Abstract: The flame-retardant properties of polymers with an aromatic main chain can be improved by incorporating therein a fluorine compound in combination with a boron compound.
Type:
Grant
Filed:
October 12, 1989
Date of Patent:
January 26, 1993
Assignee:
General Electric Co.
Inventors:
Christianus A. Claesen, Johannus H. G. M. Lohmeijer, Michael P. J. Boogers, Jan Bussink, Hermannus B. Savenije, Theodorus L. Hoeks, Johannes C. Gosens
Abstract: Thermoplastic articles molded from amorphous polyamide and polycarbonate resin blends exhibit improved color when irradiated with ionizing radiation.
Abstract: Acid contaminants leached from acidic ion-exchange resins and carried in process streams with phenol are separated from the phenol by passing the process stream in contact with an anionic exchange resin, whereby the acid contaminants react with and bond to the anionic exchange resin.
Abstract: Polyphenylene ether-polyamide compositions compatibilized with polyfunctional compounds such as aliphatic polycarboxylic acids can achieve improved impact strength and ductility by producing an intermediate polyphenylene ether-polyamide product containing at least some nylon 6,6 and thereafter further compounding the intermediate product with a second polyamide component containing at least some of a polyamide different from nylon 6,6.
Abstract: A bottle feeder comprises a tamper evident overcap, which captures a nipple and hold-down cap and has a pop-up indicator to insure the integrity of the bottle is discribed. Upon removal of the overcap the tamper evident band remains on the bottle and the pop-up indicator indicates the feeder has been opened. The nipple and hold-down cap can be withdrawn from the overcap and placed on the bottle for use.
Abstract: Improved thermoplastic articles are described, which include a substrate molded from a composition of polyphenylene ether resin and polyamide resin, and a coating which is applied directly to the substrate, in the absence of a primer layer. The substrate can be pretreated with an acid processing agent and a surfactant processing agent.
Abstract: Thermoplastic resin compositions which contain specified weight proportions of a polyphenylene ether resin, a polyamide resin and a rubber polymer consisting of a mixture of ABA or ABA' types of block copolymers and an AB block copolymer are improved by the presence of a miscibility enhancer. Representative of the miscibility enhancers are citric acid, malic acid, maleic anhydride, trimellitic chloride anhydride and the like. The compositions of the invention have been found to produce molded articles of improved low-temperature impact properties.
Abstract: Fluoropolymers in the form of solid particles of specified diameter and dispersed in water are added and mixed with polycarbonate resin particles at a rate of 0.1 to 9 liter/hour to obtain a uniform coating of the fluoropolymer on the polycarbonate resin particles. The proportion of fluoropolymer added is from 0.01 to about 70 parts for each 100 parts by weight of polycarbonates and mixing is carried out to continually bring polycarbonate resin particles (non-contacted) into contact with the fluoropolymer dispension as it is added.
Abstract: Silane esters are transesterified with hydroxyl-terminated polyester resins to obtain end-capped, extended or branched polyester molding compositions.
Type:
Grant
Filed:
October 5, 1990
Date of Patent:
February 18, 1992
Assignee:
General Electric Company
Inventors:
Christopher M. Hawkins, Edgar E. Bostick, James L. Derudder
Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether and a polyoctenylene. By using as a polyphenylene ether a mixture of at least two polyphenylene ethers, one having a comparatively low viscosity and one having a comparatively high viscosity, a polymer mixture is obtained having improved properties. The properties are improved in particular with respect to the flow properties, while no reduction of the heat distortion occurs.
Type:
Grant
Filed:
September 13, 1989
Date of Patent:
February 18, 1992
Assignee:
General Electric Co.
Inventors:
Roelof van de Meer, Marinus E. J. Dekkers
Abstract: Thermoplastic molding compositions of blends of polyphenylene ethers and polyesters are improved in respect to impact resistance by the addition of an organophosphorus compound of the formula: ##STR1## wherein R.sub.1 when taken independently is selected from divalent hydrocarbon residues containing 2-12 carbon atoms; each of R.sub.2 -R.sub.5 when taken independently are selected from the group consisting of alkyl groups of 2 to 12 carbon atoms, aryl groups containing 6-14 carbon atoms, alkyl-substituted aryl groups, aralkyl groups, halogen-substituted alkyl groups, halogen-substituted aryl groups of 6-14 carbon atoms, halogen-substituted alkyl-substituted aryl groups, and halogen-substituted aralkyl groups; two groups selected from among R.sub.1 -R.sub.5 may be bonded together and form a ring; provided at least one member selected from among R.sub.1 -R.sub.5 has a carbon-carbon unsaturated double bond or triple bond, and at least one member selected from among R.sub.1 -R.sub.
Abstract: The invention provides a process for producing a polyphenylene ether by subjecting a 2,6-dialkyl-4-halophenol to oxygen in the presence of a water-immiscible solvent, an aqueous alkali, a phase transfer agent, and a molecular-weight-controlling amount of an amine having at least one hydrogen on the amine nitrogen. The polyphenylene ether thus produced has improved flow properties, color and odor, and is suitable for polymer blending with styrenic resins.
Type:
Grant
Filed:
December 12, 1990
Date of Patent:
January 28, 1992
Assignee:
General Electric Co.
Inventors:
Timothy D. Shaffer, James G. Bennett, Jr., Mark R. Denniston
Abstract: A polycarbonate resin, containing in the polymer chain at least one divalent moiety of the formula: ##STR1## wherein E is selected from the group consisting of alkylene containing from 1 to 15 carbon atoms, inclusive, and halogen-substituted alkylene containing from 1 to 15 carbon atoms, inclusive, a is an integer of 0 or 1 and R' is hydrogen or hydrocarbyl or halogen substituted hydrocarbyl amenable to beta elimination upon thermal degradation.
Abstract: An improved process for producing a polyphenylene ether with low nitrogen content and low odor properties employs, for oxidative coupling of a 2,6-disubstituted phenol, a novel catalyst comprising a copper compound, a diamine, a tertiary amine, a quaternary compound and an unsaturated compound. The new polyphenylene ether is suitable for polymer blending, with, for example, styrenic resins, to make low odor blends.
Abstract: Linear polyester are branched by transesterification with resins having repeating or recurring polymer chain units of the formula: ##STR1## wherein m, n and p are each independent integers of 0 or 1; R represents hydrocarbyl; and E represents alkylene containing from 1 to 15 carbon atoms, inclusive, halogen- substituted alkylene of 1 to 15 carbon atoms, inclusive, alkylene of 1 to 15 carbon atoms, inclusive, substituted with a --COOR group where R is as previously defined, or alkylene having 1 to 15 carbon atoms substituted with a monovalent group of the formula: ##STR2## wherein X represents one of hydrogen, hydrocarbyl or ##STR3## wherein R is as defined above; provided there is at least one moiety present, containing an R group.
Abstract: The invention provides a process for producing a polyphenylene ether by subjecting a 2,6-disubstituted phenol to oxidative coupling by introducing oxygen in the presence of a catalyst system which comprises a manganese compound, a chelant, a base, and an alpha,beta-unsaturated ketone, a beta-diketone, or a vinyl ether. The polyphenylene oxide produced has substantially no amine odor and more stable molecular weight, and is suitable for blending with styrenic or other resins to make thermoplastic resin blends of low odor and good physical properties.
Abstract: Apparatus for the thermoplastic shaping of polymeric resins is improved by the use of thin-film resistance heaters as the means of applying thermal energy to the resin. The heaters are mounted on the resin molding surfaces.
Abstract: A die block component for use in a punch and die assembly is described, having a plurality of grooves in the die face. The block and assembly are useful for cutting articles from sheets and film of synthetic polymeric resins while avoiding the contamination of the article with severed particles and slivers.
Type:
Grant
Filed:
March 14, 1990
Date of Patent:
April 16, 1991
Assignee:
General Electric Company
Inventors:
Stephen O. Ketcham, Paul W. Ortiz, Jamie S. Jarvis, Clyde S. McCray