Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The invention particularly relates to a supported metallocene catalyst system that does not require an activator or cocatalyst for the polymerization of olefins.
Abstract: Compounds useful as catalyst components for olefin polymerization. The compounds comprise derivatives of cyclopentadienyl complexes of the ZR or HF.
Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting particularly in a slurry phase polymerization process.
Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst able to produce polymers having broader molecular weight distribution and a higher molecular weight. Not only are such polymers easily processable as compared with metallocene polymers produced with other support methods but the methods of this invention provides for a supported catalyst with increased activity.
Abstract: This invention is generally directed toward a catalyst system useful for polymerizing olefins. The method for preparing the catalyst of the invention provides for combining a bulky ligand transition metal catalyst with an activator that has been aged, optionally with a support. The catalyst system is useful in any polymerization process.
Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting particularly in a gas phase polymerization process.
Abstract: Catalysts comprising (a) derivatives of mono, bi and tricyclopentadienyl coordination complexes with a transition metal and (b) an alumoxane are employed in a process of producing polyolefins of controlled molecular weight.
Abstract: This invention relates to functionalized polymers and a method to obtain them comprising combing a living polymer or a polymer having a terminal halide with an alkylsilylpseudohalide.
Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for preparing the catalyst system of the invention provides for an optionally supported, metallocene catalyst component which when utilized in a polymerization process exhibits improved reactor operability.
Abstract: This invention relates to polypropylene blends, particularly blends of high molecular weight amorphous polypropylene with low molecular weight isotactic polypropylene. These blends exhibit unusual elastomeric properties.
Type:
Grant
Filed:
January 31, 1995
Date of Patent:
July 23, 1996
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Henry W. Yang, Jo Ann M. Canich, Gary F. Licciardi
Abstract: The invention generally relates to a catalyst, particularly a metallocene catalyst and catalyst system useful in the polymerization of olefins into a polymer product. The polymer product has a broad molecular weight distribution, a high molecular weight and a narrow composition distribution and is easily processable.
Abstract: Heat sealed articles and heat sealable films comprising a polymer blend of a first polymer having a narrow molecular weight and composition distribution and a second polymer having a broad molecular weight distribution and composition distribution. The articles and films have significantly improved physical characteristics and remarkably low heat seal initiation temperatures, high seal strength, high hot tack and therefore provide improved processibility and higher line speeds on commercial heat sealing equipment.
Type:
Grant
Filed:
May 25, 1995
Date of Patent:
June 25, 1996
Assignee:
Exxon Chemical Patents Inc.
Inventors:
James M. Farley, Prasadarao Meka, Ferdinand C. Stehling, Barry C. Trudell, Myron B. Kurtzman
Abstract: This invention relates to functionalized polymers and a method to obtain them comprising combing a living polymer or a polymer having a terminal halide group with an silyl enol ether.
Abstract: This invention relates to polypropylene blends, particularly blends of high molecular weight amorphous polypropylene with lower molecular weight isotactic polypropylene. These blends exhibit unusual elastomeric properties.
Type:
Grant
Filed:
January 31, 1995
Date of Patent:
May 14, 1996
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Jo Ann M. Canich, Henry W. Yang, Gary F. Licciardi
Abstract: This invention is generally directed toward a catalyst system useful for polymerizing olefins. The catalyst system of this invention comprises a supported bulky ligand transition metal compound and a separately supported cocatalyst or activator for the compound.
Abstract: This invention is generally directed toward a catalyst system useful for polymerizing olefins. The catalyst system of this invention comprises a supported bulky ligand transition metal compound and a separately supported cocatalyst or activator for the compound.
Abstract: The invention generally relates to a catalyst, particularly a metallocene catalyst and catalyst system useful in the polymerization of olefins into a polymer product. The polymer product has a broad molecular weight distribution, a high molecular weight and a narrow composition distribution and is easily processable.
Abstract: This invention is generally directed toward a catalyst system useful for polymerizing olefins. The method for preparing the catalyst of the invention provides for combining a bulky ligand transition metal catalyst with an activator that has been aged, optionally with a support. The catalyst system is useful in any polymerization process.
Abstract: This invention is generally directed toward a catalyst system useful for polymerizing olefins. The catalyst system of this invention comprises a supported bulky ligand transition metal compound and a separately supported cocatalyst or activator for the compound.
Abstract: The invention is directed toward polymerizing or copolymerizing alpha-olefins either alone or in combination with one or more other alpha-olefins in the presence of a metallocene catalyst in a gas phase reactor having a fluidized bed and a fluidizing medium such that the fluidizing medium entering the reactor comprises a gas and a liquid phase.
Type:
Grant
Filed:
October 3, 1994
Date of Patent:
October 31, 1995
Assignee:
Exxon Chemical Patents Inc.
Inventors:
John R. Griffin, Marc L. DeChellis, Michael E. Muhle