Abstract: This invention relates to the new norbornanyl rosin resin compositions which are easily obtainable by reacting the norbornenyl compounds or their alpha, beta-unsaturated esters with rosin derivative. In particular, this invention relates to a new process for making hybrid rosin resin suitable for production adhesive, ink, coating, plasticizer, thermoplastic or thermosetting plastic and functional polymers.

Abstract: The present invention relates to a method for preparing a functional film via coffee oil, comprising (a) extracting a coffee oil from coffee; (b) modifying the coffee oil to obtain an epoxidized coffee oil; (c) adding an alcohol into the epoxidized coffee oil to obtain a coffee polyol; (d) synthesizing a polyurethane dispersive solution with the coffee polyol; (e) coating a surface of a substrate with the polyurethane dispersive solution; and (f) drying and fixing the surface of the substrate. The present invention further provides a functional textile comprising a functional film prepared by the method of above.

Abstract: A polyester resin is a polycondensate obtained by reacting a divalent alcohol, a divalent carboxylic acid, and a mono- or divalent rosin by the use of a zinc compound as a reaction catalyst.

Abstract: This invention relates to the new norbornanyl rosin resin compositions which are easily obtainable by reacting the norbornenyl compounds or their alpha, beta-unsaturated esters with rosin derivative. In particular, this invention relates to a new process for making hybrid rosin resin suitable for production adhesive, ink, coating, plasticizer, thermoplastic or thermosetting plastic and functional polymers.

Abstract: Oil compositions having a high concentration of polyunsaturated fatty acids are described for use in various applications including use as drying oils, in ink compositions and coating compositions. Oil compositions wherein the double bonds of the fatty acids are substantially epoxidized are described and used as plasticizers and thermal stabilizers for various halogenated polymer compositions.

Abstract: Disclosed is a polyester resin containing the polycondensation product of (a) at least one diacid, acid ester, or diester, and (b) at least two diols. The at least two diols include a disproportionated rosin diol and 2,2-bis(4-hydroxyphenyl)propane. Also disclosed is a toner composition having particles which include the disclosed polyester resin. Further disclosed is a method of preparing the disclosed polyester resin, and a method of forming toner particles that includes the disclosed polyester resin.

Abstract: An adhesive composition for use in adhering insulation panels to roofing substrates and roofing membranes to the insulation panels include two components that are mixed prior to application on the roofing substrate. The first component may include a renewable polyol and catalyst. The renewable polyol is selected from any non-petroleum based polyol that is derived from a renewable source. The second component includes isocyanate, and may also include a polyol and a catalyst. The isocyanate and the polyol may each be any non-petroleum based isocyanate or polyol that is derived from a renewable source.

Abstract: Disclosed is a polyester resin comprising the polycondensation product of (a) at least one diacid, acid ester, or diester; and (b) at least one diol; wherein either (i) at least one diacid, acid ester, or diester comprises a rosin diacid, rosin acid ester, or rosin diester; or (ii) at least one diol comprises a rosin diol, and wherein at least one of the rosin diacid, rosin acid ester, rosin diester, or rosin diol is either (A) an ester of a functionalized rosin or an ester of a reduced functionalized rosin, or (B) a dimerized rosin. Also disclosed is a toner composition comprising particles which comprise the disclosed polyester resin and an optional colorant.

Abstract: Disclosed is a polyester resin comprising the polycondensation product of (a) at least one diacid, acid ester, or diester; and (b) at least one diol; wherein either (i) at least one diacid, acid ester, or diester comprises a rosin diacid, rosin acid ester, or rosin diester; or (ii) at least one diol comprises a rosin diol. Also disclosed is a toner composition comprising particles which comprise the disclosed polyester resin and an optional colorant.

Abstract: The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.

Abstract: A polyester for a toner, obtainable by polycondensing an alcohol component and a carboxylic acid component containing a (meth)acrylic acid-modified rosin; and a toner containing the polyester for a toner. The polyester for a toner of the present invention is usable as a resin binder for a toner usable in, for example, developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.

Abstract: Disclosed is a polyester resin comprising the polycondensation product of (a) at least one diacid, acid ester, or diester; and (b) at least one diol; wherein either (i) at least one diacid, acid ester, or diester comprises a rosin diacid, rosin acid ester, or rosin diester; or (ii) at least one diol comprises a rosin diol, and wherein at least one of the rosin diacid, rosin acid ester, rosin diester, or rosin diol is either (A) an ester of a functionalized rosin or an ester of a reduced functionalized rosin, or (B) a dimerized rosin. Also disclosed is a toner composition comprising particles which comprise the disclosed polyester resin and an optional colorant.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, particularly to provide a synthetic macromolecular network for a wide variety of tissue types. In particular, artificial or synthetic cartilage, vocal cord material, vitreous material, soft tissue material and mitral valve material are described. In an embodiment, the network is composed of tyramine-substituted and cross-linked hyaluronan molecules, wherein cross-linking is achieved via peroxidase-mediated dityramine-linkages that can be performed in vivo. The dityramine bonds provide a stable, coherent hyaluronan-based hydrogel with desired physical properties.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, particularly to provide a synthetic macromolecular network for a wide variety of tissue types. In particular, artificial or synthetic cartilage, vocal cord material, vitreous material, soft tissue material and mitral valve material are described. In an embodiment, the network is composed of tyramine-substituted and cross-linked hyaluronan molecules, wherein cross-linking is achieved via peroxidase-mediated dityramine-linkages that can be performed in vivo. The dityramine bonds provide a stable, coherent hyaluronan-based hydrogel with desired physical properties.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, particularly to provide a synthetic macromolecular network for a wide variety of tissue types. In particular, artificial or synthetic cartilage, vocal cord material, vitreous material, soft tissue material and mitral valve material are described. In an embodiment, the network is composed of tyramine-substituted and cross-linked hyaluronan molecules, wherein cross-linking is achieved via peroxidase-mediated dityramine-linkages that can be performed in vivo. The dityramine bonds provide a stable, coherent hyaluronan-based hydrogel with desired physical properties.

Abstract: A non-water soluble polymeric surfactant is prepared by reacting a polymerized/bodied unsaturated oil with maleic anhydride followed by a further partial or complete reaction with an amine to form an amide; or an alcohol to form an ester.

Abstract: The present invention relates to new (meth)acrylate compositions, their preparation and their use in ultraviolet light curable applications such as coatings, inks and adhesives.

Abstract: The specification describes a process for making gelled ink resins which exhibit improved properties such as lower viscosity under low shear and less viscosity decrease with increasing shear. In a preferred embodiment, a rosin-based or hydrocarbon-based resin is mixed with an organic solvent and reacted with a polyamine reactant, such as melamine-formaldehyde resin or hexamethylene diamine, under conditions sufficient to produce a substantially covalently cross-link gelled resin. The resulting gelled resin resists viscosity breakdown under high shear conditions and may be used directly for making ink compositions, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.

Abstract: A compound having the following structure: where: R1 through R9 are each independently —H, —OH, an alkoxy group, an acyloxy group, an amino group, an amido group, a sulfate group, a sulfonate group, a phosphate group, a phosphonate group, or a silicone group having the following structure: where R10 through R11 are each independently —H or an alkyl group; and n and o are independently integers from 2 to 100, where at least one of R1 through R9 is an alkoxy group, acyloxy group, amino group, amido group, sulfate group, sulfonate group, phosphate group, phosphonate group, or silicone group.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, particularly to provide a synthetic, implantable tissue matrix material for a wide variety of tissue types. In particular, artificial or synthetic cartilage, vocal cord material, vitreous material, soft tissue material and mitral valve material are described. In an embodiment, the network is composed of tyramine-substituted and cross-linked hyaluronan molecules, wherein cross-linking is achieved via peroxidase-mediated dityramine-linkages that can be performed in vivo. The dityramine bonds provide a stable, coherent hyaluronan-based hydrogel with desired physical properties.

Abstract: The present invention is drawn to surface-crosslinked latex particulates, corresponding latex suspensions, ink-jet inks, and methods for making the latex particulates. A latex suspension can include a fluid medium and surface-crosslinked latex particulates. The surface-crosslinked latex particulates can be devoid of substantially all crosslinking below the particulate surface. Such surface-crosslinked latex particulates can be prepared with a plurality of monomers and at least one crosslinking agent.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, such as artificial or synthetic cartilage. The network is made by first providing a polyamine or polycarboxylate macromolecule (having a plurality of amine or carboxylic acid groups respectively attached along the length of the molecule), reacting this macromolecule with a hydroxyphenyl compound having a free carboxylic acid group in the case of a polyamine or a free primary amine group in the case of a polycarboxylate, and substituting the hydroxyphenyl compound onto the macromolecule via a carbodiimide-mediated reaction pathway to provide a hydroxyphenyl-substituted macromolecule. This macromolecule is then linked to other such macromolecules via an enzyme catalyzed dimerization reaction between two hydroxyphenyl groups attached respectively to different macromolecules under metabolic conditions of temperature and pH.

Abstract: A method of depolymerizing galactomannan-type polysaccharide polymers and xanthan, preferably galactomannans, to a pre-selected lower molecular weight by irradiation with high energy electron beams. The preferred galactomannans for treatment according to this method are guar gum, guar splits and hydroxypropyl guar. In a preferred embodiment the guar gum is depolymerized preferably to a molecular weight of about 150,000 Daltons to about 200,000 Daltons. The depolymerized guar has a polydispersity of less than about 3.0 and is useful in oil well fracturing to enhance oil production.

Abstract: An organopolysiloxane-modified polysaccharide prepared by esterification reacting (A) an organopolysiloxane having residual carboxylic anhydride groups and (B) a polysaccharide having hydroxyl groups, wherein the organopolysiloxane is bonded to the polysaccharide through half ester groups, and a process for the preparation of organopolysiloxane-modified polysaccharide, in which component (A) and component (B) are subjected to an esterification reaction in the presence of (C) a non-protonic polar solvent. The organopolysiloxane-modified polysaccharide comprising polysaccharide and organopolysiloxane bonded thereto through half ester groups is novel. The process for the preparation of organopolysiloxane-modified polysaccharide permits introduction of organopolysiloxane into polysaccharide at a high introduction ratio.

Abstract: Methods of forming intermediates from PHAs are disclosed.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, such as artificial or synthetic cartilage. The network is made by first providing a polyamine or polycarboxylate macromolecule (having a plurality of amine or carboxylic acid groups respectively attached along the length of the molecule), reacting this macromolecule with a hydroxyphenyl compound having a free carboxylic acid group in the case of a polyamine or a free primary amine group in the case of a polycarboxylate, and substituting the hydroxyphenyl compound onto the macromolecule via a carbodiimide-mediated reaction pathway to provide a hydroxyphenyl-substituted macromolecule. This macromolecule is then linked to other such macromolecules via an enzyme catalyzed dimerization reaction between two hydroxyphenyl groups attached respectively to different macromolecules under metabolic conditions of temperature and pH.

Abstract: A crosslinking agent that is an ungelled reaction product of (a) at least one aminoplast resin and (b) at least one tall oil rosin wherein the crosslinking agent is essentially free of active hydrogen functional groups and has a glass transition temperature of at least 10° C. is disclosed. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating composition and substrates coated therewith are also disclosed.

Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, such as artificial or synthetic cartilage. The network is made by first providing a polyamine or polycarboxylate macromolecule (having a plurality of amine or carboxylic acid groups respectively attached along the length of the molecule), reacting this macromolecule with a hydroxyphenyl compound having a free carboxylic acid group in the case of a polyamine or a free primary amine group in the case of a polycarboxylate, and substituting the hydroxyphenyl compound onto the macromolecule via a carbodiimide-mediated reaction pathway to provide a hydroxyphenyl-substituted macromolecule. This macromolecule is then linked to other such macromolecules via an enzyme catalyzed dimerization reaction between two hydroxyphenyl groups attached respectively to different macromolecules under metabolic conditions of temperature and pH.

Abstract: This invention provides thermosetting adhesives which have properties advantageous for bonding electronic parts that are capable of being cured using a low dose of radiation such as electron beam. The thermosetting adhesive of the invention comprises (a) ethylene-glycidyl (meth)acrylate copolymer; (b) rosin having a carboxyl group; and (c) (meth)acrylate having a carboxyl group.

Abstract: An improved hot-melt-type adhesive is improved by including in the hot-melt-type adhesive the reaction product of pine rosin with formaldehyde. The addition of the pine rosin/formaldehyde reaction product improves the separation of the adhesive from the substrate in an alkaline washing bath. The adhesive precipitates as a coarsely dispersed non tacky form and can be easily removed from the washing bath.

Abstract: In a process for the metal-catalyzed preparation of copolymers of carbon monoxide and an olefinically unsaturated compound having from 2 to 20 carbon atoms in an aqueous medium, the copolymerization is carried out in the presence of a water-soluble macromolecular host compound which has a hydrophobic cavity and a hydrophilic shell.

Abstract: The invention is directed to a hybrid polymer material or system that combines naturally occurring building blocks with synthetic building blocks. The sets of naturally occurring and synthetic building blocks are mixed and joined on a molecular or nanoscopic level to give homogeneous or microphase-separated morphologies to the resulting mixed polymer system. These hybrid polymers combine the comfort attributes of natural materials with the robustness and design properties of synthetic materials.

Abstract: A graft polymer comprises a carbohydrate polymer having pendant 3-amino-2-hydroxy propyl groups grafted thereon and may be employed as a retention aid and strengthening additive in paper manufacture. When the carbohydrate polymer is a component of wood pulp the resulting chemically modified wood pulp may be employed in conjunction with unmodified wood pulp to incorporate therein the retention and strengthening characteristics.

Abstract: A method for making natural oil-based polyols directly from vegetable or animal oil using a consecutive two-step process involving epoxidation and hydroxylation is provided. Specifically, this process comprises adding a peroxyacid to a natural oil wherein said natural oil and said peroxyacid react to form an epoxidized natural oil and adding said epoxidized natural oil to a mixture of an alcohol, water, and a fluoboric acid catalyst. The catalytic amount of fluoboric acid is less than about 0.5% by weight of the entire reaction mixture, and the amount of water is about 10 to 30% by weight of the entire mixture. The epoxidized natural oil undergoes hydroxylation and forms a natural oil-based polyol. The present invention further includes a method for making natural oil-based polyols from epoxidized oil by hydroylating the epoxidized oil in the presence of fluoboric acid, alcohol and water in the amounts discussed above.

Abstract: This invention relates to novel rosin-based resins and the process for preparing them. In particular, the invention relates to elastomeric-modified pigment binder compositions which exhibit properties that make them useful in formulating vehicles for lithographic printing inks and other coating applications.

Abstract: Vibration-absorbing elastomeric composites, having improved vibration-damping properties with improved moldability and resin properties suitable for molded products, are obtained by reacting, insitu in a melted thermoplastic resin such as olefin-diene copolymer, a polyisocyanate with a polyol to form a polyurethane having a nitrogen atom content of at least 3% and having a solubility parameter which is higher by at least 2.5 than that of said thermoplastic resin.

Abstract: A chemical emulsifier useful to produce a cationic asphalt emulsion of different breaking characteristics, to be applied in road construction and maintenance, the emulsifier comprising a compound obtained by the reaction between a natural wood resin, colophony resin and an amine, whereby, as a result of said reaction, water is liberated as a by-product and primary, secondary and tertiary amino groups are incorporated as substituents to the resin molecules.

Abstract: A flushing vehicle for lithographic inks is the reaction product of a tall oil rosin-modified maleic ester resin with an acid number of less than about 30, and about 2-16 wt. %, based on the weight of the ester, of a polyamide resin with an amine number less than about 110. The flushing vehicle is prepared by heating a reaction mixture containing the rosin-modified ester and the polyamide resin to a temperature of about 190.degree.-280.degree. C.; and holding at a temperature of 190.degree.-280.degree. C. until the viscosity of the reaction mixture becomes constant.

Abstract: Oil-soluble, phenolic resin-modified natural resinic acid esters, which are able to form self-gelling mineral oil solutions and in the form of gel varnishes can advantageously be used as binder resins in printing inks for offset printing and letterpress printing, and also processes for their preparation from natural resins, phenols, aldehydes, condensation catalyst, esterifying agents and modifiers by reaction of the components at temperatures in the range from 80.degree. to 300.degree. C., individual components preferably being initially introduced and the other components being metered in, the combined use of a magnesium compound as condensation catalyst and the continuous removal of the water of reaction during the condensation reaction by azeotropic distillation with co-use of an inert organic solvent as distillative entraining agent being necessary and decisive for the self-gelling property of the process product.

Abstract: A catalyst selected from a perfluorosulfonic acid and an anhydride thereof enables a non-conjugated drying oil to react with a phenol to form a phenol-added vegetable oil without causing hydrolysis of the non-conjugated drying oil. The phenol-added vegetable oil is allowed to react with an aldehyde to form a vegetable oil-modified phenolic resin. A laminate produced by impregnating paper with the vegetable oil-modified phenolic resin and laminating and molding the impregnated paper is excellent in low temperature punching quality and electrical properties and is free from low molecular weight components oozing out the surface of the laminate.

Abstract: Novel graft copolymers of shellac and a polyalkyleneglycol monomethacrylate are prepared. These graft copolymers are useful in preparing water-based flexographic, i.e. packaging laminating inks, comprised of a pigment; the graft copolymer; a binder resin; an alkanol; an alkali, ammonia or an amine; and water.

Abstract: Alkali-soluble resins, their preparation and use are disclosed herein. The resins are carboxylated polyamide/acrylic resins and are synthesized in a two-step fusion process in which a polyamide is first condensed with a carboxylated rosin and this intermediate product is then further condensed with an acrylic or styrene/acrylic copolymer.

Abstract: The product of the reaction of a metal resinate and an amine-reactive polyamide is useful as the vehicle of publication gravure printing inks, resulting in prints that have superior properties such as holdout, gloss, and color development.

Abstract: Disclosed are edible film coating compositions of low moisture permeability and their methods of preparation. The compositions comprise cross-linked, refined shellac and preferably an edible member having a reactive hydroxyl or acid moiety selected from the group consisting of edible sources of polyphenolics, edible sources of benzaldehyde and derivatives, acetylated monoglycerides, polyglycerol esters, edible straight chain mono-carboxylic acid, edible di-carboxylic acids and mixtures thereof. Useful weight ratios of shellac to reactant range from 1:0.001 to 0.1. In the preferred method of preparation, the shellac is cross-linked with the reactants in a dry, molten mixture by heating at 130.degree. to 175.degree. C. for 2 to 15 minutes. The resulting coating compound while molten is dissolved in a food grade solvent, applied to a substrate and dried.

Abstract: A polyamide resin composition is described, which is characterized by blending a polyamide resin with a composition (A) comprising (i) either polyamide-rubber copolymer or polyolefin resin, and (ii) a tackiness providing resin wherein either said polyamide-rubber copolymer or the polyolefin resin is from 80 to 20% by weight based on the composition (A), and the tackiness providing resin is from 20 to 80% by weight based on the composition (A).

Abstract: The product of the reaction of a metal resinate and an amine-reactive polyamide is useful as the vehicle of publication gravure printing inks, resulting in prints that have superior properties such as holdout, gloss, and color developement.

Abstract: A urethane modified resin is prepared by reacting a resin containing carboxyl groups with an amine-alcohol to form a resin-amine salt, followed by reacting the resin-amine salt with a polyisocyanate.

Abstract: A rubber composition comprising (a) 100 parts by weight of a rubber selected from the group consisting of natural rubber and synthetic diene rubbers and (b) about 1 to about 30 parts by weight of a rosin derivative comprising a blend of (i) about 15 to about 50% by weight of a rosin, (ii) about 10 to about 70% by weight of a polymerized rosin and (iii) not more than about 55% by weight of a rosin pitch, each based on the weight of the rosin derivative.

Abstract: The process for preparing a resin metal salt involves reacting a resin containing a carboxyl group and/or an anhydride group in the state of a solution in a solvent with a hydroxide, oxide or carbonate of a divalent metal in the presence of ammonia or an amine. The resin metal salts so prepared are useful as binders in inks, paints, and adhesives.

Abstract: Process for preparing printing ink binders based on reaction products of (a) natural resins, (b) other synthetic resins, (c) .alpha.,.beta.-olefinically unsaturated carboxylic acid units and (d) calcium compounds and, if appropriate, other compounds of metals of group II of the periodic system.The compounds (a) to (c) are reacted to give a product having an acid number of 75 to 150, which is then reacted with metal compounds in such a way that the acid number is reduced by at least one third. Unreacted metal compounds present in the resulting reaction product are then converted by means of acetic acid, via acetates, into salts of the resins. The resulting binders are used for preparing printing inks.