Patents Represented by Attorney Arthur E. Kluegel
  • Patent number: 8263182
    Abstract: An inkjet printing system comprises an inkjet printer and an inkjet ink comprising water, a self-dispersing carbon black pigment, and a water soluble polymer containing carboxylate groups, wherein: the carbon black pigment comprises greater than 11 weight % volatile surface functional groups; and the ink also contains an organic base having a pKa>7.5 and an optional inorganic base in combined amounts sufficient to provide alkaline equivalents of at least 150% of the acid equivalents of the water soluble polymer; provided the equivalents of the organic base are greater than or equal to the equivalents of the inorganic base.
    Type: Grant
    Filed: October 14, 2008
    Date of Patent: September 11, 2012
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, Paul D. Zimmerman
  • Patent number: 8202585
    Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer and a porous uppermost layer, each with particular limitations The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density, and image quality.
    Type: Grant
    Filed: July 31, 2008
    Date of Patent: June 19, 2012
    Assignee: Eastman Kodak Company
    Inventors: Terry C. Schultz, Bruce C. Campbell, Andrew M. Howe, Kenneth J. Ruschak, Robin D. Wesley
  • Patent number: 8202926
    Abstract: The invention provides a dispersant for an aqueous dispersion of negatively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one basic group and having an overall basicity and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The invention also provides a coating composition containing the dispersant, an inkjet recording element containing the dispersant and methods of coating or reducing viscosity using the dispersant.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 19, 2012
    Assignee: Eastman Kodak Company
    Inventors: Alan R. Pitt, Trevor J. Wear, John H. Hone, Andrew M. Howe, Ian M. Newington
  • Patent number: 8192008
    Abstract: An inkjet printing system includes an inkjet printer responsive to digital signals and containing an ink composition having: (a) water, (b) dispersed pigment particles, (c) a humectant, and (d) a polyurethane additive having at least a first soft segment having siloxane groups, the additive having a weight average molecular weight of at least 10,000 daltons and a sufficient number of acid groups to provide an acid number greater than 60. An improved combination of scratch resistance and jetability is obtained.
    Type: Grant
    Filed: August 28, 2008
    Date of Patent: June 5, 2012
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Catherine A. Falkner, Paul D. Yacobucci, Kurt M. Schroeder
  • Patent number: 8079695
    Abstract: An inkjet printer, includes an ink containing a print uniformity improving polymer obtained by chain copolymerizing at least the following ethylenically unsaturated monomers: (a) a first monomer having a lowest pKa value greater than 3 and comprising a carboxylic acid group; (b) a second monomer having a lowest pKa value less than 2; and (c) a hydrophobic third monomer; together with pigment particles that are self-dispersed or dispersed with a dispersant other than a print uniformity improving polymer, and water. Such an ink provides improve print uniformity.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: December 20, 2011
    Assignee: Eastman Kodak Company
    Inventors: Allan Wexler, David J. Giacherio, Michael J. Carmody, Richard C. Reem, Yongcai Wang
  • Patent number: 8062719
    Abstract: The present invention relates to a material intended for forming or printing images, comprising a support and at least one hydrophilic binder-based layer, and its manufacturing method, said method enabling the gelation process of the hydrophilic binder to be controlled. The material according to the invention is characterized in that in at least one of said hydrophilic binder-based layers, said hydrophilic binder is gelated by complexation with a complexing agent present on a heat-sensitive polymer or copolymer, that is hydrophobic at temperatures higher than its lower critical solution temperature LCST to protect the complexing agent, and water-soluble at temperatures less than its LCST to make the complexing agent accessible, the LCST of the heat-sensitive (co)polymer being higher than the setting temperature of said hydrophilic binder. The material according to the invention can be used as photographic material or as material taking aqueous ink compositions applied by the inkjet printing technique.
    Type: Grant
    Filed: June 13, 2007
    Date of Patent: November 22, 2011
    Assignee: Eastman Kodak Company
    Inventors: Olivier J. Poncelet, Gérard A. Friour, Ilias Iliopoulos
  • Patent number: 8044115
    Abstract: An inkjet ink composition comprising water, pigment particles dispersed with a polymeric dispersant, at least one water-dispersible polyurethane, at least one pyrrolidinone compound, glycerol, and a 1,2-alkanediol having from four to eight carbon atoms.
    Type: Grant
    Filed: September 22, 2008
    Date of Patent: October 25, 2011
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Paul D. Yacobucci, Yongcai Wang, Catherine A. Falkner, Thanhchau T. Nguyen
  • Patent number: 7828426
    Abstract: An inkjet printing system, comprising an inkjet printer and an ink composition comprising: (a) water; (b) dispersed pigment particles; (c) a humectant; and (d) a fluorinated polyurethane additive which is different from any pigment polymeric dispersant in the ink, the additive having a weight average molecular weight of at least 10,000 daltons.
    Type: Grant
    Filed: August 28, 2008
    Date of Patent: November 9, 2010
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Catherine A. Falkner, Paul D. Yacobucci, Kurt M. Schroeder
  • Patent number: 7744206
    Abstract: A process for providing an ozone resistant dye-based image, and a resulting image, includes jetting an ink containing the dye onto a microporous media surface to form a dye-based image, and thereafter jetting over at least a portion of the dye-based image a clear ink overcoat including a transparent polymeric binder containing dispersed inorganic nano particles, wherein the median equivalent circular diameter of all of the dispersed inorganic particles is in the range of 1 to 500 nm. Color fade due to ozone effects is diminished while maintaining jetability.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: June 29, 2010
    Assignee: Eastman Kodak Company
    Inventors: Michael J. Carmody, Thomas B. Brust
  • Patent number: 7732509
    Abstract: An ink composition suitable for ink jet printing comprises a polymeric colorant in a carrier, the colorant containing at least one hydrophilic portion and at least one hydrophobic portion, wherein the composite log Kow of the polymeric colorant is more positive than ?0.7.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: June 8, 2010
    Assignee: Eastman Kodak Company
    Inventor: Mihaela L. Madaras
  • Patent number: 7662485
    Abstract: An organic light-emitting diode (OLED) device produces white light, includes a) an anode; b) a hole-transporting layer disposed over the anode; c) a blue light-emitting layer disposed over the hole-transporting layer; d) an electron-transporting layer disposed over the blue light-emitting layer; e) a cathode disposed over the electron-transporting layer; wherein the hole-transporting layer comprises an entire layer or a partial portion of a layer in contact with the blue light-emitting layer and contains a light-emitting naphthacene compound having a specified formula.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: February 16, 2010
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Tukaram K. Hatwar, Manju Rajeswaran, Natasha Andrievsky
  • Patent number: 7597967
    Abstract: An electroluminescent device comprises a cathode and an anode; and, located therebetween, a light-emitting layer (LEL) comprising at least one hole transporting co-host and at least one electron transporting co-host, together with at least one phosphorescent emitter, and wherein the triplet energy of each of the co-host materials is greater than the triplet energy of the phosphorescent emitter, and further containing an exciton blocking layer comprising a hole transporting material with triplet energy greater or equal to 2.5 eV adjacent the emitting layer on the anode side. The invention provides devices that emit light with high luminous efficiency at low voltage.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: October 6, 2009
    Assignee: Eastman Kodak Company
    Inventors: Marina E. Kondakova, Joseph C. Deaton, Christopher T. Brown, Kevin P. Klubek, Shouquan Huo
  • Patent number: 7588839
    Abstract: An OLED device comprises a cathode and an anode and has located therebetween a light-emitting layer comprising a phosphorescent light-emitting material and a host comprising a compound of a tetravalent atom wherein the four groups bonded to the atom are aromatic rings, at least one of which contains an electron-withdrawing group (EWG) substituent comprising at least three atoms, the compound having a triplet energy of at least 2.7 eV and a LUMO energy within 0.6 eV of the LUMO energy of at least one material in an adjacent layer on the cathode side of the light-emitting layer. Particular embodiments include certain tetravalent silicon compounds. The light-emitting layer emits blue light and provides good luminance and reduced drive voltage.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: September 15, 2009
    Assignee: Eastman Kodak Company
    Inventors: Xiaofan Ren, Christopher T. Brown
  • Patent number: 7579090
    Abstract: An OLED device contains a layer comprising a hole transporting compound, a certain type of oxinoid compound, and a light emitting phosphorescent compound.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: August 25, 2009
    Assignee: Eastman Kodak Company
    Inventors: Christopher T. Brown, Joseph C. Deaton, David W. Place, Marina E. Kondakova, Shouquan Huo
  • Patent number: 7553558
    Abstract: An OLED device comprises a cathode, an anode, and a light-emitting layer therebetween, and additionally comprises a layer between the cathode and the light-emitting layer including a compound comprising one and only one anthracene nucleus bearing no more than two phenanthroline-containing substituents wherein said anthracene nucleus is substituted in the 2-, 3-, 6-, or 7-position with a phenanthroline-containing substituent. When such materials are included in a layer, such as an electron-transporting layer, that provide both desirable electroluminescent properties as well as good device stability.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: June 30, 2009
    Assignee: Eastman Kodak Company
    Inventors: Kevin P. Klubek, Denis Y. Kondakov
  • Patent number: 7553556
    Abstract: An electroluminescent device comprises a light-emitting layer containing a light emitting material that contains an organometallic complex having a partial structure represented by the following formula (I): wherein, M represents a metal selected from group 8, 9, or 10 metals; and one X is a carbon that forms a covalent bond with M and the other two X is are heteroatoms, one of which forms a coordinative bond with M and the other of which forms a covalent bond with M; wherein all of the Xs are linked together to form a dianionic tridentate cyclometallating ligand to form a five or six-membered metallocycle with M where each X can be a part of a separate cyclic or acyclic structure.
    Type: Grant
    Filed: April 8, 2005
    Date of Patent: June 30, 2009
    Assignee: Eastman Kodak Company
    Inventor: Shouquan Huo
  • Patent number: 7517984
    Abstract: A process for forming a facial tris-cyclometallated iridium or rhodium complex isomer comprises heating an original composition containing (a) a meridional isomer of a tris-cyclometallated iridium or rhodium complex in (b) an organic hydrocarbon solvent, a halogenated hydrocarbon solvent, or a combination thereof, to a reaction temperature of least 150° C. for a time sufficient to form a product containing the facial isomer in an increased ratio to meridional isomer compared to the original composition. The process is simple and efficient and provides improved purity.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: April 14, 2009
    Assignee: Eastman Kodak Company
    Inventor: Shouquan Huo
  • Patent number: 7517595
    Abstract: An OLED device comprises a cathode, an anode, a light emitting layer, and on the cathode side of said emitting layer, a further layer, wherein the further layer is an electron-transporting layer containing: a) a first compound that has the lowest LUMO value of the compounds in the layer, the amount being greater than 40% by volume and less than 100% by volume of the layer; and b) at least one second compound that is a low voltage electron transport material, exhibiting a higher LUMO value than the first compound, the total amount of said compound(s) being less than 60% by volume and more than 0% by volume of the layer.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: April 14, 2009
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Tukaram K. Hatwar, Ralph H. Young, Natasha Andrievsky
  • Patent number: 7507486
    Abstract: An OLED device comprises a cathode, an anode, and located therebetween a light emitting layer containing a compound represented by formula (I): wherein M is a d-block transition metal of atomic number greater than 40; the coordination ring C is a triazole ring with the metal as a member of the triazole ring; A is a five- or six-membered ring; B is a five- or six-membered ring; R1 and R2 are groups other than hydrogen and may be joined together; n1 and n2 are independently an integer from 0 to 6; L is a ligand; n3 is zero or an integer and n4 is an integer of at least one.
    Type: Grant
    Filed: August 31, 2005
    Date of Patent: March 24, 2009
    Assignee: Eastman Kodak Company
    Inventor: Xiaofan Ren
  • Patent number: 7508500
    Abstract: A process for characterizing the phase of an organic material in a thin film comprises employing a reference spectrum library for potential phases, subjecting the film to a vibrational spectroscopy measurement to obtain a resulting spectrum; and comparing the resulting spectrum to those in the reference library to characterize the phase of the organic material.
    Type: Grant
    Filed: October 27, 2004
    Date of Patent: March 24, 2009
    Assignee: Eastman Kodak Company
    Inventors: Manju Rajeswaran, Thomas N. Blanton, Barbara J. Stwertka, Joseph L. Lippert, Christopher T. Brown