Patents Represented by Attorney Joseph C. Whalen, Lyndanne M. Gil
  • Patent number: 4578500
    Abstract: Compounds containing from 0.15 to 20.3 wt. % aromatic amino groups are produced by hydrolyzing an isocyanate compound mixed with water and a solvent or solvent mixture at -20.degree. to 185.degree. C. The isocyanate starting material must contain at least two aromatically bound isocyanate groups and an isocyanate content of from 0.5 to 40 wt. %. The water must be used in at least a stoichiometric amount but is preferably used in excess. The solvent or solvent mixture must contain 50-100 wt. % solvent containing ether and/or thioether bonds. A partly water-soluble solvent may be used in an amount no greater than 50 wt. % total solvent. No acidic or basic catalysts are present during the hydrolysis. The product amine may be isolated by phase separation, filtration or extraction. The amines thus-produced are particularly useful in the production of polyurethane(urea)s.
    Type: Grant
    Filed: November 21, 1983
    Date of Patent: March 25, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Rasshofer, Gerhard Balle
  • Patent number: 4575518
    Abstract: Homogeneous storable mixtures containing small quantities of salts and having a high mixed hydroxyl number of mixed hydroxyl/amine number are made by mixing (a) a polyoxyalkylene polyol and/or polyolamine and/or polyamine based on an alkyloxirane having a molecular weight of from 400 to 12,000, (b) a low molecular weight polyol which is not completely miscible with (a) and a solution-promoting additive in quantities such that for every 100 parts of (a), from 1 to 200 parts of (b) and from 0.01 to 10 parts of (c) are present. The solution-promoting additives are salts of cations of Groups IA, IIA and IIIA of the Periodic System of Elements or ammonium or mono- to tetra-alkylammonium ions and anions formed by removing at least one proton from an acid having a K.sub.s -value of at least 10.sup.-7. These mixtures are particularly useful in the production of polyurethanes.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: March 11, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Rasshofer, Reiner Paul
  • Patent number: 4404294
    Abstract: Light foams containing urea and urethane groups and having a density of at most 0.025 g/cc are produced by reacting a polyisocyanate with at least one equivalent of water in which mono- and/or oligo-saccharides have been dissolved (as blowing agent) in the presence of organic compounds containing at least two hydroxyl groups and having an OH number of from 30 to 250, a catalyst and a flameproofing agent. Chain extending agents having a molecular weight of from 32 to 62 and other known auxiliaries and additives may also be used. The foams thus produced are nonflammable and are particularly useful in insulation applications.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: September 13, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventor: Rolf Wiedermann