Abstract: A method for controlling snails in aqueous systems which involves treating aqueous systems which contain snails or which are prone to snail infestation with an effective amount of a water-soluble dialkyl diallyl quaternary ammonium polymer (polyquat) is disclosed. A preferred polymer is a poly(quaternary ammonium) compound having a recurring structure (DMDAAX−) resulting from the polymerization of monomeric dimethyl diallyl ammonium X−, wherein X− is any suitable anion.

Abstract: Fumed silica is used to suspend iron sulfates in concentrated sulfuric acid. The suspension system substantially reduces iron sulfate deposits in steel containment vessels.

Abstract: A filter cartridge that includes a track etched membrane sealed therein in a leak-free manner, and a method for making the cartridge. The filter cartridge has a bubble point that is at least 50% of the bubble point of the track etched membrane. In one embodiment, the method includes disposing the track etched membrane below a heat source and orienting the membrane so that it melts back on itself, and then allowing the membrane to cool to form a leak-free seal.

Abstract: A process for removing liquid from depleted ion exchange bead resin includes the steps of: transferring a slurry containing at least 10 volume % of contaminated ion exchange resin beads from storage (10) having a particle size range from 300 micrometers to 1000 micrometers to a blending tank (14) to provide a homogeneous slurry which is fed to a grinder (16) usually by means of pumps (13 and 17), where the beads are fractured, and reduced in size, where no more than 33% of the fractured beads have a relatively similar diameter, allowing subsequent random packing compression; and then passing the processed slurry to a dewatering system (18) where it is separated into liquid (20) and highly compressible waste (22).

Abstract: An article, such as a containment system (10), having sides (12) with walls (2) or (24) is made; in one method by using cast, cooled, melted, radioactive metal components where the melted metal has a specific activity over 130 Bq/g; or by providing a contaminated material in the form of a solid, liquid or mixture, and then mixing the contaminated material, to which no more than about 15 weight % of uncontaminated material has been reacted, with a binder, followed by forming the composition into a containment system and then curing it into a mass which contains both contaminated material, and uncontaminated binder acting as a matrix for the contaminated material. This article need not be a containment system but can be a wide variety of objects which are made out of radioactive waste, hazardous waste, and their mixtures.

Abstract: A method for segregating fines from the clean coarse fraction of the soil, preparing the contaminated fines for subsequent processing, and then separating the contaminants from the clean fines. The process produces a small, highly concentrated contaminanth fraction and a large fraction of clean soil. Metals, metallic compounds, and/or radioactive contaminants are removed from the fine fraction using either gravity separation, multistage gravity separation, a centrifugal jig, regular magnetic or paramagnetic separation using a high gradient magnetic separator, and/or a superconducting separator. Preparation of the fines requires selective segregation of the targeted particles size range and the removal of interfering soil fractions, and vegetation such as root hairs. This preparation is accomplished by a combination of attrition scrubbing, countercurrent jigging, and screening.

Abstract: A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO.sub.3 particles doped with an element selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by plasma spraying doped LaCrO.sub.3 powder, preferably compensated with chromium as Cr.sub.2 O.sub.3 and/or dopant element, preferably by plasma arc spraying; and, (C) heating the doped and compensated LaCrO.sub.3 layer to about 1100.degree. C. to 1300.degree. C. to provide a dense, substantially gas-tight, substantially hydration-free, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the unselected portion of the air electrode, and a fuel electrode can be applied to the solid electrolyte, to provide an electrochemical cell.

Abstract: Treatment of flowable underground contaminants comprises freezing at least one open underground barrier volume to form a wall (10) near the contaminated region (12) in the ground (14), where the wall (10) is positioned to direct the contaminant flow (16) along a subsurface path (18) and allow concentration of the contaminants and their remediation.

Abstract: A robotic sampling device (32) for cutting part of a tube wall (12) for sampling, containing a cutting head (36), a retrieval assembly (38) and a drive mechanism (40), is used to cut a window or hole (60) in the tube wall (12) and retrieve the tube wall sample (56), where the sample can be mounted onto a separate tube for testing the physical properties of the cut wall portion, and where a video probe (62) and the like can be passed through the window (60) to monitor conditions near the support plates (14) and tube sheets (16).

Abstract: The present invention provides an improved multilayered storage structure composite material. The composite contains a fibrous mat made from interwoven fibers, preferably metallic fibers, that is encased with a concrete-based mixture to form a mat layer. At least one concrete-based layer is also disposed within the composite, and this concrete-based layer preferably contains at least one shielding additive. The composite material is preferably formed into a containment vessel for the storage of hazardous, radioactive, and mixed waste materials.

Abstract: A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an electrode structure of an electrochemical cell by: (A) providing an electrode structure; (B) forming on a selected portion of the electrode surface, an interconnection layer having the general formula La.sub.1-x M.sub.x Cr.sub.1-y N.sub.y O.sub.3, where M is a dopant selected from the group of Ca, Sr, Ba, and mixtures thereof, and where N is a dopant selected from the group of Mg, Co, Ni, Al, and mixtures thereof, and where x and y are each independently about 0.075-0.25, by thermally spraying, preferably plasma arc spraying, a flux added interconnection spray powder, preferably agglomerated, the flux added powder comprising flux particles, preferably including dopant, preferably (CaO).sub.12. (Al.sub.2 O.sub.3).sub.7 flux particles including Ca and Al dopant, and LaCrO.sub.3 interconnection particles, preferably undoped LaCrO.sub.

Abstract: A dense, substantially gas-tight electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an air electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO.sub.3 particles doped with an element or elements selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by thermal spraying doped LaCrO.sub.3 particles, either by plasma arc spraying or flame spraying; (C) depositing a mixture of CaO and Cr.sub.2 O.sub.3 on the surface of the thermally sprayed layer; and (D) heating the doped LaCrO.sub.3 layer coated with CaO and Cr.sub.2 O.sub.3 surface deposit at from about 1000.degree. C. to 1200.degree. C. to substantially close the pores, at least at a surface, of the thermally sprayed doped LaCrO.sub.3 layer. The result is a dense, substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode surface.

Abstract: A process system is disclosed for the treatment of a waste sand material containing metal contaminants. The waste sand material is the product of sandblasting techniques used to remove paint. The metal contaminants generally include lead, copper, chromium, mercury and cadmium, among other heavy metals. The process particularly provides for the concentration of the lead contaminant in a waste sand that can be economically reclaimed or disposed in an environmentally safe manner. The process also produces a cleaned sand that contains only residual amounts of the metallic contaminants in environmentally acceptable levels. The process provides for the contacting of the waste sand material with a paint decomposer, attrition abrading this sand slurry, size separating the attrition abraded slurry to form a waste sand slurry and a cleaned sand, and removing a portion of the excess water content in the waste sand slurry.

Abstract: Solutions such as for example drinking water, ground water and extracting solutions contaminated with heavy metals and radioactive species, singly or in combination, are treated by first treating the contaminated solution with silicate and ammonium hydroxide solution precipitants. Then the contaminated solution is separately treated with an acid which gels, polymerizes and/or precipitates the contaminant-containing silica matrix to form an easily dewaterable and separable solid. The solid contaminants are readily removed from the cleansed solution by filtration means. The process utilizes a novel combination of steps which maximizes contaminant removal, minimizes waste volume, and produces a treatable waste solid. The preferred precipitants are sodium silicate, and ammonium hydroxide. The preferred mineral acid is hydrochloric acid.

Abstract: The present invention provides an improved design for the hindered settling bed within a mineral jig. The hindered settling bed contains relatively low density materials that can be used in conjunction with high density materials to aid in the separation of particulate materials within the mineral jig. The presence of the relatively low density barrier materials in the settling bed allow for the separation to occur with less channelling of the separated material through the bed area.

Abstract: The removal of organics and volatile metals from soils using thermal desorption comprises moving contaminated materials, positioned on a belt conveyor, through a chamber (32) under oxygen conditions, temperature conditions, and residence time effective to substantially avoid incineration of the contaminants, while volatilizing the contaminants and producing a processed material that is substantially decontaminated, where the volatilized contaminants are carried from the chamber (32) by a transport gas which is passed through a packed tower (70) where quench/scrubbing liquid flows countercurrent to gas flow, for producing a substantially cleaned gas and a contaminated liquid concentrate. The gas may be passed through a further gas cleaning system (86) prior to discharge into the atmosphere, while the liquid concentrate is passed through a water treatment system (90) for producing substantially cleaned water which may be passed through an air cooler (92) and recycled back to cool the processed material.

Abstract: A tubular, porous ceramic electrode structure (3) is made from the sintered admixture of doped lanthanum manganite and an additive containing cerium where a solid electrolyte (4), substantially surrounds the air electrode, and a porous outer fuel electrode (7) substantially surrounds the electrolyte, to form a fuel cell (1).

Abstract: A method for monitoring the environment of a vessel provides a liquid (18) which may contain particles (20) in a vessel having containment walls (12), where a hollow member (26) such as a thin tube is inserted into the liquid near the containment walls, and the hollow member contains in it a robotic device (34), which can travel within the hollow member and which can emit and receive ultrasonic waves and electromagnetic fields, where both of the ultrasonic waves and electric fields can pass through the hollow member (26) to the containment walls (12), where the device: emits and receives low frequency ultrasonic waves to and from the containment walls (12) and high frequency ultrasonic waves to and from any particles (20), and emits electromagnetic fields to the containment walls (12) or their combination, where absorptions and reflections from the hollow member walls and the containment walls, and any particles present are measured and any current generated in the hollow member walls and the containment wall

Abstract: Solutions such as for example groundwater, drinking water, extracting solutions and effluents contaminated with metals, radioactive species and organics, singly or in combination, are treated by first removing undesirable oxidizing agents from the contaminated solution. Then the contaminated solution is separately treated with aqueous solutions of ferrous sulfate and hydroxide, which precipitate substantially all of the contaminants. Next, the precipitate is treated with a flocculant and/or a coagulant to form an easily dewaterable and separable solid. The solid contaminants are readily removed from the cleansed solution. The process utilizes a novel combination of steps which maximizes contaminant removal, minimizes waste volume, and produces a recyclable solution and a manageable waste stream. The preferred hydroxide solutions are sodium hydroxide, calcium hydroxide, and ammonium hydroxide.

Abstract: A bench scale process and apparatus for determining the operating parameters, such as maximum temperature and residence time, required to remove a particular contaminant at a particular depth during a full-scale thermal desorption process, includes measuring a temperature of a representative contaminated soil sample at a particular depth as a function of residence time during a bench scale thermal desorption process. The method also includes measuring the contaminant level of the soil sample after the bench scale process to determine the required temperatures and residence times to substantially remove the contaminants from the soil. The apparatus includes a container for housing the soil sample, at least one partition positioned between adjacent layers of the soil sample and at least one thermocouple positioned within each layer of the soil sample.