Patents Represented by Attorney C. S. Janes, Jr.
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Patent number: 5405811Abstract: This invention is directed to a transparent glass which, at a thickness of 2 mm, transmits less than 1% of ultraviolet radiation having a wavelength of 380 nm and exhibits a green fixed tint bounded by apices A,C,D,E,A of the drawing, a purity between 18-32%, and a dominant wavelength between 554-564 nm, said glass having a composition consisting essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 65-72 Na.sub.2 O + K.sub.2 O 15-21 B.sub.2 O.sub.3 3-8 CaO 0-4 Al.sub.2 O.sub.3 0.5-5 ZnO 0-9 Na.sub.2 O 6-12 CaO + ZnO 1-5 K.sub.2 O 6-12 Fe.sub.2 O.sub.3 4.8-7.Type: GrantFiled: February 28, 1994Date of Patent: April 11, 1995Assignee: Corning IncorporatedInventors: David J. Kerko, David W. Morgan
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Patent number: 5403789Abstract: A transparent glass which, at a thickness of 2 mm, transmits less than 1% of ultraviolet radiation having a wavelength of 380 nm and exhibits a brown fixed tint bounded by apices A, B, D, F, A of the drawing, a purity between 48-70%, and a dominant wavelength between 580-588 nm, said glass having a composition consisting essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 65-72 CaO 0-5.5 B.sub.2 O.sub.3 3-8 ZnO 0-4 Na.sub.2 O 6-10 CaO + ZnO 2-5.5 K.sub.2 O 7-12 Fe.sub.2 O.sub.3 3-5 Na.sub.2 O + K.sub.2 O 15-20 Se 0.01-2 Al.sub.2 O.sub.3 0-4 NiO 0-0.12.Type: GrantFiled: February 28, 1994Date of Patent: April 4, 1995Assignee: Corning IncorporatedInventors: David J. Kerko, Wagner R. Lozano, David W. Morgan
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Patent number: 5395413Abstract: A method of producing a fused silica product comprising introducing a silicon-containing, organometallic compound into a flame to form molten silica particles, and collecting the molten silica particles in a furnace having a crown and cup such that a fused silica product is obtained, wherein at least the furnace crown is formed from a porous, fired, zircon refractory having a sodium ion content of less than 30 ppm. The fused silica product produced by the method has a sodium ion contamination level below 100 parts per billion.Type: GrantFiled: December 16, 1993Date of Patent: March 7, 1995Assignee: Corning IncorporatedInventors: Daniel R. Sempolinski, Latha I. Swaroop
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Patent number: 5392376Abstract: This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga.sub.2 S.sub.3, 0-35% RS.sub.x, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln.sub.2 S.sub.3, wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS.sub.x, wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga.sub.2 S.sub.3, 0-10% R.sub.2 S.sub.Type: GrantFiled: April 11, 1994Date of Patent: February 21, 1995Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Mark A. Newhouse
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Patent number: 5389584Abstract: This invention is directed to the production of transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, said glasses consisting essentially, expressed in terms of mole percent on the sulfide basis, of 55-95% GeS.sub.2, 2-40% As.sub.2 S.sub.3, 0.01-20% R.sub.2 S.sub.3, wherein R is at least one trivalent network forming cation selected from the group consisting of gallium and indium, 0-10% MS.sub.x, wherein M is at least one modifying cation selected from the group consisting of aluminum, barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-20% total of at least one halide selected from the group consisting of chloride and fluoride, 0-5% total selenide, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value.Type: GrantFiled: April 11, 1994Date of Patent: February 14, 1995Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Mark A. Newhouse
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Patent number: 5387558Abstract: This invention is directed to the formation of glass-ceramic articles which exhibit a yellow coloration in visible light and fluoresce with a yellow coloration while being exposed to ultraviolet radiation. The yellow coloration is produced through the incorporation of a color package comprising 0.05-0.5% V.sub.2 O.sub.5, 0.25-5% CeO.sub.2, and 0.1-1% Tb.sub.2 O.sub.3. When the glass-ceramic articles contain tetrasilicic fluormica as the predominant crystal phase, they are eminently suitable for use as dental prosthetic materials.Type: GrantFiled: May 2, 1994Date of Patent: February 7, 1995Assignee: Corning IncorporatedInventor: David G. Grossman
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Patent number: 5385871Abstract: This invention is directed to a glass frit composition essentially free from lead and cadmium exhibiting a linear coefficient of thermal expansion (25.degree. C.-300.degree. C.) between about 75-85.times.10.sup.-7 /.degree.C., good flow at temperatures between about 950.degree.-1000.degree. C., a softening point between about 650.degree.-725.degree. C., and excellent resistance to attack by alkaline detergent and hydrochloric acid, said frit consisting essentially, expressed in terms of weight percent on the oxide basis (except for the fluorine content), of______________________________________ SiO.sub.2 49-55 MgO 0-2 B.sub.2 O.sub.3 13-20 CaO 1-7 Al.sub.2 O.sub.3 4.5-7 SrO 0-8 Na.sub.2 O 5-8.5 BaO 0-11 K.sub.2 O 5-8.5 ZnO 0-2 Na.sub.2 O + K.sub.2 O 11-16 F 0.25-3.Type: GrantFiled: March 7, 1994Date of Patent: January 31, 1995Assignee: Corning IncorporatedInventors: Jaroslava M. Nigrin, Paul L. Rose
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Patent number: 5374595Abstract: This invention is related to glasses for use as substrates in flat panel display devices; more specifically, for use as substrates in LCDs which utilize polycrystalline silicon thin film transistors. The compositions for the inventive glasses are essentially free from alkali metal oxides and consist essentially, in mole percent, of______________________________________ SiO.sub.2 64-70 Y.sub.2 O.sub.3 0-5 Al.sub.2 O.sub.3 9.5-14 MgO 0-5 B.sub.2 O.sub.3 5-10 CaO 3-13 TiO.sub.2 0-5 SrO 0-5.5 Ta.sub.2 O.sub.5 0-5 BaO 2-7 Nb.sub.2 O.sub.5 0-5 MgO + CaO + SrO + BaO 10-20.Type: GrantFiled: November 22, 1993Date of Patent: December 20, 1994Assignee: Corning IncorporatedInventors: William H. Dumbaugh, Jr., Josef C. Lapp, Dawne M. Moffatt
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Patent number: 5353148Abstract: This invention relates to an electrochromic device comprising a layer (2') of an electrochromic product held between two conducting layers (5',6') each formed on one face of a transparent plate (3',4'), electrodes formed on each of the conducting layers, and a source of direct current for selectively supplying these electrodes with electrical energy. Electrodes (8', 9', 10, 11) are of elongated shape and extend over facing surfaces of the two conducting layers (5',6'), essentially symmetrical with respect to the plane of the electrochromic layer (2').The invention has application to windows in the building industry or the automobile industry (windshields, windows, rear view mirrors, etc.Type: GrantFiled: August 21, 1992Date of Patent: October 4, 1994Assignee: Corning IncorporatedInventors: Bernard A. G. Eid, Jean-Pierre Themont
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Patent number: 5352638Abstract: This invention is directed to the production of thermally crystallizable glasses which can be crystallized in situ via heat treatment into glass-ceramic articles containing a nickel spinelloid as the predominant crystal phase. The glasses consist essentially, in weight percent, of 40-60% SiO.sub.2, 10-35% Al.sub.2 O.sub.3, 5-35% NiO, 0-20% MgO, and 0-15% total TiO.sub.2 and/or ZrO.sub.2. The preferred glasses contain at least 2% MgO.Type: GrantFiled: February 22, 1994Date of Patent: October 4, 1994Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson
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Patent number: 5350716Abstract: There is disclosed a fiber-reinforced composite having a high degree of fracture toughness and being composed of a glass-ceramic matrix reinforced with silicon carbide or graphite type fibers, the predominant crystal phase of the matrix glass-ceramic being canasite, and/or agrellite, and/or fedorite.Type: GrantFiled: August 9, 1984Date of Patent: September 27, 1994Assignee: Corning IncorporatedInventors: George H. Beall, Kenneth Chyung, Mark P. Taylor
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Patent number: 5346865Abstract: This invention is directed to the production of transparent glasses exhibiting transmission far into the infrared regime of the radiation spectrum. The glasses consist essentially, in mole percent, of 42-55% CdF.sub.2 and/or CdCl.sub.2, 30-40% NaF and/or NaCl, 2-20% total of BaF.sub.2 and/or BaCl.sub.2 +KF and/or KCl, consisting of 0-15% BaF.sub.2 and/or BaCl.sub.2 and 0-7% KF and/or KCl, 1-12% total of at least one stabilizing metal halide selected from the group LiX, BeX.sub.2, MgX.sub.2, MnX.sub.2, PbX.sub.2, TlX, COX.sub.2, and ZnX.sub.2, and 0,005-0.5% REX.sub.3, wherein Re is at least one rare earth metal selected from the lanthanide series of rare earth metals and X is at least one halide selected from the group consisting of fluoride, chloride, and bromide. The preferred glasses contain at least 2% each of BaF.sub.2 and/or BaCl.sub.2 and KF and/or KCl.Type: GrantFiled: July 6, 1993Date of Patent: September 13, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Frank A. Annunziata, Roger F. Bartholomew, Mark A. Newhouse, Mark L. Powley, Andrea L. Sadd
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Patent number: 5342426Abstract: This invention is directed to a method for preparing glass sheet having surfaces which are essentially defect-free and equivalent in smoothness to polished glass surfaces which comprises the steps of: Two different batches of alkali-metal-free batches are melted and formed into a laminated sheet and the first glass is enclosed by the second glass. The second glass is 1000 times more soluble than the first glass. The laminate is contacted with an acid to dissolve the second glass wherein the first glass remains with essentially defect free surfaces.Type: GrantFiled: July 16, 1993Date of Patent: August 30, 1994Assignee: Corning IncorporatedInventor: William H. Dumbaugh, Jr.
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Patent number: 5343260Abstract: This invention is directed to the fabrication of composite lenses consisting of a transparent thermoset polymer exhibiting an index of refraction of at least 1.58 and a thin glass element of essentially constant thickness adhered to the front surface of the polymer without the use of an adhesive, the glass element having a thickness not exceeding 0.3 mm and the thermoset polymer being an aromatic epoxy resin.Type: GrantFiled: July 1, 1992Date of Patent: August 30, 1994Assignee: Corning IncorporatedInventors: David Henry, Andre J. Vachet, Jacques J. Vial
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Patent number: 5332530Abstract: This invention concerns an electrolytic material in the form of a solid gel for the modulation of light comprising a homogeneous mixture of:(A) at least one organic solvent;(B) at least one salt of an electrodepositable metal;( C ) at least one organic acid; and(D) at least one salt of a non-electrodepositable metal that facilitates the solubilization of metal salt (B);characterized in that it comprises in addition:(E) at least one agent gelling said mixture to a non-flowing, transparent, solid gel state.Type: GrantFiled: August 31, 1992Date of Patent: July 26, 1994Assignee: Corning IncorporatedInventors: Bernard A. G. Eid, Pascal J. J. Marque
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Patent number: 5326728Abstract: This invention is directed to the production of lead-free enamels containing finely-divided glass particles, finely-divided pigment particles, and an organic binder wherein the glass particles consist essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 35-50 Li.sub.2 O + Na.sub.2 O + K.sub.2 O <8 B.sub.2 O.sub.3 23-30 CaO 1-5 Al.sub.2 O.sub.3 10-22 CaO + MgO + ZnO + BaO + SrO <7 Li.sub.2 O 1-3 TiO.sub.2 0-2 Na.sub.2 O 0-3 ZrO.sub.2 0-5 K.sub.2 O 2-5 ______________________________________said glass having a softening temperature T.sub.L above 650.degree. C. and thermal expansion coefficient below 60.times.10.sup.-7 /.degree.C. Among other applications, said glass can be used for the decoration of low-expansion glass-ceramic cooking plates.Type: GrantFiled: October 12, 1993Date of Patent: July 5, 1994Assignee: Corning IncorporatedInventors: Gerard R. M. Boury, Daniel L. G. Ricoult
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Patent number: 5326730Abstract: This invention is directed to glass compositions particularly designed for use as substrates in flat panel display devices and, more expressly, for use as substrates in LCDs which employ polycrystalline silicon thin film transistors. The glass compositions are essentially free from alkali metal oxides and consist essentially, in mole percent, of______________________________________ SiO.sub.2 65-76 MgO 0-5 ZrO.sub.2 0-2.5 Al.sub.2 O.sub.3 7-11 CaO 0-10 TiO.sub.2 0-3 BaO 12-19 SrO 0-10 Ta.sub.2 O.sub.5 0-3 B.sub.2 O.sub.3 0-5 MgO + 0-15 ZrO.sub.2 + 0.5-5. CaO + TiO.sub.2 + SrO Ta.sub.2 O.sub.Type: GrantFiled: May 17, 1993Date of Patent: July 5, 1994Assignee: Corning IncorporatedInventors: William H. Dumbaugh, Jr., Josef C. Lapp
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Patent number: 5323191Abstract: This invention is directed to the production of glass-plastic lenses consisting of a thin glass element bonded to a relatively thick transparent lens or lens preform made of poly(diethylene glycol)bis(allyl carbonate) by a transparent thermoset, polyurethane adhesive layer of optical quality having an elongation at rupture of at least 200% and an elastic modulus in the range of 0.13-10 MPa and at 100% elongation.Type: GrantFiled: July 1, 1992Date of Patent: June 21, 1994Assignee: Corning IncorporatedInventors: Eric Firtion, David Henry, Jean-Jacques Theron, Andre J. Vachet, Jacques J. Vial
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Patent number: 5300465Abstract: A transparent photochromic glass displaying a pink hue in the darkened state which, in bodies of 2 mm cross section, will exhibit the following optical properties:(a) a clear (undarkened) luminous transmittance greater than 82%;(b) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at 25.degree. C. between about 20-32%;(c) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at 40.degree. C. between about 35-55%;(d) a rate of fading such that the luminous transmittance after 5 minutes' removal from actinic radiation at 25.degree. C. will be at least 30 percentage units higher and will exhibit a luminous transmittance greater than 50%;(e) a x trichromatic coordinate between 0.3500 and 0.3700; and(f) a y trichromatic coordinate between 0.3250 and 0.3450;said glass consisting essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 52-58 ZrO.sub.2 1.5-2.8 K.sub.2 O 4-8 B.sub.2 O.sub.Type: GrantFiled: July 26, 1993Date of Patent: April 5, 1994Assignee: Corning IncorporatedInventors: Luc Grateau, Michel Prassas
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Patent number: 5273834Abstract: This invention is directed to the fabrication of magnetic memory storage devices which consist essentially of a head pad and a rigid information disc, that disc consisting essentially of a rigid substrate having a layer of magnetic media joined to the surface of said substrate through an underlayer. The invention is particularly drawn to the substrate for the information disc which is composed of a glass-based material containing 0.05-2% by weight total of cobalt oxide and/or iron oxide and/or nickel oxide. The most preferred glass-based material comprises a glass-ceramic wherein canasite constitutes the predominant crystal phase.Type: GrantFiled: January 25, 1993Date of Patent: December 28, 1993Assignee: Corning IncorporatedInventors: Herbert L. Hoover, Roger A. Miller, Linda R. Pinckney, Brent M. Wedding