Patents Represented by Attorney Joseph J. Dvorak
-
Patent number: 5403561Abstract: The uniform distribution of mixed phase fluid stream on to the top of a contact bed in a reactor chamber is provided by a horizontal tray with a plurality of spaced-apart, vertically disposed chimneys extending through the tray. These chimneys have a first end to receive liquid and gas above the tray and a second end for distributing the liquid and gas downwardly below the tray. Importantly, the second end is provided with a spray generating device located below the tray for producing a conical downward spray of the mixed fluid phase onto the top surface of a bed of contact material positioned below the tray. The spray generating devices for producing the conical spray are located at positions so that the spray of the mixed fluid stream from one spray generating device as it impinges on the top surface of the fixed bed, will overlap the spray from an adjacent spray generating device.Type: GrantFiled: August 27, 1993Date of Patent: April 4, 1995Assignee: Exxon Research & Engineering Co.Inventors: Robert M. Koros, Yiu W. Wong, John T. Wyatt, David C. Dankworth
-
Patent number: 5399632Abstract: It has now been discovered that the hydrogenation of unsaturated homo and copolymers can be effectively carried out in the absence of added gaseous hydrogen by contacting the unsaturated polymer with a hydrogen donor compound in the presence of a Group VIII metal catalyst, especially a supported palladium catalyst, for a time and at a temperature sufficient to bring about the hydrogenation of the unsaturated polymer.Type: GrantFiled: September 30, 1992Date of Patent: March 21, 1995Assignee: Exxon Research & Engineering Co.Inventors: Christine A. Costello, Pamela J. Wright, Donald N. Schulz, Joseph A. Sissano
-
Patent number: 5393441Abstract: Briefly stated, the present invention comprises novel compounds useful as two-cycle oil additives obtained by reacting an alkyl acrylamide with a compound selected from the group consisting of polyalkylenepolyamines, polyalkylenepolyamines functionalized with polyalkyl acid anhydrides and polyalkylenepolyamines and a polyalkyl acid anhydride.Type: GrantFiled: November 23, 1993Date of Patent: February 28, 1995Assignee: Exxon Research and Engineering CompanyInventors: Warren A. Thaler, Stephen Zushma, Richard H. Schlosberg
-
Patent number: 5389271Abstract: The present invention provides novel sulfonated ethylene/alpha olefin copolymer compositions obtained by sulfonating ethylene/alpha olefin copolymer having number average molecular weights in the range of about 800 to about 50,000, and which have a high degree of terminal unsaturation. Preferably, at least 30% of the terminal unsaturation is vinylidene terminal unsaturation. Also, the alpha olefin preferably has 3 to about 12 carbon atoms.Type: GrantFiled: June 15, 1993Date of Patent: February 14, 1995Assignee: Exxon Research & Engineering Co.Inventors: Robert D. Lundberg, Robert R. Phillips
-
Patent number: 5372792Abstract: The present invention provides a cylindrical reactor vessel having a top end with an inlet and a bottom end with an outlet end. A refractory insulating lining is applied on the interior of the wall of the vessel. A cylindrical vertically disposed first inner basket having a generally closed top first end and an open second end in communication with the outlet conduit and having fluid pervious sidewalls surrounded by a vertically disposed outer cylindrical second basket defining a space therebetween for containment of subdivided contact material. The cylindrical second basket also has a top end, which is closed, and fluid pervious sidewalls. The cylindrical second basket is spaced away from the refractory lining of the vessel at a sufficient distance, to provide an annular space for fluid, admitted through the inlet, to progress downwardly through the annular space and then radially inwardly through the contact material contained in the space between the first and second basket.Type: GrantFiled: February 3, 1992Date of Patent: December 13, 1994Assignee: Exxon Research & Engineering Co.Inventors: Rodney T. Mueller, Catherine M. Murray, Donald F. Shaw, Robert F. Tammera
-
Patent number: 5362827Abstract: This invention provides a process for preparing novel hydrophobically associating polymers containing cationic functionality which are useful for clean-up of waste waters containing organic contaminants. These water soluble polymers contain both water soluble and water insoluble monomers. The water soluble monomers are acrylamide (AM) and a salt of an unsaturated amine base (C), and the water insoluble monomer is a higher alkyl(meth)acrylamide or alkyl(meth)acrylate (R). These polymers are referred to as CRAM. The process relies on the dissolution of the water insoluble monomer(s) into an aqueous solution of water soluble monomers by means of a water miscible mutual cosolvent.Type: GrantFiled: July 27, 1992Date of Patent: November 8, 1994Assignee: Exxon Research & Engineering Co.Inventors: Jan Bock, Paul L. Valint, Thomas J. Pacansky, Henry W. H. Yang
-
Patent number: 5356219Abstract: The instrumentation probe of the present invention comprises a tubular housing for enclosing a sensing element, the tubular housing being adapted to project into a process stream. The tubular housing is surrounded by an outer casing that has its longitudinal axis transverse to the longitudinal axis of the tubular housing and which outer casing is aerodynamically shaped to be substantially non-disruptive of the flow of the process stream while protecting the tubular housing from erosion.Type: GrantFiled: September 30, 1993Date of Patent: October 18, 1994Assignee: Exxon Research and Engineering CompanyInventors: Robert F. Tammera, Donald F. Shaw
-
Patent number: 5354990Abstract: The distribution of fluid flowing through a packed bed reactor is determined by placing a plurality of fiber optic sensors at desired locations within the packed bed reactor. A light analyzable tracer component is injected into the fluid flowing through the reactor. Light is supplied to each of the sensors causing any tracer component in the vicinity of the sensor to emit electromagnetic radiation. The emitted electromagnetic radiation is detected at each fiber optic sensor, thereby permitting the amount of tracer in the vicinity of each sensor to be determined, and consequently providing a measure of the distribution of fluid flowing through the reactor.Type: GrantFiled: May 18, 1993Date of Patent: October 11, 1994Assignee: Exxon Research and Engineering Co.Inventors: David C. Dankworth, Robert M. Koros
-
Patent number: 5346631Abstract: The present invention provides an improvement in separating a mixture of two distinct fluid phases of the same or different materials, one dispersed in the other, by ejecting a flowing stream of the mixed fluid phases from a conduit and then deflecting the ejected stream radially outwardly whereby centrifugal and gravitational forces cause the flowing stream to separate with the less dense phase of the two phases forming a top layer and the more dense phase forming a bottom layer and thereafter directing the more dense phase to flow into a conduit leading to a separate chamber.Type: GrantFiled: December 7, 1992Date of Patent: September 13, 1994Assignee: Exxon Research & Engineering Co.Inventor: Patrick H. Terry
-
Patent number: 5340549Abstract: In its simplest sense, the present invention provides a method for improving the contacting of plural, distinct phases in a vertically disposed vessel containing distinct fluid phases by injecting a stream of dispersed distinct phases together into the phases contained in the vessel at a sufficient velocity to force the fluid in the vessel to circulate downwardly through a central region in the vessel and upwardly in the annular region surrounding the central region.Type: GrantFiled: October 26, 1992Date of Patent: August 23, 1994Assignee: Exxon Research and Engineering CompanyInventors: Milind B. Ajinkya, Robert M. Koros, Barry L. Tarmy
-
Patent number: 5338330Abstract: A compacted, single phase or multiphase composite article. Particles for use in the compacted article are produced by providing a precursor compound containing at least one or at least two metals and a coordinating ligand. The compound is heated to remove the coordinating ligand therefrom and increase the surface area thereof. It may then be reacted so that at least one metal forms a metal-containing compound. The particles may be consolidated to form a compacted article, and for this purpose may be used in combination with graphite or diamonds. The metal-containing compound may be a nonmetallic compound including carbides, nitrides and carbonitrides of a refractory metal, such as tungsten. The metal-containing compound may be dispersed in a metal matrix, such as iron, nickel or cobalt. The dispersed nonmetallic compound particles are no larger than about 0.1 micron in particle size and have a volume fraction greater than about 0.15 within the metal matrix.Type: GrantFiled: July 24, 1991Date of Patent: August 16, 1994Assignee: Exxon Research & Engineering CompanyInventors: Richard S. Polizzotti, Larry E. McCandlish, Edwin L. Kugler
-
Patent number: 5320744Abstract: In its simplest sense, the present invention provides a uniquely shaped conduit between the primary and secondary cyclones or, in the alternative, between the riser and the primary cyclone, which creates an increase in the suction of the dilute phase vapor beyond that normally available in the reactor vessel, thereby reducing the dilute phase residence time in the vessel, reducing post-riser thermal cracking, hydrogen transfer reactions, and coking tendency of mixture in dilute phase.Type: GrantFiled: December 14, 1992Date of Patent: June 14, 1994Assignee: Exxon Research & Engineering Co.Inventor: Todd R. Steffens
-
Patent number: 5300227Abstract: Simply stated, the present invention employs a surfactant system for treatment of hydrocarbon contaminated soils and water that increases the interface between the hydrocarbon contaminant, microbial nutrients and microflora, and also stimulates the propagation of the microflora, thereby enhancing microbial degradation of the hydrocarbon contaminant.Type: GrantFiled: April 28, 1993Date of Patent: April 5, 1994Assignee: Exxon Research and Engineering CompanyInventors: Ramesh Varadaraj, Cornelius H. Brons
-
Patent number: 5300274Abstract: A method for preparing molybdenum and sulfur containing compounds of the general formula X.sub.2 Mo.sub.2 S.sub.12.yH.sub.2 O, where X is a cation selected from the group consisting of Na.sup.+, K.sup.+, R.sub.4 N.sup.+, R.sub.3 NH.sup.+, R.sub.2 NH.sub.2.sup.+, RNH.sub.3.sup.+, NH.sub.4.sup.+, R.sub.4 P.sup.+, R.sub.4 As.sup.+,(R.sub.3 P).sub.2 N.sup.+, R is a C.sub.1 -C.sub.30 alkyl, C.sub.6 -C.sub.30 aryl, C.sub.7 -C.sub.30 aralkyl or C.sub.2 -C.sub.30 alkoxyalkyl group and mixtures thereof, and y is from 0 to 2. The method comprises preparing a sulfide solution that contains from about 9 wt. % to about 13 wt. % sulfide sulfur; contacting the solution with elemental sulfur and a hydroxide; adding a molybdenum compound for a time and at a temperature sufficient to form a reaction mixture and a precipitate; separating the precipitate; and contacting the remaining reaction mixture with additional sulfide solution to form (NH.sub.4 ).sub.2 Mo.sub.2 S.sub.12.yH.sub.2 O.Type: GrantFiled: October 25, 1990Date of Patent: April 5, 1994Assignee: Exxon Research and Engineering CompanyInventors: Liwen Wei, Catherine L. Coyle, Thomas R. Halbert, Edward I. Stiefel
-
Patent number: 5294672Abstract: The present invention relates to thermoplastic reinforced elastomeric blend compositions which exhibit improved tensile strengths, wherein the elastomeric blend compositions comprises a blend of a metal neutralized sulfonated polymer with about 1 to about 40 weight percent of a metal neutralized copolymer of ethylene and methacrylate.Type: GrantFiled: August 8, 1990Date of Patent: March 15, 1994Assignee: Exxon Research & Engineering Co.Inventor: Dennis G. Peiffer
-
Patent number: 5292990Abstract: Basically, the present invention is predicated on the discovery that zeolites that have a high silica to alumina ratio, e.g., a ratio of 20 and above, pore diameters of greater than about 5.0.ANG., and which have substantially no active acid sites, i.e., zeolites which are non-reactive toward olefin isomerization and oligomerization, are especially useful in substantially separating linear olefins and paraffins from hydrocarbon mixtures containing at least linear and branched aliphatic hydrocarbons and optionally containing aromatic and other hydrocarbons.Type: GrantFiled: December 10, 1990Date of Patent: March 8, 1994Assignee: Exxon Research & Engineering Co.Inventors: Edward Kantner, David W. Savage, Richard J. Bellows
-
Patent number: 5288811Abstract: Accordingly, novel carbonyl containing compositions are prepared by contacting, in the presence of a free radical initiator, a compound selected from the group consisting of saturated hydrocarbons, substituted saturated hydrocarbons, polymers and mixtures thereof with a carbonyl containing compound or mixtures thereof having the structures: ##STR1## wherein Q.dbd.HOH, MeOH, EtOH, or n-BuOH; n.dbd.0,1,>; and X and Y are independently selected from the group consisting of CH.sub.2, C.dbd.O; W is independently selected from the group consisting of CH.sub.2, C.dbd.O, O, NH, CMe.sub.2, C.dbd.N-alkyl and N-alkyl, wherein alkyl is 1 to 18 carbons; U and V are independently selected from the same groups as W and dependently selected so that U and V taken together are one of 1,2-phenylene, 1,8-naphthalene-diyl, and 1,2-naphthalene-diyl.Type: GrantFiled: November 5, 1992Date of Patent: February 22, 1994Assignee: Exxon Research and Engineering CompanyInventor: Stanley J. Brois
-
Patent number: 5275641Abstract: Accordingly, the present invention, in one embodiment, encompasses an apparatus for the fluidized catalytic cracking of a hydrocarbon feed comprising: a riser which is generally vertically positioned within a catalyst disengaging zone and which has a plurality of openings around the circumference of the riser at its discharge end. The openings in the riser have a vertical stub portion that extends tangentially outwardly from the riser and communicates with a first end of an upwardly sloping curvilinear tunnel that terminates at a second end. The second end of the tunnel opens into a tangential opening in the primary cyclone. The area of the opening of the first end of the tunnel is larger than the area of the opening of the second end of the tunnel.Type: GrantFiled: August 26, 1992Date of Patent: January 4, 1994Assignee: Exxon Research & Engineering Co.Inventors: Robert F. Tammera, Donald F. Shaw, Kenneth J. Reinman, George Melfi
-
Patent number: 5274051Abstract: Novel carbonyl containing compositions are prepared by contacting, in the presence of a free radical initiator, a first compound selected from the group consisting of saturated hydrocarbons, substituted saturated hydrocarbons, polymers and mixtures thereof with a carbonyl containing compound or mixtures thereof having the structure: ##STR1## where X and Y are independently selected from OH, OR.sub.1, NR.sub.1 R.sub.2 and R.sub.1 wherein R.sub.1 and R.sub.2 are selected independently from the group consisting of aryl radicals or alkyl radicals of from 1 to 18 carbon atoms.Type: GrantFiled: November 5, 1992Date of Patent: December 28, 1993Assignee: Exxon Research & Engineering CompanyInventors: Stanley J. Brois, Jacqueline Ogletree
-
Patent number: 5216048Abstract: This invention relates to emulsion-type adhesive compositions which include a copolymer of a conjugated diene and sulfopropyl-N-methacroyloxyethyl-N,N-dimethyl ammonium betaine, wherein the sulfobetaine copolymer has about 0.15 to about 15 mole % sulfobetaine groups per 100 grams of the neutralized sulfonated copolymer, and less than about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and mono-olefins per 100 parts by weight of the neutralized sulfonated copolymer.Type: GrantFiled: March 7, 1990Date of Patent: June 1, 1993Assignee: Exxon Research & Engineering CompanyInventors: Pawan K. Agarwal, Allen C. Werner, Donald N. Schulz, Jeffrey Kaladas