Patents Represented by Attorney, Agent or Law Firm David M. Shold
  • Patent number: 7737092
    Abstract: A composition suitable for use as a lubricant for a transmission includes an oil of lubricating viscosity; a dispersant; a calcium detergent; a magnesium detergent; and an inorganic phosphorus compound. At least one of the dispersant or detergent components is borated.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: June 15, 2010
    Assignee: The Lubrizol Corporation
    Inventors: William C. Ward, Jr., Carlos L. Cerda de Groote, Masahiko Ikeda, Denise R. Vermilya
  • Patent number: 7727944
    Abstract: Compositions of an ester-containing phenolic antioxidant seal-conditioning agent represented by the formula and a second seal-conditioning agent selected from sulfolanes, benzyl ester, lactones, nitriles, and other ester-containing phenolic anitoxidant seal-conditioning agents, serve to protect the integrity of elastomeric materials in contact with lubricants.
    Type: Grant
    Filed: August 9, 2005
    Date of Patent: June 1, 2010
    Assignee: The Lubrizol Corporation
    Inventors: Edward J. Konzman, Richard M. Lange
  • Patent number: 7727943
    Abstract: A lubricating composition comprising an oil of lubricating viscosity, 1 to 1000 parts per million by weight of titanium in the form of an oil-soluble titanium-containing material, and at least one additional lubricant additive provides beneficial effects on properties such as deposit control, oxidation, and filterability in engine oils.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: June 1, 2010
    Assignee: The Lubrizol Corporation
    Inventors: Jason R. Brown, Paul E. Adams, Virginia A. Carrick, Brent R. Dohner, William D. Abraham, Jonathan S. Vilardo, Richard M. Lange, Patrick E. Mosier
  • Patent number: 7704289
    Abstract: The present invention is directed to a method to clean up or keep clean the fuel system of a direct injection spark-ignited engine by operating the engine with a fuel composition that includes a liquid fuel and a fuel additive composition. The fuel additive composition useful in the present invention has at least one nitrogen-containing dispersant and optionally a fluidizer where the dispersant has a specific lipophilic parameter and the dispersant or the dispersant and the fluidizer have a specific hydrophilic-lipophilic parameter, the dispersant provides about 0.15 to about 50 ppm by weight nitrogen in the fuel composition, and the fluidizer and/or the dispersant provide about 10 to about 10,000 ppm by weight active components in the fuel composition. The method of the present invention is effective in controlling deposits in fuel injectors and combustion chambers of a direct injection spark-ignited engine.
    Type: Grant
    Filed: September 13, 2005
    Date of Patent: April 27, 2010
    Assignee: The Lubrizol Corporation
    Inventors: David C. Arters, Mitchell M. Jackson, Daniel T. Daly, Malcolm G. J. Macduff
  • Patent number: 7678746
    Abstract: A lubricating composition containing (a). at least 3 weight percent of an overbased sulphonate detergent with a metal ratio of 12.5:1 to 40:1; (b). at least 1.5 weight percent of a sulphur containing phenate detergent with a metal ratio of not more than 2.5; and (c). an oil of lubricating viscosity, wherein the sulphur containing phenate contains oligomers of hydrocarbyl phenol with at least 50 wt % of said oligomers in the form of the tetramer or higher oligomers. The composition is suitable for internal combustion engines, particularly marine diesel applications to provide improved cleanliness decreased cylinder wear and reduced deposits.
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: March 16, 2010
    Assignee: The Lubrizol Corporation
    Inventors: James P. Roski, Richard Leahy, Stephen J. Cook, Alexandra Mayhew
  • Patent number: 7618929
    Abstract: A composition of a major amount of an oil of lubricating viscosity; a secondary or tertiary amine being represented by the formula R1R2NR3 wherein R1 and R2 are alkyl groups of at least 6 carbon atoms and R3 is hydrogen, a hydrocarbyl group, a hydroxyl-containing alkyl group, or an amine-containing alkyl group; and a dispersant, provides high static coefficients of friction and a durable positive slope during oxidative and mechanical stressing, particularly as a friction component of an automatic transmission.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: November 17, 2009
    Assignee: The Lubrizol Corporation
    Inventors: Craig D. Tipton, Mark R. Baker, Shreyasi Lahiri, William D. Abraham, Richard J. Vickerman, Suzanne M. Patterson
  • Patent number: 7615521
    Abstract: A dispersant composition comprising the product of an amine, an alcohol, or an amino alcohol, with a hydrocarbyl-substituted succinic anhydride component exhibits improved viscosity stability and reduced chlorine content, when the hydrocarbyl-substituted succinic anhydride component comprises: (a) 10 to 95 weight percent of a component prepared by reacting a polyisobutylene with maleic anhydride in the presence of chlorine; and (b) 5 to 90 weight percent of a component prepared by reacting a polyisobutylene with maleic anhydride in the substantial absence of chlorine.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: November 10, 2009
    Assignee: The Lubrizol Corporation
    Inventors: Renee A. Eveland, Frederick W. Koch, Robert Ian Wilby, Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, John K. Pudelski
  • Patent number: 7462583
    Abstract: Internal combustion engines exhibit improved efficiency of the emissions control system by using a lubricating oil composition of a base oil, an alkali or alkaline earth metal-containing detergent; a metal salt of one or more phosphorus-containing compounds represented by the formula (I), wherein X1 and X2 are independently O or S, and R1 and R2 are independently hydrocarbyl groups, the average total number of carbon atoms in R1 and R2 for the one or more phosphorus-containing compounds being at least 10.4; and an acylated nitrogen-containing compound having at least about 10 alphatic carbon atoms and a TBN of at least about 2; the lubricating oil composition being characterized by a phosphorus concentration of up to about 0.12% by weight and the substantial absence of copper, thereby generating a lean-phosphorus containing exhaust gas.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: December 9, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Melody A. Wilk, William B. Chamberlin, III, Jack C. Kelley, William D. Abraham
  • Patent number: 7439213
    Abstract: A composition of a major amount of an oil of lubricating viscosity; a secondary or tertiary amine being represented by the formula R1R2NR3 wherein R1 and R2 are alkyl groups of at least 6 carbon atoms and R3 is hydrogen, a hydrocarbyl group, a hydroxyl-containing alkyl group, or an amine-containing alkyl group; and a dispersant, provides high static coefficients of friction and a durable positive slope during oxidative and mechanical stressing, particularly as a friction component of an automatic transmission.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: October 21, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Craig D. Tipton, Mark R. Baker, Shreyasi Lahiri
  • Patent number: 7429554
    Abstract: A phthalic acid such as terephthalic acid is made soluble in an oil of lubricating viscosity by first mixing it with at least one phosphorus compound. The resulting product is useful for reducing corrosion in a transmission lubricant.
    Type: Grant
    Filed: January 7, 2004
    Date of Patent: September 30, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Craig D. Tipton, Bill A. Waters
  • Patent number: 7422999
    Abstract: This invention relates to an overbased vaterite containing composition, comprising: a disperse medium, and a calcium salt and calcium carbonate dispersed in the disperse medium, at least about 50% by weight of the calcium carbonate being in the form of vaterite, the composition being substantially haze free.
    Type: Grant
    Filed: February 14, 2005
    Date of Patent: September 9, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, James P. Roski, Daniel E. Barrer
  • Patent number: 7407919
    Abstract: A composition for lubricating an internal combustion engine includes an oil of lubricating viscosity; a predominantly linear alkylbenzenesulfonate detergent having a metal ratio of at least 8; and a combination of hindered phenolic ester antioxidant and aromatic amine antioxidant. The amount of any phenate detergent is less than 15% by weight of the total amount of detergents.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: August 5, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Melody A. Wilk, Brent R. Dohner, Frank V. Zalar, Jack C. Kelley
  • Patent number: 7402235
    Abstract: A mixture comprising A) a copolymer comprising from about 70 to about 79% by weight of units derived from ethylene, and having (a) Mw measured by gel permeation chromatography employing polystyrene standard ranging from about 50,000 up to less than 130,000 and/or (f) SSI?18; (b) density (D) ranging from about 845 to about 895 kg/m3; (c) Mw/ Mn less than 3; (d) melting point (Tm) measured by differential scanning calorimeter ranging from about 15° C. to about 60° C.; and (e) degree of crystallinity?15%, and B) an amorphous polymer having Mw ranging from about 130,000 to about 1,000,000 having degree of crystallinity?5%. In one embodiment the density and the melting point of the copolymer A) fulfill the expression Tm?1.247 D?1037. In another embodiment, the percentage content (E: % by weight) of repeating units derived from ethylene and melting point (Tm: ° C.) of the copolymer A) fulfill the expression 3.44E?206?Tm.
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: July 22, 2008
    Assignee: The Lubrizol Corporation
    Inventor: Chor Huang
  • Patent number: 7381691
    Abstract: A fluid composition of (a) a friction modifier derived from the reaction of a carboxylic acid or a reactive equivalent thereof with an aminoalcohol, the friction modifier containing at least two hydrocarbyl groups; and (b) a dispersant other than a species of (a), provides good friction properties to an automatic transmission.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: June 3, 2008
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, Craig D. Tipton, Shreyasi Lahiri, James H. Bush, James C. Ray, David J. Aaserud
  • Patent number: 7285516
    Abstract: Lubricating oils containing an additive formulation including at least one sulphonate, saligenin and salixarate detergent provide improved wear performance and decreased sulphur and phosphorus emissions.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: October 23, 2007
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, R. Ian Wilby, James P Roski
  • Patent number: 7238651
    Abstract: The invention relates to a process for preparing an overbased metal detergent in an oil medium comprising the steps of: (1) providing a metal salt selected from the group consisting of a hydrocarbyl-substituted organic acid; a hydrocarbyl-substituted phenol, a phenate, a hydrocarbyl-substituted carboxylate and mixtures thereof; (2) further providing methanol and a mixture of alcohols containing 2 to about 7 carbon atoms, wherein the mole ratio of methanol to the mixture of alcohols is about 2.
    Type: Grant
    Filed: April 17, 2006
    Date of Patent: July 3, 2007
    Assignee: The Lubrizol Corporation
    Inventors: Jody A. Kocsis, Albert F. Baumann, Jack L. Karn
  • Patent number: 7238650
    Abstract: A composition of matter comprising an amine acylated with a hydrocarbyl group substituted carboxylic acylating agent containing an average of from 1.3 to 1.6 groups derived from ?,?-unsaturated carboxylic compounds per Mn of the hydrocarbyl group, wherein the hydrocarbyl group has Mn determined by GPC ranging from 1500 to 3000, the amine comprises polyamine bottoms and said acylated amine has total base number (TBN) ranging from 17 to 35. A method for preparing the composition, lubricating oils containing the composition and, in another embodiment, lubricating oil compositions of this invention further comprising a metal overbased sulfonate detergent.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: July 3, 2007
    Assignee: The Lubrizol Corporation
    Inventors: Raymond M. Calder, Steven A. Goodlive, Jeffry G. Dietz, Wolfie Kotzen, Brent R. Dohner, Frederic Martin, John K. Pudelski
  • Patent number: 7189682
    Abstract: A composition of the following components: an oil of lubricating viscosity; a polymethacrylate viscosity modifier; an ester of a maleic acid/styrene copolymer; and optionally, an additive package that imparts to the fluid the capacity to meet bench and dynamometer tests specified by an equipment manufacturer, is suitable for use as a functional fluid such as a tractor hydraulic fluid, under a wide variety of climatic conditions.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: March 13, 2007
    Assignee: The Lubrizol Corporation
    Inventor: Richard E. Gapinski
  • Patent number: 7087558
    Abstract: A process for reacting relatively small hydrophilic carboxylic molecules with relatively large, hydrophobic hydrocarbon based molecules, said process comprising conducting the reacting in the presence of a sulfonic acid catalyst having solubilizing properties. In a preferred embodiment the large hydrophobic molecule comprises at least one member of the group consisting of (1) olefinically unsaturated hydrocarbons containing at least about 10 carbon atoms and (2) aliphatic hydrocarbyl group substituted hydroxy aromatic compounds wherein the aliphatic hydrocarbyl group contains at least 12 carbon atoms and the small hydrophilic molecule comprises a carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5 wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: August 8, 2006
    Assignee: The Lubrizol Corporation
    Inventors: Marvin B. DeTar, John C. Smoggie, Richard M. Lange
  • Patent number: 7067594
    Abstract: A carboxylic derivative composition derived from a carboxylated isobutylene-polyene copolymer having n ranging from about 200 to about 10,000, said copolymer having thereon from about 0.8 to about 7 moles per mole of copolymer of groups derived from at least one ?,?-unsaturated carboxylic acid or reactive equivalent thereof, reacted with at least one of (a) amines characterized by the presence within their structure of at least one condensable H—N< group, (b) alcohols. (c) reactive metals or reactive metal compounds, and (d) a combination of two or more of any of (a) through (c), the components of (d) having been reacted with the carboxylated isobutylene-polyene copolymer simultaneously or sequentially, in any order. Also, a process for preparing carboxylic derivative compositions, additive concentrates and lubricating oil compositions containing the carboxylic derivative compositions and methods for increasing the viscosity index of lubricating oil compositions.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: June 27, 2006
    Assignee: The Lubrizol Corporation
    Inventor: Christopher J. Kolp