Polymer Of Indefinite Molecular Weight Patents (Class 585/17)
  • Patent number: 10611703
    Abstract: Methods and systems for recovering dicyclopentadiene from pygas are provided. Methods can include heating pygas to generated heated pygas, recovering a C5 fraction from the heated pygas, and dimerizing cyclopentadiene from the C5 fraction to form dicyclopentadiene. Methods can further include recovering the C5 fraction from the pygas in a depentanizer column. Other methods can include heating pygas including dicyclopentadiene to form cyclopentadiene and hydrogenating cyclopentadiene in the pygas to form cyclopentane.
    Type: Grant
    Filed: December 6, 2016
    Date of Patent: April 7, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventor: Mohamed Sabri Abdelghani
  • Publication number: 20140330056
    Abstract: The present invention generally relates to a dielectric composition which is a poly-?-olefin or poly(co-ethylene-?-ol-efin) having a backbone weight average molecular weight less than 10,000 daltons. The dielectric composition uses a metal-ligand complex as a precatalyst and exhibits a hyperbranched structure that enables low viscosity, and therefore good flow characteristics, combined with high fire point due to ability to increase molecular weight via branching rather than backbone growth. Other desirable properties include lowered pour point due to crystallization disruption, and desirable thermal oxidative stability.
    Type: Application
    Filed: November 28, 2012
    Publication date: November 6, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Jerzy Klosin, Zenon Lysenko, Suh Joon Han
  • Patent number: 8846991
    Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: September 30, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. VanderLende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
  • Publication number: 20140171700
    Abstract: Provided are processes for making hydrocarbons from renewable feed sources. In an embodiment, there is provided a method for co-producing lube basestock and transportation fuel from a feedstock of biological origin, the method including: a) converting a feedstock of biological origin to a ketone or a dimer acid in the presence of a first catalyst; and b) hydrogenating the ketone or the dimer acid to produce a hydrocarbon in the presence of a second catalyst comprising a hydrogenation catalyst and a hydrothermally stable binder.
    Type: Application
    Filed: December 4, 2013
    Publication date: June 19, 2014
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Virginia M. Roberts, Suzzy Chen Hsi Ho, Paul D. Oldenburg, Michel Daage, Kun Wang, Bradley R. Fingland, Patrick Loring Hanks
  • Publication number: 20140171699
    Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.
    Type: Application
    Filed: December 4, 2013
    Publication date: June 19, 2014
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Kun Wang, Virginia M. Roberts, Paul D. Oldenburg, Suzzy Chen Hsi Ho, Michel Daage, Frank Cheng-Yu Wang
  • Publication number: 20140046102
    Abstract: An economical and environmentally friendly method for producing waxes. In particular, the methods use thermolytic degradation concurrently with a distillation process to obtaining distilled waxes from recycled polyethylene. The resulting waxes have desirable properties, such as reduced molecular weight and narrow polydispersity, that makes the waxes useful in various applications.
    Type: Application
    Filed: August 7, 2012
    Publication date: February 13, 2014
    Applicant: XEROX CORPORATION
    Inventors: Michael J. D'Amato, Santiago Faucher, Timothy L. Lincoln, Ali Darabi, Rosa Duque
  • Patent number: 8604258
    Abstract: We provide a base oil, comprising oligomerized olefins, wherein the base oil has: a) a kinematic viscosity at 100° C. greater than 10 mm2/s, b) a viscosity index from 25 to 90, and c) a pour point less than ?19° C.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: December 10, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Saleh Ali Elomari, Stephen Joseph Miller
  • Patent number: 8530712
    Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z ° C. or less, where Z=0.0648X?51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characteristics a) to h).
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: September 10, 2013
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Margaret M. Wu, Steven P. Rucker, Jo Ann M. Canich
  • Publication number: 20130172635
    Abstract: A polyoctenamer is described which at room temperature is liquid, colourless and clear, and which is produced by ring-opening, metathesis polymerization of cyclooctene.
    Type: Application
    Filed: May 26, 2011
    Publication date: July 4, 2013
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Peter Hannen, Norbert Wilczok, Manfred Thiery, Martin Roos
  • Patent number: 8388828
    Abstract: A process comprising regenerating a used ionic liquid catalyst, recovering conjunct polymer from the regenerated catalyst and using at least a portion of the conjunct polymer is disclosed.
    Type: Grant
    Filed: January 10, 2012
    Date of Patent: March 5, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Saleh A. Elomari, Hye-Kyung C. Timken
  • Publication number: 20130012675
    Abstract: A lubricant component is an oligomer of a series ?-olefins, made by forming a series of ?-olefins by oligomerization of ethylene using an ethylene oligomerization catalyst, and then oligomerizing the series of ?-olefins using a Lewis acid catalyst. The ?-olefin oligomer, which often has a high Viscosity Index, may be used for example in a lubricant as the base oil or a viscosity index modifier. The ?-olefin oligomer may also be a component of a lubricant additive, meant to be added to an already formulated lubricant to improve the lubricant's properties.
    Type: Application
    Filed: March 28, 2011
    Publication date: January 10, 2013
    Applicant: E.I. Dupont de Nemours and Company
    Inventor: Steven Dale Ittel
  • Patent number: 8288015
    Abstract: Disclosed is a triphenylene based aromatic compound, wherein a benzene center is substituted with a triphenylene group and another aromatic group such as triphenylenyl, pyrenyl, phenylvinyl, carbazolylphenyl, or arylanthryl in the meta position of the benzene center. The meta-substituted aromatic compound of the invention has better thermal stability (Tg) than the conventional para-substituted aromatic compound. The meta-substituted aromatic compound, served as a hole transporting layer or a host material applied in a light emitting layer in an OLED, is more preferable than the conventional para-substituted aromatic compound.
    Type: Grant
    Filed: April 18, 2010
    Date of Patent: October 16, 2012
    Assignee: National Tsing Hua University
    Inventors: Chien-Hong Cheng, Fang-Iy Wu, Yin-Yen Tsai, Yu-Han Chen
  • Publication number: 20120108862
    Abstract: A process comprising regenerating a used ionic liquid catalyst, recovering conjunct polymer from the regenerated catalyst and using at least a portion of the conjunct polymer is disclosed.
    Type: Application
    Filed: January 10, 2012
    Publication date: May 3, 2012
    Inventors: Saleh A. Elomari, Hye-Kyung C. Timken
  • Patent number: 8168838
    Abstract: A process for the preparation of a synthetic predominantly single carbon number hydrocarbon fluid comprises the steps of: contacting an alpha olefin having a carbon number of 4 to 30 with a single site catalyst under conditions effective to produce reactive hydrocarbon oligomers that contain reactive double bonds and comprising predominantly dimers, trimers, and tetramers wherein at least 10 weight percent of such reactive hydrocarbon oligomers at least one of trimers and tetramers; separating at least one of said trimers and tetramers in said reactive hydrocarbon oligomers; dimerizing said separated one of said trimers tetramers by contacting said separated one of said trimers or tetramers with a dimerization catalyst thereby producing an unsaturated synthetic hydrocarbon fluid; and contacting said unsaturated synthetic hydrocarbon fluid with hydrogen in the presence of a hydrogenation catalyst thereby producing a synthetic hydrocarbon fluid having predominantly single carbon number.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: May 1, 2012
    Assignee: Shell Oil Company
    Inventors: William J Heilman, Yajnanarayana Halmuthur Jois, Abraham Robert De Kraker, Wei Song
  • Patent number: 8143468
    Abstract: The present invention relates to the preparation of 3-methylbut-1-ene from a hydrocarbon stream I comprising isobutene by feeding a hydrocarbon stream II which comprises at least 70% by mass of isobutene in relation to the olefins present in the hydrocarbon stream and which has been obtained from hydrocarbon stream I or is identical to it to a process step for hydroformylation in which isobutene is hydroformylated in the presence of a rhodium catalyst, hydrogenating the aldehyde obtained from the hydroformylation of isobutene to the corresponding alcohol and preparing 3-methylbut-1-ene by water elimination from the alcohol.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: March 27, 2012
    Assignee: Evonik Oxeno GmbH
    Inventors: Alfred Kaizik, Klaus-Diether Wiese, Dietrich Maschmeyer, Dieter Hess, Wilfried Bueschken, Franz Nierlich
  • Patent number: 8101809
    Abstract: Provided is a base oil, comprising one or more oligomerized olefins, wherein the base oil has: (d) a kinematic viscosity at 100° C. grater than 2.9 mm2/s; (e) a viscosity index from 25 to 90; and (f) a cloud point less than ?55° C. Provided is a base oil made by oligomerizing propylene in an ionic liquid catalyst, where the base oil has a viscosity index from 25 to 90 and the base oil is colorless. Provided is a base oil made by oligomerizing an olefin feed comprising propylene in an acidic alkyl-pyridinium chloroaluminate ionic liquid, wherein the base oil has a viscosity index from 25 to 90, and a cloud point less than ?55° C.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: January 24, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Saleh Elomari, Stephen J. Miller
  • Publication number: 20110178348
    Abstract: A process for the preparation of a synthetic predominantly single carbon number hydrocarbon fluid comprises the steps of: contacting an alpha olefin having a carbon number of 4 to 30 with a single site catalyst under conditions effective to produce reactive hydrocarbon oligomers that contain reactive double bonds and comprising predominantly dimers, trimers, and tetramers wherein at least 10 weight percent of such reactive hydrocarbon oligomers at least one of trimers and tetramers; separating at least one of said trimers and tetramers in said reactive hydrocarbon oligomers; dimerizing said separated one of said trimers tetramers by contacting said separated one of said trimers or tetramers with a dimerization catalyst thereby producing an unsaturated synthetic hydrocarbon fluid; and contacting said unsaturated synthetic hydrocarbon fluid with hydrogen in the presence of a hydrogenation catalyst thereby producing a synthetic hydrocarbon fluid having predominantly single carbon number.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 21, 2011
    Inventors: William J. HEILMAN, Yajnanarayana Halmuthur Jois, Abraham Robert De Kraker, Wei Song
  • Publication number: 20110124932
    Abstract: A method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method comprises in broad embodiments the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. In some preferred embodiments, the method includes the step of commutating the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1.
    Type: Application
    Filed: February 2, 2011
    Publication date: May 26, 2011
    Applicant: Natural State Research, Inc.
    Inventor: Moinuddin Sarker
  • Publication number: 20110034743
    Abstract: We provide a base oil, comprising one or more oligomerized olefins, wherein the base oil has: d. a kinematic viscosity at 100° C. greater than 2.9 mm2/s; d. a viscosity index from 25 to 90; and f. a cloud point less than ?55° C. We provide a base oil made by oligomerizing propylene in an ionic liquid catalyst, where the base oil has a viscosity index from 25 to 90 and the base oil is colorless. We also provide a base oil made by oligomerizing an olefin feed comprising propylene in an acidic alkyl-pyridinium chloroaluminate ionic liquid, wherein the base oil has a viscosity index at 100° C. greater than 2.9 mm2/s, a viscosity index from 25 to 90, and a cloud point less than ?55° C.
    Type: Application
    Filed: August 10, 2009
    Publication date: February 10, 2011
    Inventors: Saleh Elomari, Stephen J. Miller
  • Patent number: 7884256
    Abstract: Higher diamondoid derivatives capable of taking part in polymerization reactions are disclosed as well as intermediates to these derivatives, polymers formed from these derivatives and methods for preparing the polymers.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: February 8, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Shenggao Liu, Robert M. Carlson, Jeremy E. Dahl
  • Patent number: 7867938
    Abstract: A catalyst precursor composition comprising: a source of chromium, molybdenum or tungsten; a first ligand having the general formula (R1)(R2P—X—P(R3)(R4); and a second ligand having the general formula (R1?)(R2?)P—X?—P(R3?)(R4?). The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
    Type: Grant
    Filed: November 20, 2006
    Date of Patent: January 11, 2011
    Assignee: Shell Oil Company
    Inventors: Eric Johannes Maria De Boer, Harry Van Der Heijden, Quoc An On, Johan Paul Smit, Arie Van Zon
  • Publication number: 20100319584
    Abstract: The invention relates to a modification additive for asphalt masses and to the manner of production of asphalt masses for the creation of mineral-asphalt mixtures having a high shear modulus. The essence of the invention is a modifier, characterized in that it comprises 50 to 97% of cyclopentadiene oligomers, which are dissolved in 2 to 30% by weight of alkenes with 9-11 carbon atoms in a molecule, and 1 to 15% by weight of cyclic and aromatic olefins, wherein the latter are segregation residues of other hydrocarbon fractions. The liquid asphalt mass is added to the above-mentioned modifier in a quantity of 0.1 to 15% by weight at a temperature of no more than 185° C. and kept in a liquid state for at least 15 minutes. The modified asphalt obtained in this way, together with the mineral additive, forms mineral-asphalt mixtures having a high shear modulus.
    Type: Application
    Filed: February 26, 2009
    Publication date: December 23, 2010
    Inventors: Wlodzimierz Górniak, Piotr Górniak, Dariusz Kowal, Antoni Wójcik, Hubert Zymek
  • Patent number: 7741526
    Abstract: A feedstock containing at least 1 wt % butenes, at least 1 wt % pentenes, at least 1 wt % hexenes, at least 10 wppm C4 dienes, at least 10 wppm C5 dienes, and optionally at least 10 wppm C6 dienes can be selectively hydrogenated over a catalyst (e.g., a noble metal) to form a stream containing 100 wppm to 4000 wppm total dienes. The hydrogenated stream, and an olefinic recycle stream having less than 10 wt. % C1+ moieties, can be contacted with a molecular sieve catalyst, e.g., at a recycle to feed ratio between 0.1 and 3.0, at a WHSV of at least 1.0 based on olefin in the feed, and at a reactor ?T no greater than 40° F. (22° C.), thus forming a reaction product that can then be separated into a distillate, e.g., having from 1 wt % to 30 wt % non-normal C9 olefins, and the aforementioned olefinic recycle stream.
    Type: Grant
    Filed: July 19, 2006
    Date of Patent: June 22, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Keith H. Kuechler, Stephen H. Brown, Marc P. Puttemans, Steven E. Silverberg, An A. Verberckmoes
  • Patent number: 7534924
    Abstract: A hydrocarbon mixture containing modified polycyclic aromatic compounds or modified PAC having a chemical structure of mean molecular weight ranging between 300 and 10,000, the chemical structure being represented by formula (I): (A)x(PAC)y, wherein x and y are integers corresponding to the numbers of A or PAC units, selected such that x/y is equal to at least 1, preferably ranging between 1 and 50 and wherein A is a unit corresponding to a polymerizable monomer containing between 2 and 60 carbon atoms.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: May 19, 2009
    Assignee: Total Fina Elf France
    Inventors: Guy Lemoine, Boulos Youssef, Claude Bunel, Yannick Jolivet, Jean-Marie Pinoche
  • Publication number: 20080253936
    Abstract: A method and system for producing petroleum jelly from hydrocarbons. The method converts the hydrocarbon source into a synthesis gas. The synthesis gas is converted into at least a light-hydrocarbons stream and a heavy-hydrocarbons stream, which both include a plurality of paraffins and a plurality of olefins. The plurality of paraffins is reacted with the plurality of olefins in the presence of a dialkyl peroxide initiator to form the petroleum jelly. A synthesis gas production system is adapted to produce a synthesis gas from at least a natural gas source. A hydrocarbon conversion system is adapted to produce heavier hydrocarbons from at least the synthesis gas, the heavier hydrocarbons containing at least a plurality of paraffins and a plurality of olefins. A petroleum-jelly production system is adapted to convert the produced heavier hydrocarbons into petrolatum.
    Type: Application
    Filed: April 16, 2007
    Publication date: October 16, 2008
    Inventor: Ramin Abhari
  • Patent number: 7335807
    Abstract: In one embodiment, this invention relates to a solventless liquid isoprene compound. The compound includes a liquid isoprene rubber. The compound also includes a curing agent selected from sulfur and/or sulfur donors. The curing agent is present in an amount of at least about 3% by weight of the compound. The compound contains substantially no solvent. In another embodiment, this invention relates to a solventless liquid isoprene compound. The compound includes a liquid isoprene rubber. The compound also includes a nonsulfur curing agent. The curing agent is present in an amount of at least about 5% by weight of the compound. The compound contains substantially no solvent.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: February 26, 2008
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Paul J. Hochgesang
  • Patent number: 7223893
    Abstract: Linear 1-butene dimers and other linear alpha-olefin dimers are manufactured in high yield and with high selectivity by coupling of alpha-olefins. The coupling is accomplished by contacting alpha olefins with an iron-based catalyst activated with an aluminum-based co-catalyst. The catalyst is structured to preclude formation of multiple dimer products, and the byproducts of the olefin coupling consist almost exclusively of methyl branched olefin dimers. The dimers have potentially diverse use in areas stretching form pharmaceuticals to plastics. Linear 1-butene dimers may be particularly useful in the production of plasticizer alcohols which may in turn be used to manufacture high quality plastics with reduced leaching.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: May 29, 2007
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Brooke L. Small, Eduardo J Baralt
  • Patent number: 7015255
    Abstract: (a) A medium oil wherein a main component is a hydrocarbon, and the number of paraffinic carbon atoms is 70% or more with respect to a total number of carbon atoms, (b) a medium oil wherein a main component is a polybutene, (c) a medium oil wherein a main component is a mixture of hydrocarbons of the formula (1): CH3—C(CH3)2—[—CH2—C(CH3)2—]n—CH2—R ??(1) wherein R is —CH(CH3)2 or —C(CH3)?CH2, and n is 1 to 10, (d) a medium oil wherein a main component is a hydrocarbon prepared by a Fischer-Tropsch synthesis, or (e) a medium oil wherein a main component is a branched paraffinic hydrocarbon prepared by hydrogenolysis of a hydrocarbon prepared by a Fischer-Tropsch synthesis, and a process of producing dimethyl ether using the medium oil, are disclosed.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: March 21, 2006
    Assignee: JFE Holdings, Inc.
    Inventors: Keiji Tomura, Takashi Ogawa, Masami Ono, Keiichi Okuyama, Seiji Aoki, Tsutomu Shikada, Masatsugu Mizuguchi, Yotaro Ohno
  • Publication number: 20040006250
    Abstract: A process for oligomerising alkenes having from 3 to 6 carbon atoms which comprises contacting a feedstock comprising a) one or several alkenes having x carbon atoms, and, b) optionally, one or several alkenes having y carbon atoms, x and y being different, with a catalyst containing a zeolite of the MFS structure type, under conditions to obtain selectively oligomeric product containing predominant amounts of certain oligomers. The process is carried out at a temperature comprised between 125 and 175° C. when the feedstock contains only alkenes with 3 carbon atoms and between 140 and 240° C., preferably between 140 and 200° C. when the feedstock contains comprises at least one alkene with 4 or more carbon atoms.
    Type: Application
    Filed: April 14, 2003
    Publication date: January 8, 2004
    Inventors: Georges Marie Karel Mathys, Jihad Mohammed Dakka, Machteld Maria Mertens, Johan A Martens, Igor V Mishin, Raman Ravishankar, Roger Eijkhoudt
  • Patent number: 6545156
    Abstract: Oligomeric compounds and methods of making the compounds having the formula: T&Parenopenst;M—F&Parenclosest;i&Parenopenst;M—F′&Parenclosest;jM  (III) wherein i and j are integers from about 0 to 300 and the sum of i and j is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd, are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, D is a hydrocarbyl group, and M is a moiety derived from one or more diamino or dihydroxy compounds that contain a 4-aminopiperidine radical.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: April 8, 2003
    Assignee: Cytec Technology Corp.
    Inventors: Thomas Patrick Sassi, Ram Baboo Gupta
  • Patent number: 6103676
    Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be functionalized by hydroformylation followed by reductive amination. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: August 15, 2000
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
  • Patent number: 5880241
    Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.
    Type: Grant
    Filed: January 24, 1996
    Date of Patent: March 9, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Steven Dale Ittel, Daniel Joseph Tempel
  • Patent number: 5856600
    Abstract: Described is a process for the production of depolymerized natural rubber, which makes it possible to obtain, at high reaction efficiency, of depolymerized natural rubber in the liquid form and having a narrow molecular weight distribution; and also a process for the production of depolymerized natural rubber which is free from odor or coloring peculiar to natural rubber and is also free from the danger of immediate allergy derived from protein.The process according to the present invention comprises adding a carbonyl compound to a natural rubber latex, and then subjecting the resulting natural rubber to air oxidation in the presence of a radical forming agent or adding a carbonyl compound to the latex of deproteinized natural rubber and then subjecting the deproteinized natural rubber to air oxidation optionally in the presence of a radical forming agent.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: January 5, 1999
    Assignees: Sumitomo Rubber Industries, Ltd, Kao Corporation, Nitto Denko Corporation
    Inventors: Yasuyuki Tanaka, Toshiaki Sakaki, Atsuko Kawasaki, Masaharu Hayashi, Eiji Kanamaru, Kazuhiko Shibata
  • Patent number: 5847247
    Abstract: The specification discloses terpene-based solvent compositions which comprise diterpenes as a major component and a minor amount of monoterpenes. The mixtures exhibit solvent properties similar to monoterpenes but have flash points high enough to be classified as combustible rather than flammable materials.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: December 8, 1998
    Assignee: Arizona Chemical Company
    Inventors: Alexander J. Conte, Bobby G. Johnson, Raymond H. Jones, Claude F. Phillips, Jr.
  • Patent number: 5723709
    Abstract: Terpene dimer compositions are provided which dry into a hard, tack free film upon exposure to air. The compositions include a terpene dimer having the molecular formula C.sub.20 H.sub.32 and contain at least one double bond. The terpene dimer is derived from a naturally occurring monoterpene, or mixtures thereof, having the molecular formula C.sub.10 H.sub.16. In an another embodiment the compositions, in addition to the terpene dimer, include isomers of the monoterpenes. The compositions are substantially free of higher terpene oligomers having molecular formulas greater than C.sub.20 H.sub.32. Processes for making the terpene dimer compositions are also provided. Advantageous utilization of these compositions is as a diluent, solvent or component in coating, adhesive, alkyd or ink formulations, as an environmentally safe non-toxic material.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: March 3, 1998
    Assignee: Arizona Chemical Company
    Inventors: Claude Frank Phillips, Jr., James William Booth
  • Patent number: 5698751
    Abstract: A branched polyene compound represented by the formula ##STR1## wherein f is an integer of 1-5; R.sup.1 and R.sup.2 represent hydrogen atoms or alkyl groups of 1-5 carbons; R.sup.3 represents a hydrogen atom or an alkyl group of 1-5 carbons or an alkenyl group represented by the formula ##STR2## wherein n is an integer of 1-5; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen atoms or alkyl groups of 1-5 carbons; all of R.sup.1, R.sup.2, R.sup.3 are not simultaneously hydrogen atoms; and all of R.sup.4, R.sup.5 and R.sup.6 are not simultaneously hydrogen atoms.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: December 16, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tatsuyoshi Ishida, Masaaki Yasuda, Hitoshi Ohnishi, Noriaki Kihara, Toshihiro Sagane, Toshiyuki Tsutsui
  • Patent number: 5637783
    Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of a ring substituted styrene and a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled residual amounts of aromatic unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 10, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Ellen B. Brandes, Frederick C. Loveless
  • Patent number: 5633415
    Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of two different conjugated dienes, a copolymer of a p-alkylstyrene and a conjugated diene, or a homopolymer of a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 27, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Ellen B. Brandes, Frederick C. Loveless
  • Patent number: 5578743
    Abstract: Novel homopolymer and copolymer compositions produced from the polymerization of non-conjugated dienes have been discovered. The novel compositions are produced by an equally novel process comprising cyclopolymerization of non-conjugated dienes employing reduced valence state Group VIB metal oxide catalyst on porous support. The preferred catalyst comprises carbon monoxide reduced chromium on silica. Copolymers are formed by copolymerization of non-conjugated dienes with 1-alkenes in contact with the activated chromium on silica catalyst. The compositions are useful as lubricants and additives.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: November 26, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Suzzy C. Ho, Margaret M. Wu, Yusheng Xiong
  • Patent number: 5545783
    Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews, Leslie R. Rudnick
  • Patent number: 5516884
    Abstract: Synthesis and characterization of polycarbynes, a new class of carbon-based random network polymers. The network backbones of the polymers are composed of tetrahedrally hybridized carbon atoms, each bearing one substituent and linked via three carbon-carbon single bonds into a three-dimensional continuous random network backbone. Silicon, germanium, tin, lead, Group 13 through Group 16 elements, lanthanides, and Group 4 metals can be incorporated into the polymer backbone. The atomic-level carbon network backbone confers unusual properties on the polymers, including thermal decomposition to form diamond or diamond-like carbon.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: May 14, 1996
    Assignee: The Penn State Research Foundation
    Inventor: Patricia A. Bianconi
  • Patent number: 5510548
    Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: April 23, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews, Leslie R. Rudnick
  • Patent number: 5446222
    Abstract: The invention provides a two-step process for converting cyclopentadiene dimer to a high density fuel mixture comprising the steps of:(a) reacting said cyclopentadiene dimer in the presence of a solid catalyst comprising a porous crystalline material having a Constraint Index of from about 0.1 to about 12 under oligomerization/isomerization conditions to convert at least a portion of said cyclopentadiene dimer to a normally liquid intermediate product containing cyclopentadiene trimer, cyclopentadiene tetramer, and the isomerized and oligomerized products derived from the reaction of at least three cyclopentadiene monomer units;(b) hydrogenating said normally liquid intermediate product of step (a) in the presence of a hydrogenation catalyst to form a normally liquid high energy density fuel.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: August 29, 1995
    Assignee: Mobil Oil Corporation
    Inventors: James R. Boulton, Ross A. Kremer
  • Patent number: 5276227
    Abstract: Liquid hydrocarbon lubricant viscosity index improver compositions are disclosed having high shear stability. The compositions comprise the homopolymer or copolymer product of the oligomerization of C.sub.3 to C.sub.5 alpha-olefin or mixtures thereof, with or without ethylene as co-monomer. The process is carried out under oligomerization conditions in contact with a reduced valence state Group VIB metal catalyst on porous support. The viscosity index improver of the invention has a regio-irregularity of at least 20%, weight average molecular weight between 6,000 and 30,000 and molecular weight distribution between 2 and 5.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: January 4, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Margaret M. Wu, Alice S. Chu
  • Patent number: 5268520
    Abstract: This invention describes highly reactive polymers obtained from lower monomers. The polymers are particularly useful in alkylation reactions.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: December 7, 1993
    Assignee: The Lubrizol Corporation
    Inventors: Jack L. Karn, Willis P. Nichols
  • Patent number: 5264642
    Abstract: A process is disclosed to produce liquid oligomers of olefins, such as l-decene, with controlled molecular weight and with branch ratios below 0.19 and having higher viscosity indices than oligomers with higher branch ratios. These oligomers with low branch ratios and controlled molecular weight can be used as basestocks for many lubricants or greases with an improved viscosity-temperature relationship, oxidative stability, volatility, etc. They can also be used to improve viscosities and viscosity indices of lower quality oils. The olefins can, for example, be oligomerized in the presence of hydrogen over a supported and reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers of controlled viscosity suitable for lubricant application.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: November 23, 1993
    Assignee: Mobil Oil Corp.
    Inventor: Margaret M. Wu
  • Patent number: 5171903
    Abstract: A lubricating oil composition for plastic working and a lubricating oil composition for cutting and grinding which contains a straight chain olefin having 6 to 40 carbon atoms. The lubricating oil composition for plastic working or the lubricating oil composition for cutting and grinding provides excellent workability and can give the material worked an excellent finish.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: December 15, 1992
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Saburo Koyama, Seiichi Shido, Kenji Onodera, Shigeo Hara, Yasunori Tomari, Toshio Saito, Tatsuo Nara
  • Patent number: 5139760
    Abstract: Disclosed are amorphous silica-alumina spherical particles having a notched surface. The particles have a small specific surface area and a highly controlled hygroscopic property. The spherical particles are obtained by exchanging at least a part of an alkali metal ion of a P-type zeolite as the starting material with a divalent metal and firing the ion-exchanged zeolite. Since the pH value is shifted to a weakly alkaline level by the ion exchange treatment, the particles are effective as a filler for stabilizing a resin or the like when incorporated therein, and the refractive index of the particles can be made close to that of a resin in which the particles are to be incorporated.
    Type: Grant
    Filed: February 26, 1990
    Date of Patent: August 18, 1992
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kiyoshi Abe, Kazuhiko Suzuki, Hiroshi Ogawa
  • Patent number: 5113030
    Abstract: Novel synthetic lubricants having high viscosity index are made from lower olefins. These materials have a viscosity above about 2 cS at 100.degree. C. and viscosity index above about 130 and are characterized by internal methyl groups attached to side chain tertiary carbon atoms.Hydrocarbon lubricant can be based on propene feedstock with the resulting oligomer containing less than 2.5 methyl groups per 12 carbon atoms.
    Type: Grant
    Filed: August 22, 1990
    Date of Patent: May 12, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Catherine S. H. Chen, Margaret M. Wu
  • Patent number: 5072067
    Abstract: Disclosed are a lubricating oil composition for plastic working and a lubricating oil composition for cutting and grinding which comprises a straight chain olefin having 6 to 40 carbon atoms. This lubricating oil composition for plastic working or a lubricating oil composition for cutting and grinding provides excellent workability and can give the material worked an excellent finish.
    Type: Grant
    Filed: November 2, 1989
    Date of Patent: December 10, 1991
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Saburo Koyama, Seiichi Shido, Kenji Onodera, Shigeo Hara