Abstract: Novel poly(3-hydroxyalkanoates), such as poly(3-hydroxybutyrate), and blends of these with other polymers are disclosed. A novel process for producing these poly(3-hydroxyalkanoates) is also disclosed which entails polymerizing one or more .beta.-substituted-.beta.-propiolactone(s) under polymerization conditions in the substantial absence of water in the presence of an anionic initiator.
Type:
Grant
Filed:
January 21, 1994
Date of Patent:
February 21, 1995
Assignee:
Eastman Chemical Company
Inventors:
John C. Hubbs, Marti N. Harrison, Charles Buchanan
Abstract: Disclosed is a novel polyethylene composition that is a blend of a polyethylene component having defined properties, a specific quantity of a defined tackifying resin and a very specific minute quantity of a unique amide of a fatty acid. The novel composition can be used in a process for extrusion coating at high speeds and relatively low extrusion coating temperatures with good adhesion to the substrate and dramatically improved chill roll release.
Abstract: Compositions are disclosed that are the urea derivatives of succinylated polyolefins (maleated polyolefins). The urea derivatives of succinylated polyolefins are of the formula; ##STR1## wherein R is a polyolefin attached at any point along the hydrocarbon chain. The urea derivative of succinylated polyolefins is useful as a coupling agent to couple polyolefins with dissimilar polymers having an excess of unreacted acid groups such as polyesters.
Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain an ethylene-alkylacrylate copolymer, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed have fast setting times and a novel combination of desired properties with good high and low temperature bond strength.
Abstract: A process for producing dimeric unsaturated aldehydes from alpha, beta unsaturated aldehyde is disclosed. This process is conducted by contacting the alpha, beta unsaturated aldehyde with a copper (II) catalyst and a complexing amine catalyst in a medium with a relatively high dielectric constant in substantially anhydrous and aprotic conditions.
Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.
Abstract: Fibers such as caustic-treated non-round polyester fibers are prepared having certain lubricants strongly adhered to the surfaces thereof. These fibers are prepared by contacting the fibers, such as immediately prior to a crimping device, with a suitable heated hydrophilic lubricant in a processing operation followed by heating to dry or bake the lubricant onto and/or into the surface of the fibers.
Type:
Grant
Filed:
June 7, 1993
Date of Patent:
December 13, 1994
Assignee:
Eastman Chemical Company
Inventors:
Richard D. Neal, Shriram Bagrodia, Lewis C. Trent, Mark A. Pollock
Abstract: A process is provided for the production of an emulsifiable polypropylene wax having a melt viscosity from 1000 to 5000 cP at 190.degree. C. This process entails reacting at a temperature below 190.degree. C. a thermally degraded polypropylene wax having a melt viscosity below 1000 cP (at 190.degree. C.) with maleic anhydride in the presence of a free radical source. Floor polish formulations containing this polypropylene wax are very clear but yet provide floor finishes that are very tough.
Type:
Grant
Filed:
January 21, 1994
Date of Patent:
November 1, 1994
Assignee:
Eastman Chemical Company
Inventors:
Thomas D. Roberts, Thomas W. Smith, Charlene A. Galvin
Abstract: Solid form additive systems which are dispersible in aqueous media are disclosed, as are methods for preparing such additive systems. The additive systems are dry, free-flowing particulate materials that contain at least one additive component, at least one tackifying agent, and at least one surfactant.
Type:
Grant
Filed:
October 4, 1991
Date of Patent:
October 25, 1994
Assignee:
Eastman Chemical Company
Inventors:
Brenda J. Hitch, Mahendra K. Sharma, Leo P. Voetgli
Abstract: A process of producing a high gloss oxidizable extrusion coated polyethylene is provided. This process entails extrusion coating a low density polyethylene of narrow molecular weight distribution having a low melt index, a low swell ratio, and a polydispersity index below 9.
Abstract: Disclosed is a water-dissipatable or dispersible polyester containing sulfonate groups that has improved stability prepared from a monocarboxylic acid sulfomonomer. This polyester can be prepared in a one or two step process but the preferred two step process entails polymerizing the reactants wherein the monocarboxylic acid sulfomonomer has been pre-reacted with a monofunctional reactant containing at least three hydroxyl groups to form a diol adduct.
Abstract: A propylene-graft-unsaturated polyester is disclosed comprising the reaction product of a polypropylene, an unsaturated polyester and a free radical initiator. The polypropylene-graft-unsaturated polyester is generally prepared by reacting at elevated temperatures using a peroxide. The polypropylene-graft-unsaturated polyester is very useful as a compatibilizing agent in blends of polyester and ethylene-propylene rubber to improve the impact strength of the polyester.
Type:
Grant
Filed:
December 31, 1992
Date of Patent:
August 30, 1994
Assignee:
Eastman Chemical Company
Inventors:
Jeffrey J. Vanderbilt, Max F. Meyer, Jr.
Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.
Abstract: A stable aqueous dispersion and process for making the dispersion are provided containing hydrolyzed cellulose ester, organic solvent, water and acrylic resin having free acid functionalities that are at least partially neutralized. The dispersion is useful in coatings and can also contain surfactant and cross-linking agent.
Type:
Grant
Filed:
January 21, 1992
Date of Patent:
August 2, 1994
Assignee:
Eastman Chemical Company
Inventors:
Chung M. Kuo, Larry G. Curtis, Paul L. Lucas
Abstract: An elastomeric composition is prepared containing an amorphous propylene/hexene copolymer and an elastomer selected from styrene butydiene styrene block copolymers.
Abstract: A low molecular weight crystalline homopolypropylene wax of low softening point is disclosed. This homopolypropylene wax is prepared from high molecular weight crystalline polypropylene by thermal degradation in the presence of a relatively high amount of peroxide.
Type:
Grant
Filed:
October 26, 1992
Date of Patent:
July 19, 1994
Assignee:
Eastman Chemical Company
Inventors:
Vernon K. Park, Randal R. Ford, Robert P. Allen
Abstract: Ester bonds are hydrolyzed in the conversion of substantially amorphous polyesters to their monomeric components, by being contacted with a mixture of (a) an alcohol, such as methanol, or glycol, (b) a polar aprotic solvent such as N-methyl-pyrrolidone or dimethyl sulfoxide and (c) an alkoxide or hydroxide such as sodium hydroxide.
Type:
Grant
Filed:
November 2, 1992
Date of Patent:
July 12, 1994
Assignee:
Eastman Chemical Company
Inventors:
George W. Tindall, Randall L. Perry, Art T. Spaugh, Jr.
Abstract: Disclosed is pigmented dispersion containing a non-amine wetting and dispersing agent and a water-dissipatable or dispersible polyester containing sulfonate groups that has improved stability having a substantial number of capped carboxyl groups attached to the sulfomonomer moieties. This polyester can be prepared by capping the carboxyl end groups of the polyester with oxirane compounds or by polymerizing the reactants wherein one reactant is a diol that is a diester adduct of a glycol and a dicarboxylic acid sulfomonomer.
Abstract: Disclosed is a novel monomer composition and its preparation that is useful in the production of polyesters. This novel monomer composition is 1-acetoacetamido-2,3-propane diol and can be used in the preparation of polyesters in combination with a dicarboxylic acid.
Abstract: A tool for spreading high tension springs used in the brakes of heavy equipment is provided. This tool spreads at least a portion of a high tension spring by squeezing the handles together by hand thereby separating the arms. This is the opposite of what happens when the handles of standard pliers are squeezed together.