Patents Represented by Attorney Janice L. Umbel
  • Patent number: 4952650
    Abstract: The present invention relates to a method for suspension polymerization of a pressure-sensitive acrylatre copolymer bead having a glass transition temperature of 0.degree. C. or less. The method comprises making a monomer premix comprising an acrylic acid ester of non-tertiary alcohol, the alcohol having from 1 to 14 carbon atoms, with the average number of carbon atoms being about 4 to about 12, a polar monomer copolymerizable with the acrylic acid ester, a chain transfer agent, a free-radical initiator, and a modifier moiety selected from the group consisting of 2-polystyrylethyl methacrylate macromolecular monomers, reactive zinc salts and hydrophobic silicas. The premix is then combined with a water phase containing a sufficient amount of suspending agent to form a suspension. The suspension is concurrently agitated and polymerization of the polymer premix is permitted until polymer beads are formed. The polymer beads are then collected.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: August 28, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Chung I. Young, Rudyard M. Enanoza