Abstract: The present invention relates to a method of making a rectangular bar have a gradient composition. In optical or ophthalmic applications, the gradient of composition ensures formation of a corresponding gradient of optical property, such as refractive index or optical density. The glass material is manufactured using a device containing several reservoirs, all designed to contain glass in the fluid state. According to the invention, the composition of the glass varies from one reservoir to the other so that the refractive indices, for example, of the three compositions are different, with an incremental progression. The fluid glass is deposited one composition on top of the next and then heated, creating a certain degree of interdiffusion between the layers. The glass is then heat-treated to create the desired property profile.
Type:
Grant
Filed:
February 13, 1998
Date of Patent:
October 31, 2000
Assignee:
Corning Incorporated
Inventors:
Claude F. M. Gille, Alain Kerdoncuff, Michel Prassas
Abstract: The invention relates to a strong UV absorbing glass consisting essentially of, expressed in cation percent, 15-30% SiO.sub.2, 50-60% B.sub.2 O.sub.3, 2-5% Al.sub.2 O.sub.3, 0-6% Li.sub.2 O, 0-3.0% Na.sub.2 O, 14-20% K.sub.2 O, 0.5-1.0% CuO, 0.4-0.7% SnO.sub.2, 0.5-1.5% Cl, and 0.7-1.5% Br. An essentially haze-free version of the glass is disclosed. A UV absorbing coating material made by suspending ground particles of the inventive glass in a suitable matrix is also disclosed.
Abstract: This invention is directed to the preparation of alloy articles consisting essentially of glass and high temperature organic thermoplastic or thermosetting polymers having working temperatures which are compatible with that of the glass and/or the precursor glass for the glass-ceramic. The glass and polymer are combined at the working temperature to form an intimate mixture; i.e., the glass and polymer are in a sufficiently fluid state to be blended together to yield a body exhibiting an essentially uniform, fine-grained microstructure wherein, desirably, there is at least partial miscibility and/or a reaction between the glass and the polymer to promote adhesion and bonding therebetween. A body is shaped from the mixture and cooled to room temperature.
Type:
Grant
Filed:
June 27, 1997
Date of Patent:
August 15, 2000
Assignee:
Corning Incorporated
Inventors:
Paul D. Frayer, Roy J. Monahan, Michelle D. Pierson
Abstract: The invention relates to a method of making glass-ceramic plates which are bent at a radius of curvature especially suitable in the manufacture of cooking plates.
Type:
Grant
Filed:
October 10, 1995
Date of Patent:
August 15, 2000
Assignee:
Corning Incorporated
Inventors:
Claude Gille, Michele Marie-Louise Meyer, Paul Leon Netter, Sophie Peschiera, Pablo Juan Luis Vilato Gailloud
Abstract: The present invention has for subjects, novel benzopyran derivatives, substituted in position 2 with an adamantyl group as well as the compositions and (co)polymer matrices containing such derivatives. Said derivatives possess interesting photochromic properties.
Abstract: The invention relates to photochromic compounds of general formula (I), in which: R3 and R5 are C1-C6 alkoxy groups and the rest of the R groups represent various substituents.
Abstract: Method of making polarizing glass having integral polarizing and non-polarizing regions disclosed. The method involves applying a protective glass/frit material capable of blocking reducing gas to the surface of the glass to form a desired pattern, exposing the glass to a reducing gas atmosphere to render unprotected glass polarizing, and removing the protective glass/frit material to reveal underlying non-polarizing regions.
Abstract: A stabilizing matrix for photochromic compounds is disclosed in which a functionalized hindered amine light stabilizer capable of reacting with an isocyanate group is linked to the polymer backbone by a covalent bond to form a grafted structure. The resulting matrix is characterized by having a stabilizing effect on the photochromic dye, in particular, spirooxazines. Preferred specific articles of the invention are photochromic organic lenses.
Abstract: These glasses incorporate a combination of F and Al.sub.2 O.sub.3 to achieve even wider fluorescence and improved gain flatness. In addition, SPCVD incorporates large amounts of N into low-loss fiber whose high charge has an impact on rare earth behavior. The Surface Plasma Chemical Vapor Deposition (SPCVD) produces fiber preforms with high levels of F, Al.sub.2 O.sub.3, and N. These heavily fluorinated glasses provide much broader Er.sup.3+ emission than Type I or Type II silica for enhanced multichannel amplifiers. SPCVD successfully fluorinates silica with losses below 5 dB/km and increased Er.sup.3+ emission width.
Abstract: These color television (CTV) panel tint glasses involve using base CTV panel glass compositions with enhanced levels of Ni and Co colorants. The approach uses non-lead CTV panel glass compositions with high levels of Ni and Co oxide as colorant glasses for tinting clear CTV non-lead panel glass. Nickel oxide was varied from 2 to 18%, while cobalt oxide was varied from 0.2 to 2%. A preferred range of compositions with cobalt oxide levels below 1% and nickel oxide levels below 10% was found to be very acceptable for CTV panel colorants.
Abstract: The material is in a fluid state at a predetermined temperature above the ambient temperature. According to the invention: a) at least two different compositions of this material in the fluid state are prepared; b) simultaneously and concentrically both the core of the rod with the aid of one of the compositions and a sheath enveloping this core with the aid of another composition are cast; and c) the casting is then taken to a temperature at which it solidifies to constitute the rod. Advantageously, the section of the casting is made to grow by its passing through a cylindrical mold shaped to define the final section of the rod. Application to the manufacture of a glass rod presenting a cross-sectional refractive index gradient.
Type:
Grant
Filed:
April 10, 1996
Date of Patent:
May 16, 2000
Assignee:
Corning Incorporated
Inventors:
Allan Mark Fredholm, Alain Kerdoncuff, Michel Prassas
Abstract: Method of making polarizing glass having integral polarizing and non-polarizing regions is disclosed. The method involves applying a protective glass/frit material capable of blocking reducing gas to the surface of the glass to form a desired pattern, exposing the glass to a reducing gas atmosphere to render unprotected glass polarizing, and removing the protective glass/frit material to reveal underlying non-polarizing regions.
Abstract: The invention relates to brown glasses which absorb ultraviolet radiation that are used in the production of ophthalmic sun glasses, and that have the following composition, expressed in wt. %:______________________________________ SiO.sub.2 59-78 Al.sub.2 O.sub.3 2-6 B.sub.2 O.sub.3 0-3 Na.sub.2 O 7-16 K.sub.2 O 2-9 CaO 0-7 BaO 0-12 ZnO 0-12 ZrO.sub.2 0-6 TiO.sub.2 0-6 MnO.sub.2 0.25-6 V.sub.2 O.sub.5 1-3 Fe.sub.2 O.sub.3 0-1.5 NiO 0-0.5 CoO 0-0.1 Sb.sub.2 O.sub.3 0-0.7 As.sub.2 O.sub.3 0-0.7 F 0.05-1.0 With MnO.sub.2 + Fe.sub.2 O.sub.3 + V.sub.2 O.sub.5 >1.5 Al.sub.2 O.sub.3 + SiO.sub.2 .gtoreq.65.
Type:
Grant
Filed:
April 14, 1998
Date of Patent:
April 11, 2000
Assignee:
Corning Incorporated
Inventors:
Yves A. H. Brocheton, Marie J. M. Comte
Abstract: The invention relates to photochromic transparent organic materials presenting an index of refraction of more than 1.55, which are free of optical distortions and are prepared by radical polymerization of a polymerizable composition comprising:a) 80-95 wt % of at least one monomer represented by the general formula (I): ##STR1## where R=H or CH.sub.3, and m and n are independently 1 or 2; b) 5-20 wt % of at least one aromatic monovinyl monomer represented by the general formula (II): ##STR2## c) an effective quantity of at least one dye that imparts photochromic properties to the material, selected from the groups of spiroxazines, spiropyrans and chromenes;d) an effective quantity of a chain transfer agent; ande) an effective quantity of a radical polymerization initiator, characterized in that the chain transfer agent is a linear alkanethiol and the radical polymerization initiator is a diazo compound.
Abstract: The invention concerns photochromic compounds having a formula (I), where R.sup.1 is a polycyclo group formed by at least one alicyclic group linked to, bridged or condensed, with at least one other aliphatic or aromatic ring.
Abstract: The present invention has for subjects novel compounds of the [benzofuran]naphthopyran type as well as the compositions and (co)polymer matrices containing them. Said compounds possess interesting photochromic properties.
Abstract: The invention concerns photochromic compounds with the following Formula: ##STR1## in which: R.sup.1 is a asymmetric aliphatic monocyclic group with the Formula, ##STR2## where l=1-12, and R.sup.9 is H or an alkyl, alkoxy, dialkylamino, alkyl ester or CN group with the condition that at least one of the R.sup.9 groups is not H,R.sup.2 -R.sup.7 can have a variety of meanings, A represents a (hetero)aromatic ring which can be substituted and n is a whole number.Application to the production of photochromic articles made of organic polymer, notably lenses.
Abstract: The invention relates to a thin layer of UV absorbing material, and a method of making such material by grinding UV absorbing glass into fine powder which can be suspended in a liquid matrix, for example, in index matching oil, thereby producing a transparent liquid which can be used to coat any material to impart UV absorption to such material.
Type:
Grant
Filed:
August 7, 1998
Date of Patent:
December 14, 1999
Assignee:
Corning Incorporated
Inventors:
Roger J. Araujo, Alain R. E. Carre, Serge A. M. Renault
Abstract: The present invention is directed to a defect-free magnetic memory disc substrate. In particular, it is directed to a composite alumina-based, glass-coated, article with a defect free surface. Several methods for its manufacture including frit bonding, molten glass submersion, and tape formation are disclosed.
Abstract: This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga.sub.2 S.sub.3, 0-35% RS.sub.x, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln.sub.2 S.sub.3, wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga.sub.2 S.sub.3, 0-10% R.sub.2 S.sub.