Patents Represented by Attorney Joyce P. Hill
  • Patent number: 4190605
    Abstract: A noble metal catalyst, such as palladium, is activated by successive and sequential reactions with an alcohol, such as hydroxybenzyl alcohol, and oxygen or a gas containing oxygen in an aqueous, preferably alkaline, medium, The catalyst activated in the aforementioned manner is particularly useful for the oxidation of alcohols to the corresponding aldehydes.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: February 26, 1980
    Assignee: The Dow Chemical Company
    Inventors: Wayne C. Muench, Glen O. Strand, Thad S. Hormel
  • Patent number: 4144265
    Abstract: Quaternary ammonium salts, such as methyl tributyl ammonium chloride, are novel catalysts in a nitrile-forming reaction which comprises stirring together aqueous sodium cyanide and the undistilled m-trifluoromethyl benzyl chloride product of the reaction of chloromethyl methyl ether, chlorosulfonic acid and trifluoromethyl benzene from which chloromethyl ether impurities, methanol, water and some of the unreacted trifluoromethyl benzene are removed. The process is conducted under alkaline conditions in a two-phase liquid reaction medium. m-Trifluoromethyl benzyl nitrile is prepared in excellent yields and purity.
    Type: Grant
    Filed: July 17, 1978
    Date of Patent: March 13, 1979
    Assignee: The Dow Chemical Company
    Inventors: William Dowd, Thomas H. Fisher