Oxygen Or Ozone Sorbed Patents (Class 95/138)
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Patent number: 7294172Abstract: A gas recovery system comprising a source of gas having a preselected concentration of a desired component (9), at least one application (1) that adds impurities to said gas, and at least one an adsorption system (6) that purifies said gas to produce a purified gas for re-use in application (1), wherein said at least one adsorption system includes at least one adsorbent bed (A) having at least three layers of adsorbents. A recovery process is also disclosed.Type: GrantFiled: July 31, 2002Date of Patent: November 13, 2007Assignee: Praxair Technology, Inc.Inventors: Mohamed Safdar Allie Baksh, Scot Eric Jaynes, Bernard Thomas Neu, James Smolarek, Mark Thomas Emley
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Patent number: 7172645Abstract: An apparatus for separating a first gas from a mixture of the first gas and at least one second gas comprises a housing having an inlet port and an outlet port and an adsorbent which is positioned in the housing. The adsorbent comprising a carbon based foam monolith that has an affinity for the first gas. Thus, as the gas mixture flows through the housing, the first gas will be adsorbed onto the adsorbent and the second gas will exit the housing through the outlet port. In this manner, the first gas is separated from the second gas.Type: GrantFiled: June 30, 2003Date of Patent: February 6, 2007Assignee: Sun Microsystems, Inc.Inventors: Dennis M. Pfister, Charles M. Byrd
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Patent number: 7169212Abstract: This invention relates to gas separation processes using a Li-rho zeolite, in particular to an air separation process where the Li-rho zeolite is an oxygen selective adsorbent.Type: GrantFiled: August 18, 2000Date of Patent: January 30, 2007Assignee: E. I. du Pont de Nemours and CompanyInventor: David Richard Corbin
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Patent number: 7160360Abstract: Purification material for removing a contaminant from an impure hydride gas comprising an adsorbent comprising a reduced metal oxide on a porous support and a desiccant. The porous support may be selected from the group consisting of activated carbon, alumina, silica, zeolite, silica alumina, titania, zirconia, and combinations thereof. The reduced metal oxide may comprise one or more metals selected from the group consisting of Group I alkali metals (lithium, sodium, potassium, rubidium, and cesium), Group II alkaline earth metals (magnesium, calcium, strontium, and barium), and transition metals (manganese, nickel, zinc, iron, molybdenum, tungsten, titanium, vanadium, cobalt, and rhodium). The desiccant may be selected from the group consisting of hygroscopic metal salts, zeolites, single metal oxides, mixed metal oxides, and combinations thereof.Type: GrantFiled: December 8, 2003Date of Patent: January 9, 2007Assignee: Air Products and Chemicals, Inc.Inventors: Dingjun Wu, Timothy Christopher Golden, Chun Christine Dong, Paula Jean Battavio
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Patent number: 7101415Abstract: A continuous method of producing a process fluid gas from a feed stream that includes the process fluid and impurities. The method includes: (a) providing a first and second vessel, each vessel containing one or more regenerable purifier materials for removing at least one of the impurities from the feed stream; (b) removing at least one of the impurities by passing the feed stream through one or the other of the vessels to provide a purified process fluid gas, with the vessel being maintained at a first temperature during the removal of impurities; and (c) regenerating the purifier materials in the vessels at a second temperature and during the time when it is not purifying the feed stream by flowing a portion of the purified process fluid or the feed stream or a separate source of the process fluid gas therethrough.Type: GrantFiled: August 28, 2003Date of Patent: September 5, 2006Assignee: Matheson Tri-Gas, Inc.Inventors: Robert Torres, Jr., Joseph Vivinski, David Lawrence
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Patent number: 6997970Abstract: A gas generation method and apparatus, capable of use in an aircraft, generates oxygen with at least one On Board Oxygen Generating System (OBOGS) and generates an inert gas with at least one On Board Inert Gas Generating System (OBIGGS) and selectively supplies an auxiliary supply of inert gas utilizing a waste gas output of the at least one OBOGS. The inert gas can include nitrogen. An auxiliary source of oxygen can also be provided. Control valves can be used to selectively supply the waste gas output of the at least one OBOGS to the atmosphere or to either of two locations. The oxygen can be used in a passenger compartment of the aircraft and the inert gas used in either a fuel tank or cargo bay of the aircraft.Type: GrantFiled: June 19, 2003Date of Patent: February 14, 2006Assignee: Carleton Life Support Systems, Inc.Inventor: Victor P. Crome
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Patent number: 6989044Abstract: A process and composition for selectively adsorbing oxygen from a gaseous mixture. The chemisorption is carried out by a porous three-dimensional transition element complex comprised of intermolecularly bound TEC units, said units further comprised of at least one multidentate ligand forming at least one five- or six-membered chelate ring on each unit.Type: GrantFiled: November 30, 2000Date of Patent: January 24, 2006Assignee: Praxair Technology, Inc.Inventors: Delong Zhang, Neil Andrew Stephenson
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Patent number: 6955711Abstract: Component contained in a gas mixture can be separated based on a PSA method and recovered with high purities at the same time, the system is simple, the system cost is low, and the operation is easy and may be used for separating oxygen and nitrogen from air or for separating noble gases and nitrogen from a gas mixture containing noble gases and nitrogen, and obtaining each gas as a product.Type: GrantFiled: March 20, 2002Date of Patent: October 18, 2005Assignee: Taiyo Nippon Sanso CorporationInventors: Masato Kawai, Akihiro Nakamura, Tatsuya Hidano
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Patent number: 6918948Abstract: A Process for the production and uses of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: GrantFiled: January 26, 2004Date of Patent: July 19, 2005Assignee: Zeochem LLCInventors: Dave Jaussaud, Kerry Weston, Armin Pfenninger, Beat Kleeb
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Patent number: 6916358Abstract: An adsorbent for separating nitrogen from a mixed gas of oxygen and nitrogen is MSC wherein an oxygen and nitrogen separation ratio ? and a ratio (t95/t50) of a time t50 required for adsorbing 50% of the oxygen equilibrium adsorption amount and a time t95 required for adsorbing 95% of the oxygen equilibrium adsorption amount satisfy the inequality (t95/t50)<0.4×(??24)??35. The amount of adsorbent used with respect to a predetermined amount of nitrogen generated can be reduced since a method is carried out which uses this adsorbent to produce nitrogen by separating nitrogen from the mixed gas of oxygen and nitrogen by means of a PSA method. By this method, it is possible to reduce the cost of the apparatus and reduce and miniaturize the scale of the apparatus, and the power consumption amount can be reduced.Type: GrantFiled: August 29, 2002Date of Patent: July 12, 2005Assignee: Taiyo Nippon Sanso CorporationInventors: Akihiro Nakamura, Masato Kawai, Masayoshi Hayashida, Yoshinori Watanabe, Shinichi Marumo
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Patent number: 6916359Abstract: Methods of providing ozone at a selected pressure above atmospheric pressure include supplying a purge gas supply (22) pressurized above the selected pressure to at least one ozone adsorption apparatus (12); desorbing ozone from the ozone adsorption apparatus (12) with the pressurized purge gas supply (22); and delivering a mixture of ozone and the purge gas supply (24) at the selected pressure without further compression.Type: GrantFiled: April 21, 2003Date of Patent: July 12, 2005Assignee: The BOC Group, Inc.Inventor: Ravi Jain
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Patent number: 6913636Abstract: An inerting system provides air with reduced oxygen content by flowing and directing air through an air separation module. Optimal working pressure for the air separation module is obtained with two compressors. A first compressor elevates air from the aircraft cabin to a second pressure. The second pressure is at an intermediate level below the working pressure of the air separation module. A second compressor elevates air from the second pressure to the working pressure. The second compressor is driven by air that is exhausted through a turbine. The pressure difference between air at the working pressure and air required by the fuel distribution system is used to power the turbine and drive the second compressor.Type: GrantFiled: December 17, 2002Date of Patent: July 5, 2005Assignee: Hamilton Sundstrand CorporationInventors: Gregory Defrancesco, Thomas Zywiak, Harold W. Hipsky
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Patent number: 6911065Abstract: A fluid purifying apparatus that includes a manifold that includes a first branch and a second branch, a first check valve coupled to the first branch of the manifold, and a purifier unit that includes a first end and a second end, wherein the first end is coupled to the second branch of the manifold. Also, a fluid purifying apparatus that includes a vessel that includes a first interior compartment for containing a purifier material and a second interior compartment for containment of a fluid containing impurities, wherein the first interior compartment is separated from the second interior compartment by a fluid permeable support, and a rupturable seal.Type: GrantFiled: December 26, 2002Date of Patent: June 28, 2005Assignee: Matheson Tri-Gas, Inc.Inventors: Tadaharu Watanabe, Robert Torres, Jr., Joseph Vininski
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Patent number: 6863713Abstract: An adsorbent composition containing a modified carbonaceous material capable of adsorbing an adsorbate is disclosed, wherein at least one organic group is attached to the carbonaceous material. Furthermore, methods to increase the adsorption capacity of a carbonaceous material capable of adsorbing an adsorbate and methods to adsorb an adsorbate using the above-described adsorbent composition are also disclosed.Type: GrantFiled: December 30, 1999Date of Patent: March 8, 2005Assignee: Cabot CorporationInventors: Ranjan Ghosal, James A. Belmont, Douglas M. Smith, Jameel Menashi
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Patent number: 6835231Abstract: In a process for the production of nitrogen by adsorption on carbons or similar molecular sieves contained in a cylinder (2), the amount of Q1 of nitrogen obtainable from the cylinder at the required purity at the cylinder pressure Pp is calculated; compressed air is fed to the cylinder which is brought to a pressure value at least equal to the pressure Pp and in any case greater than the pressure present in a collecting reservoir (3); at any cycle a fixed amount Q2 (where Q1≧Q2) of gas is transferred from the adsorber cylinder to the reservoir (3) and the cylinder is depressurised after each transfer to regenerate carbons. Also claimed are an apparatus for the production of nitrogen, the use of such an apparatus is a drink dispensing device and a drink dispensing device comprising such an apparatus.Type: GrantFiled: August 22, 2003Date of Patent: December 28, 2004Inventor: Lorenzo Cogotzi
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Publication number: 20040244585Abstract: A device for enriching air with oxygen in an aircraft, and a method for operating the device provides product gas enrichment with oxygen with minimum requirements. An oxygen measurement apparatus analyzing the product gas flow as well as a throughput sensor are provided in combination with a change-over device. A flow connection to an outlet channel is created in a first switch position, and a flow connection to a consumer conduit exists in a second switch position. A device for producing a change-over signal from the first switch position to the second switch position is provided if the determined oxygen output as a product of the product gas flow and the oxygen concentration has reached or exceeded a predefined threshold value.Type: ApplicationFiled: May 21, 2004Publication date: December 9, 2004Inventors: Rudiger Meckes, Wolfgang Rittner, Herbert Meier
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Patent number: 6824589Abstract: Regenerable gas purifier materials are provided capable of reducing the level of contaminants such as oxygen and water in an inert, nonreactive or reactive gas stream to parts-per-billion levels or sub-parts-per-billion levels. The purifier materials of this invention comprise a thin layer of one or more reduced forms of a metal oxide coated on the surface of a nonreactive substrate. The thin layer may further contain the completely reduced form of the metal.Type: GrantFiled: October 29, 2002Date of Patent: November 30, 2004Assignee: Matheson Tri-GasInventors: Tadaharu Watanabe, Dan Fraenkel, Robert Torres, Jr.
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Patent number: 6767386Abstract: CMS adsorbents having suitable indexes are used to improve greatly the performance of nitrogen-producing apparatuses where nitrogen is obtained from the air with a PSA method, so as to improve the efficiency of nitrogen production. A nitrogen PSA apparatus is formed with two adsorbing columns where an adsorption step and a regeneration step are performed alternatively and periodically. The adsorption step is for adsorbing oxygen and conducting nitrogen to a product tank with the supply of compressed air from an air compressor, and the regeneration step for releasing the adsorbed gas after the adsorption step. The adsorbing columns are filled with a carbon molecular sieve (CMS) that selectively adsorbs oxygen as an adsorbent. The CMS adsorbs an oxygen/nitrogen amount of 50% of the saturated adsorption amount with a period TO/TN starting from oxygen/nitrogen supply, wherein TO is 5˜10 seconds and TN is larger than TO by more than 41 times.Type: GrantFiled: August 14, 2002Date of Patent: July 27, 2004Assignee: Nippon Sanso CorporationInventors: Masato Kawai, Akihiro Nakamura, Masayoshi Hayashida, Yoshinori Watanabe, Shinichi Marumo
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Patent number: 6733734Abstract: Regenerable gas purifier materials are provided capable of reducing the level of contaminants such as oxygen and moisture in a hydride gas stream to parts-per-billion levels or sub-parts-per-billion levels. The purifier materials of this invention comprise a thin layer of one or more reduced forms of a metal oxide coated on the surface of a nonreactive substrate. The thin layer may further contain the completely reduced form of the metal. In one embodiment, the total surface area of the thin layer is less than 100 m2/g.Type: GrantFiled: October 31, 2001Date of Patent: May 11, 2004Assignee: Matheson Tri-GasInventors: Tadaharu Watanabe, Dan Fraenkel
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Publication number: 20040083886Abstract: A method of operating a life support system for an aircraft, the system including a plurality of oxygen supply apparatus, each of which in use is operable to supply product gas, which may be pure oxygen or oxygen enriched gas, to a breathing gas supply apparatus, at least one of the oxygen supply apparatus being a main oxygen supply apparatus and the remainder of the oxygen supply apparatus being auxiliary oxygen supply apparatus, the main oxygen supply apparatus being operable independently of the auxiliary oxygen supply apparatus, characterized in that the method includes operating the main oxygen supply apparatus and supplying product gas to each of the auxiliary oxygen supply apparatus.Type: ApplicationFiled: June 18, 2003Publication date: May 6, 2004Inventors: Robert John Phillips, Adrian Simons, Norman Francis Charles Barns
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Patent number: 6712087Abstract: The present invention relates to a rotary valve assembly for a pressure swing adsorption system. The rotary valve assembly includes a first valve member and a second valve member relatively rotatable about a common center of rotation to provide valving action for selectively transferring fluids therethrough. The second valve member has a first fluid section with at least one aperture adapted for transferring a first fluid of a first pressure and composition therethrough and a second fluid section with at least one aperture adapted for transferring a second fluid of a second pressure and composition therethrough. The first valve member has a first fluid section with at least one passage for transferring the first fluid in the valve assembly and a second fluid section with at least one passage for transferring the second fluid in the valve assembly.Type: GrantFiled: May 10, 2002Date of Patent: March 30, 2004Assignees: SeQual Technologies, Inc., Teijin LimitedInventors: Theodore B. Hill, Charles C. Hill, Adam C. Hansen
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Patent number: 6709486Abstract: A pressure swing adsorption process for recovering a less readily adsorbable component from a feed gas mixture comprising at least one less readily adsorbable component and at least one more readily adsorbable component. The process utilizes a plurality of adsorbent beds, each bed having a feed end and product end, wherein the process includes the gas transfer steps of (1) transferring gas from the product end of the bed to the product end of another bed; followed by (2) withdrawing waste depressurization gas from the feed end of the bed while continuing to transfer gas from the product end of the bed to the product end of another bed; (3) during either or both of (1) and (2), transferring gas from the feed end of the bed to the feed end or ends of the one or more other beds; and (4) prior to (1), transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure.Type: GrantFiled: April 8, 2002Date of Patent: March 23, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Sang Kook Lee, Justin David Bukowski
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Publication number: 20040040437Abstract: An oxygen concentrator system with altitude compensation includes at least one oxygen concentrator sub-system and a plenum subsystem. The at least one oxygen concentrator sub-system produces oxygen-enriched air which is outputted to both the oxygen concentrator system output and to a plenum chamber within the plenum subsystem. The plenum chamber is trickle charged with the oxygen-enriched air when the at least one oxygen concentrator sub-system produces an excess amount of oxygen-enriched air. Should the demand for oxygen-enriched air exceed the capability of the at least one oxygen concentrator sub-system, additional oxygen-enriched air is provided by the plenum chamber until such time that the capability of the at least one oxygen concentrator sub-system exceeds the demand for oxygen-enriched air. At that time, oxygen-enriched air is no longer provided by the plenum chamber, but rather the plenum chamber is again trickle charged.Type: ApplicationFiled: August 27, 2002Publication date: March 4, 2004Applicant: Litton Systems, Inc.Inventors: Tuan Q. Cao, Gary Byrd
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Publication number: 20040040439Abstract: An oxygen concentrator system includes at least one oxygen concentrator sub-system and a plenum subsystem. The at least one oxygen concentrator sub-system produces oxygen-enriched air which is outputted to both the oxygen concentrator system output and to a plenum chamber within the plenum subsystem. The plenum chamber is trickle charged with the oxygen-enriched air when the at least one oxygen concentrator sub-system produces an excess amount of oxygen-enriched air. Should the demand for oxygen-enriched air exceed the capability of the at least one oxygen concentrator sub-system, additional oxygen-enriched air is provided by the plenum chamber until such time that the capability of the at least one oxygen concentrator sub-system exceeds the demand for oxygen-enriched air. At that time, oxygen-enriched air is no longer provided by the plenum chamber but rather the plenum chamber is again trickle charged.Type: ApplicationFiled: August 27, 2002Publication date: March 4, 2004Applicant: Litton Systems, Inc.Inventors: Tuan Q. Cao, Gary Byrd, Lyle Berkenbosch, Craig Schledewitz
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Publication number: 20040011199Abstract: In a process for the production of nitrogen by adsorption on carbons or similar molecular sieves contained in a cylinder (2), the amount of Q1 of nitrogen obtainable from the cylinder at the required purity at the cylinder pressure Pp is calculated; compressed air is fed to the cylinder which is brought to a pressure value at least equal to the pressure Pp and in any case greater than the pressure present in a collecting reservoir (3); at any cycle a fixed amount Q2 (where Q1≧Q2) of gas is transferred from the adsorber cylinder to the reservoir (3) and the cylinder is depressurised after each transfer to regenerate carbons. Also claimed are an apparatus for the production of nitrogen, the use of such an apparatus is a drink dispensing device and a drink dispensing device comprising such an apparatus.Type: ApplicationFiled: August 22, 2003Publication date: January 22, 2004Inventor: Lorenzo Cogotzi
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Patent number: 6660064Abstract: A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and the apparatus are substantially free of zeolite adsorbents; feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.Type: GrantFiled: March 8, 2002Date of Patent: December 9, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Timothy Christopher Golden, Edward Landis Weist
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Patent number: 6652627Abstract: This invention relates to a process for separating a fluid component from a fluid mixture comprising the fluid component, the process comprising: (A) flowing the fluid mixture into a microchannel separator; the microchannel separator comprising a plurality of process microchannels containing a sorption medium, a header and a footer, the combined internal volume of the header and the footer being up to about 40% of the internal volume of the process microchannels; the fluid mixture being maintained in the microchannel separator until at least part of the fluid component is sorbed by the sorption medium; purging the microchannel separator to displace non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the fluid component from the sorption medium and flowing a flush fluid through the microchannel separator to displace the desorbed fluid component from the microchannel separator. The process is suitable for purifying oxygen as well as effecting other fluid separations.Type: GrantFiled: October 30, 2002Date of Patent: November 25, 2003Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Bruce F. Monzyk, Dongming Qiu, Matthew B. Schmidt, G. Bradley Chadwell, Wesley Bruno, Eric Burckle
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Patent number: 6638340Abstract: Applicant has developed an improved adsorbent useful in removing contaminants from various air streams. The adsorbent contains a zeolite, an alumina and a metal component. The metal component is present in an amount at least 10 mol-% of the stoichiometric amount of metal (expressed as the oxide) needed to balance the negative charge of the zeolite lattice. In a specific application an adsorbent comprising zeolite X, alumina and sodium is used to purify an air stream in order to remove water, carbon dioxide and other impurities including hydrocarbons.Type: GrantFiled: March 27, 2002Date of Patent: October 28, 2003Assignee: UOP LLCInventors: Vladislav I. Kanazirev, Donald G. Latus
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Patent number: 6607584Abstract: A formed adsorbent material includes an adsorbent solid phase and a gas phase ensuring transport of the gaseous components right to the adsorbent, being such that the constants for the transport kinetics of the components adsorbable in the gas phase and in the solid phase are in a ratio of between 0.1 and 10 defined for a gas discharge velocity of 0.2 m/s measured on air at 1 bar and 20° C. or in a ratio of between 0.1 and 10, defined for a gas discharge velocity of 0.01 m/s measured on hydrogen at 30 bar and 40° C.Type: GrantFiled: March 18, 2002Date of Patent: August 19, 2003Assignee: L'Air Liquide-Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Serge Moreau, Xavier Badiche
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Publication number: 20030145727Abstract: An ozone storage apparatus is disclosed for storing ozone efficiently. A process for efficient water treatment is also disclosed. The ozone storage container has a generally U-shape and is filled with an absorbent. The ozone is supplied and discharged from the same opening. The temperature of the absorbent is kept between 0° C. and −30° C. The generated ozone from an ozone generating means is cooled by a cooling device and is supplied to a storage device.Type: ApplicationFiled: February 10, 2003Publication date: August 7, 2003Inventor: Akira Murai
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Patent number: 6585192Abstract: 1. An inerting system for a vented controlled atmosphere container, for inerting a flammable gas comprising a flammable vapor and oxygen, comprising: (i) a container; (ii) an outlet in the container for the flammable gas; (iii) a compressor, in fluid communication with the outlet, which compresses the flammable gas from the container; (iv) a separator, in fluid communication with the compressor, for removing oxygen from the flammable gas to produce an oxygen-depleted flammable gas; (v) an inlet in the container, which is in fluid communication with the separator; through which the oxygen-depleted flammable gas is fed into the container.Type: GrantFiled: December 21, 2000Date of Patent: July 1, 2003Assignee: L'Air Liquide - Societe Anonyme A'Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Karl S. Beers
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Patent number: 6579344Abstract: The method provides technical nitrogen instead of pure nitrogen in liquid form which has to be heated to be brought in gaseous form for laser cutting. Atmospheric air is compressed and driven through a cascade of high density bundles of hollow membrane fibers to permeate oxygen and air's component gases and yield technical nitrogen, and the pressure of the technical nitrogen is boosted to feed the laser cutting equipment. The method thus improves the laser cutting so as to avoid the drawbacks resulting from use of nitrogen in liquid form obtained by the cryogenic process by using technical nitrogen obtained via the aforesaid hollow fiber membrane technology in an efficient and cost effective manner.Type: GrantFiled: January 3, 2002Date of Patent: June 17, 2003Inventor: Pierre Diserens
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Publication number: 20030097931Abstract: CMS adsorbents having suitable indexes are used to improve greatly the performance of nitrogen-producing apparatuses where nitrogen is obtained from the air with a PSA method, so as to improve the efficiency of nitrogen production. A nitrogen PSA apparatus is formed with two adsorbing columns where an adsorption step and a regeneration step are performed alternatively and periodically. The adsorption step is for adsorbing oxygen and conducting nitrogen to a product tank with the supply of compressed air from an air compressor, and the regeneration step for releasing the adsorbed gas after the adsorption step. The adsorbing columns are filled with a carbon molecular sieve (CMS) that selectively adsorbs oxygen as an adsorbent. The CMS adsorbs an oxygen/nitrogen amount of 50% of the saturated adsorption amount with a period TO/TN starting from oxygen/nitrogen supply, wherein TO is 5˜10 seconds and TN is larger than TO by more than 41 times.Type: ApplicationFiled: August 14, 2002Publication date: May 29, 2003Inventors: Masato Kawai, Akihiro Nakamura, Masayoshi Hayashida, Yoshinori Watanabe, Shinichi Marumo
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Publication number: 20030089230Abstract: An improved method for preparing monolith adsorbents and activating the adsorbents therein is disclosed. A mixture of lower temperature and higher temperature binders is used in fabricating the paper used to form the monolith structure. The finished monolith structure is heated to a temperature sufficient to remove the lower temperature binder while leaving the higher temperature binder to maintain integrity in the monolith.Type: ApplicationFiled: November 2, 2001Publication date: May 15, 2003Inventors: Ravi Jain, Sudhakar R. Jale
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Patent number: 6557459Abstract: The present invention relates to an apparatus for preserving and dispensing wine or champagne. The apparatus provides a housing having a container support for holding wine or champagne bottles, a plurality of removable stoppers for insertion in the bottles, a nitrogen generator for generating a nitrogen rich gas from air, a nitrogen storage tank for storing the generated nitrogen rich gas, a cooling system for cooling certain bottles and dispensers for providing wine or champagne from the bottles to a user. The nitrogen generator draws in ambient air, adsorbs the oxygen from the air and stores nitrogen rich gas in the nitrogen storage tank. The nitrogen storage tank supplies the nitrogen rich gas to the bottles for preserving the wine or champagne. The stoppers include a nitrogen line and a supply line. The nitrogen line communicates nitrogen rich gas into the bottles and the supply line communicates wine or champagne from the bottles to the dispensers.Type: GrantFiled: November 26, 2001Date of Patent: May 6, 2003Assignee: Vin Valet, Inc.Inventors: Johne Phelps, Daniel N. O'Connor, Justin R. Lydon
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Patent number: 6533999Abstract: Ozone generated from an ozonizer is added to a polluted gas containing harmful substances, which is generated from a polluted gas source. Then, the ozone-added polluted gas is allowed to flow through an adsorbing layer containing a high-silica adsorbent that adsorbs both ozone and harmful substances. The harmful substances contained in the polluted gas are converted into harmless substances within the adsorbing layer by the action of the ozone.Type: GrantFiled: April 1, 1999Date of Patent: March 18, 2003Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Jun Izumi, Akinori Yasutake, Nariyuki Tomonaga, Hiroyuki Tsutaya
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Patent number: 6530976Abstract: An ozone storage apparatus is disclosed for storing ozone efficiently. A process for efficient water treatment is also disclosed. The ozone storage container has a generally U-shape and is filled with an absorbent. The ozone is supplied and discharged from the same opening. The temperature of the absorbent is kept between 0° C. and −30° C. The generated ozone from an ozone generating means is cooled by a cooling device and is supplied to a storage device.Type: GrantFiled: March 1, 2001Date of Patent: March 11, 2003Assignee: The Kansai Electric Power Co., Inc.Inventor: Akira Murai
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Patent number: 6527828Abstract: A method and system for retrofitting an integrated scrubber to provide maximum oxygen content in a controlled decomposition oxidation (CDO) abatement process including a thermal/wet integrated scrubber, and a compressed air supply for supplying air to an oxygen separation device that separates the air into a nitrogen-enriched component and an oxygen-enriched component. The oxygen separation device includes a module, such as a vessel containing ceramic-materials arranged in an adsorbent bed or coated on a substrate. The present invention uses a ceramic oxide material through which only oxygen can diffuse. The composition of the ceramic oxide adsorbent material is such that a significant number of oxygen vacancies exist in the material. By placing either a voltage potential or a pressure gradient across the membrane, oxygen is selectively diffused in and through the oxide material to separate the air supply into an oxygen component for introduction into the integrated scrubber.Type: GrantFiled: March 19, 2001Date of Patent: March 4, 2003Assignee: Advanced Technology Materials, Inc.Inventors: Belynda G. Flippo, Keith Karrup, Robbert Vermeulen, Daniel O. Clark
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Patent number: 6527831Abstract: A pressure swing process and system for purifying a first gas, preferably argon, from a crude feed gas stream containing the first gas and second gas(es) utilizes two adsorption beds and continuously promotes the crude feed gas to the bed during the process and simultaneous equalization of pressure in the two beds in top-to-top end and bottom-to-bottom end equalizations in each bed following purging of each bed.Type: GrantFiled: December 29, 2000Date of Patent: March 4, 2003Assignee: Praxair Technology, Inc.Inventors: Mohamed Safdar Allie Baksh, Alan Barnard Stewart
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Patent number: 6524544Abstract: A method and apparatus for the decontamination of fluid ammonia are described. Liquid or gaseous ammonia is purified of contaminants by passage through an adsorbent bed, the contaminants accumulating in the bed. A portion of the purified ammonia discharged from the bed is decomposed to hydrogen and nitrogen. The hydrogen is used to regenerate an adsorbent bed which has accumulated sufficient contaminants to reduce its ability to further decontaminate incoming ammonia satisfactorily. Preferably there are a plurality of interconnected adsorbent beds, with some being operated for ammonia decontamination while others are being regenerated, with their operations being reversed as needed to maintain a continual production of decontaminated ammonia from the plurality of beds. Computers or other controllers can be used to control such bed operations and interchanges. Internal production of hydrogen makes the system self-contained and no addition of hydrogen is needed.Type: GrantFiled: October 27, 2000Date of Patent: February 25, 2003Assignee: Aeronex, Inc.Inventors: Daniel Alvarez, Jr., Jeffrey J. Spiegelman
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Patent number: 6524372Abstract: A novel compound which can be used in the field of separation and purification of gases is disclosed. The compound can be incorporated into a silica gel incorporating polyazacycloalkane structural units for separating a predetermined gas from a mixture of gases. The mixture of gases is brought into contact with a metallated hybrid gel under conditions which make possible the absorption of the gas to be separated, followed by a phase of desorption of the attached gas, and the recovery of the gas.Type: GrantFiled: July 25, 2000Date of Patent: February 25, 2003Assignee: L′Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l′Etude et l′Exploitation des Procedes Georges ClaudeInventors: Robert Corriu, Catherine Reye, Ahmad Mehdi, Gérard Dubois, Claude Chuit, Franck Denat, Bruno Roux-Fouillet, Roger Guilard, Gilles Lagrange, Stéphane Brandes
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Patent number: 6517610Abstract: A microelectromechanical gas concentrator is fabricated for extracting a gaseous component from a gas mixture. The gas concentrator consists of an adsorbent member that alternatively moves between two regions on a single substrate. When the adsorbent member is in the first region, it is allowed to adsorb the gaseous component. When the adsorbent member moves to the second region, it is exposed to radiant energy, causing it to desorb the gaseous component. As the adsorbent member moves alternatively between regions, the gaseous component is adsorbed by the adsorbent member in the first region and desorbed in the second region, resulting in a pumping action that concentrates the gaseous component from one region to the other.Type: GrantFiled: November 13, 2001Date of Patent: February 11, 2003Assignee: The United States of America as represented by the Secretary of the NavyInventor: Paul R. de la Houssaye
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Patent number: 6503297Abstract: A process for separating a gas component from a gas mixture is disclosed. A gas mixture is passed through an adsorption zone which contains an adsorbent which will selectively adsorb a gaseous component from the gas mixture. The adsorption zone contains a layer of monolithic adsorbent and a layer of adsorption beads. Optionally, a third monolithic layer may be employed. The adsorption zone is typically contained in an adsorption vessel.Type: GrantFiled: February 7, 2001Date of Patent: January 7, 2003Assignee: The BOC Group, Inc.Inventors: Yaping Lu, Divyanshu R. Acharya, Arthur I. Shirley, Norberto O. Lemcoff
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Patent number: 6500235Abstract: An improved pressure swing adsorption process and system for producing a high recovery of a highly purified product gas, such as argon, from a feed gas stream containing the product gas and impurity gases employs first and second adsorption stages with beds for adsorbing impurity gases. The system and process provides for sequential steps of: feed pressurization; simultaneous feed pressurization and product pressurization; adsorption; adsorption and purge; adsorption in the absence of purge; pressure equalization between beds; evacuation and depressurization of adsorbent bed; evacuation with product purge; evacuation without purge; and pressure equalization between beds.Type: GrantFiled: December 29, 2000Date of Patent: December 31, 2002Assignee: Praxair Technology, Inc.Inventors: Guoming Zhong, Mohamed Safdar Allie Baksh, Frank Notaro, Frederick Wells Leavitt
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Patent number: 6494262Abstract: There is disclosed a method for cleaning out of a well in which a compressed inert gas, produced by the non-cryogenic separation of air is delivered to the region of the well where particulate matter has collected that inhibits the ability of the well to produce.Type: GrantFiled: August 18, 2000Date of Patent: December 17, 2002Assignee: Weatherford/Lamb, Inc.Inventor: Gregory H. Chitty
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Patent number: 6475265Abstract: The present invention is a two stage PSA process for producing high purity oxygen from a feed air stream. Water, carbon dioxide and nitrogen are removed in a first stage. An oxygen selective adsorbent is used to adsorb oxygen in the second stage. High purity oxygen product is recovered during regeneration of the second stage. Importantly, the high purity of the oxygen product is achieved without inclusion of an oxygen rinse step in the process cycle. The high purity oxygen product is obtained by collecting the middle cut of the second stage effluent stream during regeneration.Type: GrantFiled: October 22, 1998Date of Patent: November 5, 2002Assignee: Praxair Technology, Inc.Inventors: Mohamed Safdar Allie Baksh, Atanas Serbezov, Frank Notaro, Frederick Wells Leavitt
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Patent number: 6457485Abstract: The present invention relates to a rotary valve assembly for a pressure swing adsorption system. The rotary valve assembly includes a first valve member and a second valve member relatively rotatable about a common center of rotation to provide valving action for selectively transferring fluids therethrough. The second valve member has a first fluid section with at least one aperture adapted for transferring a first fluid of a first pressure and composition therethrough and a second fluid section with at least one aperture adapted for transferring a second fluid of a second pressure and composition therethrough. The first valve member has a first fluid section with at least one passage for transferring the first fluid in the valve assembly and a second fluid section with at least one passage for transferring the second fluid in the valve assembly.Type: GrantFiled: August 8, 2001Date of Patent: October 1, 2002Assignee: SeQual Technologies, Inc.Inventors: Theodore B. Hill, Charles C. Hill, Adam C. Hansen
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Publication number: 20020134240Abstract: An improved pressure swing adsorption process and system for producing a high recovery of a highly purified product gas, such as argon, from a feed gas stream containing the product gas and impurity gases employs first and second adsorption stages with beds for adsorbing impurity gases. The system and process provides for sequential steps of: feed pressurization; simultaneous feed pressurization and product pressurization; adsorption; adsorption and purge; adsorption in the absence of purge; pressure equalization between beds; evacuation and depressurization of adsorbent bed; evacuation with product purge; evacuation without purge; and pressure equalization between beds.Type: ApplicationFiled: December 29, 2000Publication date: September 26, 2002Inventors: Guoming Zhong, Mohamed Safdar Allie Baksh, Frank Notaro, Frederick Wells Leavitt
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Publication number: 20020121193Abstract: A pressure swing process and system for purifying a first gas, preferably argon, from a crude feed gas stream containing the first gas and second gas(es) utilizes two adsorption beds and continuously promotes the crude feed gas to the bed during the process and simultaneous equalization of pressure in the two beds in top-top-top end and bottom-to-bottom end equalizations in each bed following purging of each bed.Type: ApplicationFiled: December 29, 2000Publication date: September 5, 2002Inventors: Mohamed Safdar Allie Baksh, Alan Barnard Stewart
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Publication number: 20020117052Abstract: 1.Type: ApplicationFiled: December 21, 2000Publication date: August 29, 2002Inventor: Karl S. Beers