Abstract: Polyurethanes or polyurethane-ureas prepared from: (a) polytrimethylene ether glycol having a number average molecular weight in the range of about 1,000 to about 4,000 and unsaturated end groups in the range of about 0.003 to about 0.015 meq/g; (b) diisocyanate; and (c) diol or diamine chain extender; and their manufacture, intermediates and use.
Abstract: A catalyst composition prepared from (a) titanium tetrahydrocarbyloxide, (b) zirconium tetrahydrocarbyloxide, and (c) tetraalkyl ammonium hydroxide, wherein the molar ratio of Zr:Ti is from about 0.02:1 to about 5:1 and the molar ratio of TAAH:(Ti+Zr) is from about 0.05:1 to about 2:1.
Abstract: Poly(trimethylene terephthalate) tetrachannel cross-section staple fibers, as well as yarns, fiberfill webs, batts and products, and fabrics made therewith. Also, the process of making such staple fibers, yarns, fiberfill webs, batts and products, and fabrics.
Type:
Grant
Filed:
June 24, 2002
Date of Patent:
December 28, 2004
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Ismael A. Hernandez, Geoffrey David Hietpas, James M. Howell, Claudia Schultze
Abstract: A random polytrimethylene ether ester prepared by polycondensation of 1,3-propanediol reactant and about 10 to about 0.1 mole % of aliphatic or aromatic diacid or diester, as well as its manufacture and use thereof.
Abstract: A treated poly(trimethylene terephthalate) carpet prepared by applying a polyfluoroacrylate emulsion to a poly(trimethylene terephthalate) carpet and curing the polyfluoroacrylate.
Type:
Grant
Filed:
June 18, 2002
Date of Patent:
August 17, 2004
Assignee:
E.I. du Pont de Nemours and Company
Inventors:
Joseph Varapadavil Kurian, Justine Gabrielle Franchina
Abstract: A process of making polytrimethylene terephthalate staple fibers, including (a) providing polytrimethylene terephthalate, (b) melt spinning the melted polytrimethylene terephthalate at a temperature of 245-285° C. into filaments, (c) quenching the filaments, (d) drawing the quenched filaments, (e) crimping the drawn filaments using a mechanical crimper at a crimp level of 8-30 crimps per inch (3-12 crimps/cm), (f) relaxing the crimped filaments at a temperature of 50-120° C., and (g) cutting the relaxed filaments into staple fibers having a length of about 0.2-6 inches (about 0.5-about 15 cm), and polytrimethylene terephthalate staple fibers, yarns and fabrics. Further, a process of optimizing the crimp take-up of a polytrimethylene terephthalate staple fiber including determining the relationship between denier and crimp take-up and manufacturing staple fibers having a denier selected based upon that determination.
Type:
Grant
Filed:
August 22, 2001
Date of Patent:
June 22, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Ismael A. Hernandez, Geoffrey David Hietpas, James M. Howell, Claudia Schultze
Abstract: Multilayer shaped articles, including films, preforms and containers, and method for forming the same, having at least one layer of poly(1,3-propylene 2,6-naphthalate) and at least one layer of poly(ethylene terephthalate). Poly(1,3-propylene 2,6-naphthalate) can be co-stretched with poly(ethylene terephthalate) to form oriented multilayer structures which have superior barrier properties. The poly(1,3-propylene 2,6-naphthalate) and poly(ethylene terephthalate) layers have good adhesion and do not require an adhesive tie layer.
Type:
Grant
Filed:
August 7, 2001
Date of Patent:
June 15, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Pallatheri M. Subramanian, Howard Chung-Ho Ng, Ross A. Lee
Abstract: A process of making a pigmented shaped article comprising: (a) providing polytrimethylene terephthalate chips and two or more colored pigmented chips each containing at least one different color pigment; (b) heating the polytrimethylene terephthalate chips and colored pigmented chips to a temperature of about 200-about 280° C. to melt the chips and form a polymer composition comprising the polytrimethylene terephthalate and at least one color pigment; and (c) forming a shaped article from the polymer composition.
Type:
Grant
Filed:
June 29, 2001
Date of Patent:
May 25, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Nirmal K. Agarwal, Jing C. Chang, Richard Lee Dommel, Joseph V. Kurian, Raymond Longhi
Abstract: An acid-dyeable polymer composition comprising (a) polymer and (b) polymeric additive comprising repeating units having the formula:
or salts thereof, wherein A, B and Q, which may be the same or different, are selected from aliphatic or aromatic substituents provided that at least four carbon atoms separate any two nitrogen groups, R is an aliphatic or aromatic group, a is 1 to 5, and n is 3 to about 1,000. In addition, an acid-dyed composition prepared from the composition, a process of acid dyeing the composition and a process for preparing the composition.
Abstract: The invention is a continuous process for the preparation of polytrimethylene ether glycol from 1,3-propanediol reactant. In addition, the invention is directed to a continuous multi-stage process comprising reacting at least one reactant in a liquid phase in an up-flow column reactor, and forming a gas or vapor phase by-product wherein the gas or vapor phase by-product is continuously removed at the top and at least one intermediate stage.
Type:
Grant
Filed:
December 15, 2000
Date of Patent:
April 13, 2004
Assignee:
E. I. du Pont Nemours and Company
Inventors:
Hari B. Sunkara, Ernest Keith Andrew Marchildon, Howard Chung-Ho Ng, Leo E. Manzer
Abstract: A process for production of 1,3-propanediol including the steps: (a) hydrating acrolein in the presence of an acid hydration catalyst; (b) catalytically hydrogenating the reaction mixture of step (a), which reaction mixture comprises 3-hydroxypropionaldehyde and is freed of unreacted acrolein; (c) refining the reaction mixture of step (b) containing water, 1,3-propanediol and the by-products boiling higher than 1,3-propanediol; and, (d) treating 4-oxa-1,7-heptanediol to form 1,3-propanediol by (1) removing a boiler sump comprising 4-oxa-1,7-heptanediol from the refining step (c), (2) treating the boiler sump in an aqueous solution in the presence of an acid catalyst at about 200 to about 300° C. to form a solution comprising 1,3-propanediol, (3) neutralizing the solution obtained is step (2), and returning the neutralized solution from step (3) to the refining step (c).
Type:
Grant
Filed:
April 29, 2002
Date of Patent:
February 17, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Thomas Haas, Christian Ronge, Torsten Hahn
Abstract: Processes for making poly(trimethyelene terephthalate) yarn are provided. The process includes extruding a polyester polymer through a spinneret to form non-round filaments at a spinning speed less than 4500 mpm and a temperature between about 255° C. and about 275° C. The polyester polymer composition includes at least 85 mole percent poly(trimethylene terephthalate) wherein at least 85 mole percent of the repeating units consist of trimethylene units, and the polyester polymer has an intrinsic viscosity of at least 0.70 dl/g.
Type:
Grant
Filed:
March 1, 2001
Date of Patent:
February 3, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
James M. Howell, Joe Forrest London, Jr.
Abstract: A stable partially oriented poly(trimethylene terephthalate) yarn suitable for use in subsequent drawing and/or draw-texturing operations characterized by an elongation to break of at least 110%, and a process for false-twist texturing a partially oriented poly(trimethylene terephthalate) yarn are disclosed.
Type:
Grant
Filed:
February 28, 2001
Date of Patent:
January 6, 2004
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
James M. Howell, Joe Forrest London, Jr., Michelle H. Watkins
Abstract: Fine denier poly(trimethylene terephthalate) feed yarns and drawn yarns wherein the drawn yarns are characterized by a denier per filament less than 1.5 and are drawn such that the actual draw ratio is within 10 percent of the predicted draw ratio determined according to: [(elongation to break of the feed yarn)+115]/[(elongation to break of the drawn yarn)+115)].
Type:
Grant
Filed:
February 28, 2001
Date of Patent:
December 16, 2003
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
James M. Howell, Joe Forrest London, Jr., Michelle H. Watkins
Abstract: A side-by-side or eccentric sheath-core bicomponent fiber wherein each component comprises a different poly(trimethylene terephthalate) composition and wherein at least one of the compositions comprises styrene polymer dispersed throughout the poly(trimethylene terephthalate), and preparation and use thereof.
Type:
Grant
Filed:
November 5, 2002
Date of Patent:
November 4, 2003
Assignee:
E. I. Du Pont De Nemours and Company
Inventors:
Jing C. Chang, Joseph V. Kurian, Ray W. Miller
Abstract: A random polytrimethylene ether ester prepared by polycondensation of 1,3-propanediol reactant and about 10 to about 0.1 mole % of aliphatic or aromatic diacid or diester, as well as its manufacture and use thereof.
Abstract: A polyether ester elastomer comprising about 90-about 60 weight % polytrimethylene ether ester soft segment and about 10-about 40 weight % trimethylene ester hard segment, and use thereof in fibers and other shaped articles. The fibers have excellent physical properties, including superior strength and stretch recovery.
Abstract: An acid-dyeable polyester composition comprising (a) polyester and (b) secondary amine or secondary amine salt in an amount effective to promote acid-dyeability. The acid-dyeable polyester composition may be prepared by melt blending: the polyester; and polymeric additive prepared from (i) triamine containing secondary amine or secondary amine salt unit(s) and (ii) one or more other monomer and/or polymer units. One polymeric additive comprises polyamide selected from the group consisting of poly-imino-bisalkylene-terephthalamide, -isophthalamide and -1,6-naphthalamide, and salts thereof. Also, the polymeric additive, the blends, shaped articles (e.g., fibers and films), processes of dyeing, and processes for preparing an acid dyeable polyester composition.
Abstract: A polyether ester elastomer comprising about 90-about 60 weight % polytrimethylene ether ester soft segment and about 10-about 40 weight % tetramethylene ester hard segment, and use thereof in fibers and other shaped articles. The fibers have excellent physical properties, including superior strength and stretch recovery.