Patents Represented by Attorney, Agent or Law Firm J. Jeffrey Hawley
  • Patent number: 7858160
    Abstract: The present invention relates to an inkjet recording element having very good dye keeping properties in time. Said inkjet recording element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least one hydrosoluble binder and at least one aluminosilicate polymer obtainable by a preparation method consisting in treating an aluminum halide with a mixture of at least one silicon alkoxide only having hydrolyzable substituents and at least one silicon alkoxide having a non-hydrolyzable substituent, with an aqueous alkali in the presence of silanol groups, the aluminum concentration being maintained less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the hybrid aluminosilicate polymer. The ink-receiving layer also comprises inorganic particles.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: December 28, 2010
    Assignee: Eastman Kodak Company
    Inventors: GĂ©rard A. Friour, Olivier J. Poncelet
  • Patent number: 7632555
    Abstract: The present invention relates to a recording element intended for forming images by inkjet printing having very good colorfastness over time and a good ink drying time. Said recording element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least one hydrosoluble binder and at least one aluminosilicate polymer capable of being obtained according to a preparation method consisting in treating an aluminum halide with an alkyl orthosilicate only having hydrolyzable functions with an aqueous alkali in the presence of silanol groups, the aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: December 15, 2009
    Assignee: Eastman Kodak Company
    Inventors: Stephanie V. Desrousseaux, Olivier J. Poncelet
  • Patent number: 7560092
    Abstract: The present invention relates to a method for preparing an aluminosilicate polymer and the polymer resulting from this method. Said method consists in treating an aluminum halide with an alkyl orthosilicate only having hydrolyzable functions with an aqueous alkali, in the presence of silanol groups, aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then in stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the aluminosilicate polymer.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: July 14, 2009
    Assignee: Eastman Kodak Company
    Inventors: Olivier J. Poncelet, Stephanie V. Desrousseaux
  • Patent number: 7507392
    Abstract: The present invention relates to a method for preparing a hybrid aluminosilicate polymer and the polymer resulting from this method. Said method consists in treating an aluminum halide with a mixture of at least one silicon alkoxide only having hydrolyzable substituents and at least one silicon alkoxide having a non-hydrolyzable substituent, with an aqueous alkali, in the presence of silanol groups, aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then in stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the hybrid aluminosilicate polymer.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: March 24, 2009
    Assignee: Eastman Kodak Company
    Inventors: Olivier J. Poncelet, Stephanie V. Desrousseaux
  • Patent number: 7384139
    Abstract: The present invention relates to ink for inkjet printing providing a printed image having improved stability, demonstrated by improved color fastness in time. Said ink includes at least particles of synthetic, substantially amorphous aluminosilicate polymer, the synthetic amorphous aluminosilicate polymer having an average diameter of 1 to 10 nm, wherein the aluminosilicate polymer exhibits an X-ray diffraction pattern that has weak peaks at about 2.2 and 3.3 ?.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: June 10, 2008
    Assignee: Eastman Kodak Company
    Inventors: Gerard Amede Friour, Olivier Jean Poncelet
  • Patent number: 6919171
    Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: July 19, 2005
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
  • Patent number: 6790585
    Abstract: The present invention relates to a method for developing an exposed high contrast photographic silver halide material, said photographic material comprising a support bearing at least one silver halide emulsion layer, containing at least one hydrazide nucleating agent. According to the invention, the nucleating agent has the formula (I) and the photographic material is developed in a hydroquinone-free developer, comprising a main developing agent of the ascorbic acid or ascorbic acid salt type, and as auxiliary developing agent a mixture of 3-pyrazolidones of which at least one has the formula (II): wherein at least one of the radicals R3 to R9 contains a solubilizing group. This combination enables photographic materials with ultrahigh contrast to be obtained.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: September 14, 2004
    Assignee: Eastman Kodak Company
    Inventors: Jacques Roussilhe, Siu C. Tsoi, John D. Goddard, Llewellyn J. Leyshon
  • Patent number: 6723397
    Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer, and b) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: April 20, 2004
    Assignee: Eastman Kodak Company
    Inventor: Allan Wexler
  • Patent number: 6692906
    Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: February 17, 2004
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
  • Patent number: 6685836
    Abstract: The invention relates to a method for separating a mixture of aluminosilicates, wherein said method consists in carrying out an ultrafiltration of a solution of colloidal aluminosilicate particles so as to obtain a permeate and a retentate, and an imogolite like fibrous aluminosilicate polymer of high purity with an Al:Si molar ratio between 1.8 and 2.5 is obtained in the retentate, and allophanes like spherical aluminosilicate particles are obtained in the permeate.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: February 3, 2004
    Assignee: Eastman Kodak Company
    Inventor: Olivier J. Poncelet
  • Patent number: 6680066
    Abstract: The present invention relates to a composite material with an improved structure in which is dispersed an active organic compound, and a method for treating effluents, in particular a method for treating photographic effluents. The composite material takes the form of a structured gel comprising an aluminosilicate polymer matrix in the form of fibers in which at least two distinct fibers are interconnected by at least two covalent bonds to form an irreversible chemical gel and, dispersed in the matrix, an active organic compound. The choice of the degree of cross-linking of the matrix makes it possible to control the diffusion of a hydrophilic active organic compound. The invention further concerns a method for preparing such a composite material.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: January 20, 2004
    Assignee: Eastman Kodak Company
    Inventors: Olivier J. Poncelet, Danielle M. Wettling
  • Patent number: 6652761
    Abstract: The invention relates to a method of recycling wash-water resulting from the treatment of a film provided with a carbon particles based backing layer, and especially from a washing treatment to remove the said carbon particles based backing layer. The method comprises the step of passing the wash-water through an microfiltration unit equipped with a microfiltration membrane made from a polytetrafluorethylene-based membrane. The method enables the regeneration of the wash-water and its recycling with a high efficiency and considerable lowering of the water consumption used in this step of the processing.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: November 25, 2003
    Assignee: Eastman Kodak Company
    Inventor: Didier J. Martin
  • Patent number: 6638708
    Abstract: The present disclosure relates to dispersions of silver (carboxylate-n-alkyl thiolate). The carboxylates are typically silver salts of long chain fatty acids and the n-alkyl thiolate is preferably 1-dodecanethiol. These silver (carboxylate-n-alkyl thiolate) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: October 28, 2003
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Ghyzel, Mark Lelental, David A. Dickinson, Alan R. Pitt, Trevor J. Wear
  • Patent number: 6620397
    Abstract: The present invention relates to a material and a method for treating of photographic effluents in order to eliminate microorganisms and pollutant by-products so as to control bacterial growth and thereby obtain effluents that comply with regulatory requirements. The method for preparing an oxidizing material according to the invention comprises the dispersion in colloidal form of a metal or metal compound in an aqueous solution of an inorganic aluminosilicate polymer, said aluminosilicate being able to form an inorganic gel, and said metal or metal compound being able to cause the oxidation of oxidizable products and (or) micro-organisms to be eliminated, followed by the addition of a base to cause said aluminosilicate to gel. The metal is preferably silver in a powder form that is able to form a colloid when it is dispersed. The oxidizing material of the invention is efficient especially for the treatment of photographic baths, in particular wash baths placed after the fixing step.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: September 16, 2003
    Assignee: Eastman Kodak Company
    Inventors: Danielle M. Wettling, Olivier J. Poncelet
  • Patent number: 6582881
    Abstract: An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer, a light reflecting layer is disclosed. The recording layer comprises (i) a metallized azo ether dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has an ether substituent ortho to the azo group and said phenyl nucleus is free of strong electron withdrawing groups and (ii) a cyanine dye. The recording layer also has, when unrecorded a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: June 24, 2003
    Assignee: Eastman Kodak Company
    Inventors: Derek D. Chapman, Ann L. Carroll-Lee, Csaba A. Kovacs
  • Patent number: 6447981
    Abstract: Metallized azo thioether dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has an thioether substituent ortho to the azo group but does not have electron withdrawing substituents on the phenyl nucleus. The dyes are useful in optical recording elements.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: September 10, 2002
    Assignee: Eastman Kodak Company
    Inventors: Derek D. Chapman, Csaba A. Kovacs
  • Patent number: 6391537
    Abstract: There is disclosed a nanoparticulate dispersion of a silver carboxylate particles having on the surface of the particles a surface modifier which is a nonionic oligomeric surfactant based on vinyl polymer with an amido function. In particular, the surface modifier is acrylamide, methacrylamide or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: May 21, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Alan R. Pitt, David A. Dickinson, James L. Wakley, Peter J. Ghyzel
  • Patent number: 6387611
    Abstract: There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: May 14, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, David A. Dickinson, James L. Wakley, Michael W. Orem, Peter J. Ghyzel
  • Patent number: 6365336
    Abstract: There is disclosed an aqueous photothermographic composition comprising a) a photosensitive silver halide emulsion precipitated in a water dispersible cationic starch peptizing agent and b) an oxidation-reduction imaging forming composition comprising (I) a colloidal dispersion of silver compound particles and (ii) an organic reducing agent. The use of a starch peptizing agent reduces the fog in an element using the composition upon thermal processing.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: April 2, 2002
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, David A. Dickinson, Mark Lelental
  • Patent number: 6361916
    Abstract: A composition that is useful in a wide variety of applications comprises a latex having water as a continuous phase and, as the dispersed phase, hydrophobic polymer particles having associated therewith both a dye and a stabilizer for the dye. In a particularly preferred embodiment, the dye is an infrared absorbing dye. The composition can be used as an inkjet ink, as a coating composition to form an infrared sensitive optical recording layer or for other purposes.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: March 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Huijuan D. Chen, Tien-Teh Chen, Kevin W. Williams