Abstract: Polyisocyanates are stabilized against discoloration by the addition of certain hindered phenols such as o,o-di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyl benzyl phosphonate.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as triethyl phosphate.
Abstract: Menthanediamine, isophorone diamine and the like compounds have been discovered to be an effective substitute for 4,4'-methylenebis(2-chloroaniline) in the preparation of flexible polyurethane foams. This substituted crosslinker is not suspected of being carcinogenic.
Type:
Grant
Filed:
December 27, 1976
Date of Patent:
September 13, 1977
Assignee:
The Dow Chemical Company
Inventors:
Billy Quock, Don Howard Kelley, Sehon Lester Warneke
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a cyclic sulfone.
Abstract: Low density polyurethanes having the ability to reproduce mold detail in excellent quality from rapid-setting polyurethane-forming compositions are obtained by mixing a rapid-setting polyurethane-forming composition with light weight hollow spheres or microballoons and a liquid viscosity reducing agent such as xylene.
Abstract: A process is described for preparing rapid-setting polyurethanes which comprises admixing in the absence of a catalyst a liquid polyol component with a liquid polyisocyanate component wherein the temperature of said components prior to mixing is such that the resultant mixture has a temperature of at least 50.degree. C and will result in a peak exotherm temperature of at least 85.degree. C.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compounds having a boiling point above about 150.degree. C such as a mixture of 1-chloronaphthalene, butyl oleate and 3-methylsulfolane.
Abstract: Oxazolines such as 2-(1,1-bis(hydroxymethyl)ethyl)-2-oxazoline have been found to be an effective crosslinker, curing agent or chain extender for polyurethanes.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as an organic carbonate.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a polyoxyalkylene polyol relatively high in molecular weight or capped derivatives thereof.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a chlorinated aliphatic compound.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a cyclic ether.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a glycerine initiated polyoxyalkyleane compound.
Abstract: Coatings having good weatherability characteristics are obtained by curing an epoxy resin which is an adduct of glycidol and an aliphatic or cycloaliphatic diisocyanate such as hexamethylene diisocyanate with an aliphatic or cycloaliphatic acid or anhydride such as tetrahydrophthalic anhydride.
Abstract: Rapid-setting polyurethanes are prepared from organic aromatic polyisocyanates and polyols having an average functionality of 2-8 and an equivalent weight less than 500 by admixture thereof in the presence of a non-amine nitrogen-containing compound such as urea as a catalyst therefor.
Abstract: Synergistic antioxidant compositions consisting of certain hindered phenols such as 2,4-dimethyl-6-octyl phenol and 4,4'-bis (.alpha.,.alpha.-dimethylbenzyl) diphenyl amine are useful to stabilize polyether polyols against oxidative degradation and prevent scorch in polyurethane foams prepared from the polyether polyols.
Abstract: Reaction products of isocyanuric acid and derivatives thereof such as hydroxy-phenyl isocyanuric acid reacted with 1,2-epoxy-containing compounds such as a mixture of propylene oxide and phenyl glycidyl ether have been discovered to be effective substitutes for 4,4'-methylene-bis(2-chloroaniline) as a crosslinker in high resiliency, flexible, polyurethane foams. The crosslinkers of the present invention are not presently suspected of being carcinogenic.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as trichlorobenzene.
Abstract: Mixtures comprising a low molecular weight diol, a liquid modifier compound having a boiling point above about 150.degree. C, such as an aromatic compound or partially hydrogenated aromatic compound, a polyisocyanate having a functionality of at least about 2.5 and an organometallic catalyst instantly set, after a brief induction period, to a solid, dense, rigid polymeric product which can be demolded within a period of from less than 1 minute to about 5 minutes.
Abstract: Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as dioctylphthalate.