Abstract: A method for operating a combustor having a catalyst bed. The method includes the steps of directing a flow of air through a catalyst bed, providing heat to the catalyst bed, sensing the temperature in an upstream portion of the catalyst bed to provide an upstream temperature, directing a flow of a fuel through the catalyst bed when the upstream temperature reaches a light-off temperature to produce a combustion reaction, increasing the flow of the fuel until the flow of air and the flow of fuel have a selected air to fuel ratio, and controlling the combustion reaction within the catalyst bed by adjusting the flow of air and the flow of fuel while maintaining the selected air to fuel ratio. The method can include sensing temperatures within the catalyst bed and controlling the combustion reaction in response to the sensed temperatures. The heat provided to the catalyst bed can also be adjusted in response to the sensed temperatures.

Abstract: The present invention provides a method and apparatus for identifying an activation of a burst disk. A pressure data or a temperature data relating to a flow is received. A determination is made whether the flow is interrupted based upon the at least one of the pressure data and the temperature data. A burst disk activation is identified in response to determining that the flow is interrupted.

Abstract: A coolant subsystem for use in a fuel processor and a method for its operation are disclosed. In accordance with a first aspect, the coolant subsystem is separate from the feed to the processor reactor and is capable of circulating a coolant through the processor reactor. In accordance with a second aspect, the constituent elements of the fuel processor are housed in a cabinet, and the coolant subsystem is capable of cooling both the processor reactor and the interior of the cabinet. In various alternatives, the fuel processor can be employed to reform a fuel for a fuel cell power plant and/or may be used to provide thermal control for unrelated mechanical systems.

Abstract: A method for controlling the purity of hydrogen in a reforming apparatus is described where in the apparatus includes a fuel processor, a purification unit and a system controller. The controller determines a calculated flow of reformate from the fuel processor and operates the purification unit based on the calculated flow. The calculated flow is derived from a process model of the fuel processor and known feed(s) to the fuel processor. The calculated flow of reformate is used to control the flow of reformate to adsorbent beds within the purification unit and can be used to control other materials flows within the apparatus. Means for reducing fluctuations in the pressure and/or flow rate of reformate flowing from the fuel processor to the purification unit are also disclosed. The purity of the hydrogen produced can be maintained by adjusting the operation of the purification unit in response to changes in reformate composition, pressure and/or flow rate.

Abstract: A system for mitigating slugging in the conveyance of hydrocarbons in a flowline includes a first portion of flowline that extends substantially longitudinally along a declining surface. The first flowline portion carries multiphase hydrocarbons. A second portion of flowline extends upward from adjacent the first portion of flowline, and is in fluid communication with the first portion of flowline. A slug-mitigating region is between the first and second portions of flowline so slug-mitigating assembly receives the hydrocarbons from the first portion of flowline and conveys the hydrocarbons to the second portion of flowline. The slug-mitigating region has consecutively joined tubular segments that are each arcuate along a predetermined arcuate angle, with substantially uniform cross-sections. The first portion of flowline can be a subsea flowline extending along a sea floor, and the second portion of flowline can be a riser.

Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of reaction zones arranged in an insulated, box-shaped, compact fuel processor. The multi-step process includes preheating the hydrocarbon fuel utilizing integration with the inherent exothermic processes utilized with the fuel processor, reacting the preheated hydrocarbon fuel to form the hydrogen rich gas, and purifying the hydrogen rich gas to produce a gas that is suitable for consumption in a fuel cell.

Abstract: Methods for converting hydrocarbon fuels to hydrogen-rich reformate that incorporate a carbon dioxide fixing mechanism into the initial hydrocarbon conversion process. The mechanism utilizes a carbon dioxide fixing material to remove carbon dioxide from the reformate product stream. The removal of carbon dioxide from the product stream shifts the reforming reaction equilibrium toward higher hydrocarbon conversion with only small amounts of carbon oxides produced. Repeated absorption/desorption of carbon dioxide by the fixing materials tends to decrease the fixing capacity of the materials. Hydration of the carbon dioxide fixing materials between one or more cycles serves to sustain their fixing capacity and to enhance the efficiencies of the reforming and shift reactions occurring in the catalyst bed. Hydration can occur during reactor start-up or shut down, periodically over a number of cycles, and/or upon a monitored change in the reformate composition.

Abstract: An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for converting a fuel to a reformate having fluctuations in pressure and or flow rate, means for reducing the fluctuations, a compression unit for compressing the reformate and one or more of a purification unit and a storage unit downstream of a compression unit. Means for reducing the fluctuations in the reformate can include one or more of a buffer and a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. The supplemental fluid can include the compressed reformate, a hydrogen-enriched reformate, and mixtures thereof. The apparatus can include means for regulating power to the compression unit that can incrementally increase power to the compression unit particularly during start up. The purification unit can include one or more of a hydrogen selective membrane and a pressure swing adsorption unit. Methods for producing hydrogen are also disclosed.

Abstract: An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for producing a reformate having fluctuations in a pressure and/or flow rate and means for reducing the fluctuations. The reformate comprises impurities that are removed by a purification unit having a plurality of adsorbent beds. A valve assembly controls the flow of reformate to the adsorbent beds based upon sensed product data generated by a product sensor. A compression unit optionally compresses the reformate prior to entering the purification unit. Means for reducing fluctuations in the pressure and/or flow rate include a buffer and/or a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. A product valve can control the flow of hydrogen-enriched reformate out of the purification unit.

Abstract: Method and apparatus for separating components of a slurry comprising solid particles and liquid components, particularly where the slurry is under pressure. The components are separated in a hydrocyclone such that a solids-enriched slurry exits the separator via an underflow outlet while a solids-depleted slurry exits the separator through an overflow outlet and passes into a products vessel. Fluid communication is provided between the products vessel and the underflow outlet so that gas can circulate through the hydrocyclone. This gas circulation pathway may be achieved by enclosing the separation system in a housing or providing a gas circulation conduit between the products vessel and the underflow outlet of the separator or an optional solids vessel connected to the underflow outlet. Pressure within the separator apparatus may be adjusted and controlled at a negative, neutral or positive pressure while operating the hydrocyclone in balanced mode to achieve efficient separation.

Abstract: Apparatus and method for rapidly heating one or more reactants for use in a fuel reformer. The apparatus includes a combustion section having an outer wall enclosing a combustion chamber and a catalyst disposed within the combustion chamber. A heat recovery section is in fluid communication with the combustion section and has an outer wall defining a heat recovery chamber. At least one heat exchanging element is located within the heat recovery chamber having an inlet for receiving a fuel reforming reactant and an outlet for directing a heated reactant out of the heat recovery section. The combustion section is elevated relative to the heat recovery section such that heated combustion gases are displaced down into the heat recovery section. The housing has an internal diameter of less than about 10 inches, or alternatively, has a length and a diameter in a ratio of between about 7:1 and about 4:1.

Abstract: An apparatus for vaporizing a liquid and heating the vaporized liquid to an elevated temperature. The apparatus has a heat transfer wall having an outer surface for receiving heat and transferring the heat to an inner surface. A wick material is disposed so that a portion of the wick material is in contact with the inner surface and another portion is remote from the heat transfer wall. A wick support in contact with the wick material opposite the inner surface of the heat transfer wall provides structural support to the wick material and further provides a path for vaporized liquid to flow from the wick material. Vaporizable liquid is delivered to the portion of the wick material that is remote from the heat transfer wall and is allowed to migrate to the portion that is in contact with the inner surface. Heat from the inner surface converts the liquid to a vaporized liquid. Optionally, a gaseous fuel may be introduced into the wick support for pre-heating and mixing with the vaporized liquid.

Abstract: A method and system are disclosed for controlling a process by establishing a control factor for a proportional-integral-derivative (PID) controller used to control a parameter of a process relative to a setpoint. A feedback signal regarding the parameter of the process is received via a sensor of the process and a first feedback loop. Automatic adjusting of the control factor of the PID controller is based on the feedback signal.

Abstract: A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore alumina containing molecular sieves dispersed therein. The molecular sieves have a silica-to-alumina molar ratio of less than 1.0, more preferably, less than 0.3, and most preferably less than 0.1. In some cases, the molecular sieves have no appreciable amounts of silica. Exemplary compositions include aluminophosphates (AlPO) and silicoaluminophosphates (SAPO). When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. The molecular sieves have pores with a largest minor crystallographic free diameter of 4.0 Angstroms or less. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.

Abstract: A combustor for oxidizing a combustion fuel and pre-heating one or more reactants for fuel reforming. The combustor includes an elongated housing having an inlet for receiving a combustion fuel and an outlet for exhausting combustion products. The elongated housing further includes a cylindrical side wall, a bottom wall, and a top wall. Inert particles are disposed within the housing adjacent the inlet. A combustion catalyst bed is disposed within the housing above the inert particles that is a mixture of inert particles and combustion catalyst. The inert particles and the combustion catalyst preferably have a volumetric ratio of inert particles to catalyst between about 2:1 and about 4:1. The combustor has at least one heat exchanger within the combustion catalyst bed for heating a reformer reactant and generating steam. Preferably, the combustor includes at least two heat exchangers within the combustion catalyst bed, the heat exchanging elements have different surface areas.

Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of modules arranged in a nested manner along a common axis. The multi-step process includes: providing a fuel processor having a plurality of modules arranged so that they are nested one within the other; and feeding the hydrocarbon fuel successively through each of the modules in the reactor to produce the hydrogen rich gas.