Abstract: The present invention relates to ?-amylase variants that are stabilized to solvent-exerted hydrolysis, in particular at elevated temperatures or high pH, by point mutagenesis of asparagine (N) or glutamine (Q) residues located on the surface of the molecule to give other amino acid residues. The invention further relates to methods of increasing the stability of an ?-amylase to solvent-exerted hydrolysis, in particular at elevated temperatures or high pH, whereby at least one asparagine (N) or glutamine (Q) residue on the surface of the molecule is replaced with a different amino acid residue. The ?-amylase variants obtained thereby exhibit better stability to influences of the solvent, increased processivity, and are suited for numerous industrial areas of use, in particular as active ingredients in detergents and cleansers.
Type:
Grant
Filed:
March 28, 2007
Date of Patent:
December 20, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Cornelius Bessler, Susanne Wieland, Karl-Heinz Maurer
Abstract: A hot-melt adhesive for resealable packaging, containing 30 to 90 wt. % of at least one copolymer based on ethylene and/or propylene together with C4 to C12-?-olefins, which is obtainable by metallocene-catalyzed polymerization, with a melt index of 5 to 100 g/10 min (DIN ISO 1133), 5 to 50 wt. % of tackifier resins with a softening point of 80 to 140° C., 0 to 15 wt. % of waxes with a melting point of 120 to 170° C., 0.1 to 20 wt. % of additives and auxiliaries, the adhesive having a viscosity of 25,000 mPa·s to 250,000 mPa·s, measured at a temperature of 170 to 190° C.
Type:
Grant
Filed:
June 11, 2010
Date of Patent:
December 13, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Marcus Heemann, Eckhard Pürkner, Volker Erb, Maja Schroeder, Dirk Vianden
Abstract: Applicator tip for applying fast curing adhesive of low viscosity to a surface. The applicator tip comprises a body with an inner canal for feeding the adhesive to an orifice. Spikes in various shapes and placements are arranged around the orifice for preventing the orifice from contacting the surface.
Type:
Grant
Filed:
November 24, 2009
Date of Patent:
November 1, 2011
Assignee:
Henkel AG & Co., KGaA
Inventors:
Kenneth N. Broadley, Michael Mulvey, Nico Zinndorf
Abstract: Textiles are washed by a method comprising contacting the textile with a cleaning composition comprising a copolymer comprising styrene, methacrylic acid, hydroxyethyl methacrylate, and methyl acrylate.
Abstract: Agent for lightening keratin fibers containing in a cosmetic carrier (1) at least one cationic 2-acylpyridinium derivative of formula (I), wherein R is a C1-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 hydroxyalkyl group, a C1-C6 alkoxy C2-C6 alkyl group, a carboxy C1-C6 alkyl group, an aryl C1-C6 alkyl group, a heteroaryl C1-C6 alkyl group, a mono- or di-(C1-C6 alkyl)amino C2-C6 alkyl group, a 3-oxobutyl group, a 2-oxopropyl group, an aryl group or a heteroaryl group, R? is a C4-C4 alkyl group, a C2-C6 hydroxyalkyl group or a C1-C6 alkoxy C2-C6 alkyl group, and X? is a physiologically acceptable anion, (2) at least one alkyl ether sulfate, and (3) an oxidizing agent, especially hydrogen peroxide.
Abstract: Agent having at least one non-ionic component having an HLB of 8.0 or less are disclosed, as well as the combination of a blue and red substantive dye wherein the weight ratio of the blue dyes as opposed to the red dyes is 1 or greater. Further disclosed are agents for dyeing human hair blond having at least one oxidizing agent preparation and optionally a bleaching force reinforcing preparation. The agents make it possible to avoid undesired color shifts towards yellow or red nuances during blond hair dyeing.
Abstract: A pulverulent composition comprising 50 to 95% by weight of an aqueous solvent, hydrophobicized silicon dioxide powder and at least one film-forming and/or setting polymer for the temporary shaping of keratin fibers and a corresponding pulverulent styling composition. Upon mechanical stress, the powder releases the solvent and the film-forming and/or setting polymer so that the desired shaping or setting of, for example, a mechanically produced shape of the treated fibers is achieved.
Abstract: Agent for dyeing keratin fibers while simultaneously bleaching the keratin fibers. The agent contains, in a cosmetic carrier, at least one oxidation dye precursor and at least one cationic acylpyridinium derivative.
Type:
Grant
Filed:
February 28, 2011
Date of Patent:
September 20, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Wibke Gross, Denise Fuhr, Ralph Nemitz, Astrid Kleen
Abstract: The aim of the invention is to diminish the odor, often perceived as unpleasant, that is left behind on human skin, in particular on the hands as a result of contact with agents containing chlorine bleach after use of the agent. This was achieved by the use of odorants selected from the group comprising diphenylmethane, diphenyl oxide, 2-methyl naphtyl ether, and mixtures thereof.
Type:
Grant
Filed:
June 4, 2008
Date of Patent:
August 30, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Carlos Malet, Mercedes Mendoza Cruz, Pilar Ibanez, Miguel Osset
Abstract: Agent for bleaching keratin fibers comprising in a cosmetic carrier at least one cationic acyl pyridinium derivative of formula (I) where R is a C1-C6-alkyl group, a C2-C6-alkenyl group, a C2-C6-hydroxy alkyl group, a C1-C6-alkoxy-C2-C6-alkyl group, a carboxy-C1-C6-alkyl group, an aryl-C1-C6-alkyl group, a C1-C6-dialkylamino-C2-C6-alkyl group, a heteroaryl-C1-C6-alkyl group, a 3-oxobutyl group, a 2-oxopropyl group, an aryl group, or a heteroaryl group, R? is a C1-C4-alkyl group, a C2-C6-hydroxy alkyl group, or a C1-C6-alkoxy-C2-C6-alkyl group, X? is a physiologically compatible anion, at least one toxicologically safe co-bleaching activator and/or the physiologically compatible salt thereof, and hydrogen peroxide.
Type:
Grant
Filed:
November 5, 2010
Date of Patent:
July 19, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Wibke Gross, Denise Fuhr, Ralph Nemitz, Kristin Mielich
Abstract: The present invention relates to the use of enzymes and/or whole-cell catalysts for the removal of undesired by-products from crosslinkable preparations.
Abstract: The invention relates to encapsulated bleaching agent particles. Said particles consist of a core that contains a bleaching-agent active ingredient and a coating of water-soluble material that at least partially surrounds said core, the core containing peroxocarboxylic acid and the coating material containing polyvinyl alcohol. The particles can be produced by introducing a particulate peroxocarboxylic acid into a fluidized bed, by spraying an aqueous solution containing polyvinyl alcohol onto said bed and by subsequent drying or spray drying.
Type:
Grant
Filed:
October 4, 2006
Date of Patent:
March 1, 2011
Assignee:
Henkel AG & Co. KGaA
Inventors:
Georg Assmann, Horst-Dieter Speckmann, Frank Meier, Helga Werner
Abstract: An aqueous liquid laundry detergent containing methylcarboxymethyl cellulose having a degree of methylation in the range from 0.01 to 0.3, surfactant, and at least one typical ingredient of laundry detergents. The detergent inhibits graying of textile fabrics during the washing of the fabrics.