Abstract: An adsorption-desorption apparatus, for storage and dispensing of a sorbable gas, wherein a carbon physical sorbent medium bearing the adsorbed gas to be selectively dispensed is delivered by pressure differential desorption and/or thermal desorption of the sorbate gas from the sorbent material. The carbon sorbent material preferably comprises a material which is characterized by a Sorbent Working Capacity, measured for arsine at 40 Torr and at 650 Torr, of at least 100 grams arsine per liter of bed of the sorbent material, e.g., a carbon sorbent material having the adsorption isotherm characteristic of curve A in FIG. 1 herein.

Abstract: A regenerative desiccant air dryer system. Dry air is alternately drawn from approximately the center of two desiccant housings which are open at the top and bottom. A reclamation assembly directs dry air into the housing being purged to assist in the purging of moisture from the desiccant, and subsequently cooling the desiccant. The system is portable and operated by a programmable controller.

Abstract: A process for the separation of solutes dissolved in a gaseous solvent. The process may be used to extract and recover solutes from solvents in either the supercritical or subcritical region. The process can be used to purify solvents containing solutes by removing solutes whose chemical potential decreases as the density of the solvent increases. The process utilizes a sorbent to remove the solute followed by an in situ regeneration of the sorbent and recovery of the solute. Typically, a gaseous solvent containing at least one solute is passed through a bed of sorbent to sorb at least one of the solutes to the bed of sorbent, producing a purified gaseous solvent. At least a portion of the gaseous solvent is then acted upon to increase its solvent capacity for the at least one sorbed solute.

Abstract: A system for recovery of adsorbed gas remaining in a used storage and dispensing vessel containing sorbent material having residual sorbate gas thereon, when the vessel is taken out of service, in which the used storage and dispensing vessel is coupled in flow communication with at least one fresh storage and dispensing vessel containing sorbent material therein having sorptive capacity for the residual sorbate gas. The fresh vessel is maintained in a first zone and the used vessel is maintained in a second zone, at temperature and/or pressure conditions relative to one another that cause the residual sorbate gas to desorb from the sorbent material in the used storage and dispensing vessel and flow into the fresh storage and dispensing vessel for sorption of the residual sorbate gas on the sorbent material in the fresh storage and dispensing vessel.

Abstract: A method for the collection and subsequent regeneration of substances exhausted through a vacuum pump. In a first phase, an exhaust stream from the pump to an adsorption bed in which one or more components of the stream are adsorbed. In a second phase, adsorbed component(s) are regenerated from the bed by connecting the bed to the inlet side of the vacuum pump.

Abstract: Method and apparatus for separating gases, especially for removing water or from a gas such as air. This invention uses a short-cycle process which produces reduction in dewpoint (for dehydrating gas separation processes) or change in gas concentration (for non-dehydrating gas separation processes) at high pressure, and which includes adding a short burst of heat during the beginning of the reactivation cycle to boost desorption and complete it typically in about thirty minutes or less time. An easily desorbed desiccant (or other adsorbent material for non-dehydrating applications) and the short low-temperature burst of heat serve to reactivate a significant portion of the desiccant bed (or adsorbent bed), and the cooler purge fluid that follows cools that portion of the bed in preparation for the next drying (or adsorbing) cycle.

Abstract: A method for the removal from a feed gas stream such as air of at least two contaminating gas components such as water and CO.sub.2 features repeated cycles of operation the improvement which comprise: feeding a regenerating gas such as dry nitrogen at a higher temperature, e.g. 70.degree. C., in a direction counter-current to the feed direction in contact with the adsorbent to produce a heat pulse travelling in the counter-current direction to desorb the less strongly adsorbed second contaminating gas component from the downstream (with respect to the feed direction) portion of the adsorbent by TSA while at the same time desorbing the more strongly adsorbed second contaminating gas component from the upstream (with respect to the feed direction) portion of the adsorbent by PSA.

Abstract: A process is described for the separation of solutes dissolved in a gaseous solvent. The process is useful in the extraction and recovery of solutes using supercritical fluid extraction, and in the purification of impure steam. The process utilizes a sorbent to remove solute followed by an in situ regeneration of the sorbent and the recovery of the solute.

Abstract: An adsorption process in which high and low pressure feed streams are introduced into a plurality of beds to produce product streams by adsorbing one or more preferentially adsorbed components within the beds. Each bed is subjected to a low pressure feed stage to produce a low pressure product stream followed by a high or higher pressure feeding stages to produce one or more high pressure product streams. Thereafter the beds are regenerated through depressurization and purge stages. The cycle is conducted out of phase so that one of the beds is producing the high pressure product stream while another bed is producing a low pressure product stream.

Abstract: An air separation method in which a pre-purification unit is provided with three or more beds which are subjected to a pressure swing adsorption process. Each of the beds is subjected to feed, pressurization, purge and repressurization stages. The purge stages are conducted with a waste stream from the air separation unit and the duration of the purge stage is equal to the total time of the cycle divided by the number of beds.

Abstract: Apparatus and a process for producing nitrogen or air containing not more than 0.5 ppm by volume of carbon monoxide. A nitrogen stream or air stream containing up to about 100 ppm by volume of carbon monoxide is subjected to cryogenic temperature swing adsorption in an adsorption bed containing calcium-exchanged type X zeolite, type 5A zeolite or 13X zeolite, which removes substantially all of the carbon monoxide from the nitrogen stream or air stream.

Abstract: A process and apparatus for the selective recovery of solvents from solvent gas mixtures according to which the solvent gas mixture undergoes a sorption process, individual solvent gas fractions are fractionally desorbed from the sorption agent, condensed at staggered time intervals, measured to determine their composition, and collected separately.

Abstract: 16-membered macrolide derivatives represented by the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a COR.sup.6 group, wherein R.sup.6 represents a straight-chain alkyl group having 1 to 3 carbon atoms; R.sup.2 represents a hydrogen atom or a COR.sup.6 group, wherein R.sup.6 is as defined above; R.sup.3 represents a hydrogen atom or a COR.sup.6 group, wherein R.sup.6 is as defined above; R.sup.4 represents a straight-chain alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted allyl group; and R.sup.5 represents a substituted or unsubstituted, straight-chain or branched alkyl, alkenyl or aralkyl group having 1 to 10 carbon atoms;and pharmaceutically acceptable salts thereof are disclosed. These compounds show excellent and long-acting antimicrobial activities. A novel process for producing these 16-membered macrolide derivatives is further disclosed.

Abstract: A process claimed for the removal of VOCs from fluid streams. The process comprises a vacuum swing adsorption zone containing at least 2 adsorption beds wherein the adsorbent beds are cocurrently purged with a diluent stream comprising an inert gas prior to a countercurrent evacuation step. In addition, the adsorbent beds may contain a first adsorption layer comprising an adsorbent selective for the adsorption of the inert gas, whereby the inert gas is retained within the VSA system to prevent the creation of an explosive mixture upon the recovery of the desorbed VOCs.

Abstract: A process is described for the separation of solutes dissolved in a gaseous solvent. The process is useful in the extraction and recovery of solutes using supercritical fluid extraction, and in the purification of impure steam. The process utilizes a sorbent to remove solute followed by an in situ regeneration of the sorbent and the recovery of the solute.

Abstract: Waste heat generated within a pressure swing adsorption system is effectively captured and utilized to preheat the feed gas passing to a feed gas blower for compression to the desired adsorption pressure level. The energy efficiency of the system, and overall system performance, are thereby enhanced.

Abstract: A system for controlling the atmosphere of a container for use in the storage and/or transportation of perishable goods which includes adsorption apparatus for the selective adsorption in whole or in part and in a predeterminded order of any water vapor, carbon dioxide, oxygen or ethylene contained within the atmosphere, a blower for urging the atmosphere to the adsorption apparatus, and a conduiting for returning the controlled atmosphere to the container.

Abstract: Apparatus and a process for producing high purity oxygen containing not more than 1 ppm by volume of hydrocarbons. An oxygen stream containing up to about 100 ppm by volume of hydrocarbons is subjected to cryogenic temperature swing adsorption in an adsorption bed containing calcium-exchanged type X zeolite, type 5A zeolite or 13X zeolite, for the removal of the hydrocarbons and any nitrogen present in the oxygen stream.

Abstract: In a regenerable collective protection system the turbine of an air cycle machine is driven by a potion of the clean air output of a pressure swing adsorber bed pair in the system. The beds in the pair are used alternately to cleanse contaminated air. They are then alternately purged of contaminant products. Valves are used to direct these alternate operations. The valve closures cause overpressures in the clean air output. The overpressures are predictable in relation to the valve actuation sequence and are removed by coordinating operation of a surge air bleed valve in the clean air output with valve actuation in the pressure swing adsorber bed pair.

Abstract: Crystalline molecular sieves containing octahedral sites such as the sieves known as ETS-4, ETS-10 and ETAS-10 are used to remove volatile organic compounds from a mixture of the same with moist air at ambient temperature.

Abstract: A method and an apparatus for separating a specific component gas from a mixed gas, wherein granular adsorbent is held in a sealed space in a layered state, easily adsorptive gas is adsorbed to the granular adsorbent by blowing material mixed gas into the adsorbent layers and contacting the granular adsorbent with a counter-current of material gas, and the granular adsorbent is transferred gradually out of the sealed space, and reactivated by desorbing the easily adsorptive gas from the granular adsorbent, and the reactivated granular adsorbent is returned to the inside of the sealed space to be reused. Therefore, frequent actions of opening and closing valves are unnecessary, so that it is possible to separate and produce excellent product gas with high purity.

Abstract: A process for removal of contaminants from a fluid stream comprising adsorbing the contaminants with an adsorbent, contacting the resulting contaminant-laden adsorbent with a heated fluid, incinerating a portion of the contaminant-laden fluid, mixing at least a portion of the products of combustion with the remaining portion of contaminant-laden fluid, recirculating the mixture of contaminant-laden fluid and combustion products through the adsorbent to increase the concentration of contaminants in the mixture, and incinerating at least a portion of the recirculated mixture.

Abstract: A gas separation process and a unit therefor. The process comprises the steps of: introducing a gas consisting of two or more components into an adsorption system in which adsorbent particles circulate in a fluidized state, thereby to allow, at atmospheric pressure or an elevated pressure, the adsorbent particles to adsorb a gas component to be separated from the gas; transferring the adsorbent particles adsorbing the gas component to a desorption system; and then desorbing the gas component from the adsorbent particles in the desorption system which is regulated to have either a lower pressure or a lower pressure and a higher temperature than the adsorption system.

Abstract: A pressure swing and temperature swing adsorption system is disclosed which continuously purges contaminants such as nuclear, biological and chemical warfare agents from intake air and provides cool clean air to the crew compartment of a vehicle by progressively directing contaminated air through a first adsorption bed to clean the air, while simultaneously directing hot exhaust gases at about 600.degree. F. through a second adsorption bed for purging contaminants therefrom, while simultaneously cooling a third adsorption bed for enhancing adsorption of contaminants in the purging bed upon repeating the cycles of operation.

Abstract: Improved process for separating ethylsilane from silane by selective adsorption onto an effectively treated carbon bed and method of treatment of such carbon bed to enhance the selective adsorption of ethylsilane.

Abstract: A method and system for treating liquid chlorine to remove inert gases therefrom. Liquid chlorine is treated by passing it through a molecular sieve having a molecular pore diameter greater than the molecular diameter of the inert gases and smaller than the molecular diameter of chlorine so that the inert gases are adsorbed by the sieve while the liquid chlorine passes therethrough. The sieve may be regenerated by heating the sieve and evacuating by vacuum, followed by a purging with a gas and then a further vacuum evacuation.