Abstract: The present invention relates to an imaged article including a substrate having a primed surface layer. The primed surface layer is included of a base polymer having a solubility parameter, molecular weight (Mw) and glass transition temperature within a specified range. The presence of the primer improves the overall image quality by improving at least one property including ink uptake, dot gain, color density and/or ink adhesion. Preferred primer compositions are soluble at least in part in the ink composition resulting in an increase in ink layer thickness that further improves the durability and/or day/night color balance. A variety of substrates may be primed including various sheeting for traffic control signage and commercial graphic films for advertising and promotional displays.

Abstract: A method for molding and aligning microstructures on a patterned substrate using a microstructured mold. A slurry containing a mixture of a ceramic powder and a curable fugitive binder is placed between the microstructure of a stretchable mold and a patterned substrate. The mold can be stretched to align the microstructure of the mold with a predetermined portion of the patterned substrate. The slurry is hardened between the mold and the substrate. The mold is then removed to leave microstructures adhered to the substrate and aligned with the pattern of the substrate. The microstructures can be thermally heated to remove the binder and optimally fired to sinter the ceramic powder.

Abstract: The invention relates to optical filters comprising an opacified portion. The optical filters are preferably suitable for use in illuminators for weathering devices.

Abstract: A detection system determines the position of an object moving along a first direction. The system includes a magnetic field source generating a magnetic field signal and a magnetic field detection system coupled to the object. The detection system includes a source interface module with magnetic field sensors positioned a known distance apart along a second direction different from the first direction. Each sensor detects the magnetic field generated by the magnetic field source and generates a magnetic field signal. A processing module processes the magnetic field intensity signal produced by the source interface module. The processing module generates data for each sensor in the source interface module, which is made up of points representing peak magnetic field and sensor location along the second direction. The points are compared to determine the distance of the object from the magnetic field source along the second direction.

Abstract: A exposed-lens retroreflective article exhibiting retroreflection under dry and wet conditions is provided. The inventive article comprises a first set of optical elements having a first reflective layer disposed on the embedded portion of the elements. The first set contributes mainly to dry retroreflection. The article further comprises a second set of optical elements having a second reflective layer behind a spacing layer. The second set contributes mainly to wet retroreflection. In one embodiment, the first and second sets of optical elements have substantially the same average diameters, refractive index, and density.

Abstract: The present invention provides a new sheeting article that may suitably include: a carrier having a first major surface and a second major surface; and a plurality of discrete segments of a sheeting (e.g., a retroreflective sheeting), wherein the sheeting has a first major viewing surface and a second major opposing surface, and the first major viewing surface of the sheeting is preferably removably attached to the second major surface of the carrier. Preferably, the first major surface of the carrier comprises a release surface, the second major opposing surface of the sheeting comprises an adhesive, the article is provided in the form of a roll, and the adhesive surface of the sheeting is adjacent the release surface of an adjacent layer of the roll. In a presently preferred embodiment the present invention provides novel easy-to-use truck conspicuity sheeting.

Abstract: A polymerizable composition that includes a monomer of the formula wherein X is hydrogen or one or more of methyl, chlorine, bromine or iodine, R1 is a straight or branched alkyl linking group of 2 to 12 carbon atoms, R2 is hydrogen or methyl, and n is 1 to 3; and a monomer of the formula wherein X1 and X2 are each independently hydrogen or one or more of methyl, chlorine, bromine or iodine, and R2 is hydrogen or methyl is described having a high index of refraction and being suitable for use in forming an optical product.

Abstract: The present invention relates to colored articles such as flexible films and retroreflective sheeting that exhibit an improvement in color stability.

Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.

Abstract: The invention relates to articles comprising a sheeting having a microstructured surface that reflects light in a moiré-like pattern. The invention further relates to methods of making a master and replicas thereof including tooling that results in sheeting having such pattern. A preferred method comprises forming V-shaped grooves in a substrate (e.g. metal plate) wherein the intersections of three grooves form cube-corner elements. The cube-corner elements are formed in such a manner that adjacent parallel grooves have substantially the same groove spacing and groove depth throughout the array. The master as well as corresponding tooling and sheeting preferably have a groove spacing within the range of about 0.0005 inches (0.0127 mm) to about 0.007 inches (0.1778 mm) throughout the array and more preferably a groove spacing of less than about 0.004 inches (0.1016 mm).

Abstract: Adhesives having a microreplicated topography are prepared from contacting a microembossed pattern to a layer of adhesive. When an adhesion interface is established between the layer of adhesive and a supporting substrate, the topography of the adhesive surface controls the performance of the adhesion interface. Articles having microreplicated adhesive surfaces are also disclosed that have an advantage of providing microchannels for fluid egress for an effective period of time. Multiple microeombossed patterns produce microreplicated adhesive surfaces having both microchannels for fluid egress and pegs for improved adhesive properties.

Abstract: The present disclosure is directed to an optical filter that advantageously approximates sunlight that is both durable and stable for long periods of time when subject to harsh light intensity, thermal and moisture loads of accelerating weathering devices. The optical filter includes a glass having a lead content of between 0.5% and 50% by weight. In some examples, the filter can be constructed to have a thickness of 0.7 mm to 10 mm. In another aspect of the disclosure, the optical filter is part of an optical filter assembly suitable for manipulating spectral power distribution. The optical filter assembly includes a lead glass optical filter having a lead content of between 0.5% and 50% by weight and an ultraviolet transmissive optical filter. In one example, the ultraviolet transmissive optical filter is constructed from quartz glass. The ultraviolet transmissive optical filter can further include an infrared absorbing coating.

Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments having the general structure Rf-[G]m(CH2)n—X wherein Rf is a fluorinated alkyl group, G is a divalent linking group selected from oxygen (—O—) and sulfonamido (—SO2R—), m is an integer ranging from 0 to 1, n is an integer ranging from 1 to 24, and X is polar group or polar group containing radical. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements.

Abstract: The present invention relates to an imaged article comprising a substrate having a primed surface layer. The primed surface layer is comprised of a base polymer having a solubility parameter, molecular weight (Mw) and glass transition temperature within a specified range. The presence of the primer improves the overall image quality by improving at least one property including ink uptake, dot gain, color density and/or ink adhesion. Preferred primer compositions are soluble at least in part in the ink composition resulting in an increase in ink layer thickness that further improves the durability and/or day/night color balance. A variety of substrates may be primed including various sheeting for traffic control signage and commercial graphic films for advertising and promotional displays.

Abstract: The present-invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements.

Abstract: The invention relates to a method of making retroreflective sheeting and other articles prepared from casting a moldable synthetic resin onto a tool having a microstructured surface.

Abstract: The invention relates to articles comprising a substrate comprising an ink receptive layer and an ink-jet printed image as well as methods of ink jet printing. The ink receptive layer comprises certain urethane-containing polymers and blends.

Abstract: A method of producing a substrate (12) for a plasma display panel, which comprises the steps of: contacting a rib precursor composition (32) containing a first photo-setting initiator having a first absorption edge and a first photo-setting component, closely with a base (12); filling a mold (30), obtained by photo-setting of a second photo-setting component in a presence of a second photo-setting initiator having a second absorption edge whose wavelength is shorter than that corresponding to the first absorption edge of the first photo-setting initiator, with the rib precursor composition (32); irradiating the rib precursor composition (32) with light having a wavelength longer than that corresponding to the second absorption edge to set the rib precursor composition (32), thereby forming a rib (34) on the base (12); and removing the mold (30) from the resulting base (12) on which the rib (34) is formed.

Abstract: The invention discloses form constructions and methods of making form constructions comprising a substrate having a printable surface portion and a sticker. In preferred embodiment the sticker is a face adhering validation sticker and/or the form substrate comprises a cutout with the viewing surface of the sticker releasably attached to the perimeter of the cutout and exposed through the cutout.

Abstract: A pavement marking article that has an adhesive composition for adhering the article to a pavement substrate, where the adhesive composition includes a reaction product of an acrylic acid ester of a monohydric alcohol whose homopolymer has a Tg less than 0° C., a non-polar ethylenically unsaturated monomer, and 0-10 parts by weight of a polar ethylenically unsaturated monomer. Preferably the amount of the acrylic acid ester is about 60-90 parts by weight, and the amount of the non-polar ethylenically unsaturated monomer is about 10-40 parts by weight. Also, a raised pavement marker that comprises: (a) a pavement marker body having upper and lower surfaces and an apparent flexural modulus of at least about 50,000 psi and (b) a pressure sensitive adhesive layer disposed upon the lower surface of the marker, wherein the adhesive has: (i) a transition region that begins at a frequency of about 10,000 radians/s or more and extends to a frequency of about 100 radians/s or less at about 25° C.