Patents Represented by Attorney Brian M. Bolam
  • Patent number: 6133224
    Abstract: Process for making a free-flowing, particulate dye transfer inhibiting detergent admix for inclusion in a granular laundry detergent composition consisting essentially of the steps of: charging from 50% to 95%, by weight of the dye transfer inhibiting detergent admix, of a detergent builder into a mixer/granulator; adding to the detergent builder from 5% to 50%, by weight of the dye transfer inhibiting detergent admix, of a dye transfer inhibitor solution to thereby form a mixture; and agglomerating the mixture of the dye transfer inhibitor solution and the detergent builder so as to form the dye transfer inhibiting detergent admix.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: October 17, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Adrian John Waynforth Angell, Gary Ray Cutter, Robert Gary Welch
  • Patent number: 6121229
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the overall steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, in a mixer, wherein first agglomerates are formed, (b) spraying on finely atomized liquid to the first agglomerates in a mixer, wherein second agglomerates are formed, and (c) the second agglomerates are thoroughly mixed in a mixer to provide rounding and growth.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: September 19, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Manivannan Kandasamy
  • Patent number: 6093690
    Abstract: A process for producing an agglomerated detergent composition comprises premixing an acid precursor of a detersive surfactant and a water-soluble or dispersible, modified polyamine in a mixer to form a premix, inputting the premix and dry detergent materials such as builders into a high speed mixer/densifier and neutralizing the acid precursor to form agglomerates and further agglomerating in a moderate speed mixer/densifier to form a detergent composition having a bulk density of at least 650 g/l.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: July 25, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Benjamin Edgar Chapman
  • Patent number: 6087321
    Abstract: Liquid detergent compositions are presented which comprise at least 5%, by weight, anionic surfactants selected from the group of alkyl alkoxy sulfates and alkyl sulfates wherein at least 25%, by weight of the anionic surfactant, is alkyl sulfates; and from about 0.1% to about 5% of an amine cosurfactant of the formula: ##STR1## wherein R.sub.1 is a C.sub.8 -C.sub.12 alkyl group; n is from about 2 to about 4, X is an optional bridging group which is selected from NH, CONH, COO, or O; and R.sub.3 and R.sub.4 are individually selected from H, C.sub.1 -C.sub.4 alkyl, or (CH.sub.2 --CH.sub.2 --O(R.sub.5)) wherein R.sub.5 is H or methyl.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: July 11, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Rajan Keshav Panandiker, Dimitris Lappas, Robert W. Boswell
  • Patent number: 6046153
    Abstract: A process is provided in which selected modified polyamines are incorporated into fully formulated detergent compositions in a manner that unexpectedly results in enhanced cleaning performance. The process involves premixing the modified polyamine with a detersive surfactant or acid precursor thereof, and thereafter, adding adjunct ingredients such as builders and water. The entire mixture is then spray dried to form spray-dried granular detergent composition.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: April 4, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Benjamin Edgar Chapman, James Robert Lickiss, Randall Alan Watson
  • Patent number: 6037318
    Abstract: An improved process for the manufacture of alkaline bleaching compositions, especially liquid and/or gel compositions of high solubility and low abrasiveness, useful to the consumer, especially as products for hard surface cleaning, bleaching or disinfectancy. The products are made by a three-stage process and comprise particular chlorine and bromine bleach sources and particular aminofunctional materials such as low-impurity sulfamate.
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: March 14, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Henry Cheng Na, Michael Charles Frazee, James Charles Theophile Roger Burckett St. Laurent, Kyle David Jones, Marco Petri
  • Patent number: 6017873
    Abstract: Two processes for producing agglomerated high density detergent compositions are provided. On process comprises blending secondary (2,3) alkyl sulfate with a detergency builder to form a homogeneous powder mixture which is agglomerated with a surfactant paste mixture comprising C.sub.10-20 linear alkylbenzene sulfonates, C.sub.10-20 alkyl sulfates, C.sub.10-18 alkyl ethoxy sulfates having from about 1 to about 7 ethoxy groups, alcohol ethoxylates and polyethylene glycol and drying the agglomerates. Another process comprises blending secondary (2,3) alkyl sulfate with a detergency builder to form a homogeneous powder mixture which is agglomerated with a liquid acid precursor of C.sub.10-20 linear alkylbenzene sulfonate so as to form an agglomerated detergent composition which has a density of at least about 650 g/l.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: January 25, 2000
    Assignee: The Procter & Gamble Compnay
    Inventors: Stephen William Sikra, James Bert Royston
  • Patent number: 6013613
    Abstract: Automatic dishwashing detergent compositions comprising a mixed nonionic surfactant system comprising low cloud point and high cloud point nonionic surfactants.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: January 11, 2000
    Assignee: The Procter & Gamble Company
    Inventors: William Michael Scheper, Laura Lee Turner, Kuntal Chatterjee
  • Patent number: 5967157
    Abstract: Automatic dishwashing detergent compositions comprising a nonionic surfactant having the formula:R.sub.1 O[CH.sub.2 CH(CH.sub.3)O].sub.x [CH.sub.2 CH.sub.2 O].sub.y [CH.sub.2 CH(OH)R.sub.2 ]wherein R.sub.1 is a linear or branched, aliphatic hydrocarbon radical having from about 4 to about 18 carbon atoms including mixtures thereof; R.sub.2 is a linear or branched aliphatic hydrocarbon radical having from about 2 to about 26 carbon atoms including mixtures thereof; x is an integer having an average value of from 0.5 to about 1.5; and y is an integer having a value of least about 15; employed in conjunction with a detersive enzyme such as amylase are provided.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: October 19, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Kuntal Chatterjee, Graeme Duncan Cruickshank, Lynda Anne Jones, Eugene Steven Sadlowski
  • Patent number: 5968881
    Abstract: Automatic dishwashing detergent compositions comprising phosphate builder and metal-containing bleach catalyst, preferably catalysts containing manganese and/or selected from selected cobalt/ammonia catalysts. Preferred compositions comprise cobalt bleach catalyst having the formula:[Co(NH3).sub.n (M).sub.m (B).sub.b ]T.sub.ywherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0); and when b=0, then m+n=6, and when b=1, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, wherein y is an integer to obtain a charge-balanced salt (preferably y is 1-3; most preferably 2 when T is a -1 charged anion); and wherein further the catalyst has a base hydrolysis rate constant of less than 0.23M.sup.-1 s.sup.-1 at 25.degree. C.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: October 19, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Donna Jean Haeggberg, William Michael Scheper
  • Patent number: 5965516
    Abstract: The present invention concerns aqueous surfactant composition comprising poly hydroxy fatty acid amides of formula (A), ##STR1## wherein R.sup.2 is C.sub.11 -C.sub.19 alkyl, alkenyl or mixtures thereof, Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain; and in a part of the total amide surfactant (a) R.sup.1 is a methyl group and in the remainder of the total amide surfactant (b) R.sup.1 is an alkyl group with from 3 to 8 carbon atoms; said composition further comprising (c) from 0% to 15% by weight of an organic solvent; wherein the ratio of N-methyl poly hydroxy fatty acid amide (a) to N-alkyl (C.sub.3 -C.sub.8) polyhydroxy fatty acid amide (b), is from 25:1 to 1:1.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: October 12, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Jean-Pol Boutique, Patrick Firmin A. Delplancke
  • Patent number: 5962397
    Abstract: Disclosed are granular detergent components and processes for making these components. The processes comprise the steps of: i) forming the granular detergent component by drying an aqueous solution, the aqueous solution comprising at least 50% of a cationic surfactant, to form a powder; and then ii) densifying the powder in the presence of a detergent powder selected from the group consisting of aluminosilicate, carbonate, bicarbonate, silicate, sulphate, citrate, clay and mixtures thereof and an acid selected from the group consisting of citric, sulphuric, hydrochloric, polycarboxylic acids and mixtures thereof. This granular detergent component consists essentially of the cationic surfactant, the acid and the particulate builder and the granular detergent component has a reserve acidity of at least 1.0 g HCl/100 g.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: October 5, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Mark William Ridyard, David William York
  • Patent number: 5958858
    Abstract: Detergent compositions comprising: a) a dianionic cleaning agent comprising a structural skeleton of at least five carbon atoms to which two anionic substituent groups spaced at least three atoms apart are attached, wherein one anionic substituent group is a sulfate group and the other anionic substituent is selected from sulfate and sulfonate; b) a nonionc surfactant (preferably alkyl ethoxylates, especially alkyl ethoxylates having an average of at least 3 ethoxylates); c) in total, less than about 20% by weight anionic surfactants; d) optionally, co-surfactants selected from the group consisting of amphoteric surfactants, zwitterionic surfactants, cationic surfactants, and mixtures thereof; and e) detergent composition adjunct ingredients; and wherein the weight ratio of anionic surfactant to nonionic surfactant plus any optional co-surfactant d) is with the range of from about 1:1 to about 1:10.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: September 28, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Jean-Luc Philippe Bettiol, Peter Robert Foley, Stephen Wayne Heinzman, Barry Thomas Ingram, Alison Lesley Main
  • Patent number: 5955416
    Abstract: The present invention relates to detergent compositions comprising lipases, a lipase compatible anionic surfactant system, and a gemini polyhydroxy fatty acid amide. The anionic surfactant system comprises alkyl alkoxylated sulphates having specific ratios of mono-, di- and tri-alkoxylated sulphates. The detergent compositions provide improved greasy soil removal over a wide range of temperatures.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: September 21, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Barry Thomas Ingram, Christian Leo Marie Vermote
  • Patent number: 5948744
    Abstract: Detergent compositions comprise, by weight, from 0.01% to 10% of a nonionic polysaccharide ether having a degree of polymerization of at least 100, and from 0.01% to 5% of a soil release agent. The soil release agent comprises at least one oxyalkylene unit and at least one terephthalate or substituted terephthalate unit and has a molecular weight of less than 10,000. The detergent composition comprises the polysaccharide ether and the soil release agent in a weight ratio of from 0.1:1 to 20:1.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: September 7, 1999
    Inventors: Gerard Marcel Baillely, Nour-Eddine Guedira, Robin Gibson Hall
  • Patent number: 5919271
    Abstract: The invention relates to a detergent composition which comprises a nonionic polysaccharide ether, a surfactant, a dye transfer inhibition agent, a cellulase enzyme and a chelating agents. In addition the invention further relates to a method of treating fabrics with the detergent composition.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: July 6, 1999
    Assignee: Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Robin Gibson Hall, Nour-Eddine Guedira
  • Patent number: 5916481
    Abstract: Low hue photobleaching compositions comprising organosilicon(IV) phthalocyanine and naphthalocyanines having Q-band absorption maxima at wavelengths greater than 660 nm and increased triplet state yields whereby production of singlet oxygen is increased. Use of Si.sup.4+ phthalocyanine and naphthalocyanines compounds in photobleaching compositions allows for formulation of low hue laundry compositions, bleach compositions, and hard surface cleaners.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: June 29, 1999
    Assignee: The Procter & Gamble Company
    Inventor: Alan David Willey
  • Patent number: 5914307
    Abstract: A process for preparing a high density detergent-composition is provided. The process comprises the steps of:a) drying detergent agglomerates to a free moisture content of less than about 7% by weight thereby forming substantially dry detergent agglomerates; andb) charging the substantially dry detergent agglomerates into a moderate speed mixer/densifier to densify the substantially dry detergent agglomerates to form a high density detergent having a density of at least about 900 g/l. In preferred embodiments, the process also comprises forming hydrated detergent agglomerates via the steps of hydrating an anhydrous hydratable detergent salt to a degree of hydration of at least about 60% and agglomerating the hydrated detergent salt by charging the hydrated detergent salt and additional detergent ingredients into a high speed mixer/densifier and agglomerating the hydrated detergent salt and additional detergent ingredients to form hydrated detergent agglomerates.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: June 22, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Frank William DeNome, John Frederick Lange
  • Patent number: 5912221
    Abstract: The present invention relates to laundry detergent compositions which are suitable for use in inhibiting the re-deposition of fugitive dyes onto fabric during the course of the laundry process, said compositions comprising:a) 0.01% to 3% by weight, of a substantially water-insoluble polymeric dye transfer inhibiting agent, said agent consisting of a substantially water-insoluble cross linked polymer selected from the group consisting of polyamine N-oxide polymers; copolymers of N-vinylpyrrolidone and N-vinylimidazole; polyvinylpyrrolidones; polyvinyloxazolidones; polyvinylimidazoles; and mixtures thereof; wherein said agents have a particle size less than 50 microns;b) from 0.2% to 25% by weight of a surfactant system, said surfactant system comprising one or more detersive surfactants selected from the group consisting of anionic, nonionic, cationic, zwitterionic, ampholytic surfactants, and mixtures thereof; andc) the balance carriers and adjunct ingredients.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: June 15, 1999
    Assignee: Procter & Gamble Company
    Inventors: Petrus Johannes Van Leeuwen, Andre Christian Convents, Alfred Busch, Thierry Laurent Cachet, Conny Erna Alice Joos
  • Patent number: 5912218
    Abstract: Automatic dishwashing detergent compositions comprising a mixed surfactant system comprising low cloud point nonionic surfactant and charged surfactant selected from anionic surfactants, zwitterionic surfactants, and mixtures thereof
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 15, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Kuntal Chatterjee, William Michael Scheper