Abstract: A process for reducing the total acid number of an acidic crude by treating the crude with hydrogen treat gas in the presence of a hydrotreating catalyst wherein the treat gas also contains hydrogen sulfide.

Abstract: A process for reducing the acidity of acidic crude oils by contacting the crude oil with a hydrotreating catalyst in the absence of hydrogen.

Abstract: A FCC process in which spent catalyst is stripped of hydrocarbon in a stripping zone prior to entering the regenerator. In order to maximize the amount of strippable hydrocarbon removed in the stripping zone with minimal use of stripping gas, a sample of spent catalyst is removed prior to entering the regenerator. The spent catalyst is analyzed for strippable hydrocarbon by conducting the sample to a heated catalyst collection vessel, evacuating the catalyst, collecting the gases from the collection vessel and analyzing the gases for amount of strippable hydrocarbon on the spent catalyst.

Abstract: A FCC process in which spent catalyst is stripped of hydrocarbon in a stripping zone prior to entering the regenerator. In order to maximize the amount of strippable hydrocarbon removed in the stripping zone, a sample of spent catalyst is removed prior to entering the regenerator. The spent catalyst is analyzed for strippable hydrocarbon by conducting the sample to a heated catalyst collection vessel, stripping hydrocarbon from the catalyst using an inert stripping gas, oxidizing the gasses from the collection vessel to carbon dioxide and water, and measuring the amount of carbon dioxide and/or water which amount of carbon dioxide and/or water can be correlated to the amount of strippable hydrocarbon on the catalyst sample.

Abstract: A fluid cat cracking process for catalytically cracking a feed containing vanadium into lower boiling products, includes a cat cracker and a regenerator, with the feed entering the catalytic cracking zone preheated by indirect heat exchange with spent, stripped catalyst particles being recycled from the cracking reactor to the regenerator. Operating the regenerator at a temperature no higher than about 1150.degree. F. permits the amount of vanadium in the feed to be substantially increased with no loss of catalytic activity due to vanadium poisoning of the catalyst, when compared to a higher regenerator temperature of 1365.degree. F. Using the stripped, spent catalyst for heating the feed reduces feed coking and heat exchanger fouling, compared to using the hotter regenerated catalyst for feed preheat.

Abstract: A process for increasing the yield of C.sub.3 and C.sub.4 olefins by injecting light cat naphtha together with steam into an upstream reaction zone of a FCC riser reactor. The products of the upstream reaction zone are conducted to a downstream reaction zone and combined with fresh feed in the downstream reaction zone.

Abstract: A method for producing a process oil is provided in which an aromatic extract oil is added to a naphthenic rich feed to provide a blended feed. The blended feed is then extracted with an aromatic extract solvent to yield a raffinate which subsequently is hydrotreated to provide a process oil.

Abstract: A heavy feed, such as a resid which contains coke precursors and metals, is upgraded by dissolving a feed soluble metal alkoxide in the feed which is heated to a temperature sufficient to decompose the alkoxide, but below 450.degree. F. The alkoxide decomposition precipitates at least a portion of the coke precursors and metals out of the feed as a separate phase, thereby effectively removing them to form an upgraded feed. The upgraded feed, with or without the precipitate present, is then sent to a cat cracker or to other upgrading. When fed into a cat cracker, such as a FCC, the upgraded feed is converted to lower boiling liquids with less deactivation of the cracking catalyst than would occur if the metals and coke precursors remained in the feed, even with the precipitate present in the feed. In the cat cracker, the precipate which contains the alkoxide metal and coke precursors and metals from the feed, is converted into coke particles having a particle size smaller than the catalyst particles.

Abstract: Spent FCC catalyst is regenerated under net reducing conditions in a regenerator to minimize the migration of vanadium on the spent FCC catalyst particles. Reducing conditions in at least the bottom 50% of the catalyst bed are maintained by using at least two air distribution grids located in the lower 50% of the catalyst bed.

Abstract: This invention relates to a method for rapidly determining weight and volume percent true boiling point curves for crude oils and fractions thereof. The method involves at least a partial separation of the crude oil or fraction into constituent chemical components, obtaining mass spectra of the chemical components, correlating retention time windows with boiling points for standard hydrocarbon mixtures, and converting the total ion current obtained from the mass spectra for selected components to weight and volume percent true boiling points by comparison with data obtained from a standard crude oil or fraction thereof.

Abstract: A catalytic cracking catalyst and catalytic cracking process for cracking the 650.degree. F.+ portion in a heavy feed to lighter products. The catalytic cracking catalyst contains a Y zeolite in a silica binder that is substantially free of catalytically active alumina. The silica binder contains silica gel as a component.

Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalysts being formed into a discrete particle.

Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing step between the catalytic cracking reaction steps in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, the hydroprocessing step is included between the reaction stages, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.

Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing process step between the catalytic cracking reaction steps in order to maximize olefins production, mid-distillate quality and naphtha octane level in the cracked products. Preferably, a first cracked hydrocarbon product is obtained from a first cracking stage and separated into a mid-distillate and gas oil containing fraction having an initial boiling point of at least 300.degree. F., the distillate and gas oil containing fraction is hydroprocessed, and a naphtha fraction and a gas oil containing bottoms fraction of the hydroprocessed material are cracked in a second cracking stage.

Abstract: The invention relates to a method for determining total reactive sulfur in a crude oil or fraction thereof using a mass spectrometer or gas chromatograph and mass spectrometer. Selecting fragment ions characteristic of reactive sulfur species enables the quantitative determination of total reactive sulfur species. The use of a low resolution mass spectrometer allows the rapid determination of total reactive sulfur in field or remote locations where more sophisticated instruments are not available.

Abstract: An improved dispersant formulation for dispersing oil which contains a mixture of a sorbitan monoester of an aliphatic monocarboxylic acid, a polyoxyethylene adduct of a sorbitan monoester of an aliphatic monocarboxylic acid, an alkali metal salt of a dialkyl sulfosuccinate, a polyoxyethylene adduct of a sorbitan triester or a sorbitol hexaester of an aliphatic monocarboxylic acid and a solvent comprising at least one of a propylene glycol ether, ethylene glycol ether, water, alcohol, glycol, and a paraffinic hydrocarbon.

Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalysts being formed into a discrete particle.

Abstract: A method for controlling the manufacture of lubricating oils involving the steps of distillation, extracting, dewaxing and optionally hydrofining; or for controlling operating units associated with refinery or chemical processes with feed stocks and products boiling above 350.degree. C. The method comprises selecting one or more chemical or perceptual or physical or performance properties of the lubricating oil or the feedstock, distillate or raffinate used in the manufacturing process; or of the refinery or chemical process feed stocks or products; creating a training set from reference samples which contain characteristic molecular species present in the lubricating oil, feedstock, distillate or raffinate used in the manufacturing process or from the refining or chemical operations. The reference samples are subjected to GC/MS analysis wherein the often collinear data generated is treated by multivariate correlation methods.

Abstract: A method for predicting the properties of crude oils or their boiling fractions which comprises selecting a chemical or perceptual or physical or performance property or groups of properties of the crude oil or its boiling fractions and creating a training set from reference samples which contain characteristic molecular species present in the crude oil or its boiling fractions. The reference samples are subjected to GC/MS analysis wherein the often collinear data generated is treated by multivariate correlation methods. The training set produces coefficients which are multiplied by the matrix generated from a GC/MS analysis of an unknown sample to produce a predicted value of the chemical, performance, perceptual or physical property or groups of properties selected.

Abstract: Disclosed is a system for fluidizing a dense phase bed of solid particles, preferably a dense bed of solid catalyst particles. The system includes a dense bed solids housing, a dense bed solids support within the housing, a fluid injection component which sends fluids toward the solids supported within the housing, and a stuctural component which is capable of decreasing the distance between the dense bed solids support and the fluid injection component as the fluid is sent toward the solids that are supported within the housing.