Patents Represented by Attorney David M. Frischkorn
  • Patent number: 4795846
    Abstract: An improved dehydrocyclization process for the selective conversion of light hydrocarbons to aromatics is presented. The activity of a catalyst containing nonacidic L-zeolite is greatly enhanced by the addition of water, water precursors, or mixtures thereof to the reaction zone during the dehydrocyclization reaction. Addition of between 10 and 100 wt. ppm H.sub.2 O results in a higher product yield of aromatics with increased product octane.
    Type: Grant
    Filed: October 1, 1987
    Date of Patent: January 3, 1989
    Assignee: UOP Inc.
    Inventors: Joseph Zmich, Michael B. Russ, Visnja A. Gembicki
  • Patent number: 4795550
    Abstract: This invention presents a novel treating process for the removal of trace quantities of olefinic impurities from a hydrocarbon process stream. Specifically, this process operates at liquid phase conditions treating hydrocarbon streams comprising substantially aromatics and naphthenes having Bromine Index values of about 50 to 2,000. A solid medium comprising a crystalline aluminosilicate zeolite and a refractory oxide is used to reduce the level of olefin impurities to Bromine Index values of 0.1 to 50.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: January 3, 1989
    Assignee: UOP Inc.
    Inventors: J. W. Adriaan Sachtler, Paul T. Barger
  • Patent number: 4795545
    Abstract: A pretreatment process for removal of contaminants from a light hydrocarbon feedstock is presented. The feedstock is passed to a first adsorption zone containing a molecular sieve and thereafter passed to a second adsorption zone containing activated alumina. The process produces a hydrocarbon feedstock substantially free of sulfur compounds, oxygenates, and water. Such a process finds utility as a feed pretreatment step preceding a catalytic isomerization process.
    Type: Grant
    Filed: September 17, 1987
    Date of Patent: January 3, 1989
    Assignee: UOP Inc.
    Inventor: Robert J. Schmidt
  • Patent number: 4791087
    Abstract: A novel trimetallic catalytic composite, a method of manufacture and process use thereof is dislcosed. The composite comprises a refractory support having a nominal diameter of at least 650 microns and having deposited thereon a uniformly dispersed platinum component, a uniformly dispersed Group IVA metal component and a surface-impregnated metal component selected from the group consisting of rhodium, ruthenium, cobalt, nickel, or iridium. When this catalytic composite is used in the reforming of hydrocarbons at low pressures, significant improvements in activity stability is observed compared to catalysts of the prior art.
    Type: Grant
    Filed: June 23, 1987
    Date of Patent: December 13, 1988
    Assignee: UOP Inc.
    Inventors: Mark D. Moser, R. Joe Lawson
  • Patent number: 4762957
    Abstract: An improved process for the isomerization of non-equilibrium C.sub.8 aromatics is presented which utilizes a catalytic composition prepared by a novel method of incorporating magnesium into a crystalline aluminosilicate. The catalyst comprises an alumina matrix, a magnesium-containing zeolite, and a Group VIII metal component. It has also been found that the method of magnesium addition can dramatically affect the selectivity to para-xylene, as measured by the loss of C.sub.8 aromatics due to undesirable side-reactions. The method of the instant invention involves addition of the magnesium to a hydrogel comprising pseudoboehmite and zeolite.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: August 9, 1988
    Assignee: UOP Inc.
    Inventors: J. W. Adriaan Sachtler, R. Joe Lawson