Abstract: A fire suppression blends of CF3I and 2-BTP with mol ratios from 1:5 and 5:1 are capable of passing peak inerting and sub-inerting tests. The CF3I:2-BTP fire suppression blends can also include carbon dioxide of up to 80% of the fire suppression blend to provide additional cooling.

Abstract: A non-flammable refrigerant composition for a HVACR system that includes R134a refrigerant, a hydrofluorocarbon refrigerant that has a global warming potential (GWP) of less than 150 or a hydrofluoroolefin refrigerant, and CF3I. A method of making a refrigerant composition for a HVACR system that includes selecting an amount of a first refrigerant that is a hydrofluorocarbon refrigerant or a hydrofluoroolefin refrigerant, selecting an amount of CF3I, and selecting an amount of R134a refrigerant. A method of retrofitting a refrigerant composition in an HVACR system that includes adding one or more compounds to the refrigerant composition. The retrofitted composition including R134a refrigerant, a hydrofluorocarbon refrigerant having a GWP of less than 150, and CF3I, or R134a refrigerant, a hydrofluoroolefin refrigerant, and CF3I.

Abstract: A non-flammable refrigerant composition for a HVACR system that includes R134a refrigerant, a hydrofluorocarbon refrigerant that has a global warming potential (GWP) of less than 150 or a hydrofluoroolefin refrigerant, and CF3I. A method of making a refrigerant composition for a HVACR system that includes selecting an amount of a first refrigerant that is a hydrofluorocarbon refrigerant or a hydrofluoroolefin refrigerant, selecting an amount of CF3I, and selecting an amount of R134a refrigerant. A method of retrofitting a refrigerant composition in an HVACR system that includes adding one or more compounds to the refrigerant composition. The retrofitted composition including R134a refrigerant, a hydrofluorocarbon refrigerant having a GWP of less than 150, and CF3I, or R134a refrigerant, a hydrofluoroolefin refrigerant, and CF3I.

Abstract: Methods are provided for forming aromatic compounds from a highly unsaturated aliphatic feeds optionally in combination with methanol. The method can include dehydrogenating a feed containing at least about 50 vol % C1-C4 alkanes under dehydrogenation conditions to form a dehydrogenation effluent containing at least about 25 vol % alkynes. Alternatively, other sources of alkyne-containing feeds can be used. At least a portion of the alkyne-containing feed can then be converted under effective conversion conditions to form a conversion effluent comprising a hydrocarbon product containing aromatic compounds.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises E-1,2-difluoroethylene. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and power cycle working fluids.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises Z-1,2-difluoroethylene (Z-HFO-1132a). The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and power cycle working fluids.

Abstract: A fire suppressant mixture comprising: an organic or supplemental organic fire suppressant compound; a halogen element, and an organic compound, wherein the organic fire suppressant compound, the halogen element and the organic compound are combined such that a boiling point of the mixture is lower than the boiling point of the organic fire suppressant. In some embodiments, the organic fire suppressant compound is FK 5-1-12 and the organic compound is carbon dioxide. In other embodiments, the mixture is supplemented with an additional organic compound such as CF3I or 2,2-Di-chloro-1,1,1-trifluoroethane (R123), or an halogen element. In some embodiments an inorganic pressurizing gas, such as nitrogen, is also added.

Abstract: A fire suppressant mixture comprising: an organic or supplemental organic fire suppressant compound; a halogen element, and an organic compound, wherein the organic fire suppressant compound, the halogen element and the organic compound are combined such that a boiling point of the mixture is lower than the boiling point of the organic fire suppressant. In some embodiments, the organic fire suppressant compound is FK 5-1-12 and the organic compound is carbon dioxide. In other embodiments, the mixture is supplemented with an additional organic compound such as CF3I or 2,2-Dichloro-1,1,1-trifluoroethane (R123), or an halogen element. In some embodiments an inorganic pressurizing gas, such as nitrogen, is also added.

Abstract: Compositions are described that may be used for applications such as a fire extinguishing composition in fire extinguishing unit, refrigeration, and the like. These compositions include halocarbons and additives that may stabilize the composition in the presence of a metal, water, and/or air. For example, the compositions may include a bromofluorocarbon, such as a bromofluoroalkene, an acid scavenger stabilizer, and an antioxidant stabilizer.

Abstract: Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO-HFO-1233, or HFO-1354 having properties highly beneficial in foaming and blowing agent applications, articles and methods.

Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with E-1-chloro-3,3,3-trifluoropropene or 2-chloro-3,3,3-trifluoropropene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.

Abstract: Compositions are described which are useful in many applications such as fire extinguishing or refrigeration. The compositions may include a hydrochlorofluorocarbon such as 2,2-dichloro-1,1,1-trifluoroethane, a dispersant such as CF3I, and an inert gas such as argon, and may in some embodiments be held under pressure. For example, some fire extinguishing compositions may be composed of 2,2-dichloro-1,1,1-trifluoroethane, CF3I, and argon.

Abstract: A gas storage container, such as a gas cylinder, is filled with a gas mixture comprising a first gas and a second gas under pressure by feeding a liquid/solid mixture comprising liquefied first gas and solidified second gas into the gas storage container; closing the gas storage container to the passage of gas into or out from the container; and allowing said liquefied first gas and said solidified second gas to become gaseous within said closed gas storage container. Such a process is easier and more energy efficient as compared to direct compression processes, and is safer and results in less wastage as compared to direct liquid injection processes.

Abstract: Provided are azeotrope-like compositions comprising heptafluoropropane and trifluoroiodomethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agents, fire suppressant compositions, and aerosol propellants.

Abstract: An autonomous fire-fighting agent (10) formed from a material with fire-extinguishing properties. The material includes: microcapsules with a fire-extinguishing composition, the microcapsules having sizes of from 2 to 100 ?m and being in the form of a halocarbon enclosed in a polymeric shell consisting of polyurea and/or polyurethane; and a binder. The binder includes a composite material having a polymeric component and mineral fibers and/or particles. The invention also relates to a method for manufacturing an autonomous fire-fighting agent (10) and an object which uses the autonomous fire-fighting agent (10) to fight a fire 10-20 s after ignition.

Abstract: Fire extinguishing compositions and methods of extinguishing a fire comprising compounds of formula (I) where Rf is a fluorocarbon group. The compounds and compositions described herein are useful as intermediates in the preparation of or as additives to AFFF (aqueous film forming foam) formulations used for the extinguishment of fuel and solvent fires.

Abstract: Compositions are described which are useful in many applications such as fire extinguishing or refrigeration. The compositions may include a hydrochlorofluorocarbon such as 2,2-dichloro-1,1,1-trifluoroethane, a dispersant such as CF3I, and an inert gas such as argon, and may in some embodiments be held under pressure. For example, some fire extinguishing compositions may be composed of 2,2-dichloro-1,1,1-trifluoroethane, CF3I, and argon.

Abstract: A combination of a liquid fire extinguishing composition including potassium salts or aluminum salts of an organic acid, resulting in a viscous liquid, is finely divided by a nozzle into droplets which may be applied to a fire or fuel therefor or form a cloud of droplets which settle onto such fire and/or fuel which is particularly effective for fighting fires where fuel is at least initially contained such as oil and grease fires in cooling utensils being heated on stoves. Propellant is contained and not entrained in the dispensed fire fighting composition to avoid at least spreading of the fuel beyond the containment.

Abstract: A fire control system according to various aspects of the present invention includes an extinguishant configured to absorb heat from the fire. In one embodiment, the extinguishant is configured to absorb thermal radiation from the fire and inhibit reflection of thermal radiation from the extinguishant and/or other surfaces back into the fire. In additional and alternative embodiments, the extinguishant includes a thermal absorbant may be configured to transfer heat into the surface and/or interior of suppressant particles or droplets to promote activation of the suppressant.

Abstract: Compositions are described which are useful in many applications such as fire extinguishing or refrigeration. The compositions may include a hydrochlorofluorocarbon such as 2,2-dichloro-1,1,1-trifluoroethane, a dispersant such as CF3I, and an inert gas such as argon, and may in some embodiments be held under pressure. For example, some fire extinguishing compositions may be composed of 2,2-dichloro-1,1,1-trifluoroethane, CF3I, and argon.

Abstract: Disclosed are coolants comprising brazed metal corrosion inhibitors. In one embodiment, the disclosed brazed metal corrosion inhibitor will comprise a polycarboxylic acid functional compound having the structure: wherein R1, R2, R3, and R4 are each independently selected from the group consisting of H, OH, COOH, C1-C10alkyl groups, glycol esters, anhydride groups, —COOM, and combinations thereof, wherein M is at least one of H, alkali metal ions, alkali earth metal ions, NH4+, amines, imidazoline, polyalcohol esters, C1 to C12 alkyl groups, and combinations thereof; wherein (1) at least three of R1, R2, R3, and R4 contain the group —COOM, wherein M is defined above; or (2) at least two of R1, R2, R3, and R4 contain an anhydride group, and at least one of R1, R2, R3, and R4 contain the group —COOM, wherein M is defined above.

Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with E-1-chloro-3,3,3-trifluoropropene or 2-chloro-3,3,3-trifluoropropene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.

Abstract: A fire control system according to various aspects of the present invention includes an extinguishant having a suppressant and a thermal absorbant. The suppressant is configured to suppress the fire. The thermal absorbant is configured to absorb heat from the fire. In one embodiment, the thermal absorbant is configured to absorb thermal radiation from the fire and inhibit reflection of thermal radiation from the suppressant and/or other surfaces back into the fire. In additional and alternative embodiments, the thermal absorbant may be configured to transfer heat into the surface and/or interior of suppressant particles or droplets to promote activation of the suppressant.

Abstract: Process for the obtention of HFC-227ea having a reduced content of organic impurities, comprising at least subjecting a crude HPC-227ea to two distillation steps at different pressures.

Abstract: Methods of reducing smoke levels in smoke-affected areas, reducing the level of toxic compounds produced by fires, fire suppression, and increasing flame retardancy. In particular, methods according to the present invention comprise dispersing nanocrystalline particles in the areas affected by smoke for sorption of smoke particulates and toxic compounds produced from a fire. The nanocrystalline particles are also effective for use in methods of fire suppression and flame retardancy.

Abstract: Composition comprising at least one hydrofluoroalkane and at least one fluoropolyether.

Abstract: Fire retardant compositions containing an extract of African Oil Palm fruit, methods of preparing such compositions, and their use in imparting fire resistance to objects are disclosed.

Abstract: Provided are azeotrope-like compositions comprising difluoroethane and trifluoroiodomethane, azeotrope-like compositions comprising difluoroethane, tetrafluoropropene and trifluoroiodomethane, and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.

Abstract: The present invention relates to methods of using at least one fluoroketone selected from monobromoperfluoroketones, monohydromonobromoperfluoroketones, (perfluoroalkoxy)monobromoperfluoroketones, (fluoroalkoxy)monobromoperfluoroketones, and monochloromonobromoperfluoroketones for i) extinguishing fire by applying to the fire such a fluoroketone, ii) preventing fire in an air-containing enclosed area containing combustible materials by introducing into the area such a fluoroketone and maintaining the fluoroketone in an amount sufficient to suppress combustion of combustible materials in the enclosed area, and iii) reducing or eliminating the flammability of a flammable working fluid, by mixing between about 0.1 to about 99 percent by weight of such a fluoroketone with the flammable working fluid.

Abstract: Methods of reducing smoke levels in smoke-affected areas, reducing the level of toxic compounds produced by fires, fire suppression, and increasing flame retardancy. In particular, methods according to the present invention comprise dispersing nanocrystalline particles in the areas affected by smoke for sorption of smoke particulates and toxic compounds produced from a fire. The nanocrystalline particles are also effective for use in methods of fire suppression and flame retardancy.

Abstract: A fire extinguishing agent contains at least one compound selected from the group consisting of an alkali hydrogencarbonate and an alkali carbonate, the alkali hydrogencarbonate being thermally decomposed to generate carbon dioxide and an alkali carbonate, a metal oxide that reacts with the alkali carbonate to generate carbon dioxide, and a hydrophobic binder.

Abstract: A foam concentrate provides a fire-fighting composition when mixed with water so that the fire-fighting composition does not form a stable seal on cyclohexane and meets UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents without requiring organic fluorine. The concentrate is formed from water and a high molecular weight acidic polymer (HMWAP) and a coordinating salt.

Abstract: Solid composition has an organic spill absorbing material in which is absorbed certain of a liquid organic compound or composition. The organic spill absorbing material can be water insoluble, particulate polymer particles that imbibe liquid organic materials. A halogenated organic can provide the liquid organic compound or composition. The halogenated organic can be a halogenated hydrocarbon. A fire can be fought by transmitting the solid composition containing a suitable flame retardant to the base of the fire under conditions such that the absorbed liquid in liquid or vapor form is released; and a living target can be stupefied by transmitting the solid composition containing a suitable stupefying agent under conditions such that vapors of the stupefying agent are released and stupefy the target.

Abstract: A fire or explosion suppression system comprises a source (30) of a liquid suppressant under pressure, and a source (32) of an inert gas under pressure. The liquid suppressant is a chemical substance having a low environmental impact, with a short atmospheric lifetime of less than 30 days. The inert gas may be nitrogen, carbon dioxide, argon, neon or helium or mixtures of any two or more of them. The suppressant and the inert gas are fed under pressure to an output unit (34) comprising a mixing chamber in which the liquid and the gas impinge to produce a mist of the liquid suppressant of very small droplet size which is entrained in the pressurised gas together with vapour from the liquid, the so-entrained mist and vapour and the gas being discharged by a nozzle (44) into an area to be protected. The mist and vapour are therefore carried by the entraining and transporting high pressure gas into regions of the areas to be protected, enabling a total flooding capability.

Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula CaHbBrcCldFeIfNgOh, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.

Abstract: A foam concentrate or fire fighting composition for extinguishing and/or retarding fires is provided that meets UL162, Class B performance criteria for at least one of AFFF agents, AR-AFFF agents and fluoroprotein (FP) agents. The concentrate is used to form the fire fighting composition when mixed with water. The concentrate or fire fighting composition includes a high molecular weight fluoropolymer and water and may have a fluorine content wherein less than about 0.008% fluorine by weight of the fire fighting composition is provided from any fluorochemical surfactant. Further, the composition may meet the UL162, Class B performance criteria without forming a stable seal on cyclohexane.

Abstract: A foam concentrate provides a fire-fighting composition when mixed with water so that the fire-fighting composition does not form a stable seal on cyclohexane and meets UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents without requiring organic fluorine. The concentrate is formed from water and a high molecular weight acidic polymer (HMWAP) and a coordinating salt.

Abstract: A method of fire extinguishment with a gas, characterized by extinguishing a fire by ejecting at least one gaseous fire-extinguishing agent selected from the group consisting of argon, nitrogen, and carbon dioxide using a foam, powder, or water as a carrier.

Abstract: Highly fluorinated, saturated, and unsaturated fluoroethers are efficient, economical, non-ozone-depleting fire extinguishing agents used alone or in blends with other fire extinguishing agents in total flooding and portable systems. Methods for producing ethers, halogenated ether intermediates, and fluoroethers are disclosed. Novel fluoroether compositions are disclosed. Fluoroether extinguishing mixtures, methods, and systems are disclosed.

Abstract: The present invention provides a foam fire-extinguishing agent devoid of environmentally harmful fluorochemical surfactant. The foam fire-extinguishing agent comprises a foamable synthetic surfactant consisting of (a) polyoxyethylene alkyl sulfate ester salt, and (b) at least either one of lauric acid amide propyldimethyl amino betaine acetate and lauric acid amide propylhydroxy sulfobetaine. This foam fire-extinguishing agent may further include at least either one of (c) polyoxyalkylenediamine having both terminal ends substituted with amino alkyl, and derivatives thereof, (d) polyoxyethylene coconut fatty acid monoethanol amide phosphate ester and (e) dodecyl alcohol.

Abstract: A gel is produced by magnetically treating and mixing two solutions and in one embodiment subsequently introducing carbon dioxide gas. The first solution is comprised of water and sodium bicarbonate, and the second solution is comprised of water and sodium silicate. The first solution is passed through a positively charged magnetic field, and the second solution is passed through a negatively charged magnetic field. The two solutions are then mixed together to form a gel. The resulting gel has excellent fire-fighting capabilities because of its high heat absorption and emissive qualities. The gel can also be used to aid in the removal of surface coatings.

Abstract: A biodegradable, non-toxic firefighting concentrate composition. The preferred compositions include a mixture of a C14-C18 5 mole ethoxylated tallow amine, 2 mole ethoxylated coconut amine, and 5 mole ethoxylated coconut amine, wherein the blend is neutralized with a C6 carboxylic acid; an aliquot of 33 parts is added to 3 parts of a 2 mole ethoxylated linear alcohol having 6 to 16 carbon atoms, and enough water to bring the total weight percentage to 70%. Ten to fifteen parts of sodium lauryl sulfate is added and the balance of water is added to bring the total up to 100%. The composition is also effective when mixed with glycol dimethyl ether, the incorporation of a filming protein based agent, dye, or foam forming materials. In addition, the composition is useful with soil bacteria for remediating soil contaminated with hydrocarbon fuel and for facilitating fuel dispersion and degradation within bacterial-action sewage systems.

Abstract: The invention provides for a substantially non-aqueous, flame extinguishing composition for extinguishing a fire at the sight of a potential flame having a flurocarbon in admixture with a gelled powder additive having salts of weak acids which decompose at the temperature of the sight to reduce or eliminate HF released by the composition when used to extinguish flames.

Abstract: The present invention relates to a solution and to a method of treating copper surfaces, the copper surfaces being brought into contact with an acidic treatment liquid which contains hydrogen peroxide and at least one five-membered heterocyclic compound as well as additionally at least one microstructure modifying agent selected from the group comprising thioles A, disulfides B, sulfides C and thioamides D having the following respective general formulae: 1

Abstract: Composition consisting essentially of 55 to 94% R-125, 2.5 to 35% of R-134a and 3.5 to 25% by weight of DME, and its use as a refrigerant in a heat transfer system designed for R-22 and comprising, as lubricant, a mineral oil or an alkylbenzene oil.

Abstract: A method for suppressing a fire at a burning material comprising delivering to said burning material (a) an inert gas and (b) a gaseous compound selected from the group consisting of a hydrofluorocarbon, an iodofluorocarbon, and a mixture thereof, gases (a) and (b) being delivered in a combined concentration sufficient to extinguish the fire.

Abstract: A class of fire suppressant compounds which have labile bromine atoms bound to atoms other than carbon have been discovered to be more effective at suppressing fires than Halon 1211 and Halon 1301. Moreover, this class of fire suppressant compounds hydrolyze or oxidize rapidly in the troposphere and as a consequence thereof, they have minimal ozone depletion potential.

Abstract: A class of fire suppressant compounds which have labile bromine atoms bound to atoms other than carbon have been discovered to be more effective at suppressing fires than Halon 1211 and Halon 1301. Moreover, this class of fire suppressant compounds hydrolyze or oxidize rapidly in the troposphere and as a consequence thereof, they have minimal ozone depletion potential.

Abstract: A class of fire suppressant compounds which have labile bromine atoms bound to atoms other than carbon have been discovered to be more effective at suppressing fires than Halon 1211 and Halon 1301. Moreover, this class of fire suppressant compounds hydrolyze or oxidize rapidly in the troposphere and as a consequence thereof, they have minimal ozone depletion potential.