Zeolite Or Clay, Including Gallium Analogs Patents (Class 502/60)
  • Patent number: 11992828
    Abstract: The present disclosure provides molecular sieves with intergrown phases of AEI and CHA topologies and a catalyst thereof. A preparation method for the molecular sieves include the following steps: mixing a hydroxyphosphono organic alkali R with an aluminum source and a silicon source to obtain a sol-gel precursor, putting the sol-gel precursor into a closed hydrothermal synthesis reactor for reaction, filtering the reaction solution, washing, drying, and calcination to obtain the molecular sieves with intergrown phases of AEI and CHA topologies. The molecular sieves and the catalyst thereof can be directly synthesized under mild conditions with a hydroxyphosphono organic alkali as a structure-directing agent and a phosphorus source, have a pH value of 6-9 and low requirements for corrosion resistance of production devices, and are suitable for large-scale production.
    Type: Grant
    Filed: June 19, 2023
    Date of Patent: May 28, 2024
    Assignees: CHINA AUTOMOTIVE TECHNOLOGY AND RESEARCH CENTER CO., LTD, CATARC AUTOMOTIVE TEST CENTER (TIANJIN) CO., LTD
    Inventors: Kaixiang Li, Zhenguo Li, Xiaoning Ren, Yuankai Shao, Jianhai Wang, Li Zhang, Lingfeng Jia, Cheng Lv
  • Patent number: 11975980
    Abstract: A molecular sieve of MFI structure has a ratio of n(SiO2)/n(Al2O3) of more than 15 and less than 70. It has a content of phosphorus of 1-15 wt %, calculated as P2O5 and based on the dry weight of the molecular sieve and a content of the supported metal in the molecular sieve 1-10 wt % based on the oxide of the supported metal and the dry weight of the molecular sieve. The supported metal is one or two selected from lanthanum and cerium. The volume of mesopores in the molecular sieve represents 40-70% by volume of the total pore volume of the molecular sieve by volume, measured by a nitrogen adsorption BET specific surface area method, and the volume of mesopores means the pore volume of the pores having a diameter of more than 2 nm and less than 100 nm.
    Type: Grant
    Filed: October 17, 2019
    Date of Patent: May 7, 2024
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yibin Luo, Ying Ouyang, Li Zhuang, Jianqiang Liu, Minggang Li, Xingtian Shu
  • Patent number: 11975309
    Abstract: Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high SiO2/Al2O3 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: May 7, 2024
    Assignee: Ketjen Limited Liability Company
    Inventors: Amir Sabahi, Eswaramoorthi Iyyamperumal, Nataly G. Vargas, William Knowles, Andrew Loebl, Julie Francis
  • Patent number: 11964262
    Abstract: A rare earth- and phosphorus-containing molecular sieve of MFI structure rich in mesopores has a ratio of n(SiO2)/n(Al2O3) of more than 15 and less than 70. The molecular sieve has a content of phosphorus of 1-15 wt %, calculated as P2O5 and based on the dry weight of the molecular sieve. The content of the supported metal in the molecular sieve is 1-10 wt % supported metal M1 and 0.1-5 wt % supported metal M2 based on the oxide of the supported metal and the dry weight of the molecular sieve. The supported metal M1 is one or two selected from lanthanum and cerium, and the supported metal M2 is one selected from iron, cobalt, nickel, copper, manganese, zinc, tin, bismuth and gallium; the volume of mesopores in the molecular sieve represents 40-70% by volume of the total pore volume of the molecular sieve by volume.
    Type: Grant
    Filed: October 17, 2019
    Date of Patent: April 23, 2024
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Ying Ouyang, Yibin Luo, Jianqiang Liu, Li Zhuang, Minggang Li, Xingtian Shu
  • Patent number: 11951462
    Abstract: The present invention relates to the use of a catalyst for production of methanol from methane, wherein the catalyst comprises a zeolite having Al pairs in the skeleton of at least 10 percent, based on the total number of all aluminium atoms in the zeolite, and further comprising a transition metal cation coordinated at beta-cationic positions, selected from the group consisting of Fe, Co, Mn, and Ni, wherein the ratio of the transition metal to Al is in the range of from 0.01 to 0.5; and with the proviso that the zeolite is not ZSM-5 and mordenite. The present invention further relates to the method of production of methanol, the catalyst for production of methanol by direct oxidation of methane, and to a method of production thereof.
    Type: Grant
    Filed: April 2, 2020
    Date of Patent: April 9, 2024
    Assignee: USTAV FYZIKALNI CHEMIE J. HEYROVSKEHO AV CR, V.V.I.
    Inventors: Jiri Dedecek, Edyta Tabor, Zdenek Sobalik, Stepan Sklenak, Kinga Mlekodaj
  • Patent number: 11926796
    Abstract: Process for the preparation of a catalyst and a catalyst comprising the use of more than one silica source is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 15 to about 35 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized basic colloidal silica, greater than about 0 to about 30 wt % silica from acidic colloidal silica or polysilicic acid, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with a good accessibility.
    Type: Grant
    Filed: July 15, 2022
    Date of Patent: March 12, 2024
    Assignee: Ketjen Limited Liability Company
    Inventors: Amir Sabahi, Andrew J Loebl, Sandra Gavalda, Julie Francis, Eswaramoorthi Iyyamperumal
  • Patent number: 11904304
    Abstract: Disclosed are a zeolite-like material, and a preparation method and use thereof. In the disclosure, cyclic molecules of the zeolite-like material form a closed cage-like cavity structure with each other. The zeolite-like material is synthesized using an inorganic solid waste as a raw material.
    Type: Grant
    Filed: April 22, 2022
    Date of Patent: February 20, 2024
    Assignees: Tibet University, Tianjin Chengjian University
    Inventors: Xuebin Lv, Wenli Feng, Jian Xiong, Guanyi Chen, Rui Zhang, Shijie Yang, Jianguo Cui, Wei Li, Zeng Dan, Duo Bu
  • Patent number: 11891347
    Abstract: Improved alkylation catalysts, alkylation methods, and methods of making alkylation catalysts are described. The alkylation method comprises reaction over a solid acid, zeolite-based catalyst and can be conducted for relatively long periods at steady state conditions. The alkylation catalyst comprises a crystalline zeolite structure, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals, and further having a characteristic catalyst life property. Some catalysts may contain rare earth elements in the range of 10 to 35 wt %. One method of making a catalyst includes a calcination step following exchange of the rare earth element(s) conducted at a temperature of at least 575° C. to stabilize the resulting structure followed by an deammoniation treatment. An improved method of deammoniation uses low temperature oxidation.
    Type: Grant
    Filed: January 26, 2022
    Date of Patent: February 6, 2024
    Assignee: Exelus Inc.
    Inventors: Mitrajit Mukherjee, Eric Daniel Gauthier, Kelly Ann Coley
  • Patent number: 11878291
    Abstract: Methods of solid catalyst manufacture using a peptization agent, a peptization agent, and formed solid catalyst materials are provided. The peptization agent includes one or more oxidized disulfide oil (“ODSO”) compounds. These ODSO compounds peptization agents are used to replace conventional acids used as peptization agents.
    Type: Grant
    Filed: May 16, 2022
    Date of Patent: January 23, 2024
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Guanghui Zhu, Omer Refa Koseoglu
  • Patent number: 11879374
    Abstract: The present invention is directed to a method of preparing a molecular sieve of SWY framework type, denominated STA-30. STA-30 is synthesized using 1,4-diazabicyclo[2.2.2]octane, 1-azabicyclo[2.2.2]octane derivates and combinations thereof as structure directing agents. The resulting molecular sieve is useful as catalysts, particularly when used in combination with exchanged transition metal(s) for the Selective Catalytic Reduction (SCR) of NO.
    Type: Grant
    Filed: April 5, 2022
    Date of Patent: January 23, 2024
    Inventors: Ruxandra Georgiana Chitac, Nicholas McNamara, Alessandro Turrina, Paul Anthony Wright
  • Patent number: 11872543
    Abstract: A method of manufacturing a methane oxidation catalyst and methane oxidation catalysts formed by the method are provided. The method includes providing a palladium (Pd)-based catalyst including Pd dispersed onto a support. A magnesium (Mg) precursor is introduced to the Pd-based catalyst by one of ion exchange or incipient wetness impregnation. After introducing the magnesium precursor to the Pd-based catalyst, the catalyst is dried and subjected to a final heat treatment that includes hydrothermal calcination. A method of methane oxidation in a lean exhaust environment via the methane oxidation catalyst is also provided.
    Type: Grant
    Filed: May 9, 2022
    Date of Patent: January 16, 2024
    Assignee: UT-BATTELLE, LLC
    Inventors: Melanie M. Debusk, Sreshtha Sinha Majumdar, Josh A. Pihl
  • Patent number: 11865527
    Abstract: A hydroisomerization catalyst comprising a molecular sieve belonging to the ZSM-48 family of zeolites; an inorganic oxide support; one or more first modifiers selected from Groups 8 to 10; and one or more second modifiers selected from the group consisting of calcium (Ca), chromium (Cr), magnesium (Mg), lanthanum (La), barium (Ba), praseodymium (Pr), strontium (Sr), potassium (K) and neodymium (Nd). The molecular sieve comprises: a silicon oxide to aluminum oxide mole ratio of about 40 to about 220; at least about 70% polytype 6 of the total ZSM-48-type material present in the product; and an additional EUO-type molecular sieve phase in an amount of between about 0 and about 7.0 percent by weight of the total product. The molecular sieve has a morphology characterized as polycrystalline aggregates comprising crystallites collectively having an average aspect ratio of between about 1 and about 8.
    Type: Grant
    Filed: January 13, 2021
    Date of Patent: January 9, 2024
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Yihua Zhang, Adeola Florence Ojo, Guan-Dao Lei
  • Patent number: 11857955
    Abstract: A process of producing a catalyst comprises forming mesoporous beta zeolite particles, impregnating mesoporous beta zeolite particles with a metal and phosphorus to produce a metal and phosphorus impregnated zeolite, and incorporating the metal and phosphorus impregnated zeolite with clay and alumina to produce the catalyst. The forming step comprises converting a crystalline beta zeolite to a non-crystalline material with reduced silica content relative to the crystalline beta zeolite, and crystalizing the non-crystalline material to produce mesoporous beta zeolite particles.
    Type: Grant
    Filed: October 12, 2022
    Date of Patent: January 2, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Aaron Chi Akah, Veera Venkata Ramakrishna Tammana
  • Patent number: 11840580
    Abstract: A method for producing Metal Organic Framework (MOF) having a framework that encapsulates a bio-molecule, the method comprising combining in a solution the bio-molecule and MOF precursors, wherein the bio-molecule promotes formation of the encapsulating framework.
    Type: Grant
    Filed: February 2, 2021
    Date of Patent: December 12, 2023
    Assignee: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
    Inventors: Kang Liang, Raffaele Ricco, Cara Maxwell Doherty, Paolo Falcaro
  • Patent number: 11826737
    Abstract: Disclosed is a method of preparing a high-performance zeolite catalyst for reducing nitrogen oxide emissions, and more particularly a technique for preparing a zeolite catalyst, suitable for use in effectively removing nitrogen oxide (NOx), among exhaust gases emitted from vehicle internal combustion engines through selective catalytic reduction (SCR), thereby exhibiting high efficiency, high chemical stability and high thermal durability upon SCR using the prepared catalyst.
    Type: Grant
    Filed: December 22, 2021
    Date of Patent: November 28, 2023
    Assignees: Hyundai Motor Company, Kia Corporation, Heesung Catalysts Corporation
    Inventors: Pyung Soon Kim, Young Jin Kim, Chang Hwan Kim, Seung Chul Na, Seung Ho Oh, Young San Yoo, Ho Dong Kim
  • Patent number: 11819834
    Abstract: An aluminophosphate molecular sieve SCM-18 has a schematic chemical composition, expressed on a molar basis, of Al2O3.n P2O5, in which n represents a phosphorus to aluminum molar ratio, and is in a range of about 0.8-1.2. The aluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.
    Type: Grant
    Filed: September 19, 2019
    Date of Patent: November 21, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
    Inventors: Weimin Yang, Zhiqing Yuan, Jiawei Teng, Wenhua Fu, Songlin Liu
  • Patent number: 11801499
    Abstract: The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.
    Type: Grant
    Filed: June 25, 2021
    Date of Patent: October 31, 2023
    Assignee: PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED
    Inventors: Chularat Wattanakit, Chadatip Rodaum, Anawat Thivasasith, Sitthiphong Pengpanich
  • Patent number: 11779909
    Abstract: Disclosed is a hydrocracking catalyst, a preparation method and an application thereof. The catalyst comprises a carrier, silicon dioxide and active ingredients loaded on the carrier, wherein the carrier comprises Y molecular sieves and SAPO-34 molecular sieves. The preparation method of the hydrocracking catalyst comprises the following steps: (1) mixing materials comprising Y molecular sieves and SAPO-34 molecular sieves, and then subjecting the mixture to molding, drying and calcinating to obtain a carrier; (2) introducing silane and the active ingredients into the carrier prepared in the step (1), subsequently performing the drying and calcinating to prepare the hydrocracking catalyst. The catalyst prepared with the method can be used for hydrocracking reaction, thereby significantly increase yield of jet fuel.
    Type: Grant
    Filed: December 12, 2019
    Date of Patent: October 10, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Zhaoji Tang, Yanze Du, Hongfei Fan, Jifeng Wang, Zhengmin Yu, Xiaoyan Sun
  • Patent number: 11766667
    Abstract: A CON zeolite satisfying the following (1) to (2): (1) The framework is CON as per the code specified by the International Zeolite Association (IZA); and (2) It contains silicon and aluminum, and the molar ratio of aluminum to silicon is 0.04 or more.
    Type: Grant
    Filed: March 8, 2021
    Date of Patent: September 26, 2023
    Assignees: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Hiroaki Onozuka, Masahiro Hara, Masato Yoshioka, Toshiyuki Yokoi
  • Patent number: 11752487
    Abstract: Provided are a pentasil-type zeolite that is less likely to adsorb water compared to conventional zeolites and has excellent strength when used as a molded body, and a method for producing the pentasil-type zeolite. A pentasil-type zeolite having a water adsorption amount of 4.0 g/100 g-zeolite or less under the conditions of 25° C. and a relative humidity of 90% and having a major axis diameter of primary particles of from 0.2 ?m to 4.0 ?m, and a method for producing the pentasil-type zeolite.
    Type: Grant
    Filed: October 18, 2019
    Date of Patent: September 12, 2023
    Assignee: TOSOH CORPORATION
    Inventors: Hidenori Yamada, Hiroshi Okaniwa, Satoshi Yoshida
  • Patent number: 11753355
    Abstract: Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.
    Type: Grant
    Filed: April 30, 2020
    Date of Patent: September 12, 2023
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Howard Steven Lacheen, Hye-Kyung Cho Timken
  • Patent number: 11701615
    Abstract: This exhaust gas purifying catalyst is provided with a substrate and a catalyst layer formed on a surface of the substrate. The catalyst layer contains zeolite particles that support a metal, and a rare earth element-containing compound that contains a rare earth element. The rare earth element-containing compound is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite is 0.001 to 0.014 in terms of oxides.
    Type: Grant
    Filed: October 26, 2021
    Date of Patent: July 18, 2023
    Assignee: Cataler Corporation
    Inventors: Shu Miyasaka, Eriko Tanaka, Norihiko Aono, Mai Huong Tran, Keigo Hori, Daisuke Sugioka
  • Patent number: 11679987
    Abstract: A family of new crystalline molecular sieves designated SSZ-91 is disclosed, as are methods for making SSZ-91 and uses for SSZ-91. Molecular sieve SSZ-91 is structurally similar to sieves falling within the ZSM-48 family of molecular sieves, and is characterized as: (1) having a low degree of faulting, (2) a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, and (3) is substantially phase pure.
    Type: Grant
    Filed: May 11, 2021
    Date of Patent: June 20, 2023
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Adeola Florence Ojo, Dan Xie, Yihua Zhang, Guan-Dao Lei
  • Patent number: 11648541
    Abstract: Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.
    Type: Grant
    Filed: December 16, 2021
    Date of Patent: May 16, 2023
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: An-Hsiang Wu, Joseph Bergmeister
  • Patent number: 11628448
    Abstract: The invention provides a method for the production of a zeolite particle composition which has optimized characteristics, such as enhanced adsorption and specific ion exchange properties. A method and an apparatus for producing improved zeolite particle compositions are provided, where the particles are treated with an oxygen-containing gas during micronisation. The zeolite particle compositions can be used in a method for treatment of the human or animal body by therapy and/or prophylaxis, and specifically in a method of treating or preventing conditions of the human or animal body or symptoms of these conditions that are related to heavy metals, endotoxins, exotoxins, and/or bacterial, viral or parasitic intoxications in or of the digestive system, mucosal surfaces or the skin. Also, new zeolite particle compositions can be used as food additive, as filter for purification of water, in packaging materials, or as cosmetic ingredient.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: April 18, 2023
    Inventor: Jakob Hraschan
  • Patent number: 11618013
    Abstract: According to one or more embodiments, non-agglomerated, nano-sized ZSM-22 zeolites may be synthesized by methods comprising operating a mechanical rotation drum unit at a first temperature of from 40° C. to 60° C. and a first speed of from 200 rpm to 1000 rpm for a first time period of from 1.3 hours to 2.7 hours; operating the mechanical rotation drum unit at a second speed of from 30 rpm to 90 rpm for a second time period of from 0.05 hours to 0.4 hours; heating the mechanical rotation drum unit at a ramping temperature of from 8° C./minute to 12° C./minute to a second temperature of from 115° C. to 185° C. at the second speed; operating the mechanical rotation drum unit at the second temperature and the second speed for a third time period of from 30 hours to 90 hours; and cooling the mechanical rotation drum unit at a fourth speed of 0 rpm.
    Type: Grant
    Filed: March 19, 2021
    Date of Patent: April 4, 2023
    Assignees: Saudi Arabian Oil Company, King Fahd University of Petroleum & Minerals
    Inventors: Emad Al-Shafei, Oki Muraza, Anas Karrar Jamil, Ki-Hyouk Choi, Ashok K. Punetha, Zain Hassan Yamani
  • Patent number: 11618721
    Abstract: A method for isomerising dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V?, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.
    Type: Grant
    Filed: April 4, 2019
    Date of Patent: April 4, 2023
    Assignees: IFP Energies Nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Sylvie Maury, Vincent Coupard, Delphine Bazer-Bachi, Joseph Lopez, Nikolai Nesterenko, Guillaume Duplan, Colin Dupont
  • Patent number: 11602734
    Abstract: A method of producing a acid/metal bifunctional catalyst may include: mixing an acid catalyst, a metal catalyst, and a fluid to produce a slurry, wherein the acid catalyst is present at 50 wt % or less relative to a total catalyst weight in the slurry; heating the slurry; producing a powder from the slurry; and calcining the powder to produce the acid/metal bifunctional catalyst. Such acid/metal bifunctional catalyst would be useful in the direct conversion of syngas to dimethyl ether as well as other reactions.
    Type: Grant
    Filed: August 13, 2020
    Date of Patent: March 14, 2023
    Assignee: EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY
    Inventors: Chuansheng Bai, Majosefina Cunningham, Jihad M. Dakka, Preeti Kamakoti, Aruna Ramkrishnan, Anjaneya S. Kovvali, Anita S. Lee
  • Patent number: 11596932
    Abstract: Disclosed in the present invention is a tail gas treatment catalyst. The catalyst consists of a carrier, a first catalyst, and a second catalyst. The first catalyst and the second catalyst are provided on both ends of the carrier. The first catalyst can purify pollutants in tail gas. The second catalyst can purify a byproduct, ammonia, obtained by the purification by the first catalyst and pollutants that are not completely purified by the first catalyst. The second catalyst is of a double-layer structure; the lower layer consists of an oxygen storage material, aluminum oxide, and a second active component; the second active component is a composition of Pt and Pd, or a composition of Ce, Fe, Ni and Cu; the upper layer consists of a molecular sieve and a third active component; the third active component is Cu or a composition of Cu and Fe.
    Type: Grant
    Filed: May 30, 2019
    Date of Patent: March 7, 2023
    Assignee: Sinocat Environmental Technology Co., Ltd.
    Inventors: Yun Wang, Yi Dan, Hongyi Du, Zan Zhu, Tiantian Luo, Yanhua Zhang, Qin Wang, Yun Li, Qizhang Chen, Yongxiang Cheng
  • Patent number: 11590482
    Abstract: Provided is a catalytic washcoat having a catalyst component and an alumina binder, wherein the catalyst component includes an aluminosilicate molecular sieve having a beta (BEA) and/or chabazite (CHA) framework, and about 1 to about 10 weight percent of a base metal component comprising iron and/or copper, wherein said weight percent is based on the weight of the aluminosilicate molecular sieve.
    Type: Grant
    Filed: March 11, 2019
    Date of Patent: February 28, 2023
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Stuart David Reid, Alexander Nicholas Michael Green, Guy Richard Chandler
  • Patent number: 11571685
    Abstract: A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-116, is provided. SSZ-116 can be synthesized using 3-[(3,5-di-tert-butylphenyl)methyl]-1,2-dimethyl-1H-imidazolium cations as a structure directing agent. SSZ-116 may be used in organic compound conversion reactions and/or sorptive processes.
    Type: Grant
    Filed: September 17, 2020
    Date of Patent: February 7, 2023
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Stacey Ian Zones, Jesus Pascual, Dan Xie, Cong-Yan Chen
  • Patent number: 11549071
    Abstract: A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.
    Type: Grant
    Filed: August 9, 2021
    Date of Patent: January 10, 2023
    Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: Khalid R. Alhooshani, Saheed Adewale Ganiyu, Abdulkadir Tanimu
  • Patent number: 11547987
    Abstract: The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.
    Type: Grant
    Filed: November 27, 2019
    Date of Patent: January 10, 2023
    Assignee: FURUKAWA ELECTRIC CO., LTD.
    Inventors: Takao Masuda, Yuta Nakasaka, Takuya Yoshikawa, Sadahiro Kato, Masayuki Fukushima, Hiroko Takahashi, Yuichiro Banba, Kaori Sekine
  • Patent number: 11549070
    Abstract: A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.
    Type: Grant
    Filed: August 9, 2021
    Date of Patent: January 10, 2023
    Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: Khalid R. Alhooshani, Saheed Adewale Ganiyu, Abdulkadir Tanimu
  • Patent number: 11498061
    Abstract: A method of preparing a mesoporous Fe—Cu—SSZ-13 molecular sieve includes activating an aluminum source, a silicon source, an iron source and a copper source respectively; mixing the activated minerals with sodium hydroxide, water and a seed crystal at 25-90° C., while controlling feeding amounts of respective raw materials so that molar ratios of respective materials in a synthesis system are as follows: SiO2/Al2O3=10-100, SiO2/Fe2O3=30-3000, SiO2/CuO=1-100, Na2O/SiO2=0.1-0.5, H2O/SiO2=10-50, template/SiO2=0.01-0.5; adding an acid source to adjust pH of the system for first aging; and adding the acid source again to adjust the pH of the system for second aging to obtain aged gel; pouring an aged mixture into a kettle; cooling a crystallized product and filtering to remove a liquor; washing a filter cake; drying to obtain a solid; performing ion exchange; and filtering, washing and drying the solid to obtain powder; and placing the powder in a muffle furnace.
    Type: Grant
    Filed: December 27, 2018
    Date of Patent: November 15, 2022
    Inventors: Yuanyuan Yue, Ben Liu, Nangui Lv, Xiaojun Bao, Jie Liu, Tinhai Wang, Pei Yuan, Haibo Zhu, Zhengshuai Bai, Qingyan Cui
  • Patent number: 11458456
    Abstract: Process for the preparation of a catalyst and a catalyst comprising more than one silica is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized colloidal silica, greater than about 0 to about 30 wt % silica from ammonia stabilized or lower sodium colloidal silica, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with good performance.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: October 4, 2022
    Assignee: Albemarle Corporation
    Inventors: Amir Sabahi, Andrew Loebl, Sandra Gavalda, Julie Francis, Eswaramoorthi Iyyamperumal, Min Li, Andrea Marcinkova
  • Patent number: 11452985
    Abstract: The invention is to provide a method for producing a metal-supported zeolite for alcoholic beverages capable of efficiently removing unwanted components contained in alcoholic beverages to thereby reduce silver release, and the metal-supported zeolite for alcoholic beverages, and to provide a method for producing alcoholic beverages using the metal-supported zeolite for alcoholic beverages.
    Type: Grant
    Filed: February 15, 2016
    Date of Patent: September 27, 2022
    Assignees: IDEMITSU KOSAN CO., LTD., THE NIKKA WHISKY DISTILLING CO., LTD.
    Inventors: Shun Fukasawa, Yoshimi Kawashima, Narinobu Kagami, Kenji Hosoi, Toshikazu Sugimoto
  • Patent number: 11427764
    Abstract: Process for the preparation of a catalyst and a catalyst comprising the use of more than one silica source is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 15 to about 35 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized basic colloidal silica, greater than about 0 to about 30 wt % silica from acidic colloidal silica or polysilicic acid, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with a good accessibility.
    Type: Grant
    Filed: August 4, 2017
    Date of Patent: August 30, 2022
    Assignee: Albemarle Corporation
    Inventors: Amir Sabahi, Andrew J Loebl, Sandra Gavalda, Julie A Francis, Eswaramoorthi Iyyamperumal
  • Patent number: 11400421
    Abstract: In production of a zeolite membrane complex, a starting material solution containing at least a structure-directing agent and FAU-type zeolite particles having an average particle diameter of 50 to 500 nm is prepared. Then, a support is immersed in the starting material solution to form a zeolite membrane on the support by hydrothermal synthesis, the zeolite membrane being composed of AFX-type zeolite. After that, the structure-directing agent in the zeolite membrane is removed.
    Type: Grant
    Filed: August 11, 2021
    Date of Patent: August 2, 2022
    Assignee: NGK Insulators, Ltd.
    Inventors: Kenichi Noda, Makoto Miyahara
  • Patent number: 11291978
    Abstract: Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of impregnating the bound zeolite base with the transition metal, fluorine, and high loadings of chlorine. The resultant high chlorine content supported catalysts have improved catalyst activity in aromatization reactions.
    Type: Grant
    Filed: December 19, 2019
    Date of Patent: April 5, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Gabriela D. Alvez-Manoli
  • Patent number: 11278873
    Abstract: According to the subject matter of the present disclosure, a method of producing an aromatization catalyst may comprise producing a plurality of uncalcined ZSM-5 nanoparticles via a dry-gel method, directly mixing the plurality of uncalcined ZSM-5 nanoparticles with large pore alumina and a binder to form a ZSM-5/alumina mixture, and calcining the ZSM-5/alumina mixture to form the aromatization catalyst. The plurality of uncalcined ZSM-5 nanoparticles may have an average diameter of less than 80 nm.
    Type: Grant
    Filed: July 16, 2020
    Date of Patent: March 22, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Manal Al-Eid, Lianhui Ding, Essa Alnaimi
  • Patent number: 11229882
    Abstract: A monolithic separation membrane structure according to the present invention includes a porous support body and a separation membrane. The porous support body has a plurality of filtration cells opening at both end surfaces, a plurality of water collecting cells closed on the both end surfaces, a plurality of discharge flow paths running through the plurality of water collecting cells and opening on an outer peripheral surface, and a monolithic base body including the outer peripheral surface. The separation membrane is formed on inside surfaces of the plurality of filtration cells. The plurality of filtration cells includes a first filtration cell and a second filtration cell which are adjacent to each other. The plurality of water collecting cells include water collecting cell which is adjacent to the first filtration cell and are separated from the second filtration cells.
    Type: Grant
    Filed: September 12, 2018
    Date of Patent: January 25, 2022
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Teranishi, Kenji Yajima, Hideyuki Suzuki
  • Patent number: 11229898
    Abstract: A particulate material and a process for the production thereof are provided, which particulate material comprises zeolitic particles having a crystalline structure, which contain as the main component a zeolite material having a zeolitic framework structure formed from Si, O and optionally Al, and/or a zeolite-like material having a zeolitic framework structure which is formed not only from Si, O and optionally Al, wherein the zeolitic particles are in the form of essentially spherical particles with nanometer dimensions.
    Type: Grant
    Filed: December 28, 2016
    Date of Patent: January 25, 2022
    Assignee: Friedrich-Alexander-Universität Erlangen-Nürnberg
    Inventors: Wilhelm Schwieger, Albert Gonche Fortunatus Machoke
  • Patent number: 11202991
    Abstract: This exhaust gas purifying catalyst is provided with a substrate 10 and a catalyst layer 20 formed on a surface of the substrate 10. The catalyst layer 20 contains zeolite particles 22 that support a metal, and a rare earth element-containing compound 24 that contains a rare earth element. The rare earth element-containing compound 24 is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite 22 is 0.001 to 0.014 in terms of oxides.
    Type: Grant
    Filed: February 19, 2018
    Date of Patent: December 21, 2021
    Assignee: Cataler Corporation
    Inventors: Shu Miyasaka, Eriko Tanaka, Norihiko Aono, Mai Huong Tran, Keigo Hori, Daisuke Sugioka
  • Patent number: 11203555
    Abstract: The present invention provides a method of stabilizing a nitrate-based explosive through the use of a NOx scavenger. The present invention further provides a blasting agent including ammonium nitrate and a NOx scavenger. The present invention further provides for a method of blasting adapted for use in reactive and/or elevated temperature ground.
    Type: Grant
    Filed: September 1, 2016
    Date of Patent: December 21, 2021
    Inventors: James Kenneth Beattie, Alex Masato Djerdjev, Brian Stanley Hawkett, Chiara Neto, Pramith Priyananda
  • Patent number: 11185850
    Abstract: Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.
    Type: Grant
    Filed: December 2, 2019
    Date of Patent: November 30, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Munir D. Khokhar, Zahra Almisbaa, Sohel K. Shaikh, Raed Abudawoud
  • Patent number: 11185849
    Abstract: A catalyst includes a zeolite, wherein the zeolite has: a CHA framework; a particle size less than or equal to 100 nanometers; and a silica to alumina mole ratio in the range of about 50:1 to about 150:1. The catalyst can include a metal dopant. The catalyst can be used for purifying a product by flowing a reactant across the catalyst to form the product; and condensing or separating the product. The product can be an olefin or alkenes with an increased carbon chain. The catalyst can be used for selective catalytic reduction of nitrogen oxide or a gas to liquid reaction. A method of producing the catalyst can include selecting the concentration of a crystal growth inhibitor based on the ratio of the silica precursor and an alumina precursor such that the zeolite crystals have a mean particle size less than or equal to 100 nanometers.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: November 30, 2021
    Assignee: SABIC Global Technologies, B.V.
    Inventors: Dustin Fickel, Katherine Barton
  • Patent number: 11179705
    Abstract: A modified Y-type molecular sieve contains 0.5-2 wt. % of Na2O based on the total amount of the modified Y-type molecular sieve. In the modified Y-type molecular sieve, the ratio between the total acid amount measured by pyridine and infrared spectrometry and total acid amount measured by n-butyl pyridine and infrared spectrometry is 1-1.2. The total acid amount measured by pyridine and infrared spectrometry of the modified Y-type molecular sieve is 0.1-1.2 mmol/g. The acid center sites of the molecular sieve of the modified Y-type molecular sieve are distributed in the large pore channels. The molecular sieve is used in the hydrocracking reaction process of a wax oil.
    Type: Grant
    Filed: November 29, 2017
    Date of Patent: November 23, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Wei Liu, Minghua Guan, Yanze Du, Fenglai Wang, Bo Qin, Hang Gao
  • Patent number: 11167245
    Abstract: This exhaust gas purifying catalyst is provided with a substrate 10 and a catalyst layer 20 formed on a surface of the substrate 10. The catalyst layer 20 contains zeolite particles 22 that support a metal, and a rare earth element-containing compound 24 that contains a rare earth element. The rare earth element-containing compound 24 is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite 22 is 0.001 to 0.014 in terms of oxides.
    Type: Grant
    Filed: February 19, 2018
    Date of Patent: November 9, 2021
    Assignee: Cataler Corporation
    Inventors: Shu Miyasaka, Eriko Tanaka, Norihiko Aono, Mai Huong Tran, Keigo Hori, Daisuke Sugioka
  • Patent number: 11161093
    Abstract: A nanomaterial catalyst comprising a partially crystalline porous magnesium silicate support and gold nanoparticles, the catalyst being useful for oxidative cracking of hydrocarbons, specifically the production of light olefins from propane. Methods of producing the nanomaterial catalyst as well as a method of oxidative cracking of a hydrocarbon to produce light olefins are provided.
    Type: Grant
    Filed: April 16, 2021
    Date of Patent: November 2, 2021
    Assignee: King Abdulaziz University
    Inventors: Katabathini Narasimharao, Sulaiman Nasir Basahel, Abdulmohsen Al Shehri, Fawaz Saleh Al-Sultan