Optical Clarity Patents (Class 526/937)
  • Patent number: 8927650
    Abstract: There are provided a radical polymerizable composition having a low viscosity suitable for coating and a cured product and a plastic lens each obtained by curing the composition, the cured product having a high refractive index, good adhesiveness to a plastic film substrate, and good adhesiveness kept even under high-temperature and high-humidity conditions. The radical polymerizable composition includes phenylbenzyl (meth)acrylate (A), an epoxy (meth)acrylate (X) having an aromatic ring in its molecular structure, and a radical polymerization initiator (Y) as essential components.
    Type: Grant
    Filed: December 30, 2013
    Date of Patent: January 6, 2015
    Assignee: DIC Corporation
    Inventors: Nobuo Kobayashi, Akihiro Kondo, Atsuhisa Miyawaki, Naoya Ikushima, Kazuaki Hatsusaka
  • Patent number: 8344083
    Abstract: The present invention relates to a transparent resin composition which comprises (a) a (meth)acrylate based unit comprising one or more (meth)acrylate based derivatives; (b) an aromatic based unit having a chain having the hydroxy group containing portion and an aromatic moiety and (c) a styrene-based unit comprising one or more styrene-based derivatives, and an optical film that is formed by using the same.
    Type: Grant
    Filed: May 4, 2009
    Date of Patent: January 1, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Jun-Geun Um, Min-Hee Lee, Nam-Jeong Lee, Jong-Hun Lee, Dong-Ryul Kim, Sae-Han Cho
  • Patent number: 7985356
    Abstract: A non-linear optical device comprising a polymer configured to be photorefractive upon irradiation by a green laser. The polymer comprises a repeating unit including a moiety selected from the group consisting of the structures (M-1), (M-2) and (M-3), as defined herein.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: July 26, 2011
    Assignee: Nitto Denko Corporation
    Inventors: Michiharu Yamamoto, Peng Wang
  • Patent number: 7842740
    Abstract: Provided are an optical resin and an optical member using the same, both orientation birefringence and photoelasticity birefringence of the optical material being deadened and generally eliminated. The optical material consists of a composite constituent system of three or more constituents including a copolymerization system of monomer-element number not smaller than two, combination and constituent ratio of the composite constituent system being set so that both orientation birefringence and photoelasticity birefringence of the optical material are deadened at the same time and 5.0×10?5 or less is given under a condition that principal chains of the copolymerization system have degree of orientation equal to 0.03, and further a photoelasticity constant not greater than 1.0×10?12 (Pa?1) is obtained. The composite constituent system may contain an additive containing a low molecular weight compound which has an anisotropic polarizability and can be orientated in a polymer.
    Type: Grant
    Filed: April 18, 2006
    Date of Patent: November 30, 2010
    Inventor: Yasuhiro Koike
  • Patent number: 7736548
    Abstract: A non-linear optical device comprising a polymer configured to provide a grating holding ratio of 20% or higher after about four minutes, wherein the polymer comprises a first repeating unit comprising a first moiety having formula (M-1) and a second repeating unit comprising a second moiety having formula (M-2), as defined herein.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: June 15, 2010
    Assignee: Nitto Denko Corporation
    Inventors: Michiharu Yamamoto, Peng Wang
  • Patent number: 6914113
    Abstract: A method of modifying a polyethylene material is accomplished by providing a polyethylene resin. The initial rheological breadth of the polyethylene resin is determined. The resin is then modified to adjust the rheological breadth of the polyethylene from the initial rheological breadth to a different rheological breadth that corresponds to a desired resin property, such as haze. A method for predicting clarity and rheological breadth properties is also provided, which utilizes a template of measured properties for polyethylene resins.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: July 5, 2005
    Assignee: Fina Technology, Inc.
    Inventors: Michael McLeod, Gerhard Guenther, Nguong van Nguyen
  • Patent number: 6794474
    Abstract: The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.
    Type: Grant
    Filed: December 8, 2003
    Date of Patent: September 21, 2004
    Assignee: Essilor International Compagnie Generale d'Optique
    Inventors: Gilles Richard, Odile Primel, Leanirith Yean
  • Patent number: 6355307
    Abstract: Clear lacquer coating media suitable for multi-layer coatings, containing self-crosslinking or externally crosslinkable binder vehicles, organic solvents, and in the case of externally-crosslinkable binder vehicles containing one or more crosslinking agents which are different from aldehyde condensation resins, and optionally also containing one or more reactive thinners and customary additives for clear lacquers, with an additional content of A) 0.1 to 3% by weight one or more urea compounds, and B) 0.05 to 10% by weight one or more substances which supply formaldehyde, with respect in each case to the resin solids content which is formed by the binder vehicles, reactive thinners and crosslinking agents.
    Type: Grant
    Filed: March 16, 2000
    Date of Patent: March 12, 2002
    Assignee: Dupont Performance Coatings GmbH & Co.
    Inventors: Stephan Brenke, Karl-Friedrich Dössel, Friedrich Herrmann, Heinz-Walter Reifferscheidt
  • Patent number: 5326843
    Abstract: An emulsion polymerization process for making a low molecular weight alkali-soluble copolymer of a water insoluble monoethylenically unsaturated aromatic monomer and methacrylic acid, includes heating an aqueous reaction mixture, said reaction mixture having a pH of less than or equal to about 4.5 and including from about 25 parts by weight to about 75 parts by weight of the water insoluble monoethylenically unsaturated aromatic monomer; from about 25 parts by weight to about 75 parts by weight methacrylic acid; a polymerization initiator; a reducing agent; a catalyst effective for promoting decomposition of the polymerization initiator in the presence of the reducing agent; and an amount of a chain transfer agent effective to limit copolymer weight average molecular weight to a range of about 2,000 to about 40,000; to a temperature greater than or equal to about 75.degree. C.; and maintaining the reaction mixture at a temperature greater than or equal to about 75.degree. C.
    Type: Grant
    Filed: October 4, 1993
    Date of Patent: July 5, 1994
    Assignee: Rohm and Haas Company
    Inventors: Dennis P. Lorah, Thomas G. Madle
  • Patent number: 5198305
    Abstract: A novel optical element substrate which comprises a random copolymer comprising, in specific weight proportions, a methyl methacrylate unit, an aromatic vinyl compound unit, an unsaturated aliphatic acid unit and a hexagonal acid anhydride unit of the formula ##STR1## The substrate has excellent heat resistance, thermal stability, transparency, resistance to scratching and metal layer corrosion preventive properties and exhibits advantageously low double refraction and warpage. The novel substrate can be advantageously employed as a substrate for an optical element such as an optical disc, e.g. a digital audio disc, a video disc and a disc capable of being directly read after recording, a mirror, a lens and the like.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: March 30, 1993
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Akihiro Wada, Rin-ichi Kakuta
  • Patent number: 5081315
    Abstract: Compounds of the formula ##STR1## in which A represents the radicals ##STR2## in which R.sup.1 and R.sup.2 are different from one another and denote hydrogen, --NO.sub.2 or --NH.sub.2, R.sup.3 is hydrogen or halogen, X represents --NO.sub.2 or --NH.sub.2, with the proviso that R.sup.1 is hydrogen, if R.sup.2 is --NO.sub.2 or --NH.sub.2 and R.sup.2 is hydrogen, if R.sup.1 is --NO.sub.2 or --NH.sub.2.The compounds are prepared from 4,4'-bis[2-(4-hydroxyphenyl)hexafluoroisopropyl]diphenyl ether by nitration or reaction with nitrobenzenes followed by reduction of the nitro groups. They are used for the preparation of high-temperature-resistant polycondensates.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: January 14, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Lau, Gunter Siegemund
  • Patent number: 5026805
    Abstract: Optical materials having well balanced properties such as high heat resistance, low hygroscopicity and low double refractivity. The optical materials are derived from a low hygroscopic, random copolymer comprising units of methacrylic acid and ester derivatives, and units of a six-membered ring acid anhydride.
    Type: Grant
    Filed: December 1, 1989
    Date of Patent: June 25, 1991
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Hosoya, Ikuji Ohtani, Kimio Imaizumi
  • Patent number: 4978790
    Abstract: Compounds of the formula ##STR1## in which A represents the radicals ##STR2## in which R.sup.1 and R.sup.2 are different from one another and denote hydrogen, --NO.sub.2 or --NH.sub.2, R.sup.3 is hydrogen or halogen, X represents --NO.sub.2 or --NH.sub.2, with the proviso that R.sup.1 is hydrogen, if R.sup.2 is --NO.sub.2 or --NH.sub.2 and R.sup.2 is hydrogen, if R.sup.1 is --NO.sub.2 or --NH.sub.2.The compounds are prepared from 4,4'-bis[2-(4-hydroxyphenyl)hexafluoroisopropyl]diphenyl ether by nitration or reaction with nitrobenzenes followed by reduction of the nitro groups. They are used for the preparation of high-temperature-resistant polycondensates.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: December 18, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Lau, Gunter Siegemund
  • Patent number: 4939190
    Abstract: An aqueous emulsion-type pressure sensitive adhesive characterized in that the aqueous emulsion is prepared by(i) a first step of emulsion polymerizing an ethylenically unsaturated monomer composed essentially of at least one type of styrene, alpha-methylstyrene, acrylonitrile, methyl methacrylate and vinyltoluene in the presence of an emulsion composed of at least one tackifier resin selected from a rosin ester, a petroleum resin and a terpene resin to form an aqueous emulsion containing particles of a two-layered structure having a core layer of the tackifier resin and a layer of a polymer (polymer A.sub.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: July 3, 1990
    Assignee: Dainippon Ink And Chemicals, Inc.
    Inventors: Reizaburo Tomioka, Yasuhiro Shigematsu
  • Patent number: 4725397
    Abstract: This invention provides novel thermosetting preform having superior transparency which is composed of the resin produced by partially polymerizing the mixture of (A) 4 to 30 wt % of at least one vinyl monomer containing carboxyl group, (B) 4 to 96 wt % of at least one vinyl monomer containing glycidyl group, and (C) up to 92 wt % of at least one copolymerizable monomer, said preform being characterized in that the amount of unreacted monomer remaining therein is less than 20 wt % and the glass transition temperature range is 120.degree. C. or lower. This invention also provides a method of production of a highly transparent molded article with high productivity which is superior in heat resistance and in chemical resistance by heating and molding said preform.
    Type: Grant
    Filed: November 25, 1985
    Date of Patent: February 16, 1988
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Jun Nakauchi, Shunsuke Minami
  • Patent number: 4628071
    Abstract: An emulsion polymer of a water insoluble vinylic monomer and an acrylic monomer is formed by precharging a portion of the acrylic monomer and thereafter adding a comonomer charge corresponding to the final desired composition of the vinylic monomer and acrylic monomer at an addition rate generally corresponding to the steady state monomers concentration. A high non-volatiles content is maintained to inhibit the acrylic monomer from partitioning into the aqueous phase.
    Type: Grant
    Filed: August 16, 1985
    Date of Patent: December 9, 1986
    Assignee: S. C. Johnson & Son, Inc.
    Inventor: Lee W. Morgan