Abstract: An apparatus for mixing vapor and liquid reactants within a column. The apparatus forms a first mixing zone into which a first reactant (e.g., vapor) is homogenized by swirl flow and flows vertically downward. The apparatus further forms a second mixing zone into which a second reactant (e.g., liquid) is homogenized by swirl flow and flows vertically downward. Additional amounts of either the first reactant, the second reactant or both may be added into or ahead of the first mixing zone or the second mixing zone as appropriate. The first reactant is directed radially to collide in crossflow with a thin sheet of the second reactant to provide intense mixing of the first and second reactants. Due to separate mixing zones for the two reactants, the mixing conditions for each can be tailored to best mix each reactant while minimizing pressure drop and minimizing the space and volume requirements for this mixing.

Abstract: A method for recovering viscous oil from a subterranean formation through a wellbore having a horizontal section into the formation. Steam is circulated through the horizontal section to initially heat the formation and to produce fluids to the surface. After the initial heating is complete, production is ceased while the injection of steam is continued to accumulate a slug of steam within and around the horizontal section. The well is then shut-in and the formation is allowed to "soak". Production is then resumed and steam is again continuously injected into the well when oil appears in the produced fluids. This cycle is repeated until the production of oil drops belows an acceptable rate.

Abstract: Multi-phase fluid flow in a pipeline or other flowline is monitored using a combination of flow type detectors. One set of detectors monitors the interfaces between fluid interfaces and the other monitors the presence of different fluid phases around the periphery of the flowline. The relative volumetric fluid flow rates can be measured by detecting changes in the phase interfaces between two sets of sensor rings using sensors spaced around the flowline with the fluid flow type being detected across the flowline with an annular capacitance detector. The sensor rings typically use ultrasonic transducers for detecting the phase interfaces while the capacitance device indicates the presence (or absence) of different phases around the periphery of the flowline. By combining the outputs of the different detectors, an indication of the flow phenomena in the flowline can be obtained.

Abstract: A method for modifying a crystalline molecular sieve material is provided. The crystalline molecular sieve material is modified by functionalizing it and concurrently removing its templating surfactant. The method is accomplished by contacting the crystalline molecular sieve material with a treatment composition including a functionalizing agent, an exchanging moiety and a solvent.

Abstract: A process to improve the performance of furfural for aromatics extraction from gas oils and lube distillates by the addition of ethers and/or aldehydes, preferably having a dielectric constant less than about 40 @ 25.degree. C.

Abstract: A method for removing a gravel-pack screen from a wellbore. of a well which has been "gravel packed". When it is desired to remove the screen from the wellbore, a washstring is lowered down the wellbore and into the interior of said screen. A wash fluid is then flowed fluid down the washstring and out through said screen into said mass of gravel surrounding the screen to fluidize, loosen, and remove said gravel. Once the mass of gravel has been loosen, the screen can then lifted upward out of said wellbore by applying a normal upward force the workstring which suspends the screen within the well.

Abstract: An improved stripper section design is provided for use in fluid catalytic cracking (FCC) units. The stripper section contains means for imparting rotational movement to the FCC cracking catalyst as it traverses the stripping section. In one embodiment the stripper section contains at least one rotation vane that is preferably disposed on the surface of a stripper section tray. The rotation vane provides angular, rotational movement to the cracking catalyst as it traverses the stripper section. Vertical movement is imparted to the cracking catalyst due to gravity and radial movement is imparted to the catalyst due to the slanted nature of the tray. Through the use of the rotation vanes the contact between the catalyst particles and the stripping steam is increased, thereby improving the overall efficiency of the FCC operation.

Abstract: There is provided a catalyst comprising yttrium containing zeolite Y. The zeolite Y is essentially free of rare earth ions. There is also provided a method for making this catalyst. There is further provided a process for using this catalyst for cracking gas oils. It has been discovered that when yttrium is incorporated into this zeolite Y, and when this catalyst is used to crack gas oils, these results improved gasoline selectivity and reduced dry gas make.

Abstract: This invention is directed to an improved process scheme to process sour feed in the reaction section of the process unit, including isomerization dewaxing with zeolite beta. The instant invention employs countercurrent flow in the fixed bed of the MIDW(Mobil Isomerization Dewaxing) reactor (the reactor in which isomerization dewaxing occurs) with recycle gas being the gas stream in the MIDW bed. With this arrangement hydrodesulfurization(HDS) and MIDW occur in an integrated process.

Abstract: This invention is directed to a catalyst that comprises (i) an acidic solid oxide component comprising an oxide of a Group IVB metal modified with an anion or oxyanion of a Group VIB metal, and (ii) a Group IB metal or metal oxide component. This catalyst may be used, for example, to isomerize paraffins.

Abstract: There is provided a process for producing alkylaromatics, especially ethylbenzene and cumene, wherein a feedstock is first fed to a transalkylation zone and the entire effluent from the transalkylation zone is then cascaded directly into an alkylation zone along with an olefin alkylating agent, especially ethylene or propylene.

Abstract: Alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a paraffin alkylating agent under alkylation reaction conditions in the presence of catalyst comprising synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07, and 3.42.+-.0.06 Angstroms.

Abstract: A gravel-pack, well screen having an internal shunt tube positioned inside the screen for delivering gravel slurry to different levels within the well annulus during a gravel pack operation. The screen includes one or more joints with each joint includes a base pipe having a screen section therein. The internal shunt extends substantially throughout the length of the base pipe. Bolts, each having a passage therethrough, provide fluid passages between the exterior of the screen and the internal shunt tube near either end of the base pipe. During operation, slurry enters the internal shunt tube through the uppermost bolt and exits into the annulus through the passages in the lower bolts to distribute gravel to to different levels of the annulus.

Abstract: This invention discloses a process for producing a high Viscosity Index lubricant having a VI of at least 125 from a waxy hydrocarbon feed having a wax content of at least 40 wt %. The process comprises catalytically dewaxing waxy paraffins present in the feed by isomerization in the presence of hydrogen and in the presence of a low acidity large pore zeolite isomerization catalyst. This catalyst has a ratio of SiO.sub.2 /Al.sub.2 O.sub.3, as synthesized, of at least 50:1, wherein the catalyst is prepared in the absence of boron. The alpha value of the catalyst is no greater than 20. The catalyst comprises a noble metal hydroisomerization catalyst such as Pt. The feed may be hydrocracked prior to dewaxing with the large pore zeolite. The effluent of the process may also be further dewaxed by either solvent or catalytic means in order to achieve target pour point.

Abstract: A method for breaking an emulsion comprising oil and water into oil and water phases comprising treating the emulsion with a chemical demulsifier and passing the mixture through a hollow chamber having a uniform cross-section and subjecting the mixture to acoustic energy in the frequency range of about 0.5 to 10.0 kHz, preferably 1.25 kHz, to enhance breaking the emulsion into a water phase and oil phase. The oil phase is then separated from the water phase by gravity separation and recovered. The sonic energy is generated by a transducer attached to the mid-section of the upper or lower outer surface of the hollow chamber. For emulsions containing light oil having an API gravity greater than 20 and water, the emulsion can be broken by the use of acoustic energy in the frequency range of about 0.5 to 10.0 kHz without the addition of chemical demulsifiers.

Abstract: A method and system for determining the viscosity index of a petroleum liquid. The determination may be made on a single, discrete sample or on a continuous sample stream. A sample is fed into a first pressure drop device where a first pressure drop is measured. A first sample temperature and mass flow are measured at that point. A first density of the sample is determined from a sample mass flow meter so that a first kinematic viscosity can then be determined using the first sample pressure drop, temperature, and density. Then the sample temperature is changed to a second sample temperature and the sample is passed through a second pressure drop device. The second sample temperature, sample density and pressure drop are used to determine a second kinematic viscosity at the second sample temperature. The viscosity index of the sample is determined using the first kinematic viscosity and the second kinematic viscosity. The viscosity index of the sample is presented in digital form to system operators.

Abstract: An alternate-path, well screen made-up of joints and having a sleeve positioned between the ends of adjacent joints which acts as a manifold for fluidly-connecting the alternate-paths on one joint with the alternate-paths on an adjacent joint.

Abstract: Low sulfur gasoline is produced from an olefinic, cracked, sulfur-containing naphtha by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 to crack low octane paraffins and olefins under mild conditions with limited aromatization of olefins and naphthenes. A benzene-rich co-feed is co-processed with the naphtha to reduce the benzene levels in the co-feed by alkylation. This initial processing step is followed by hydrodesulfurization over a hydrotreating catalyst such as CoMo on alumina. In addition to reducing benzene levels in the combined feeds, the initial treatment over the acidic catalyst removes the olefins which would otherwise be saturated in the hydrodesulfurization, consuming hydrogen and lowering product octane, and converts them to compounds which make a positive contribution to octane. Overall liquid yield is high, typically at least 90 percent or higher.

Abstract: This is a process for upgrading a petroleum naphtha fraction. The naphtha is subjected to reforming and the reformate is cascaded to a benzene and toluene synthesis zone over a benzene and toluene synthesis catalyst comprising a molecular sieve of low acid activity. The preferred molecular sieve is steamed ZSM-5. The benzene and toluene synthesis zone is operated under conditions compatible with the conditions of the reformer such as pressures of above about 50 psig (446 kPa) and temperatures above about 800.degree. F. (427.degree. C). In one aspect of the invention, the benzene and toluene synthesis catalyst includes a metal hydrogenation component such as cobalt, nickel, platinum or palladium. In one mode of operation, the benzene and toluene synthesis catalyst replaces at least a portion of the catalyst of the reformer. The process produces a product containing an increased proportion of benzene and toluene, and a reduced proportion of C8 aromatics, particularly ethylbenzenes, as compared to the reformate.

Abstract: Low sulfur gasoline is produced from an olefinic, cracked, sulfur-containing naphtha by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 to crack low octane paraffins and olefins under relatively mild conditions, with limited aromatization of olefins and naphthenes. This is followed by hydrodesulfurization over a hydrotreating catalyst such as CoMo on alumina. The initial treatment over the acidic catalyst removes the olefins which would otherwise be saturated in the hydrodesulfurization, consuming hydrogen and lowering product octane, and converts them to compounds which make a positive contribution to octane. Overall liquid yield is high, typically at least 90 percent of higher. Product aromatics are typically increased by no more than 25 weight percent relative to the feed and may be lower than the feed.