Abstract: The instant invention relates to novel compositions comprising highly dispersed Group VIII metal-phosphorus compounds or Group VIII metal-arsenic compounds supported on a high surface area solid support selected from the group consisting of carbon, alumina, silica, silica-alumina, zeolite, kieselguhr, vermiculite, and the refractory oxides of Group IVb and Vb, transition metals, and mixtures thereof.The instant invention further relates to a method for the preparation of the above compositions. In the preparation of the supported Group VIII metal-phosphorus compounds, the support is impregnated with both a phosphorus source, e.g. elemental phosphorus or a water soluble phosphorus salt, and a Group VIII metal source. The Group VIII metal source is impregnated onto the support from a solution of a water soluble Group VIII metal salt. Reduction of the resultant impregnated composition at temperatures above about 200.degree. C.

Abstract: The instant invention relates to a process for separating components from liquid mixtures which comprises emulsifying said liquid mixture in an immiscible liquid which is characterized as a solvent for the components. The emulsion is then contacted with an inert gas whereby the components of the mixture which, because of their solubility, permeate into said immiscible liquid, and are stripped therefrom by the inert gas. The components may then be separated from said inert gas stream by condensation and subsequent phase separation or fractionation, by absorption, distillation or by adsorption. In a preferred embodiment of the instant invention the liquid mixture comprises a hydrocarbon which is emulsified in an aqueous surfactant containing liquid. The hydrocarbon mixture contains hydrocarbons of different types, as well as hydrocarbons mixed with oxygenated compounds, i.e. alcohols, ketones, acids, and mixtures thereof. In a particular embodiment the hydrocarbon mixture contains toluene and heptane.

Abstract: This invention relates to a method of producing a dibenzocycloheptene compound of the structure ##STR1## in high yields which comprises: (a) hydrogenating an anthracene derivative in the 9,10 position to form a 9,10-dihydroanthracene derivative, (b) selectively mono-carbonylating one of the hydrogens in the 9,10 position to form a monoaldehyde, (c) reducing the aldehyde to form the corresponding alcohol and (d) dehydrating and expanding the center ring to form the dibenzocycloheptene compound.

Abstract: A process for demulsifying an emulsion containing a continuous phase and a dispersed phase comprising removing a portion of the continuous phase, combining the remaining emulsion with a liquid miscible with the dispersed phase and applying a mechanical shearing stress to the resulting combination.

Abstract: Vinylic thiophosphorus acid esters of either cis- or trans-configuration can be synthesized in a stereospecific reaction of a cis- and a trans-vinylic metal compound with diorgano phosphoryl disulfide and a diorgano phosphoryl sulfenyl halide, respectively, and the product can be isomerized to the thermodynamically more stable mixture of isomers by free radical and ionic catalysts. The new cis- and/or trans-vinylic thiophosphorus esters are mainly useful in the field of plant and animal pesticides.

Abstract: A process for removing a dissolved component from a feedstream. The feedstream is contacted with a liquid membrane emulsion which removes a portion of the dissolved component. After separation of the emulsion from the feedstream, a substantial portion of the remaining dissolved component is removed by solvent extraction.

Abstract: In the partial or full combustion of fuels in a fluidized bed, the provision of heat transfer surfaces within the bed impedes particle circulation resulting in localized regions of relative intense chemical reaction which can damage the heat transfer surfaces and cause detrimental physical and/or chemical changes in the bed particles. This problem is exacerbated when the bed is relatively deep and narrow and when the part of full combustion is effected under pressure. In the invention, at least one conduit connects an upper region of the bed to a lower region of the bed, and expedients are provided to cause a downward particle flow through the conduit(s) thereby promoting an upward flow in the bed. Heat exchange surfaces may be in the bed and/or in the conduit(s).

Abstract: The instant invention relates to novel compositions, methods for their preparation and the use of said compositions for the purposes of slow or controlled release of active ingredients such as fragrances and pharmaceuticals. These novel compositions are prepared by dispersing an aqueous phase into an oil to form a first emulsion. This first emulsion is then dispersed as droplets in a second aqueous phase in the presence of a water soluble protein and a gelling polysaccharide. These novel compositions are characterized as stable to layering and coalescence of the droplets of the first emulsion while retaining pourability.

Abstract: The instant invention relates to an improvement in the liquid membrane process for removing soluble materials from solution. More specifically, in a process wherein soluble materials are removed from solution by contacting said solution with an emulsion, the external phase of which is immiscible with said solution and permeable to said soluble materials and the internal phase contains a reactant which reacts with said soluble material and converts said soluble material to a material which is insoluble and thus trapped in the internal phase, the improvement which comprises maintaining the concentration of said reactant in the internal phase of the emulsion at a level at which the concentration of said soluble material in the internal phase of the emulsion is less than the concentration to which it is desirable to lower said soluble material in said solution. Preferably the solution is aqueous and said soluble material is a salt.

Abstract: This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e. the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g. ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g. steam.

Abstract: Nickel supported on TiO.sub.2, other titanium-containing oxides or mixtures of various titanium oxides results in a catalyst system which exhibits superior hydrocarbon synthesis characteristics. Such supported nickel catalysts exhibit selectivity to paraffinic hydrocarbon products of from C.sub.2 to C.sub.7 which are free of olefins and oxygenated products. They generate CO conversions of up to 60% at pressures of 3090 kPa without significant change in product distribution. A large fraction of the product obtained contains 2 or more carbon atoms in the chain up to conversions of 60%. The supported nickel catalysts exhibit enhanced activity, improved selectivity to higher molecular weight normal paraffins, improved longevity and tolerance to sulfur and resistance to nickel carbonyl formation as compared to nickel catalysts on other supports such as Al.sub.2 O.sub.3, silica or carbon.A new method for the selective synthesis of higher molecular weight normal paraffins from CO and H.sub.

Abstract: A new method for the synthesis of hydrocarbons with chain lengths of from 2 to 10 carbon atoms inclusive and for selective generation of olefinic hydrocarbons in this carbon number range with reduced wax formation, said products being synthesized from CO and H.sub.2 at pressures of from 100 to 3100 kPa which method comprises the steps of passing a synthesis gas stream of CO and H.sub.2 at a H.sub.2 /CO ratio of from 0.1-10 at a space velocity of from 100 hr.sup.-.sup.1 to 50,000 hr.sup.-.sup.1 over a catalyst comprising from 0.01 to 15 wt. % ruthenium on TiO.sub.2, other titanium-containing oxides or mixtures of said titanium-containing oxides for a time sufficient to effect the generation of desired olefinic hydrocarbon products, at a temperature of from 100.degree. to 500.degree. C and a pressure of from 100 to 10.sup.5 kPa (1-1000 atm). The supported ruthenium catalyst has a BET surface area of from 10 to 60 m.sup.2 g.sup.

Abstract: The instant invention relates to novel liquid membrane formulations, i.e., emulsions, which comprise an aqueous interior phase and a water-immiscible exterior phase; said water-immiscible exterior phase comprising an ethylene vinyl acetate copolymer and a solvent for this polymer. These compositions may additionally contain a water insoluble surfactant to stabilize the emulsions. In the most preferred embodiment, the aqueous interior phase comprises a strong acid, for example from about 1 to 10 percent by weight sulfuric acid. These emulsions are useful in liquid membrane processes for the separation of dissolved components from aqueous solution. Emulsions of the instant invention are characterized as showing very low swelling when contacted with aqueous solutions, especially at higher temperatures and thus are especially effective for use in the treatment of sour water feed streams by the liquid membrane technique.

Abstract: A catalyst comprising at least one metal selected from the group consisting of rhodium, palladium, ruthenium, iridium and platinum in combination with a Group VB element supported on a porous carrier is employed in the hydrocracking of heavy aromatic hydrocarbons using steam as the hydrogen source. The product consists mainly of hydrogen, carbon dioxide and lower molecular weight aromatic hydrocarbons. The catalyst is especially useful for the dealkylation of aromatic hydrocarbons.