treating agent for imparting the durable press configuration on a fiber product by a heating treatment with e.g. an iron, which comprises a specific amount of (i) two or more compounds forming mutually a crosslinked structure by heating and/or (ii) a compound forming a self-crosslinked structure by heating, and water, wherein the content of a nonvolatile matter is 0.01 to 30%.

Abstract: The present invention relates to a specific process in which wool is initially subjected to a plasma treatment and then to a wet chemical treatment with a finishing agent, which provides nonfelting wool in a technically simple and easily handleable manner.

Abstract: A wool or the like fiber scour including at least one of the following, (a) scouring process wherein the fiber is subjected to an acid extraction process to remove absorbed iron, and by to greatly improve the brightness (Y tristimulus value) of the wool; (b) a scouring process wherein a bleaching process is carried out part way through the wet process following by dying, rewriting and chemical reduction, therefore stabilising the bleached color to prevent subsequent reversion in the dyebath; or (c) a scouring process wherein scoured clean fiber is dried and dusted, and then reimmersed in liquors containing detergents and dispersants, thereby effectively removing extra amounts of residual dirt. The scour produces an improved quality of fibres.

Abstract: Novel perfluoroalkyl-substituted mono-, di- and poly-amide compounds which are reaction products of a mono-, di- or polyamine of 60 to 2000 molecular weight with a perfluoroalkyl substituted unsaturated acid or its corresponding lower alkyl ester and optionally a non-fluorinated amino-reactive compound such as an acid, ester, anhydride, epichlorohydrin, isocyanate or urea, are useful as internally or externally applied paper sizes to impart oil and grease resistance to paper, and as oil proofing coatings on textiles, wood, masonry and the like, or as high-performance surface active agents.

Abstract: The invention relates to a method for printing fibrous textile materials using the ink-jet printing technique, wherein the fibrous materials are printed with an aqueous ink that comprises at least one acid dye according to claim 1 and that has a viscosity of from 1 to 40 mPa·s.

Abstract: A durable press process for rayon fiber-containing fabrics comprising treating a rayon fiber-containing fabric with an aqueous mixture containing a high concentration of formaldehyde, and a catalyst capable of catalyzing the crosslinking reaction between formaldehyde and the rayon, wherein the concentration of the formaldehyde is sufficient to produce a durable press fabric without substantially shrinkage of the treated fabric, followed by heat curing the treated fabric to produce a durable press rayon fabric without substantial shrinkage.

Abstract: The present invention relates to a specific process in which wool is initially subjected to a plasma treatment and then to a wet chemical treatment with a finishing agent, which provides nonfelting wool in a technically simple and easily handleable manner.

Abstract: A process and apparatus for the treatment of hides and skins (3). The hide or skin is placed on a support (1, 2) and sealed to the support around the edges of the skin or hide. A treatment liquor is then supplied under pressure between the skin or hide and the support to distend and stretch the skin or hide to permit the more rapid penetration of the treatment liquor into the skin or hide.

Abstract: A process for treating a textile fabric to impart or enhance at least one property of the fabric comprising: introducing the fabric into an aqueous formaldehyde containing solution to provide a wet pickup of an effective amount of the solution by the fabric, applying to the fabric an effective amount of a catalyst for catalyzing a reaction between formaldehyde and the fabric; thereafter exposing the wet fabric to a temperature of at least about 300° F. to react the formaldehyde with the fabric to impart or enhance the property of the fabric before there is a substantial loss of formaldehyde from the exposed fabric.

Abstract: There is provided a process for manufacturing woven or knitted fabrics comprising modifying the woven or knitted fabrics by applying a skeleton triazine cross-linking reaction using a sericin fixing method of raw silk to enhance its shrink and crease resistance and shape stability and thereafter removing the sericin using a special scouring. The process for manufacturing a woven or knitted fabric, comprises the steps of finishing and treating raw silk and/or cellulose fibers by using a silk sericin fixing method; doubling and twisting thus finished/treated raw silk and/or cellulose fibers; weaving or knitting the doubled and twisted yarns; swelling the woven or knitted fabric forming a cloth by dipping it in a bath; and, scouring the woven or knitted fabric swelled in the bath with an enzyme whereby the woven or knitted fabric is provided with shrink and crease resistance and shape stability.

Abstract: The present invention relates to methods of producing wool or animal hair material with improved properties such as shrink-proofed (anti-felting tendency), increased whiteness, improved dyeability, increased softness and/or reduced pilling tendency, the method comprising the steps of treating wool, wool fibers or animal hair material in a process selected from the group consisting of plasma treatment processes and the Delhey process, and subjecting the wool or animal hair material to a treatment with a proteolytic enzyme (a protease), preferably a serine protease, more preferably a subtilisin, in an amount effective for improving the properties.

Abstract: The present invention relates to methods of producing wool or animal hair material with improved properties such as shrink-proofed (anti-felting tendency), increased whiteness, improved dyeability, increased softness and/or reduced pilling tendency, the method comprising the steps of treating wool, wool fibres or animal hair material in a process selected from the group consisting of plasma treatment processes and the Delhey process, and subjecting the wool or animal hair material to a treatment with a proteolytic enzyme (a protease), preferably a serine protease, more preferably a subtilisin, in an amount effective for improving the properties.

Abstract: The invention relates to the antifelt finishing of wool in which the wool is (a) first exposed to a plasma in a corona treatment and (b) subsequently treated with an aqueous dispersion of self-dispersing isocyanates.

Abstract: Modified silk processed according to an embodiment of the present invention is an all-natural stretchable silk textile processed without synthetics. The modified silk includes commercially-advantageous physical properties such as stretchability and it is machine washable, wrinkle resistant, stain resistant, and water proof/repellant, which render the silk very versatile and wearable. The process comprises collecting silk, boiling the silk in a water and vinegar solution, whereupon the silk becomes stretchable or elastic. The silk may then be soaked in water and vinegar to add a wrinkle resistant effect. The silk is then fabricated into a silk textile for example in a cross weave configuration, adding an elastic quality without synthetics. The finished product may then be soaked in lemon grass and water to make it stain resistant.