Patents Represented by Attorney Fred S. Valles
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Patent number: 4037011Abstract: Novel injection molding fiberglass reinforced thermoplastic concentrate granules are prepared by a process wherein continuous multifilament glass strands are impregnated with from 10 to 30 percent by weight of thermoplastic resin and, while the strand is maintained under controlled temperature conditions, the impregnated strand is cut to lengths of at least 1/8 of an inch.Type: GrantFiled: February 28, 1975Date of Patent: July 19, 1977Assignee: Dart Industries Inc.Inventors: Kiyoshi Hattori, Edward L. Lowery, William H. Chadbourne, William M. Boyer
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Patent number: 4027085Abstract: In apparatus for polymerizing high-pressure ethylene to produce polyethylene, a tubular reactor is connected to a source of solution to the tubular reactor. This solution includes one or more catalysts which promote the polymerization reaction. Within the tubular reactor, a peak temperature occurs in proximity of the point at which the catalysts are introduced. If the catalysts are introduced at more than one point, peak temperatures will result downstream of each of such points. For various reasons, the peak temperatures are displaced along the tubular reactor and a plurality of thermocouples are distributed at spaced positions in the tubular reactor to measure the temperatures at the positions at which the peak temperature might occur. These thermocouples generate signals which are fed into a gating arrangement which selects the peak signal which is compared in a comparator circuit with an adjustable or selectable signal representative of the peak temperature which is desired.Type: GrantFiled: May 19, 1975Date of Patent: May 31, 1977Assignee: Dart Industries Inc.Inventors: Clyde C. Clemmer, Ward C. Alcorn, III
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Patent number: 4008162Abstract: A two-step process for the waste treatment of fluoroborate solutions which involves hydrolysis at an acidic pH in the presence of calcium ions to liberate fluoride and subsequent removal of fluoride values, e.g. by precipitation as calcium fluoride under alkaline conditions.Type: GrantFiled: August 5, 1975Date of Patent: February 15, 1977Assignee: Dart Industries Inc.Inventors: Theodore Frank Korenowski, Jerry Lee Penland, Chalmer John Ritzert
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Patent number: 4008049Abstract: In apparatus for polymerizing high-pressure ethylene to produce polyethylene, a tubular reactor is connected to a source of high pressure ethylene. An intensifier supplies an initiator solution to the tubular reactor. This solution includes one or more catalysts which promote the polymerization reaction. Within the tubular reactor, a peak temperature occurs in proximity of the point at which the catalysts are introduced. If the catalysts are introduced at more than one point, peak temperatures will result downstream of each of such points. For various reasons, the peak temperatures are displaced along the tubular reactor and a plurality of thermocouples are distributed at spaced positions in the tubular reactor to measure the temperatures at the positions at which the peak temperature might occur.Type: GrantFiled: October 30, 1972Date of Patent: February 15, 1977Assignee: Dart Industries Inc.Inventors: Clyde C. Clemmer, Ward C. Alcorn, III
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Patent number: 4006114Abstract: A filled polypropylene composition having excellent flame retardance is prepared by blending polypropylene resin with chlorinated paraffin hydrocarbon, chlorinated polyethylene, antimony oxide and alumina trihydrate.Type: GrantFiled: November 26, 1975Date of Patent: February 1, 1977Assignee: Dart Industries Inc.Inventor: Allen William Carlson
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Patent number: 4002813Abstract: The catalyst stream used for regulating high pressure polymerization reactions of monoolefins such as ethylene can be supplied in a positive, clean and accurately controllable fashion by delivering it through a separate conduit which terminates in an orifice tip located within and substantially coplanar with the entry port of the monomer stream into the reaction zone. The subject technique simplifies start-up as well as maintenance of good temperature control throughout the polymerization process.Type: GrantFiled: August 16, 1974Date of Patent: January 11, 1977Assignee: Dart Industries Inc.Inventors: Robert Bruce Steinert, William Arthur Schuessler
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Patent number: 3997629Abstract: A propylene polymer composition having excellent affinity towards basic dyestuffs is produced by blending a propylene polymer with an alternating copolymer of an alkyl vinyl ether and maleic anhydride, the alkyl group of the alkyl vinyl ether containing at least 8 carbon atoms.Type: GrantFiled: December 29, 1975Date of Patent: December 14, 1976Assignee: Dart Industries Inc.Inventors: Ramchandra K. Hulyalkar, Marvin Michael Fein, Jan Edmond Vandegaer
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Patent number: 3969242Abstract: A control system for a liquid-solid contacting apparatus and method therefor is designed to greatly minimize the dilution and contamination of the product streams as well as to perform the desired separation, concentration or conversion reactions at peak efficiency.The liquid-solid contactor comprises a loop; a plurality of loop valves dividing the loop into loading, pulse and regenerating sections; feed means for supplying a feed containing sorbable material to the loading section; sorption solid substantially filling the loop; regenerating means for supplying regenerating fluid to the regenerating section; first removal means for removing the material desorbed by the regenerating fluid from the loop; second removal means for removing the processed liquid from the loop; pulse inlet means for supplying a pulse liquid to the pulse section and an outlet means for removing a portion of the pulse liquid from the loop.Type: GrantFiled: October 2, 1974Date of Patent: July 13, 1976Assignee: Dart Environment and Services CompanyInventor: David C. Kruse
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Patent number: 3964310Abstract: A fluid flow meter of the variable area flow passage type is provided wherein the variation in said flow passage area is effected by the displacement of a control boundary which is supported by an annular diaphragm element. Said control boundary is shaped and sized so that the overall displacement required for the flow rate range desired is within the stroke capacity delivered by the free flexing action of said diaphragm element, thereby achieving substantially constant differential pressure operation at a very reasonable value which is due almost entirely to gravity. The resulting unit is very compact and stable and is characterized by very smooth linear response between vertical displacement and fluid flow rate. Said vertical displacement can be measured by various means but is preferably transduced to an equally linear, smooth and steady electrical signal by a direct connection with a specially adapted differential transformer.Type: GrantFiled: May 17, 1974Date of Patent: June 22, 1976Assignee: Dart Industries Inc.Inventor: Nyyrikki K. Stenberg
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Patent number: 3960987Abstract: Propylene, for example, is polymerized with crystalline TiCl.sub.3 --AlCl.sub.3 and diethylaluminum monochloride catalyst at a rate of at least 300 lbs. polymer/lb. catalyst/hr. based on TiCl.sub.3 with partial H.sub.2 pressure of about 150 to about 1000 psi and sufficient total pressure to maintain propylene in liquid form. The resulting propylene homopolymer, while still containing active catalyst residues, is then reacted further with at least one additional alpha-olefin, preferably ethylene or ethylene-containing alpha-olefin mixtures in suitable amounts. The resulting waxy block copolymer has a melt flow of 40 to 400 as determined by ASTM-D-1238-62T at 230.degree.C.Type: GrantFiled: September 23, 1974Date of Patent: June 1, 1976Assignee: Dart Industries Inc.Inventors: Joseph M. Kelley, John J. Miskel, Jr.
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Patent number: 3959244Abstract: Hydroxy-terminated polymers of butadiene having two hydroxy groups per molecule are prepared by polymerizing butadiene in a chain transfer solvent at a temperature of from about 50.degree. to about 170.degree.C. with t-butyl beta-hydroxyethyl peroxide as an initiator.Type: GrantFiled: August 27, 1973Date of Patent: May 25, 1976Assignee: Dart Industries Inc.Inventor: Norman G. Gaylord
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Patent number: 3957909Abstract: ABS compositions of improved impact strength are obtained by adding thereto controlled amounts of a synthetic hydrocarbon resin having a ring and ball softening point of at least 70.degree.C and derived from deeply cracked petroleum stocks.Type: GrantFiled: March 3, 1975Date of Patent: May 18, 1976Assignee: Dart Industries Inc.Inventors: Peter James Perron, Joseph Leopold Schafer
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Patent number: 3953304Abstract: An aqueous acid nickel electroplating bath containing as a brightener-leveling agent the reaction product of an acetylenic diester of a halogenated saturated aliphatic acid with a heterocyclic compound containing a tertiary nitrogen atom. The brightener may have the general formula ##EQU1## wherein R.sub.1 and R.sub.2 are hydrogen, halogen or a hydroxy, carboxy, carboxyester, sulphoxy, alkyl, amino or amido group;R.sub.3 is a hydrogen or an alkyl group;R.sub.4 and R.sub.5 are hydrogen or an alkyl group;X is halogen andN is an integer from 0 to 2.Type: GrantFiled: June 23, 1975Date of Patent: April 27, 1976Assignee: Dart Industries Inc.Inventors: John L. Allan, Kollengode V. Srinivasan, Philip D. Readio, Judit Cestero
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Patent number: 3953306Abstract: An improved process for preparing highly concentrated salt solutions of metals of high purity from waste metal sludges at superior dissolution rates is achieved by preparing, concentrating and washing the sludge containing insoluble metal hydroxide under specific conditions to safeguard against the solids being exposed to air or dried out. The wet sludge is then dissolved in a dilute acid. The resultant solution can be used directly e.g. as make up in many electrolytic metal finishing processes to compensate for drag out losses occurred, or as the primary metal source in electrolytic processes employing insoluble anodes. Other specific uses for the process include the preparation of aluminum sulfate coagulants.Type: GrantFiled: October 3, 1973Date of Patent: April 27, 1976Assignee: Dart Environment and Services CompanyInventor: Leslie E. Lancy
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Patent number: 3951911Abstract: Propylene-based, normally solid polymer compositions are stabilized against oxidative degradation especially when exposed to both a metal such as copper and a soft hydrocarbon medium such as petrolatum. Highly synergistic levels of stability are achieved by combining in said polymer compositions three different stabilizer additives (a), (b) and (c) as follows:A. between about 0.4 and about 1.6% by weight of the tetraester of pentaerythritol with 3(3',5'-ditertiary butyl, 4'-hydroxy phenyl) propionic acid,B. between about 0.1 and about 0.4% by weight of N,N'" diacetyl N',N" adipoyl dihydrazide, andC. between about 0.15 and about 0.Type: GrantFiled: November 22, 1974Date of Patent: April 20, 1976Assignee: Dart Industries Inc.Inventor: Kornel D. Kiss
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Patent number: 3945865Abstract: Evolution of NOx fumes during dissolution of metal values in mineral acid solutions of nitric acid can be eliminated by the addition of small quantities of hydrogen peroxide to the acid solution.Type: GrantFiled: July 22, 1974Date of Patent: March 23, 1976Assignee: Dart Environment and Services CompanyInventor: David Robert Kamperman
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Patent number: 3940379Abstract: A process is provided for the degradation of propylene polymers comprising contacting a propylene polymer exhibiting a first melt flow rate with oxygen or an oxygen-containing gas and an organic or inorganic peroxide; melting and working and resulting mixture in a high shear zone thereby degrading said propylene polymer; and recovering an essentially odor free propylene polymer exhibiting a second melt flow rate higher than said first melt flow rate.Type: GrantFiled: May 21, 1973Date of Patent: February 24, 1976Assignee: Dart Industries, Inc.Inventors: Eugene G. Castagna, Albert Schrage, Michael Repiscak
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Patent number: 3937758Abstract: Novel polypropylene compositions comprising blends of 85-97wt percent block copolymers of propylene and ethylene with 3-15wt percent linear polyethylene and a process therefor. The compositions exhibit improved impact and low temperature brittleness properties.Type: GrantFiled: July 1, 1975Date of Patent: February 10, 1976Assignee: Dart Industries Inc.Inventor: Eugene G. Castagna
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Patent number: 3935128Abstract: An improved copper chromite catalyst having high density, low monovalent ion content, high activity and resistance to poisoning is prepared by reacting a soluble copper salt with chromic acid or a dichromate in solution in the presence of ammonia and urea to precipitate a copper-chromium-nitrogen complex, washing, drying and calcining the precipitate.Type: GrantFiled: December 30, 1974Date of Patent: January 27, 1976Assignee: Dart Industries Inc.Inventors: Marvin Michael Fein, Paul Alexander Colgate, Ronald Allan Kent