Abstract: An adhesion promoter comprises a polymeric strand with an epoxy-reactive group other than a phenolic hydroxyl group, and a crosslinking group that crosslinks the polymeric strand with a rubber in a crosslinking reaction, wherein the polymeric strand is water soluble in an amount of at least 10 g/l, and more preferably at least 100 g/l. Particularly contemplated adhesion promoters may further comprise styrene-butadiene-vinylpyridine copolymer, and may advantageously be employed as a replacement for resorcinol-formaldehyde latex in the fabrication of a rubber containing tire. Especially contemplated rubber compositions may additionally comprise maleinized polybutadiene to synergistically improve adhesion of the rubber to a polymeric fiber coupled via contemplated adhesion promoters.
Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.
Type:
Grant
Filed:
February 14, 2002
Date of Patent:
June 29, 2004
Assignee:
Honeywell International Inc.
Inventors:
Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft
Abstract: A process for making load limiting yarn comprising making block copolymer and then spinning the block copolymer into yarn. The process employs a twin screw extruder and comprises (A) forwarding aromatic polyester melt to an injection position in a twin screw extruder, (B) injecting lactone monomer into the molten aromatic polyester, (C) dispersing the monomer into the aromatic polyester melt so that a uniform mixture forms in less than about thirty seconds, and (D) reacting the uniform mixture resulting from step (C) at a temperature from about 250° C. to from a block copolymer. Steps (A) through (D) occur in less than about four minutes residence time in the twin screw extruder. The process is advantageous because high IV starting aromatic polyester can be used and the short reaction time at high temperature results in block copolymer with minimum transesterification, a high melting point, and a high melt viscosity.
Type:
Grant
Filed:
December 19, 2000
Date of Patent:
September 2, 2003
Assignee:
AlliedSignal Inc.
Inventors:
Weiming Tang, Frank Mares, Robert Clark Morgan
Abstract: Stable concentrated suspensions readily dispersible in water comprising ammonium sulfate, a surfactant, and an oil. The ammonium sulfate particles are at least about 99 wt. % passable through a Tyler #48 sieve. The surfactant has an HLB rating from about 10 to about 15. The oil is a hydrocarbon or other non-polar oil having a viscosity of at least about 5 centipoises at 40° C. The ammonium sulfate suspensions of the invention are useful as herbicidal adjuvants, herbicidal compositions or for other purposes.