Abstract: The present invention provides poly(ureaurethane)s including a reaction product of components comprising: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.1 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; (c) about 0.1 to about 0.9 equivalents of at least one aliphatic diol having 2 to 18 carbon atoms; and (d) at least one amine curing agent, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

Abstract: A coated substrate is disclosed. The coated substrate includes a substrate and a coating composition over the substrate comprising at least one metal based layer selected from tungsten, chromium, tantalum, molybdenum, aluminum, niobium, and mixtures and alloys thereof; and mixtures and alloys of cobalt and chromium; and at least one dielectric layer including SixNy, where x/y ranges from 0.75 to 1.5, over the metal based layer. The ?Ecmc (1.5:1) (T), ?Ecmc (1.5:1) (R1) and ?Ecmc (1.5:1) (R2) of a non-heat treated, coated substrate as compared to a heat treated, coated substrate according to the present invention are no greater than 8 units.

Abstract: A foam mount of an aircraft window has a groove to receive an electro chromic window. The foam mount is painted by placing a blank in the groove to divide the foam mount into a first section designated to face the exterior of the aircraft and an opposite second section. The groove and the first section are coated with an electric conductive paint, and the second section is covered with a decorative paint. The conductive coating on the foam mount and the conductive coating of the electrodes of the electro chromic window provide an RF shielding to prevent electronic signals from personal electronic equipment from passing through the cabin and door windows of the aircraft. A mask is also provided to coat one section of the foam mount while covering the other section.

Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.

Abstract: A device for maintaining a cutting edge, e.g. a focused laser beam at a constant distance from a surface of the work piece as the cutting edge imposes a cut line in a coating on the surface of the work piece. The device includes a constant force spring connecting a tube to a support and a surface follower mounting an end of the tube. The positions of a surface of the surface follower and the cutting edge have a predetermined relationship to one another. Gas moving out of the tube provides a first gas bearing between the surface follower and inner surface of the tube, and gas moving through passageways in the surface follower provide a second gas bearing between the surface of the surface follower and a surface of the coating. The thicknesses of the bearings remain constant as the follower moves over the surface of the piece to maintain the cutting edge at a constant distance from the surface of the coating.

Abstract: An insulating unit having a neutral grey color and a solar heat gain coefficient less than 0.40 includes a clear glass sheet spaced from a coated glass sheet. The coated glass sheet includes a colored glass substrate having a solar infrared reflective coating. The composition of the coated substrate includes a base glass portion and a glass colorant portion, the glass colorant portion including total iron in the range of 0.04 to less than 0.28 weight percent; CoO in the range of 32 to 90 parts per million, and Se in the range of greater than 0 to less than 5.5 parts per million. In one non-limiting embodiment of the invention the glass substrate at a thickness of 0.223 inches has a* chromaticity coordinates of ?3.5 to +2.5 and b* chromaticity coordinates of ?1 to ?15, and a visible light transmittance of 40 to 80%.

Abstract: A method of tempering a glass sheet heated to a tempering temperature includes cooling the glass sheet at a first heat transfer coefficient at a first quench station and cooling the glass sheet at a second heat transfer coefficient at a second quench station downstream of the first quench station. The second heat transfer coefficient is greater than the first heat transfer coefficient. In a multistage process of the invention, a plurality of quench stations could be used with each downstream quench station having a larger heat transfer coefficient than the previous upstream quench station.

Abstract: Various embodiments of the present invention relate to glass fiber forming bushings, to methods of controlling the temperature of bushings having multiple segments, to systems of controlling the temperature of bushings having multiple segments, and to other systems and methods. In one embodiment, a method of controlling the temperature of a bushing having multiple segments comprises forming a plurality of filaments from a bushing comprising at least two segments, gathering the filaments into at least two ends, measuring the size of each of the at least two ends, comparing the measured size of the at least two ends to a desired end size, adjusting the amount of current passing through the at least two bushing segments in response to the end size comparisons.

Abstract: The present invention provides methods for preparing polyurethanes from reaction components including: (a) reacting about 1 equivalent of at least one polyisocyanate; and about 0.1 to about 0.5 equivalents of at least one polyol having 2 to 18 carbon atoms to form an isocyanate functional urethane prepolymer; and (b) reacting the isocyanate functional urethane prepolymer, about 0.05 to about 1.0 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and up to about 0.9 equivalents of at least one polyol different from the branched polyol and having 2 to 18 carbon atoms, wherein the reaction components are essentially free of polyester polyol and polyether polyol, as well as methods for preparing polyurethanes using a one pot process.

Abstract: An article includes a first substrate, a functional coating deposited over at least a portion of the substrate, and a protective coating deposited over the functional coating. The functional coating and the protective coating define a coating stack. A polymeric material is deposited over at least a portion of the protective coating. The protective coating has a refractive index that is substantially the same as the refractive index of the polymeric material.

Abstract: The durability of a transparent pyrolytic spray applied coating is improved by providing a spray solution of metal acetylacetonates having different particle size distribution. More particularly, the particle size distribution of each of the metal acetylacetonates is a function of its melting temperature, and optionally of its melting temperature and solubility.

Abstract: A mechanical device for displacing jaws of a spring biased clamp includes a housing for receiving handles of the spring biased clamp. The housing has a platform moveable toward and away from a wall to move the handles of the clamp toward and away from one another, to move the jaws of the clamp away from and toward one another, respectively. A control member activates and deactivates a force applying member operationally connected to the platform, wherein activating the force applying member moves the platform toward the wall and deactivating the force applying member moves the platform away from the wall of the housing. The device is used to apply clamps to marginal edge portions of a stack of two one or more sheets to provide a clamped subassembly. The clamped subassembly in one embodiment is laminated to provide an aircraft transparency.

Abstract: The present invention is directed toward a method for making a polymer that has nanostructures incorporated into the matrix of the polymer. The method of the invention involves the following steps: mixing a precursor solution for the polymer with a precursor for the nanostructures to form a mixture; forming nanostructures in the mixture from the precursor of the nanostructures; and forming a polymer from the precursor solution of the polymer so that the nanostructures are incorporated into the polymer matrix.

Abstract: Repair or replacement of a transparency mounted in body of a vehicle, e.g. an aircraft when one or more properties of the transparency is (are) operating outside of an acceptable limit(s) is arranged by monitoring operating performance of a property of the transparency, e.g. by mounted a sensor, e.g. a sensor for detecting moisture; a sensor for detecting impacts and vibrations; a sensor for detecting fractures; a sensor for detecting electric arcing, and a sensor for measuring temperature of an electrically conductive coating, on the transparency. Scheduling repair or replacement of the transparency at a geographical area when the operating performance of the property is outside an acceptable operating performance limit, and forwarding the schedule to the vehicle and to a maintenance location to prepare for the repair or replacement of the transparency at the geographical work area.

Abstract: A coating includes the reaction product of (a) a hybrid copolymer incorporating (i) a first monomer including a hydroxy-functional organoacrylate and (ii) a second monomer including an organoalkoxysilane and (b) a second material including an organofunctional alkoxysilane. The first monomer can be a hydroxy functional acrylate and/or a hydroxyalkylacrylate. The second monomer can be a trialkoxysilane. The second material can be a trialkoxysilane.

Abstract: A coated article includes a substrate and a first coating formed over at least a portion of the substrate. The first coating includes a mixture of oxides including oxides of at least two of P, Si, Ti, Al and Zr. A photoactive functional coating is formed over at least a portion of the first coating. In one embodiment, the functional coating includes titania.

Abstract: A foam mount of an aircraft window has a groove to receive an electro chromic window. The foam mount is painted by placing a blank in the groove to divide the foam mount into a first section designated to face the exterior of the aircraft and an opposite second section. The groove and the first section are coated with an electric conductive paint, and the second section is covered with a decorative paint. The conductive coating on the foam mount and the conductive coating of the electrodes of the electro chromic window provide an RF shielding to prevent electronic signals from personal electronic equipment from passing through the cabin and door windows of the aircraft. A mask is also provided to coat one section of the foam mount while covering the other section.

Abstract: A coated substrate is disclosed. The coated substrate includes a substrate; an undercoating layer comprising at least one layer selected from a mixture of silica and zirconia; a mixture of silica and alumina; or a mixture of silica, alumina and titania overlaying at least a portion of the substrate; and a functional coating overlaying at least a portion of the undercoating. The coated substrates of the invention exhibit improved properties such as increased durability, photocatalytic activity, etc. as a result of the undercoating layer.

Abstract: An electrochromic device includes a first substrate spaced from a second substrate. A first conductive member is formed over at least a portion of the first substrate. A first electrochromic electrode comprising a tungsten oxide coating is formed over at least a portion of the first conductive member. A second conductive member is formed over at least a portion of the second substrate. A second electrochromic electrode is formed over at least a portion of the second conductive member. An ionic liquid is positioned between the first electrode and the second electrode. In one aspect of the invention, the ionic liquid can include nanoparticles of metals or metal oxides. In a further aspect of the invention, the second conductive member and second electrode can be formed by a single material.

Abstract: A spacer stock has a pair of outer legs joined by a base to provide the spacer stock with a generally U-shaped cross section. The outer legs are formed e.g. each leg has a pair of members having a hairpin cross section to reduce the degree of torsional twist of the spacer stock and/or spacer frame with the legs preferably only connected by the base having only one thermal conducting path e.g. through the base from one leg to the other leg. The spacer stock may be shaped or sections of spacer stock joined to provide a spacer frame. The spacer frame may be used to fabricate a multi-sheet glazing unit e.g. by securing a sheet to each of the outer legs with moisture impervious adhesive or sealant.