Patents Represented by Attorney, Agent or Law Firm Joel J. Hayashida
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Patent number: 6361787Abstract: The present invention provides an improved antimicrobial composition which includes at least one quaternary ammonium compound and nerolidol. The nerolidol component of the composition provides enhanced antimicrobial efficacy, even when used in small amounts. Further, the nerolidol component provides such enhanced antimicrobial efficacy that the quaternary ammonium compound may be used in reduced amounts as compared to the amounts used for antimicrobial effect in prior formulations. The enhanced antimicrobial composition of the present invention is especially useful in cleaning or disinfecting applications, such as the cleaning of hard surfaces.Type: GrantFiled: May 27, 1998Date of Patent: March 26, 2002Assignee: The Clorox CompanyInventors: Elias A. Shaheen, Judy Y. Ikawa, Robert L. Blum
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Patent number: 6358909Abstract: An oil-in-water suspoemulsion system is provided for the delivery of actives for laundering, cleaning or surface treatment, in which the suspoemulsion includes a major portion of water as a continuous phase, at least one Active, and an encapsulate including an oil, and at least first and second nonionic surfactants, the first and second nonionic surfactants having a HLB of at least about 3, the encapsulate substantially completely coating the active and suspending it within the aqueous phase.Type: GrantFiled: June 15, 2000Date of Patent: March 19, 2002Assignee: The Clorox CompanyInventors: Maria G. Ochomogo, Malcolm A. Deleo, Hanneliese S. Selbach
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Patent number: 6340663Abstract: The invention provides an improved cleaning wipe which requires no scrubbing, buffing, polishing or rinsing, with the following components: (a) a wipe which comprises at least one layer of absorbent/adsorbent material; (b) a liquid cleaner which comprises (i) a low residue surfactant; (ii) a hydrophilic polymer; and (iii) the remainder, water.Type: GrantFiled: November 24, 1999Date of Patent: January 22, 2002Assignee: The Clorox CompanyInventors: Malcolm A. Deleo, Robert L. Blum, Maria G. Ochomogo, Paul A. Pappalardo, Elizabeth N. Swayne
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Patent number: 6297400Abstract: A new composition of matter for a diamidodiol and a method for preparing the diamidodiol. The exemplary diamidodiol has the formula C15H30N2O4 and is prepared by reacting a first quantity of 2-amino-2-methyl-1-propanol with a second quantity of a di-substituted malonyl dichloride (i.e., diethylmalonyl dichloride), preferably in ethyl acetate as solvent. A tetraamido macrocycle is prepared from the diamidodiol in two steps by oxidizing the diamidodiol to form a diacid followed by coupling using a known procedure of the diacid with an aryl diamine (e.g., 1,2-diaminobenzene)to yield the tetraamido macrocycle.Type: GrantFiled: July 2, 1999Date of Patent: October 2, 2001Assignee: The Clorox CompanyInventors: James E. Deline, Michael M. Ott
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Patent number: 6284723Abstract: The invention provides an aqueous, antimicrobial, no-rinse hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising: (a) an effective amount of a solvent selected from C1-6 alkanol, C3-24 alkylene glycol ether, and mixtures thereof; (b) an effective amount of a surfactant selected from amphoteric, nonionic surfactants, and mixtures thereof, (c) an effective amount of a quaternary ammonium surfactant; (d) an effective amount of a builder; and (e) the remainder as substantially all water.Type: GrantFiled: January 10, 2000Date of Patent: September 4, 2001Inventors: Boli Zhou, Anna G. Stanislowski, Wayne B. Scott
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Patent number: 6245728Abstract: An aqueous hard surface cleaner with improved soil removal is provided and has, as components, the following: (a) either an anionic, nonionic, amphoteric surfactant, and mixtures thereof with, optionally, a quaternary ammonium surfactant, the total amount of the surfactants being; present in a cleaning effective amount; (b) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., present in a solubilizing—or dispersion—effective airmount; (c) a combination of (i) an incompletely neutralized potassium ethylenediamine—tetraacetate (EDTA) and (ii) a precipitating co-builder as chelating agents present in an amount effective to enhance soil removal in said cleaner; and (d) the remainder, water.Type: GrantFiled: October 25, 1999Date of Patent: June 12, 2001Assignee: The Clorox CompanyInventors: Michael H. Robbins, Jennifer C. Julian, Suzanne M. Thompson, Gary L. Robinson, Clement K. Choy, Elizabeth A. Gossett
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Patent number: 6242402Abstract: An improved cleaning composition is provided for shower and tub surfaces which is of the “shower rinsing” type, requiring no scrubbing, wiping, or immediate rinsing. The composition comprises: (a) a glycoside surfactant, the total amount of said surfactant being present in a cleaning effective amount; (b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water. A solvent such as isopropyl alcohol may also be added. The employment of a glycoside surfactant, especially one having an HLB value of greater than 13, remarkably improves the performance of such a shower rinsing composition both with respect to surface appearance streaking and filming and also bathroom soil and soap scum removing ability.Type: GrantFiled: October 11, 2000Date of Patent: June 5, 2001Assignee: The Clorox CompanyInventors: Michael H. Robbins, David Peterson, Clement K. Choy, Jana W. Chu, James R. Latham
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Patent number: 6235218Abstract: A process is provided for the preparation of a compound having the structure of Formula I The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of pH control substantially prevents formation of an undesirable protonated reaction intermediate.Type: GrantFiled: November 19, 1999Date of Patent: May 22, 2001Assignee: The Clorox CompanyInventors: Ulrich Annen, James E. Deline, Lafayette D. Foland, Kevin A. Klotter, Josef Müller, Michael Müller, Klaus Mundinger, Martin A. Phillippi, Alfred Ruland, Wolfgang Schäfer, Gregor Schürmann, Rudi Widder, Alfred G. Zielske
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Patent number: 6214784Abstract: An aqueous hard surface cleaner with improved soil removal is provided and has, as components, the following: (a) either an anionic, nonionic, amphoteric surfactant, and mixtures thereof with optionally, a quaternary ammonium surfactant, the total amount of the surfactants being present in a cleaning effective amount; (b) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., present in a solubilizing—or dispersion—effective amount; (c) Tetrapotassium ethylenediamine—tetraacetate (potassium EDTA) as a chelating agent, present in an amount effective to enhance soil removal in said cleaner; and (d) the remainder, water.Type: GrantFiled: October 25, 1999Date of Patent: April 10, 2001Assignee: The Clorox CompanyInventors: Michael H. Robbins, Jennifer C. Julian
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Patent number: 6183665Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source.Type: GrantFiled: March 29, 1999Date of Patent: February 6, 2001Assignee: The Clorox CompanyInventors: Sarah P. Blondeau, Susan P. Huestis, Agnes Jaszenovics, Gregory M. Piche, David C. Sandoval, William P. Sibert
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Patent number: 6159916Abstract: An improved cleaning composition is provided for shower and tub surfaces which is of the "shower rinsing" type, requiring no scrubbing, wiping, or immediate rinsing. The composition comprises:(a) a glycoside surfactant, the total amount of said surfactant being present in a cleaning effective amount;(b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and(c) the remainder, water. A solvent such as isopropyl alcohol may also be added. The employment of a glycoside surfactant, especially one having an HLB value of greater than 13, remarkably improves the performance of such a shower rinsing composition both with respect to surface appearance streaking and filming and also bathroom soil and soap scum removing ability.Type: GrantFiled: June 12, 1998Date of Patent: December 12, 2000Assignee: The Clorox CompanyInventors: Michael H. Robbins, David Peterson, Clement K. Choy, Jana W. Chu, James R. Latham
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Patent number: 6156363Abstract: A closure bag having a bag body with internal tack surfaces.Type: GrantFiled: June 11, 1999Date of Patent: December 5, 2000Assignee: First Brands CorporationInventors: Chih-Hung Chen, Andrius Dapkus, Jack A. Mac Pherson
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Patent number: 6127536Abstract: An improved synthesis for preparing a tetraamido-macrocyclic ligand, such as 5,6-Benzo-3,8,11,13-tetraoxo-2,2,9,9-tetramethyl-12,12-diethyl-1,4,7,10 -tetraazacyclotridecane, H.sub.4, in greatly improved yield and in a commercially viable manner, comprising the steps of dissolving a quantity of a 1,2-bis(2-aminoalkanamido)benzene in a solution comprised of ethyl acetate and methylene chloride to yield a first reaction solution; dissolving a quantity of a malonyl dihalide in an ethyl acetate solution to yield a second reaction solution; adding the first reaction solution and the second reaction solution to a reaction vessel containing a third reaction solution comprised of refluxing ethyl acetate solution and an acid scavenger to form a reaction mixture; and isolating a solid product comprised of the tetraamido-macrocycle directly from the reaction mixture by filtration.Type: GrantFiled: May 25, 1999Date of Patent: October 3, 2000Assignee: The Clorox CompanyInventors: James E. Deline, Michael M. Ott, Kevin A. Klotter
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Patent number: 6100228Abstract: The invention provides a bleaching gel cleaner and a method for preparing it, said cleaner comprising:a) an effective amount of a hypochlorite-generating compound;b) a ternary thickening system which comprises: (i) alkali metal soap; (ii) a hydrotrope selected from the group consisting of trialkylamine oxides, betaines and mixtures thereof; and (iii) a bleach stable solvent, each in amounts appropriate to create a gelled composition;c) a buffer/electrolyte in an amount effective to stabilize the hypochlorite; andd) the remainder as water.Type: GrantFiled: June 7, 1995Date of Patent: August 8, 2000Assignee: The Clorox CompanyInventors: Brian P. Argo, Clement K. Choy, Aram Garabedian, Jr.
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Patent number: 6080387Abstract: An aerosol antimicrobial composition is provided with the following ingredients: a) an anionic polymer or prepolymer; (b) a quaternary ammonium compound, the components (a) and (b) combining to form an antimicrobially effective complex; (c) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25.degree. C., said at least one organic solvent present in a solubilizing--or dispersion--effective amount; (d) an effective amount of a propellant; and (e) the remainder, water. Further is provided a novel method of decontaminating a surface fouled with microorganisms and a dispenser for said aerosol composition. The novel composition advantageously has both disinfectancy (contact efficacy) and residual antimicrobial efficacy.Type: GrantFiled: July 15, 1998Date of Patent: June 27, 2000Assignee: The Clorox CompanyInventors: Boli Zhou, Maria G. Ochomogo, Elias A. Shaheen
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Patent number: 6046150Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I ##STR1## wherein A is a saturated ring formed by five atoms in addition to the N.sub.1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 CN where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.Type: GrantFiled: April 30, 1999Date of Patent: April 4, 2000Assignee: The Clorox CompanyInventors: Clement K. Choy, James E. Deline, Lafayette D. Foland, Aram Garabedian, Jr., Kevin A. Klotter, Michael J. Petrin, Martin J. Phillippi, William L. Smith
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Patent number: 6037316Abstract: The invention provides an improved surface safe, aqueous, liquid hard surface cleaner which contains a nonionic surfactant, or combination of nonionic and anionic surfactants, a water soluble abrasive, namely, borax pentahydrate, in an amount which takes at least a portion of the abrasive out of solution, and water.Type: GrantFiled: September 17, 1996Date of Patent: March 14, 2000Assignee: The Clorox CompanyInventors: Denise A. Garner, James R. Latham, Donald K. Swatling, Kelley A. Henderson, David G. Cohen
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Patent number: 6022843Abstract: The invention is an improved, non-phosphate, non-bleach, agglomerated laundry booster which has a) a solids portion with i) at least 5% by weight of a first builder selected from the group consisting of alkali metal carbonate, alkali metal bicarbonate, alkali metal sesquicarbonate, and mixtures thereof; and ii) a second builder of at least 25% by weight alkali metal tetraborate pentahydrate; and b) i) a first liquid which comprises an anionic, acidic surfactant, in an amount no greater than about 10% by weight; and ii) a second liquid which comprises an agglomerating agent. The first liquid is neutralized by the first builder of a)i) to form a first set of particles, the second builder forms a second set of particles, and the second liquid co-agglomerates both the first and second sets of particles. The invention also provides a method for preparing this laundry booster.Type: GrantFiled: September 9, 1998Date of Patent: February 8, 2000Assignee: The Clorox CompanyInventors: Philip C. Shanks, Arnold J. Lim, William P. Sibert
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Patent number: D439156Type: GrantFiled: November 24, 1999Date of Patent: March 20, 2001Inventors: Jack P. Hall, David Merrill, Brian J. Olson, James M. Rubenstein, James D. Mitchell, Katie K. Chow
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Patent number: D446726Type: GrantFiled: May 19, 2000Date of Patent: August 21, 2001Assignee: The Clorox CompanyInventors: Jack P. Hall, David Merrill, Brian J. Olson, James M. Rubenstein, James D. Mitchell, Katie K. Chow