Patents Represented by Attorney, Agent or Law Firm K. W. Zerby
  • Patent number: 5576283
    Abstract: Aqueous liquid detergent compositions are described which comprise a proteolytic enzyme wherein the proteolytic activity is reversibly inhibited by a peptide aldehyde.
    Type: Grant
    Filed: February 8, 1995
    Date of Patent: November 19, 1996
    Assignee: The Procter & Gamble Company
    Inventors: James P. Johnston, Regine Labeque, Pierre M. A. Lenoir, Christiaan A. J. K. Thoen, John M. McIver
  • Patent number: 5565556
    Abstract: Starch is oxidized in a controlled manner using nitric acid, sulfuric acid and vanadium catalyst. The resulting oxidized starch is useful in detergent compositions as a dispersant, builder and cleaning auxiliary.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: October 15, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Stephen W. Heinzman, Jeffrey S. Dupont
  • Patent number: 5565145
    Abstract: Cleaning and soil dispersing compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers are provided. Thus, detergent compositions which comprise ethoxylated/propoxylated polyalkyleneamine polymers, such as poly(ethyleneimine) with a degree of ethoxylation of 1.0, provide soil dispersing performance in the wash liquor and whitening and/or cleaning benefits to fabrics, hard-surfaces, or dishware.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: October 15, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Randall A. Watson, Eugene P. Gosselink, Shulin Zhang
  • Patent number: 5562847
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; and (B) an ester of an alcohol perfume wherein the ester has at least one free carboxylic acid. The ester has the general formula: ##STR1## wherein R is selected from the group consisting of substituted or unsubstituted C.sub.1-C.sub.30 straight, branched or cyclic alkyl, alkenyl, alkynyl, alkylaryl, aryl group; or ring containing a heteroatom, R' is a perfume alcohol with a boiling point at 760 mm Hg of less than about 300 .degree. C.; and m and n are independently an integer of 1 or greater.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: October 8, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Scott W. Waite, John C. Severns, Mark R. Sivik, Frederick A. Hartman
  • Patent number: 5560858
    Abstract: A) A metallocatalyst selected from: a) metalloporphin and water-soluble or water-dispersable derivatives thereof; b) metaloporphyrin and water-soluble or water-dispersable derivatives thereof; c) metallophthalocyanine and water-soluble or water-dispersable derivatives thereof; B) a polyamine N-oxide containing polymers; C) an efficient amount of a bleaching agent.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Abdennaceur Fredj, Frederick E. Hardy, Alan D. Willey, James P. Johnston, Regine Labeque, Christiaan A. J. K. Thoen
  • Patent number: 5560748
    Abstract: Laundry and cleaning compositions which comprise large pore size redox catalysts.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Athanasios Surutzidis, Robert Y. Pan, Gregory S. Caravajal, James C. T. R. Burckett-St. Laurent
  • Patent number: 5560862
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Gregory S. Miracle, Alan D. Willey, Michael E. Burns, Kevin L. Kott, Mark R. Sivik, Lucille F. Taylor
  • Patent number: 5561235
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom,, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Gregory S. Miracle, Alan D. Willey, Michael E. Burns, Kevin L. Kott, Mark R. Sivik, Lucille F. Taylor
  • Patent number: 5559261
    Abstract: A method for manufacturing cobalt complexes having the formula:[Co(NH.sub.3).sub.5 OAc]T.sub.ysaid method comprising reacting cobalt (II) acetate having the formula Co(OAc).sub.2 4H.sub.2 O with concentrated ammonium hydroxide/ammonium acetate, followed by oxidizing agent (e.g., peroxide).
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: September 24, 1996
    Assignee: The Procter & Gamble Company
    Inventor: Mark R. Sivik
  • Patent number: 5538671
    Abstract: Soil removal performance of granular laundry detergents containing aluminosilicate builders is improved by presence of polyaspartic acid (or its water-soluble salts) as a co-builder/soil dispersant.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: July 23, 1996
    Assignee: The Procter & Gamble Company
    Inventor: Stephen W. Morrall
  • Patent number: 5536435
    Abstract: A process for preparing particulate bodies containing a substantially water-insoluble organic peroxyacid compound, which process does not include a solidification step, including an early step of intimately mixing substantially water-insoluble peroxyacid compound with a peroxyacid-stable, water-soluble surfactant.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: July 16, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Benjamin E. Chapman, Steven M. Gabriel, Jeffrey E. Boucher, Daniel L. Strauss
  • Patent number: 5534197
    Abstract: Gemini polyhydroxy fatty acid amide compounds and laundry, cleaning, fabric and personal care compositions comprising these compounds.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: July 9, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey J. Scheibel, Daniel S. Connor, Yi-Chang Fu
  • Patent number: 5534179
    Abstract: Improved detergent compositions, especially granular detergents, comprising bleach activators which form multiperacids, especially specific monoquaternary substituted bis(peroxycarbonic) acids, upon perhydrolysis are provided.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: July 9, 1996
    Inventors: Gregory S. Miracle, Mark R. Sivik, Patti J. Kellett
  • Patent number: 5534180
    Abstract: Improved automatic dishwashing detergent compositions, especially granular detergents, comprising bleach activators which form multiperacids, especially specific monoquaternary substituted bis(peroxycarbonic) acids, upon perhydrolysis are provided.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: July 9, 1996
    Inventors: Gregory S. Miracle, Mark R. Sivik
  • Patent number: 5534642
    Abstract: Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfates for use as bleach activators, starting from carboxylic acids and lactams.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: July 9, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Stephen W. Heinzman, Jeffrey S. Dupont, William C. Tettenhorst
  • Patent number: 5520835
    Abstract: Improved detergent compositions, especially granular automatic dishwashing detergents, comprising multiquaternary bleach activators are provided. The bleach activators contain multiple quaternary nitrogen groups, preferably at least three such groups and preferably have at least one quaternary nitrogen group in the peracid-forming portion of the bleach activator as well as at least one quaternary nitrogen group in the leaving-group portion.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: May 28, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Mark R. Sivik, Lucille F. Taylor, James C. T. R. Burckett-St. Laurent
  • Patent number: 5520838
    Abstract: The present invention concerns cellulase-containing granular detergent compositions which are in a "compact" form, i.e. they are of a relatively high density and contain a relatively low amount of inorganic filler salt compared to conventional detergent compositions. In the detergent compositions herein the cellulase is defined by the C14CMC method described herein and preferably comprises a specific single-component endoglucanase.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: May 28, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Andre C. Baeck, Raphael A. Ceulemans, Alfred Busch
  • Patent number: 5510477
    Abstract: High quality acyl lactam imides are prepared by reacting an acyl lactam of the formula ##STR1## where 5 carbon atoms and an acylating acid of the formula R'CO.sub.2 H or by reacting a lactam, an anhydride of the formula (RCO).sub.2 O where R is 1 to 5 carbon atoms and an acylating acid, preferably in the presence of a base catalyst. The process affords acyl lactam imides in high yield and at lower reaction temperatures by providing for the removal of volatile carboxylic acid by-products under vacuum or by the use of a stripping gas. The acyl lactam imides are particularly suited for use as bleach activators in detergent compositions.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: April 23, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Alan D. Willey, Larry E. Miller
  • Patent number: 5496728
    Abstract: Yeast or other micro-organism cells for use in the encapsulation of liquids (e.g. liquid bleach activators for use in laundry detergent compositions) are deodorised by treatment with a peroxygen bleach, e.g. hydrogen peroxide.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: March 5, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Frederick E. Hardy, Alan D. Willey, Stefano Scialla
  • Patent number: 5470510
    Abstract: Poly(glutamic acid) is used as a dispersing, soil-suspending or anti-redeposition agent in laundry detergent or other cleaning compositions that also contain a detersive surfactant. Suitable polymers include not only the homopolymers of glutamic acid but also block, graft or random copolymers of glutamic acid with biodegradable monomers or polymers, e.g., other amino acids or polyethylene glycol.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: November 28, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Alan D. Willey, Robin G. Hall