Abstract: Disclosed a method for the preparation of granular sorbent based on LiCl.2Al(OH)3.nH2O for lithium recovery from lithium-containing brines, comprising production of a powder of LiCl.2Al(OH)3.nH2O (DHAL-Cl) from aluminum chloride solution comprising lithium, separation of the powder DHAL-Cl from the obtained solution by centrifugation with further removing the excess LiCl, drying of the powder DHAL-Cl; and, granulation of the powder DHAL-Cl with the addition of chlorinated polyvinylchloride and a organochlorine solvent to obtain the granular sorbent based on LiCl.2Al(OH)3.nH2O; wherein the aluminum chloride solution comprising lithium is prepared by dissolving crystalline hydrate of hexaaqua aluminum chloride in aqueous solutions comprising lithium in the form of LiCl, Li2CO3, or LiOH.H2O or mixtures thereof, and concentration of aluminum chloride in the solution is 45-220 kg/m3.

Abstract: An oxygen storage material including a compound of the formula: Ca2MnAlO5+? wherein 0???0.5 wherein the compound includes at least one dopant said dopant selected from alkaline earth ions at the Ca site, trivalent ions at the Al site, and 3d transition metal ions at the Mn site wherein the an oxygen release temperature or an oxygen storage temperature is modified in comparison to an un-doped Ca2MnAlO5+? material.

Abstract: A hydrogen generator comprises a reformer configured to generate a hydrogen-containing gas through a reforming reaction using a raw material; a hydrodesulfurization unit configured to remove a sulfur compound from the raw material; a recycle passage configured to flow therethrough the hydrogen-containing gas to be added to the raw material in a state before the raw material flows into the hydrodesulfurization unit, the recycle passage having a downward slope; and a water drain passage configured to discharge condensed water generated in the downward slope of the recycle passage.

Abstract: Methods for the preparation of fluorided-chlorided silica-coated alumina activator-supports are disclosed. These activator-supports can be used in catalyst systems for the production of olefin-based polymers, such as polyethylene and polypropylene.

Abstract: This invention relates to a particulate extraction material for the extraction of lithium from a geothermal brine or lithium containing solution. The particulate material includes an inorganic or polymer based substrate that includes a lithium aluminate intercalate layer applied to the exterior of the substrate, wherein the lithium aluminate intercalate layer is operable to capture lithium ions from solution.

Abstract: An adsorbent for carbon dioxide may include a composite metal oxide including a divalent first metal (M1), a trivalent second metal (M2), and at least one polyoxometalate (POM) ion selected from an anion represented by a first formula (e.g., Chemical Formula 1) and an anion represented by a second formula (e.g., Chemical Formula 2). A capture module for carbon dioxide may include the adsorbent.

Abstract: Disclosed is a self-supporting solid compacted composition of material comprising an ammonia storage material capable of reversibly absorbing and desorbing ammonia in its ammonia saturated state and compacted to such a density that it has of at least 70% of the single crystal density of said material in its ammonia-saturated state in admixture with one or more additive incapable of storing ammonia and having a thermal conductivity of at least five times the thermal conductivity of the ammonia storage material at a temperature of from at least ?45° C. to 250° C., as well as a process for preparing it.

Abstract: An alumina support comprises alpha-alumina as the main crystal phase of its backbone, and having a specific surface area of no higher than 3.0 m2/g, a pore volume ranging from 0.3 ml/g to 0.8 ml/g, an alkaline earth metal content ranging from 0.05% to 2.0% by weight of the support, wherein the support has such properties that treating the support with an aqueous oxalic acid solution having a concentration ranging from 0.4% to 2.0% by weight and having twice the weight of the support for 30 minutes can produce a leach liquor having an aluminum content of no higher than 60 ?g/mL, a sodium content of no higher than 20 ?g/mL, and a silicon content of no higher than 40 ?g/mL. Processes for preparing the alumina support, silver catalysts comprising the alumina support, and methods of preparing ethylene oxide by ethylene oxidation using the silver catalyst are also disclosed herein.

Abstract: Porous composites of mullite and cordierite are formed by firing an acicular mullite body in the presence of a magnesium source and a silicon source. In some variations of the process, the magnesium and silicon sources are present when the acicular mullite body is formed. In other variations, the magnesium source and the silicon source are applied to a previously-formed acicular mullite body. Surprisingly, the composites have coefficients of linear thermal expansion that are intermediate to those of mullite and cordierite alone, and have higher fracture strengths than cordierite at a similar porosity. Some of the cordierite forms at grain boundaries and/or points of intersection between mullite needles, rather than merely coating the needles. The presence of magnesium and silicon sources during acicular mullite formation does not significantly affect the ability to produce a highly porous network of mullite needles.

Abstract: A carbon dioxide adsorbent may include an amorphous mixed metal oxide including a divalent first metal (M1), a trivalent second metal (M2) different from the divalent first metal (M1), an alkali metal (M3), and an element (A) with an electronegativity of about 2.0 to about 4.0. The alkali metal (M3) may be present in the form of a crystalline halide, an oxide, or a combination thereof. The carbon dioxide adsorbent may also be used in a method of separating carbon dioxide.

Abstract: The invention is directed to shaped composite adsorbent material, comprising particulate activated carbon material, bound by a suitable binder, preferably selected from the group of sodium alginate calcium alginate, chitosan, polyacrylamide, polyethylene oxide and mixtures thereof, more in particular a combination of chitosan and alginate, whereby the activation of the carbon material has taken place before binding the material.

Abstract: A treatment medium has a particulate natural substrate saturated, suffused and/or coated with hydrous iron oxide. The particulate substrate can be wood based, such as wood chips, bark, sawdust, wood waste or other plant material (such as straw, lucerne, hay, coconut husk or other bulk particulate plant material). The hydrous iron oxide is provided in aqueous suspension form. The substrate may be tumbled in aqueous hydrous iron suspension to achieve saturation/coating. The resulting hydrous iron oxide bearing medium is either placed loose directly into the target treatment site or contained in bags 18 before placing into the target site.

Abstract: A dry material is synthesized by alkali metal (Li, Na and K) promoted calcium aluminate carbonates to obtain a CO2 sorbent used at a temperature higher than 600 Celsius degrees (° C.). The key composition of the sorbents is 52˜69% of CaO, which is beneficial to capture CO2 at 400˜800° C. A breakthrough result is achieved by using this sintering-resistant sorbent, which includes the features of 50% initial carbonation capacity and 20 folds CO2 capturing performance maintained after 40˜60 hours. Besides, alkali bearing material provides good velocity in CO2 capturing/releasing cycles; for example, by using Li and K series sorbents, 40 hours is required for 40 cycles only.

Abstract: The invention relates to aggregate zeolitic adsorbents based on faujasite X type zeolite powder having a low silica content and small crystals, exchanged with barium or based on faujasite X type zeolite having a low silica content and small crystals, exchanged with barium and potassium. The invention also relates to the method for preparing said aggregate zeolitic adsorbents, and also their uses for separating sugars, polyhydric alcohols, isomers of substituted toluene, cresols, or for recovering very high purity paraxylene.

Abstract: The invention relates to a process for the preparation of a particulate polyethylene product in a loop reactor, wherein the polymerization catalyst applied in the polymerization process comprises a particulate metallocene-alumoxane catalyst immobilized on a porous silica support; and whereby said metallocene-alumoxane catalyst is heterogeneously distributed on said porous silica support.

Abstract: Methods and systems for reducing mercury emissions from fluid streams are provided herein. In embodiments, mercury is removed from flue gas streams by injecting a dry admixture of a porous mercury adsorptive material and at least one halide containing agent into the flue gas stream.

Abstract: This invention relates to a particulate extraction material for the extraction of lithium from a geothermal brine or lithium containing solution. The particulate material includes an inorganic or polymer based substrate that includes a lithium aluminum intercalate layer applied to the exterior of the substrate, wherein the lithium aluminum intercalate layer is operable to capture lithium ions from solution.

Abstract: A method of saturating reversible ammonia storage materials inside a container for the purpose of achieving high volumetric ammonia storage capacity and containers filled with the materials are disclosed.

Abstract: A regenerating method for activated alumina used in regenerating working fluid of hydrogen peroxide comprises the following steps: adding deactivated alumina discharged from a regenerating bed for working fluid of hydrogen peroxide into a reactor through the top of the reactor and settling by gravity, oxidizing atmosphere entering into the reactor from the bottom of the reactor and running upwardly, then discharging exit gas and regenerated alumina through the discharge port on the top and discharging device on the bottom of the reactor respectively. The method is economic, environment-protective, safe, low-costly. The regenerated alumina will not poison palladium catalyst.

Abstract: A regenerating method for activated alumina used in regenerating working fluid of hydrogen peroxide comprises the following steps: adding deactivated alumina discharged from a regenerating bed for working fluid of hydrogen peroxide with fire resistant alumina into a reactor through the top of the reactor and settling by gravity, oxidizing atmosphere entering into the reactor from the bottom of the reactor and running upwardly, discharging regenerated alumina and fire resistant alumina through the discharging device on the bottom of the reactor, discharging exit gas through the discharge port on the top of the reactor, the reaction temperature ranging from 360-800° C., the residence time of solid feed in the reactor ranging from 3-15 h. The method is economic, environment-protective, safe, and low-costly. The regenerated alumina will not poison palladium catalyst.

Abstract: The present invention relates to a method for hydrothermal preparation of a solid made up of a metal-organic framework (MOF) of crystallised, porous aluminium carboxylates, in an aqueous medium. The invention also relates to solids made up of metal-organic frameworks (MOF) of porous, crystallised aluminium carboxylates capable of being obtained by the method of the invention as well as to the uses thereof for the storage of liquid or gaseous molecules, for selective separation of gas and for catalysis.

Abstract: This invention relates to a particulate extraction material for the extraction of lithium from a geothermal brine or lithium containing solution. The particulate material includes an inorganic or polymer based substrate that includes a lithium aluminum intercalate layer applied to the exterior of the substrate, wherein the lithium aluminum intercalate layer is operable to capture lithium ions from solution.

Abstract: A clay comprising a 2:1 aluminosilicate clay having negative charge sites, the 2:1 aluminosilicate clay containing subnano-sized zero valent iron (ZVI) particles distributed on clay surfaces is provided. In one embodiment, at least some or all of the particles have a cross-section of five (5) angstroms or less. Methods of synthesizing and the novel clays and the clay-templated subnano-scale ZVI particles themselves are also described. Such novel products are useful in a variety of remediation applications, including for reduction and dechlorination reactions.

Abstract: The invention relates to a method for preparing a chemical composition obtained by co-impregnating water-soluble salts Ba/Mg and phosphoric acid H3PO4 on boehmite alumina which has been calcined in the presence of water vapor. Said chemical composition is used as an additive in the catalytic cracking process in order to capture metals originating from the charge, particularly vanadium, in the presence of SO2 and thus to protect the activity and selectivity of the catalytic cracking catalyst.

Abstract: The invention relates to composite adsorbent materials, and in particular, to highly porous carbon-based composite materials for the adsorption and stabilisation of inorganic substances. The composite adsorbent material comprises a porous carbon carrier matrix and an adsorbent species, wherein the adsorbent species is precipitated within the pores of the carrier matrix. The invention extends to various uses of such adsorbent materials, for example in water purification, recovery of metals from waste streams and remediation applications, and where the adsorbant material is amended into soil, waste etc. for the purpose of breaking pollutant-receptor linkages.

Abstract: Sorption media for removal of contaminants from fluid streams are provided. The sorption media comprise an active compound bound or linked to a support substrate or matrix. Support substrates can include iron- and alumina-based materials. A method for making sorption media for the removal of contaminants from fluid streams is also described. The method includes selecting a support substrate, and, optionally, providing a doping mixture comprising an active compound. The selected support substrate can be contacted with the doping mixture to form a doped mixture. The doped mixture can be reacted at a predetermined temperature and atmospheric environment for a predetermined duration to form an active media, wherein the active compound is bound or linked to the support substrate.

Abstract: Getter systems are provided having a phase being active in the sorption of gas inserted in the pores of a porous material. The porous material is, in turn, dispersed in a polymeric means that is permeable to the gas to be sorbed.

Abstract: Method for preparation of an adsorbent that comprises successive shaping stages by co-granulation of a faujasite-type zeolite powder A, with a powder B that consists of alumina, whereby the ratio per unit of mass of the powder A in the mixture of powders A and B is between 10 and 70%, for treatment under water vapor and drying. The invention also relates to a process for adsorption of organic contaminants that contain at least one heteroatom and that are present in an olefinic feedstock that comprises at least 50% by volume of hydrocarbons, whereby this process comprises the stage for bringing the olefinic feedstock into contact with the adsorbent that is obtained by the preparation method according to the invention.

Abstract: An adsorbent for carbon dioxide may include a composite metal oxide including a divalent first metal (M1), a trivalent second metal (M2), and at least one polyoxometalate (POM) ion selected from an anion represented by a first formula (e.g., Chemical Formula 1) and an anion represented by a second formula (e.g., Chemical Formula 2). A capture module for carbon dioxide may include the adsorbent.

Abstract: An odor filtration media having a chemical reagent which removes odor causing fluid contaminants from a fluid stream through the use of granular or shaped media have a chemical composition including permanganate is provided. A method of producing the odor absorbing media having a chemical reagent is also provided and comprises the steps of mixing H2O, KMnO4, and at least one salt adding ions or ionic compounds selected from the group consisting of Na+, Li+, K+, NH4+, Cl?, SO42?, BO32?, CO32?, PO43?, NO3? and combinations thereof, or from the group consisting of Na+, Li+, K+, NH4+, Mg2+, Ca2+, Cl?, BO32?, NO3? and combinations thereof, forming an impregnating solution. The impregnating solution is heated and combined with a support material to form a coherent mass.

Abstract: The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15<Si/AL<1.5, consisting of crystals with a mean diameter of 1.7 mm or less and of an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X being occupied by barium ions. They may be obtained by agglomerating a zeolite X powder having a mean diameter of 1.7 mm or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged.

Abstract: Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH)2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH)2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH)2. The resulting Mg(OH)2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.

Abstract: Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: In a ceramic honeycomb structure, a catalyst material used for burning soot discharged from an internal combustion engine is supported on partition walls that are inner surfaces of cells. For example, a catalyst material to be used for burning carbon includes silver and alumina as components, and the catalyst material has a dumbbell-shaped O—Ag—O structure. Thus, the ceramic honeycomb structure can burn soot at low temperature using the supported catalyst material without corroding the honeycomb structure.

Abstract: A treatment medium has a particulate natural substrate saturated, suffused and/or coated with hydrous iron oxide. The particulate substrate can be wood based, such as wood chips, bark, sawdust, wood waste or other plant material (such as straw, lucerne, hay, coconut husk or other bulk particulate plant material). The hydrous iron oxide is provided in aqueous suspension form. The substrate may be tumbled in aqueous hydrous iron suspension to achieve saturation/coating. The resulting hydrous iron oxide bearing medium is either placed loose directly into the target treatment site or contained in bags 18 before placing into the target site.

Abstract: A heavy metal absorbent, and a filter device including the same, include heavy metal absorbing particles each having a surface with a —NOx (1?x?2) functional group. The heavy metal absorbing particles are one selected from inorganic oxide particles, graphite-based carbon particles, and a combination thereof.

Abstract: Methods and systems for reducing mercury emissions from fluid streams having a high concentration of sulfur oxide species are provided herein. In embodiments, mercury is removed from flue gas streams by injecting a dry admixture of a porous mercury adsorptive material and at least one dry agent into the flue gas stream.

Abstract: Superabsorbents comprising pyrogenic aluminum oxide exhibit a low caking tendency coupled with good absorption properties and rapid water absorption.

Abstract: Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.

Abstract: A composition and process for removing sulfur from middle distillate petroleum hydrocarbon fuels. The composition includes an alumina component and a carbon component. The composition is present in an amount effective to adsorb sulfur compounds from the fuel. The alumina component and the carbon component preferably collectively comprise a composite material. The composition can further include a sulfur component, preferably a metal sulfide or sulfur oxide. The composition can also further include at least one compound having a Group VI or Group VIII metal from the periodic table.

Abstract: A mixed powder of AlH3 and MgH2 is ball-milled in a hydrogen atmosphere while applying force of 5 G through 30 G (in which G is gravitational acceleration), and the thus-obtained milled product is dehydrogenated to produce a hydrogen storage material. The hydrogen storage material comprises an amorphous phase containing an Al—Mg alloy as a mother phase, and a crystalline Al phase having a maximum length of 100 nm or less, the crystalline Al phase being distributed as a dispersed phase in the mother phase.

Abstract: Embodiments of the invention relate to a fluid storage unit comprising a composite fluid storage material and one or more internal fluid distribution features. The one or more internal fluid distribution features increase the homogeneity of fluid interaction within the composite fluid storage material, benefiting a number of properties and functions.

Abstract: A process for desulfurizing a process fluid includes contacting a sulphur compound containing feed stream with an absorbent including an iron, copper or nickel compound capable of forming a metal sulphide, a support material, a first binder and a second binder where the first binder is a cement binder and the second binder is a high aspect ratio aluminosilicate clay binder having an aspect ratio >2 and a ratio of the first binder to the second binder is in the range 2:1 to 3:1.

Abstract: Compositions and methods suitable for removing poisonous metals from hydrocarbons are provided. The compositions comprise hydrotalcite having one or more trapping metals dispersed on the outer surface thereof.

Abstract: This invention relates to catalyst carriers to be used as supports for metal and metal oxide catalyst components of use in a variety of chemical reactions. More specifically, the invention provides a process of formulating a low surface area alpha alumina carrier that is suitable as a support for silver and the use of such catalyst in chemical reactions, especially the epoxidation of ethylene to ethylene oxide. A precursor for a catalyst support comprises an admixture of an alpha alumina and/or a transition alumina; a binder; and either a solid blowing agent which expands, or propels a gas upon the application of sufficient heat, and optionally contains talc and/or water soluble titanium compound.

Abstract: The invention relates to a method for producing an aluminium strip, in which the aluminium strip is coated with a sorption layer which has a binder and a sorbent. The object to propose a method for producing an aluminium strip coated with a sorption layer, by means of which an aluminium strip can be coated cost-effectively having constant performance characteristics with respect to the sorption of, for example, water vapour, is achieved according to the invention by means of a method for producing an aluminium strip coated with a sorption layer by applying a suspension to the aluminium strip in the coil-coating process, which in addition to a liquid comprises at least one binder, formed as a solid, and a sorbent, and by subjecting the aluminium strip, together with the applied suspension, to a drying process, in which the binder is activated.

Abstract: A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide in the catalyst converts to catalytically active iron sulfide in the presence of hydrogen and sulfur.

Abstract: An animal litter such as a clay material is treated to reduce the bulk density thereof by contacting the clay material with an aqueous electrolyte solution and then heating at an elevated temperature. Substantial reductions in bulk density have been achieved without reducing the absorption capacity of the clay granule.

Abstract: A gas separation process uses a structured particulate bed of adsorbent coated shapes/particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages/bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders/hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.

Abstract: A regenerable, high-capacity sorbent for removal of mercury from flue gas and processes and systems for making and using the sorbent. A phyllosilicate substrate, for example vermiculite or montmorillinite, acts as an inexpensive support to a thin layer for a polyvalent metal sulfide, ensuring that more of the metal sulfide is engaged in the sorption process. The sorbent is prepared by ion exchange between the silicate substrate material and a solution containing one or more of a group of polyvalent metals including tin (both Sn(II) and Sn(IV)), iron (both Fe(II) and Fe(III)), titanium, manganese, zirconium and molybdenum, dissolved as salts, to produce an exchanged substrate. Controlled reaction of a sulfide ion source with the one or more polyvalent metals that are exchanged on the silicate substrate produces the sorbent. The sorbent is used to absorb elemental mercury or oxidized mercury species such as mercuric chloride from flue gas containing acid gases (e.g.