Abstract: A process for storing a refined liquid hydrocarbon product in a storage tank having a dead volume. The process comprises filling the dead volume with a rigid crosslinked polymer gel and storing product in the remaining internal volume of the storage tank.

Abstract: A method and means for delivering the liquid generated by a coreflood experiment to test tubes and the gas so generated to a gas outlet. A mixture of gas and liquid is fed through an axially rotating tube extending through the central portion of a sealed chamber in which the test tubes are arranged in a circular path. The tube has a transversely extending delivery portion which deposits liquid into the test tubes, while gas is collected through a conduit leading from the chamber. The tube is incrementally rotated through a mechanism which allows fluid from the core sample to flow into the tube at the same back pressure under which the experiment takes place.

Abstract: An apparatus for containing liquids and pollution within a liquid drainage comprising a first conduit, a second conduit, a liquid barrier, a means for lifting, and a means for sensing pollution. The second conduit is smaller in relative diameter than the first conduit and is positioned so that the second conduit outlet end is located within the first conduit. The second conduit has a flexible portion of its length which permits the outlet end of the second conduit to be lifted while the inlet end of the second conduit remains stationary. The liquid barrier guides fluid flow into the second conduit inlet during normal flow, guides fluid flow into the second conduit and liquid flow over the top of the liquid barrier and into the first conduit during floods and retains liquid during normal flow when the outlet end of the second conduit is lifted. The apparatus further comprises a means for lifting which is electrically connected to a sensing means.

Abstract: A semi-permeable membrane process of separating impurities from a hydrocarbon mixture. A fuel gas sweep gas is used to purge and dilute the permeate. Because this reduces the partial pressure of the impurities, the driving force for permeation is increased even though the permeate mixture pressure is increased to the extent that the system need not employ a compressor or vacuum pump. The mixture of permeate, fuel gas and permeated hydrocarbon product can be delivered at a pressure sufficient to flow directly to the plant fuel system or other system for use therein. Specific membrane units employing hollow fiber membranes or spirally wound stacked membrane layers are disclosed.

Abstract: An apparatus and method for injecting fluid into and producing fluid, including gas, from a subterranean formation via a well in fluid communication with the formation. Fluid is injected into the subterranean formation through a first generally tubular conduit in the well and fluid is produced from formation to the surface through this conduit until fluid flow ceases. Thereafter, fluid is pumped from the formation into the tubular conduit and diverted into the annulus defined between the conduit and the well. The pressure drop created by this diversion causes gas to break out of the produced fluid. The remaining fluid is diverted back into the conduit and pumped to the surface while the gas is produced to the surface via the annulus.

Abstract: A method for identification and quantification of sulfonation by-products by ion chromatography. The method utilizes 2 eluants and preferably 3 eluants to identify and quantify the by-products on a single chromatographic run.

Abstract: A conformance improvement treatment process is provided for reducing the permeability of a higher-permeability zone in a subterranean hydrocarbon-bearing formation which is in fluid communication with a lower-permeability zone of the formation. The process includes preparing a gel precursor solution at the surface, injecting the solution into a wellbore penetrating the formation, placing the solution in the higher-permeability zone and gelling the solution therein. In situ gelation of the solution results in substantial permeability reduction to the higher-permeability zone. A specific gel precursor solution is utilized which contains a gelling agent and a polymer formed from at least two distinct monomers wherein the first monomer has a relatively faster, yet controlled, rate of hydrolysis and the second monomer has a relatively slower rate of hydrolysis. Gelation of the solution is delayed until a substantial number of carboxylate groups are formed in situ on the polymer.

Abstract: A polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas is injected into a fractured subterranean formation via a first well in fluid communication with the formation and preferentially enters fractures present in the formation. The injected polymer enhanced foam promotes the recovery of liquid hydrocarbons from said formation via the first well or a second well in fluid communication with the formation.

Abstract: Method and means for preventing fluidization or mobilization of a gravel pack in a fluid producing well as a result of increased fluid pressure caused by a well shut-in or other pressure surge. A pressure relief valve in the form of a check valve is provided in a tubing string below a packer surrounding the string and above the top of the gravel pack. The check valve is held in closed position by a biasing force, such as a spring, which is less than the pressure which will cause mobilization or fluidization of the gravel pack. A pressure surge such as a well shut-in or flow rate decrease increases tubing pressure which causes the check valve to open, thereby relieving the pressure in the gravel pack to a point below the critical level.

Abstract: A method of selectively and variably positioning tubing within the generally horizontal section of a horizontally drilled well. A tubing string having a guide shoe secured to the end thereof is inserted into a portion of the horizontal section of a horizontal well. Smaller diameter tubing is then inserted through the tubing string and past guide shoe into the generally horizontal section. The smaller diameter tubing can be inserted to a point proximate the end of the horizontal section of the well or intermediate between the end and the guide shoe. The subterranean formation surrounding the generally horizontal section may be stimulated or treated by injecting a fluid via the smaller diameter tubing.

Abstract: A foam is provided having utility for improving sweep efficiency in subterranean oil-bearing formations and having specific utility for conformance improvement treatments and mobility control in such formations. The foam is a gel medium having a gas dispersed therein. The gel medium is made up of a crosslinkable polymer, a crosslinking agent, a surfactant and a liquid solvent.

Abstract: A sealed valve body housing a rotary valve rotated by a spindle. The spindle is connected to a disc mounted in a chamber in the valve body adjacent a valve body wall. Polyphase drive coils on the valve body wall induce a current in the disc, causing it to rotate. A pulse sensor mounted on the valve body detects the rotative position of the disc and a counter signals the power source to stop movement of the valve. The periphery of the disc is notched to permit the pulses to pass through the rotating disc and be counted. The torque of the disc can be increased through use of more sets of coils, more discs or gears interconnecting the spindle and the rotary valve.

Abstract: A composition for use as a road base or levee fill. The composition comprises catalytic cracking catalyst particles in the size range of 1 to 200 microns and a binder the type and amount of which depend on the end use. Hydrated lime is employed as the binder in road base construction while hydrated lime, portland cement, fly ash or mixtures of fly ash and portland cement can be used in levee construction. The spent catalyst particles are present in amounts of 80% to 96% and the binder is present in amounts of 4% to 20%, both percentage ranges being determined according to the dry weight of the composition.

Abstract: A relatively high molecular weight polyvinyl sulfonate and a process for inhibiting scale deposition, particularly inorganic sulfate such as barium sulfate, wherein an aqueous fluid present in or produced from a subterranean formation is contacted with an aqueous solution having a relatively high molecular weight polyvinyl sulfonate dissolved therein. The aqueous fluid has a pH equal to or less than 6.0 and the polyvinyl sulfonate has a molecular weight of from about 9,000 to about 30,000.

Abstract: Reversible crosslinked polymer gels are prepared by adding a degelling agent precursor to a gelation solution during initial preparation. The precursor is integrated into the resulting gel and undergoes hydrolysis to transform into an active degelling agent which reverses the gel. The process has specific utility to hydrocarbon recovery applications where in situ gels are difficult to contact with conventional reversing agents.

Abstract: A process is provided for sand consolidation treatment in a subterranean hydrocarbon-bearing formation in fluid communication with a hydrocarbon production well bore. An immature flowing gel is injected through the well bore into a treatment zone of the formation and followed by an overdisplacement fluid which displaces a portion of the immature gel from the zone. Displacement of a portion of the immature gel from the zone establishes flow pathways through the zone for subsequent hydrocarbon production while the gel remaining in the zone matures and effectively consolidates the sand therein.

Abstract: Degasification of liquid sulfur produced by the Claus process to remove hydrogen sulfide. The liquid sulfur is caused to flow continuously through a vessel where it is contacted by a counter-flowing inert gas, thereby stripping hydrogen sulfide from the sulfur. Nitrogen and air are preferred examples of inert gas which can be used in the method.

Abstract: A process for in-situ enrichment of gas used in miscible flooding in a subterranean hydrocarbon-bearing reservoir. A drive gas such as methane, lean natural gas, nitrogen, carbon dioxide or mixtures thereof is used to immiscibly displace formation hydrocarbons. After gas breakthrough the produced fluid is separated into oil and gas components. The separated gas, which has been enriched with intermediate hydrocarbon compounds extracted from the formation hydrocarbons, is mixed with the drive gas injected into the reservoir so as to enrich the injected gas sufficiently to cause miscible displacement of the formation hydrocarbons. When the drive gas is carbon dioxide, methane and/or nitrogen may be extracted from the separated gas prior to being mixed with the drive gas.

Abstract: Method and means for redistributing fluid flow through a catalyst bed in a reactor by applying uniform flow resistance. A mat to which a series of uniformly spaced disks are adhered is placed within the catalyst bed. The disks are formed of a material capable of withstanding the temperatures within the reactor, while the mat is formed of a material which is not. The mat is destroyed by the heat of the reactor, leaving the disks in place. Localized high flow rates are smoothed out by the flow resistance provided by the disks, with flow taking place between the disks. Since the disks are small relative to the opening used to dump the spent catalyst, special consideration for disk recovery and handling are not necessary as the disks flow out the opening with the spent catalyst.

Abstract: An offshore submersible jacket assembly having bouyancy means at the lower portion of the jacket support legs. Relatively short pile sleeves are attached in a cluster to a support leg by shear plates extending generally along the length of the pile sleeves, each sleeve being connected to the leg by a pair of spaced shear plates. Upper and lower transverse plates seal off the ends of the spaced shear plates, creating airtight compartments.