Abstract: This invention relates to coppered azo dyestuffs containing an alkyl-, aryl or alkoxyalkyl sulfamyl group on one moiety of the molecule and an alkyl-, aryl or alkoxyalkyl ammonium sulfonate or carboxylate group on the other moiety. The invention also relates to various intermediates, to compositions and to processes for preparing the metalized dyestuffs. The compounds are particularly suited for the application in laquers, ink-jet inks and electrographic toners.
Abstract: The invention relates to polymeric phosphinic acids and their salts of the formula (I) where X is hydrogen or 1/m of a metal of valency m, or is a protonated nitrogen base, R1 and R2 are identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, R3 and R4 may be identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, or are OX, with the above meaning for X, and ? is the average number of monomer units. The invention further relates to a process for preparing the above-mentioned compounds, and to their use.
Type:
Grant
Filed:
March 4, 2004
Date of Patent:
October 31, 2006
Assignee:
Clariant GmbH
Inventors:
Martin Sicken, Werner Krause, Norbert Weferling, Hans-Peter Schmitz
Abstract: The invention relates to a diaryl yellow pigment preparation, including a) at least one diaryl yellow pigment b) at least one natural resin on the basis of rosin or modified rosin, c) at least one compound of formula (1), and d) an aluminum, zinc, manganese or iron compound in an amount of from 0.1 to 8% by weight (calculated as a metal cation), based on component b). The inventive preparations are suitable for a variety of applications, among them the production of printing inks, especially offset printing inks.
Type:
Grant
Filed:
February 28, 2002
Date of Patent:
October 10, 2006
Assignee:
Clariant GmbH
Inventors:
Heinz Bach, Ulrich Ott, Rainer Winter, Thomas Heber, Rolf Kaiser
Abstract: The instant invention relates to stabilizer compositions for thermoplastic polymers comprising a) at least one organophosphine, b) at least one 2-phenylbenzofuranone, and c) at least one sterically hindered piperidine based stabilizer (HAS), wherein the weight ratio of component a) to component b) to component c) is from 1:0.05:0.5 to 1:3:5. The instant compositions need an overall lower concentration as compared with the conventional phenol-containing formulations. In polyolefin articles, particularly in polyolefin-fibers, discoloration during processing and service life by both the formation of quinoid products and by action of NOx gases (gasfading) is avoided.
Abstract: The invention provides novel pigment dispersants of the formula (I): in which Q is a radical of the formula (Ia): s is a number from 0.1 to 4.0 and n is a number from 0 to 2.0; and provides pigment preparations comprising an organic base pigment and a pigment dispersant of the formula (I).
Type:
Grant
Filed:
March 24, 2004
Date of Patent:
September 5, 2006
Assignee:
Clariant GmbH
Inventors:
Joachim Weber, Felix Wendelin Grimm, Erwin Dietz
Abstract: The present invention relates to a process for reducing water carry-over during the production of polyolefin films or polyolefin tapes which are passed through a waterbath, where the polyolefin formulation comprises polyolefin waxes. The results are that less water is carried over and that the products have higher quality and better processing properties.
Abstract: The invention relates to surface-modified phosphinic salts of the formula (I) and/or diphosphinic salts of the formula (II) and/or polymers of these, where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, wherein the phosphinic salts and/or diphosphinic salts, or their polymers, have been encapsulated with a surface layer composed of a synthetic resin or a wax, and to a process for their preparation, and to their use as flame retardants for thermoplastic and thermoset polymers.
Type:
Grant
Filed:
September 5, 2003
Date of Patent:
August 8, 2006
Assignee:
Clariant GmbH
Inventors:
Sebastian Hoerold, Franz-Leo Heinrichs, Elisabeth Jung
Abstract: The invention is directed to a polymer and pigment composition utilizing a polyolefin wax produced by metallocene catalysis as a pigment dispersing auxiliary.
Abstract: The invention relates to a synergistic mixture comprising a) at least one compound from the group which consists of the phosphanes of the formula (I), (di/oligo)phosphanes of the formulae (II) and (III) and cyclophosphanes of the formula (IV) and b) at least one 6-hydroxychromane derivative of the general formula (V) and also to a process which stabilizes polymers with respect to thermooxidative degradation by addition and incorporation of this synergistic mixture.
Abstract: A stabilizer mixture for one or more compounds of the general formula (1) and (1A) but preferably (1), wherein the groups R independently stand for an alkyl-, cycloalkyl-, aralkyl- or aryl-rest whereas the aromatic ring system may be optionally substituted by one or more groups R? which may be identical or different and which groups R? can be an aryl-, a saturated or unsaturated alkyl-, aralkyl- or cycloalkyl-group as well as halogen, an amino-, aminoalkyl-, aminocycloalkyl-, cyano-, thiocyano- or nitrogroup. and a UV-absorber, hindered amine stabilizer, sterically hindered phenol, organophosphite, organophosphonite, organophosphine, or mixtures thereof. The present invention is useful in the protection of various polymeric substrates against the damaging influence of light exposure by the long term storage of polymers. This effect can be observed especially in so-called engineering plastics (such as, for example, PC, PET, PBT, ABS, TPU).
Type:
Grant
Filed:
May 14, 2002
Date of Patent:
July 25, 2006
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Christoph Krōhnke, Joseph R. Webster, Ernst Gronmaier, Lajos Avar
Abstract: A process for preparing 1,3-di-halo-substituted benzene derivatives (II) from 2,6-di-halo-substituted benzaldehydes (I) (where X1, X2 are each independently F, Cl, Br, and R1, R2, R3 are each independently H, halogen, OH, C1–C12-alkyl, CF3, CHO, C6–C14-aryl, Oalkyl, Oaryl, NO2) by reacting with an alkaline medium, which comprises initially charging the alkaline medium and metering in the 2,6-di-halo-substituted benzaldehyde (I) or initially charging the 2,6-di-halo-substituted benzaldehyde (I) and metering in the alkaline medium
Type:
Grant
Filed:
October 24, 2003
Date of Patent:
July 18, 2006
Assignee:
Clariant GmbH
Inventors:
Stefan Brand, Daniel Decker, Thomas Wessel
Abstract: The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.
Abstract: The invention relates to a colorant composition that substantially comprises a colorant of formula (1) and a colorant formula (2) or (3). The magenta colorant mixture is advantageously used in ink-jet printing and yields storage-stable and water-proof ink formulations.
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
June 27, 2006
Assignee:
Clariant GmbH
Inventors:
Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
Abstract: The invention relates to a method for producing vattable organic pigments. The invention is characterized in that an agueous or an aqueous-organic suspension of a coarse crystalline raw mineral is vatted and re-oxidised, and the pigment suspension is ground to a diameter equal to or less than 0.9 mm during vatting and/or during oxidation by means of an agitator ball mill, which is operated at a power density of more than 1.0 KW per litre per grinding chamber and at an agitator peripheral speed of more than 12 m/s, using grinding bodies.
Type:
Grant
Filed:
March 17, 2003
Date of Patent:
June 6, 2006
Assignee:
Clariant GmbH
Inventors:
Joachim Weber, Manfred Urban, Erwin Dietz
Abstract: The present invention relates to an agent for removing pollutants from gases comprising a wax which has a drop melting point between 40 and 150° C., a melt viscosity of 2 to 20 000 mPas and a needle penetration of 1 to 50, and which contains at least one alkoxylated compound.
Abstract: The invention provides novel pigment dispersants of the formula (I) in which is a radical of the formula (Ia) s is a number from 0.1 to 4.0 and n is a number from 0 to 2.0; and provides pigment preparations comprising an organic base pigment and a pigment dispersant of the formula (I).
Type:
Grant
Filed:
February 27, 2003
Date of Patent:
May 16, 2006
Assignee:
Clariant GmbH
Inventors:
Joachim Weber, Felix Wendelin Grimm, Erwin Dietz
Abstract: The invention provides novel pigment dispersants of the formula (I) in which Q is a radical of the formula (Ia) s is a number from 0.1 to 4.0 and n is a number from 0 to 2.0; and provides pigment preparations comprising an organic base pigment and a pigment dispersant of the formula (I).
Type:
Grant
Filed:
February 27, 2003
Date of Patent:
May 16, 2006
Assignee:
Clariant GmbH
Inventors:
Joachim Weber, Felix Wendelin Grimm, Erwin Dietz
Abstract: The present invention relates to the use of wax-coated pigment granules as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters, wherein the coated pigment granules have a particle size of between 0.05 and 5 mm and a wax content of from 1 to 50% by weight, based on the overall weight of the coated pigment granules.
Type:
Grant
Filed:
November 1, 2001
Date of Patent:
April 18, 2006
Assignee:
Clariant GmbH
Inventors:
Ulrike Rohr, Ruediger Baur, Hans-Joachim Metz, Andreas Stohr
Abstract: The invention relates to addition compounds of formula (1): in which: n is a number from 1 to 10; R1 and R2 are identical or different and are each a hydrogen atom or a saturated or unsaturated aliphatic radical having 1 to 4 carbon atoms; R3 and R4 are identical or different and are each a hydrogen atom or alkyl having 1 to 3 carbon atoms, and the bridge member (R3+R4) is in each case positioned ortho or meta in relation to the phenolic oxygen atom; Z represents a group —CH2—CH2—, —CH2—CH(CH3)—, —CH(CH3)—CH2— or a combination thereof; s is number from 1 to 200; B represents hydrogen, —CO—CH?CH—COOM, —COCH(SO3M)CH2COOM, —CO—CH2—CH(SO3M)—COOM, —SO3M, —SO2M and/or —PO3MM, whereby M is preferably a cation selected from the group Li+, Na+, K+, NH4+, HO—CH2—CH2—NH3+, (HO—CH2—CH2—)2NH2+ or (HO—CH2—CH2—)3NH+; and Y is a radical of an amine. The inventive addition compounds are used as dispersing agents of solids, for example, pigments, particularly in aqueous media.
Type:
Grant
Filed:
February 26, 2002
Date of Patent:
March 21, 2006
Assignee:
Clariant GmbH
Inventors:
Martin Alexander Winter, Hans Joachim Metz, Andreas Harz, Andreas Pfrengle