Patents Represented by Attorney, Agent or Law Firm Bernard Lau
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Patent number: 8344079Abstract: Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing an internal electron donor, a support made by contacting substantially equal molar amounts of a magnesium compound and an epoxy compound in the presence of an aprotic solvent and subsequent treatment with a halogenating agent to provide a magnesium based catalyst support. The catalyst system can further contain an organoaluminum compound and an organosilicon compound. Also disclosed are methods of polymerizing or copolymerizing an alpha-olefin. The methods involve contacting an olefin with a catalyst system containing the solid titanium catalyst component.Type: GrantFiled: December 31, 2007Date of Patent: January 1, 2013Assignee: BASF CorporationInventor: Michael D. Spencer
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Patent number: 8343885Abstract: Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt % to about 20 wt %. Exemplary stabilizers include one or more of ZrO2, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 wt %. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.Type: GrantFiled: December 21, 2010Date of Patent: January 1, 2013Assignee: BASF CorporationInventors: Wolfgang Ruettinger, Ahmad Moini, Bala Ramachandran, Sukwon Choi
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Patent number: 8343326Abstract: Sulfonate-, sulfate-, or carboxylate-capped, alkoxylated anti-misting agents having the structure: R((AO)nX)m((AO)nH)p, and methods of suppressing mist from electrolyte solutions by adding a mist-suppressing amount of one or more compounds selected from the group consisting of compounds of the Formulas R((AO)nX)m((AO)nH)p and R3N+(CH3)2R4, and mixtures thereof, to electrolyte solutions.Type: GrantFiled: July 2, 2008Date of Patent: January 1, 2013Assignee: BASF CorporationInventors: Michael Virnig, Jack Bender, Louis Rebrovic
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Patent number: 8318626Abstract: The present invention relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound containing at least one 1,8-naphthyl diester compound. The 1,8-naphthyl diester compounds include naphthalene-1,8-diyl dicycloalkanecarboxylate derivatives, dicycloalkenecarboxylate derivatives, 8-(cycloalkanecarbonyloxy)naphthalene-1-yl benzoate derivatives, and 8-(cycloalkenecarbonyloxy)naphthalene-1-yl benzoate derivatives. The present invention further relates to catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The present invention also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.Type: GrantFiled: March 1, 2010Date of Patent: November 27, 2012Assignee: BASF CorporationInventor: Main Chang
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Patent number: 8311625Abstract: Methods, compositions, devices, and systems for administration to a biological tissue of a composition comprising a chlorine dioxide source are provided.Type: GrantFiled: January 20, 2010Date of Patent: November 13, 2012Assignee: BASF CorporationInventors: Barry Keven Speronello, Linda Hratko, Frank S. Castellana, Andrew Patrick Full, Marcos Gomez
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Patent number: 8303939Abstract: A non-cytotoxic chlorine dioxide composition and a mixed agent bleaching composition for tooth whitening are disclosed. Methods of use are also provided.Type: GrantFiled: July 15, 2009Date of Patent: November 6, 2012Assignee: BASF CorporationInventors: Barry Keven Speronello, Frank S. Castellana, Linda Hratko
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Patent number: 8298510Abstract: The addition of a compatible metal salt crystal to the organic solution entering the mixer(s) in the solvent extraction stage(s) and/or the stripping stage(s), or to the emulsion mixture of the organic solution and the aqueous solution in the mixer(s), or to the mixture of the organic solution and the aqueous solution in a settler tank(s) following the mixer(s) in the solvent extraction and/or stripping stage(s) following the leaching of metal values from the ore containing that/those value(s) into an aqueous solution, and prior to the further refining of those values in processes, such as electrowinning, during mining operations for those metal values in order to improve the phase separation of the organic phase and the aqueous phase, and to promote the removal of contaminants from the organic phase.Type: GrantFiled: May 16, 2007Date of Patent: October 30, 2012Assignee: BASF CorporationInventors: Eladio Rojas, Hans C. Hein
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Patent number: 8282729Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.Type: GrantFiled: July 26, 2011Date of Patent: October 9, 2012Assignee: BASF CorporationInventors: Daniel S. Fuller, Curtis J. Zimmermann
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Patent number: 8221693Abstract: A two stage-carbon monoxide preferential oxidation article and method that uses a single injection of an O2-containing gas.Type: GrantFiled: August 1, 2005Date of Patent: July 17, 2012Assignee: BASF CorporationInventors: Lawrence Shore, Robert J. Farrauto
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Patent number: 8211819Abstract: The present invention relates to catalyst systems containing solid catalyst components comprising titanium, magnesium, halogen and a 1,8-naphthyl diaryloate internal electron donor compound; organoaluminum compounds and alkyl benzoate derivatives as external electron donors. The present invention also relates to methods of making the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.Type: GrantFiled: December 21, 2009Date of Patent: July 3, 2012Assignee: BASF CorporationInventor: Main Chang
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Patent number: 8211486Abstract: The invention is directed to a process for the hydrogenation of unsaturated triglycerides in the presence of a supported precious metal catalyst and hydrogen, in which process a precious metal catalyst is used, comprising an aggregate of solid support, precious metal nano particles and surfactant or polymer.Type: GrantFiled: May 9, 2005Date of Patent: July 3, 2012Assignee: BASF CorporationInventors: Annemarie Elisa Wilhelmina Beers, Pieter Hildegardus Berben
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Patent number: 8206682Abstract: A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.Type: GrantFiled: May 15, 2009Date of Patent: June 26, 2012Inventors: Lawrence Shore, Ramail Matlin, Robert Heinz
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Patent number: 8207083Abstract: The present invention relates to a catalyst nickel, silica, alumina and magnesium, wherein the nickel to magnesium atomic ratio is 5-75. In particular the present invention relates to a catalyst comprising nickel, silica, alumina and magnesium, wherein the nickel to silicium atomic ratio (Ni/Si) is 2 to 30 to nickel to aluminum atomic ratio (Ni/Al) is 9 to 40 and the nickel to magnesium atomic ratio (Ni/Mg) is 5-75. The invention further relates to a method for preparing such a catalyst. The invention further relates to a process for hydrogenating unsaturated organic compounds.Type: GrantFiled: March 26, 2009Date of Patent: June 26, 2012Assignee: BASF CorporationInventors: Pieter Hildegardus Berben, Tjalling Rekker
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Patent number: 8137581Abstract: A composite article that includes a ClO2-producing material integrated into an organic matrix and methods of using the same are described. The organic matrix of the composite article is formable at a temperature under about 150° C., permits contact between an activating stimulus (e.g., water vapor and/or electromagnetic energy) and the ClO2-producing material when the composite article is exposed to the activating stimulus, and is permeable to ClO2.Type: GrantFiled: July 29, 2004Date of Patent: March 20, 2012Assignee: BASF CorporationInventors: Barry K. Speronello, Linda Hratko, Michael S. Cochran
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Patent number: 8129302Abstract: The disclosed invention relates to a blended hydrous kaolin clay product comprising a platy coarse kaolin clay and a fine, hydrous kaolin clay. The blended kaolin clay product is suitable for use as a raw material component in the formation of cordierite products.Type: GrantFiled: August 18, 2009Date of Patent: March 6, 2012Assignee: BASF CorporationInventors: Sharad Mathur, Michael B. Sigman
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Patent number: 8124261Abstract: The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.Type: GrantFiled: June 20, 2006Date of Patent: February 28, 2012Assignee: BASF CorporationInventor: Lawrence Shore
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Patent number: 8088300Abstract: Disclosed is a stabilized chlorine dioxide generating composition containing an oxy-chlorine salt, an acid source, optionally a free halogen source, and an endothermic agent. The endothermic agent neutralizes heat evolved by exothermic reaction of the oxy-chlorine salt by the endothermic reaction of the endothermic agent. Since the endothermic reaction eliminates and/or mitigates propagation of the exothermic reaction of the oxy-chlorine salt from a localized area through the total mass of the material, the chlorine dioxide generating composition is thereby stabilized during making, storing, or shipping the composition.Type: GrantFiled: June 21, 2006Date of Patent: January 3, 2012Assignee: BASF CorporationInventors: John Byrne, Barry Speronello
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Patent number: 8088214Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.Type: GrantFiled: February 10, 2006Date of Patent: January 3, 2012Assignee: BASF CorporationInventors: Daniel S. Fuller, Curtis J. Zimmermann
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Patent number: 8088212Abstract: An effect pigment formed from a synthetic platelet substrate such as glass flake has improved sparkle by reducing the amount of substrate particles having a size of less than 9 microns and greater than 85 microns. The present effect pigment is useful in cosmetics, personal care products, and industrial applications such as automotive paints.Type: GrantFiled: March 29, 2006Date of Patent: January 3, 2012Assignee: BASF CorporationInventor: Frank Bagala, Sr.
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Patent number: 8083846Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.Type: GrantFiled: August 18, 2004Date of Patent: December 27, 2011Assignee: BASF CorporationInventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller