Abstract: A one-component air-activatable polymerisable adhesive composition comprising:(a) a free-radically polymerisable monomer, and an activator system for effective polymerisation of the free-radically polymerisable monomer, said activator system comprising:(b) an autoxidisable compound which is a dihydropyridine (other than a stabilised 1,4-dihydropyridine)(c) a tetrazo le having the formula III ##STR1## wherein R.sup.8 is selected from hydrogen and hydrocarbyl groups, and (d) a soluble ionic salt,with the proviso that the composition does not contain a peroxide, or a peroxide precursor which produces peroxide in the absence of air or any ingredient which is a significant source of radicals in the absence of air, the composition having been prepared under anaerobic conditions and stored under anaerobic conditions.

Abstract: The invention relates to a dispensing process particularly for a sealing/adhesive product which comprises at least one step of pumping the sealing/adhesive product to allow a step of distribution thereof onto at least one part to be sealed, such as for example a motor vehicle mechanical component; an intermediate step of deaeration of the sealing/adhesive product, so as to optimize its distribution on the part to be sealed, is provided between the pumping step and the distribution step. The apparatus for dispensing the sealing/adhesive product (14) comprises elements (2) for feeding the sealing/adhesive product to elements (4) for distributing it onto at least one part (5) to be sealed and sealing/adhesive product deaeration means (3) which cooperate with the pumping and distribution elements for the uniform deposition of the sealant/adhesive on the part.

Abstract: Stable thiol-ene compositions are provided which comprise a polythiol, a polyene and a stabilizer system comprising an alkenyl substituted phenolic compound having a formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of H, OR, a C.sub.1 -C.sub.8 alkyl, substituted alkyl, alkenyl or substituted alkenyl, a C.sub.6 -C.sub.20 aryl or substituted aryl, or a cyano group; R.sup.4 is H, R, OR, halogen, COR, COOR, or SR; R.sup.5 is OH, OR, OCOR, OCOOR, OCONHR, or OTMS; R is a C.sub.1 -C.sub.6 alkyl, a cycloalkyl, or a C.sub.6 -C.sub.20 caryl or substituted aryl; x and y are 1, 2, or 3; z is 0, 1, or 2; and x+y+z=2, 3, or 4; or a formula: ##STR2## where x, y, z, w, R.sup.1 R.sup.2 R.sup.3, R.sup.4 and R.sup.5 are defined as above, except that x+y+z=2-6, and R.sup.6 is CH.sub.2, C(CH.sub.3).sub.2, O, S, or SO.sub.

Abstract: A process for treating waste washing water, which is only slightly affected by temperature, can dispense with any chemical, and wherein the quality of treated water is not affected by a change in the waste water concentration. The process comprises conducting impregnation with an impregnant having a composition comprising triethylene glycol dimethacrylate, 2-hydroxyethyl methacrylate, lauryl methacrylate, nonionic surfactant and azobisisobutyronitrile; separating the impregnant thereafter; washing the surface of the impregnated article with water; and treating the waste water by filtering the liquid having the above composition though a filter having a retained particle diameter of at most 20 .mu.m.

Abstract: A method for illuminating explosive, flammable, and other hazardous environments. The method employs electroluminescent lights heaving controlled dielectric strength and capacitance, which when matched with the low current and voltage from an intrinsically safe power supply, and the controlled capacitance of each lighting circuit, produces an emergency lighting system which is both safe and effective.

Abstract: A process for sealing or adhering two surfaces having gaps of more than 100 micrometers between the surfaces which comprises:(A) applying to at least one of said surfaces an anaerobic composition comprising:(i) a room temperature polymerizable (meth)acrylic monomer,(ii) a peroxy free radical initiator, and(iii) an amount effective as an accelerator of a combination of saccharin and at least one onium salt (other than an iodide); and(B) placing said surfaces in an abutting relationship until the composition has cured through the gaps.Exemplified onium salts are phosphonium salts of the formula IV and quaternary ammonium salts of the formula II: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which may be the same or different, are hydrocarbyl, hydrocarbylaryl, aryl or a substituted derivative thereof;X is Cl, Br or F, or a soft anion.

Abstract: In a method for manufacturing ophthalmic, telescopic, microscopic, etc. lenses, the use of a radiation (e.g., UV or visible light) curable adhesive formulation containing a predominant amount of an acrylic capped organic prepolymer; a lesser amount of an ethylenically unsaturated diluent monomer; a minor amount of a non-reactive releasing agent and a suitable photoinitiator for blocking (bonding) and deblocking (debonding) a lens blank to a support member.

Abstract: A package, with a nozzle, a chamber, a cap which fits over the nozzle, and a pin attached to the interior of the cap which fits into the opening of the nozzle, for storing and dispensing a liquid, having an improved closure mechanism comprising at least one rectangular stopping member and at least one rectangular band in the interior of the cap and at least one guide flange on the nozzle. The package also has a plurality of guide ribs located around the nozzle to aid in the proper placement of the cap. The package is designed to be leak proof, nonclogging, able to dispense the liquid precisely, and can be easily opened even when the pin has bonded to the opening of the nozzle without breaking or shearing the pin.

Abstract: The present invention relates to improvements in the design and construction of apparatus for dispensing microwaveable hot melt adhesives and other heat sensitive materials. The apparatus comprises a dispenser which is heated by microwaves and then used to dispense a material therefrom. The dispenser is specifically designed to convert microwave energy into heat and to transfer the heat to the material to be dispensed in a more efficient and/or safe manner.

Abstract: Modular positive displacement apparatus for dispensing precise quantities of a fluid product including a dispensing unit and an actuator unit. A housing of the dispensing unit defines a reservoir which contains the product under pressure. Within the housing is a ball-type closure mechanism. A deformable diaphragm isolates the reservoir from the mechanism which actuates the valve to prevent undesirable entry of the product. The diaphragm may be of a number of shapes, depending upon the length of the stroke desired for the ball mechanism. The dispensing unit is readily removable from the actuator unit and can be readily replaced with another dispensing unit. Different nozzle sizes can also be accommodated. The extent of the closure opening is adjustable in discrete increments.

Abstract: Polymerizable calixarene and oxacalixarene derivates wherein at least one aryl group of the macrocyclic ring has a phenolic side chain of the formula VII: ##STR1## wherein Z is a group containing an acrylate or methacrylate functional group. Linear polymers may be formed from these compounds by free radical polymerization at the (meth)acrylate group. Such compounds and their polymers are capable of sequestering metals.

Abstract: Calixarene and oxacalixarene derivatives of the formula IV: ##STR1## wherein m'+m"=0-8n=0-8m'.gtoreq.1/2(m'+m")3.ltoreq.m'+m"+n.ltoreq.8if n=0, m'+m".gtoreq.4R.sup.3 is H, halogen, or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof and R.sup.3 may be the same or different on each aryl group;R.sup.15 is H or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof;X is selected from ##STR2## wherein R.sup.7 and R.sup.8 which may be the same or different are H or hydrocarbyl (including a cycloaliphatic ring formed by R.sup.7 and R.sup.8 together), aryl, hydrocarbylaryl or a substituted derivative thereof; R.sup.9 is --OH, --NH.sub.2, --NHC(O)NH.sub.2 or --NHAr, wherein Ar is aryl or a substituted derivative thereof,n' is 0 or 1.Use of the compounds for sequestration of metals is also described.

Abstract: A method of forming liquid crystal alignment layers of high tilt angle, said method comprising preparing a polymeric film of a monomer of the formula IV: ##STR1## wherein X and Y are strong electron withdrawing groups, optionally substituted with or containing Si or Ti, and A is --H or --CH.dbd.CH.sub.2 or, provided that X and Y are both --CN, A may be --R.sup.2 or --CH.dbd.CHR.sup.2 wherein R.sup.2 is hydrocarbyl, aryl or alkaryl; exposing said polymeric film to ultraviolet radiation for sufficient period of time to photochemically modify the polymer and, thereafter, subjecting the modified polymer to a heat treatment in the range of 100.degree.-400.degree. C. for at least 5 seconds.

Abstract: A photoresist coating for use in microlithography comprises a polymer of a monomer of the formula ##STR1## wherein X and Y are strong electron withdrawing groups and R.sup.4 is H or, providing that X and Y are both --CN, R.sup.4 may be aliphatic hydrocarbyl, aryl or alkaryl. Preferred monomers are of the formula ##STR2## wherein R.sup.7 is a C.sub.1 -C.sub.5 alkyl or C.sub.2 -C.sub.5 alkenyl group, more particularly ethyl 2-cyanopenta-2,4-dienoate or allyl 2-cyanopenta-2,4-dienoate.Methods for applying a resist coating by vapor deposition of these monomers and exposure to radiation are described. A positive or negative tone image can be produced, depending upon the imaging method employed.

Abstract: A method of forming high-temperature resistant polymers by a 2 step curing process comprising(a) curing a polymerizable composition at least one aromatic compound having alpha and/or beta instruction which is not substantially reactive under the curing condition of step a, particularly allyl or properyl, and(b) heating the cured composition of step a in the presence of acid to form a crosslinked resin.

Abstract: A method of forming a gasket in situ between two components which includes injecting into a groove in at least one of said components a curable composition including:one or more free-radical polymerizable vinyl esters, and ingredients of a rapid free-radical cure system therefor,the cure system being inactivated prior to injection of the composition,and the composition having a viscosity at 25.degree. C. in the range from 200 to 500,000 mPas;and permitting the composition to cure.The composition can be a two part composition wherein the first part contains a prepolymer, monomer and activator and the second part a prepolymer, monomer and activator. The composition can also include two expansion reactants, each in a separate part of the composition prior to injection, which react to form a gas in situ in the composition. The gasketing composition is suitable for use in engines and other machines e.g. in industrial manufacturing plants.

Abstract: The silicon-containing phenoxy ethers are of the formula III: ##STR1## wherein R.sup.1 and R.sup.2 which may be the same or different are selected from H, --R.sup.3 --X, aliphatic hydrocarbyl having 1-6 carbon atoms or aryl, or substituted derivatives thereof, provided that not more than one of R.sup.1 and R.sup.2 is H;R.sup.3 is a divalent C.sub.1 -C.sub.30 aliphatic and/or aromatic hydrocarbyl group which may optionally be substituted, or interrupted, by a hetero atom;R.sup.4 and R.sup.5 which may be the same or different are H, ##STR2## or an ortho para directing activating group for aromatic electrophilic substitution, other than an amine;and X is a reactive functional group capable of undergoing an acid-catalyzed electrophilic aromatic substitution reaction with a phenol, for example an aldehyde group. They can be polymerized to produce silicone-modified polymers of the phenol-aldehyde type without the use of free aldehyde.