Patents Represented by Attorney, Agent or Law Firm Cynthia S. Kovacevic
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Patent number: 6933078Abstract: This invention relates to crosslinked polymers useful as electrolytes in rechargeable batteries, to electrolytes containing such crosslinked polymers, to methods for making such polymer electrolytes, to electrodes incorporating such crosslinked polymers, to rechargeable batteries employing such crosslinked polymers as the electrolyte and to methods for producing such batteries.Type: GrantFiled: December 18, 2002Date of Patent: August 23, 2005Assignee: Valence Technology, Inc.Inventors: Biying Huang, George W. Adamson
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Patent number: 6913855Abstract: A method for making an active material comprises the steps of forming a slurry, spray drying the slurry to form a powdered precursor composition, and heating the powdered precursor composition at a temperature and for a time sufficient to form a reaction product. The slurry has a liquid phase and a solid phase, and contains at least an alkali metal compound and a transition metal compound. Preferably the liquid phase contains dissolved alkali metal compound, and the solid phase contains an insoluble transition metal compound, an insoluble carbonaceous material compound, or both. Electrodes and batteries are provided that contain the active materials.Type: GrantFiled: July 22, 2002Date of Patent: July 5, 2005Assignee: Valence Technology, Inc.Inventors: Johnnie Stoker, James Hodge
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Patent number: 6815122Abstract: Electrode active materials comprising lithium or other alkali metals, a transition metal, and a phosphate or similar moiety, of the formula: Aa+xMbP1−xSixO4 wherein (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0<a<1.0 and 0≦x≦1; (b) M comprises one or more metals, comprising at least one metal which is capable of undergoing oxidation to a higher valence state, where 0<b≦2; and wherein M, a, b, and x are selected so as to maintain electroneutrality of the compound. In a preferred embodiment, M comprises at least one transition metal selected from Groups 4 to 11 of the Periodic Table. In another preferred embodiment, M comprises M′cM″d, where M′ is at least one transition metal from Groups 4 to 11 of the Periodic Table; and M″ is at least one element from Groups 2, 3, 12, 13, or 14 of the Periodic Table, and c+d=b. Preferably, 0.1≦a≦0.8.Type: GrantFiled: March 6, 2002Date of Patent: November 9, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
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Patent number: 6794084Abstract: The present invention relates general to a method for making an alkali metal hydrogen phosphate of the general formula AxH3−xPO4, wherein A is an alkali metal and 0≦x≦3, prepared by admixing an alkali metal-containing compound, a phosphate-supplying compound, and water, where water is present in the mixture at a level of from about 5% to 25% by weight.Type: GrantFiled: July 26, 2002Date of Patent: September 21, 2004Assignee: Valence Technology, Inc.Inventors: George W. Adamson, Jeremy Barker, Titus Faulkner, M. Yazid Saidi, Jeffrey Swoyer
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Patent number: 6777132Abstract: The present invention relates to novel electrode active materials represented by the general formula AaMb(XY4)cZd, wherein: (a) A is one or more alkali metals, and 0<a≦8; (b) M is at least one metal capable of undergoing oxidation to a higher valence state, and 1≦b≦3; (c) XY4 is selected from the group consisting of X′O4−xY′x, X′O4−yY′2y, X″S4, and a mixture thereof, where X′ is P, As, Sb, Si, Ge, S, and mixtures thereof; X″ is P, As, Sb, Si, Ge, and mixtures thereof, Y′ is halogen, 0≦x<3, 0<y<4, and 0<c≦3; and (d) Z is OH, a halogen, or mixtures thereof, and 0<d≦6.Type: GrantFiled: October 26, 2001Date of Patent: August 17, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
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Patent number: 6730281Abstract: A method for carrying out solid state reactions under reducing conditions is provided. Solid state reactants include at least one inorganic metal compound and a source of reducing carbon. The reaction may be carried out in a reducing atmosphere in the presence of reducing carbon. Reducing carbon may be supplied by elemental carbon, by an organic material, or by mixtures. The organic material is one that can form decomposition products containing carbon in a form capable of acting as a reductant. The reaction proceeds without significant covalent incorporation of organic material into the reaction product. In a preferred embodiment, the solid state reactants also include an alkali metal compound. The products of the method find use in lithium ion batteries as cathode active materials. Preferred active materials include lithium-transition metal phosphates and lithium-transition metal oxides.Type: GrantFiled: May 17, 2002Date of Patent: May 4, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer, Ming Dong
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Patent number: 6723470Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.Type: GrantFiled: July 18, 2001Date of Patent: April 20, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
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Patent number: 6720112Abstract: An electrochemical active material contains a lithiated zirconium, titanium, or mixed titanium/zirconium oxide. The oxide can be represented by the formula LiM′M″XO4, where M′ is a transition metal, M″ is an optional three valent non-transition metal, and X is zirconium, titanium, or a combination of the two. Preferably, M′ is nickel, cobalt, iron, manganese, vanadium, copper, chromium, molybdenum, niobium, or combinations thereof. The active material provides a useful composite electrode when combined with a polymeric binder and electrically conductive material. The active material can be made into a cathode for use in a secondary electrochemical cell. Rechargeable batteries may be made by connecting a number of such electrochemical cells.Type: GrantFiled: October 2, 2001Date of Patent: April 13, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
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Patent number: 6720315Abstract: The present invention relates to a class of compounds represented by the Formula 1. or a pharmaceutically acceptable salt thereof, pharmaceutical compositions comprising compounds of the Formula 1, and methods of selectively inhibiting or antagonizing the &agr;V&bgr;3 and/or the &agr;V&bgr;5 integrin.Type: GrantFiled: June 15, 2001Date of Patent: April 13, 2004Assignee: Pharmacia CorporationInventors: Thomas Rogers, Michael Clare, Hwang-Fun Lu, Mark Russell, James W. Malecha, Ish Kumar Khanna, Thomas Penning, Srinivasan Raj Nagarajan, Heather Stenmark
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Patent number: 6720110Abstract: The invention provides an electrochemical cell which comprises a first electrode and a second electrode which is a counter electrode to said first electrode. The first electrode comprises a phosphorous compound of the nominal general formula Li3E′aE″b(PO4)3, desirably at least one E is a metal; and preferably, Li3M′M″(PO4)3. E′ and E″ are the same or different from one another. Where E′ and E″ are the same, they are preferably metals having more than one oxidation state. Where E′ and E″ are different from one another, they are preferably selected from the group of metals where at least one of E′ and E″ has more than one oxidation state.Type: GrantFiled: February 5, 2001Date of Patent: April 13, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi
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Patent number: 6716372Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.Type: GrantFiled: October 19, 2001Date of Patent: April 6, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer
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Patent number: 6706445Abstract: An electrochemical active material contains a lithiated zirconium, titanium, or mixed titanium/zirconium oxide. The oxide can be represented by the formula LiM′M″XO4, where M′ is a transition metal, M″ is an optional three valent non-transition metal, and X is zirconium, titanium, or a combination of the two. Preferably, M′ is nickel, cobalt, iron, manganese, vanadium, copper, chromium, molybdenum, niobium, or combinations thereof. The active material provides a useful composite electrode when combined with a polymeric binder and electrically conductive material. The active material can be made into a cathode for use in a secondary electrochemical cell. Rechargeable batteries may be made by connecting a number of such electrochemical cells.Type: GrantFiled: October 2, 2001Date of Patent: March 16, 2004Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
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Patent number: 6645452Abstract: The invention provides a method for making lithium mixed metal materials in electrochemical cells. The lithium mixed metal materials comprise lithium and at least one other metal besides lithium. The invention involves the reaction of a metal compound, and a phosphate compound, with a reducing agent to reduce the metal and form a metal phosphate. The invention also includes methods of making lithium metal oxides involving reaction of a lithium compound, and a metal oxide with a reducing agent.Type: GrantFiled: November 28, 2000Date of Patent: November 11, 2003Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer
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Patent number: 6596435Abstract: The invention provides an electrochemically active material comprising particles of spinel lithium manganese oxide having on the surface of each particle cationic metal species bound to the spinel at anionic sites of the particle surface; where the cationic metal species includes a metal selected from the group consisting of transition metals, non-transition metals having a +3 valence state, and mixtures thereof. The active material is characterized by a reduced surface area and increased capacity expressed in milliamp hour per gram as compared to the spinel alone.Type: GrantFiled: September 25, 2001Date of Patent: July 22, 2003Assignee: Valence Technology, Inc.Inventors: Tracy E. Kelley, Porter H. Mitchell, Chariclea A. Scordilis-Kelley
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Patent number: 6528033Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.Type: GrantFiled: January 18, 2000Date of Patent: March 4, 2003Assignee: Valence Technology, Inc.Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer
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Patent number: 6503284Abstract: Anodes, cathodes, and/or solid electrolytes (or separator layers) of an electrochemical cell can be fabricated from aqueous compositions containing monomers and/or polymers. In one formulation, the aqueous composition contains binding materials that are polymerized and crosslinked. In a second formulation, the composition is a latex having as aqueous phase and a solid polymer phase. Upon removal of water, the compositions provide a polymeric structure suitable for use as an electrode or solid electrolyte.Type: GrantFiled: May 26, 2000Date of Patent: January 7, 2003Inventors: Peikang Liu, Porter Mitchell, Feng Gao
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Patent number: 6468695Abstract: In one embodiment, the invention provides a novel composition which is stabilized against decomposition when used as an active material for an electrochemical cell. The active material of the present invention comprises particles of spinel lithium manganese oxide (LMO) enriched with lithium by a decomposition product of lithium hydroxide forming a part of each of the LMO particles. The spinel LMO product formed by the decomposition of lithium hydroxide in the presence of the LMO is characterized by a reduced surface area and increased capacity retention (reduced capacity fading) as compared to the initial, non-treated, non-enriched spinel. In another aspect, the treated spinel LMO product is combined with lithium carbonate in a cathode mixture.Type: GrantFiled: August 18, 1999Date of Patent: October 22, 2002Assignee: Valence Technology Inc.Inventor: Jeremy Barker
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Patent number: 6467156Abstract: A method of fabricating electrochemical cells and batteries wherein the successive anode and cathode layers are separated by a polymeric electrolyte layer having a protruding polymer edge around its perimeter which reduces the likelihood of inadvertent contact between the anode and cathode current collectors is provided. The polymer edge functions as a non-conducting physical barrier positioned between adjacent current collectors. An apparatus for preparing electrochemical cells is also disclosed.Type: GrantFiled: April 12, 1996Date of Patent: October 22, 2002Assignee: Valence Technology, Inc.Inventors: David A. Velasquez, Douglas B. Holmes, E. Lawrence Goglin
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Patent number: 6414180Abstract: The invention herein is directed to a process for the preparation of chiral &bgr;-amino acids and esters of the formula wherein X and Y are the same or different halo groups, R2 is H or lower alkyl and isomers and pharmaceutically acceptable salts thereof.Type: GrantFiled: March 2, 1999Date of Patent: July 2, 2002Assignee: G. D. SearleInventors: Pierre-Jean Colson, Alok K. Awasthi, Srinivasan R. Nagarajan
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Patent number: 6172256Abstract: The present invention is directed to a method for the preparation of a chiral &bgr;-amino ester of the formula wherein R is lower alkyl; and X and Y are the same or different Cl, Br or I.Type: GrantFiled: March 3, 1999Date of Patent: January 9, 2001Assignee: G.D. Searle & Co.Inventors: James W. Malecha, Thomas P. Fraher