Patents Represented by Attorney Mark J. DiPietro
  • Patent number: 4321214
    Abstract: A purification process of crude oil soluble hydrocarbon sulfonic acid mixtures which comprises washing the crude oil soluble hydrocarbon sulfonic acid with water, contacting the washed, partially pure oil soluble hydrocarbon sulfonic acid with an excess of calcium carbonate to neutralize entrained sulfuric acid and adsorb impurities, removing the resulting calcium sulfate along with the remaining calcium carbonate, and recovering the pure sulfonic acid. Sulfonic acid produced in this manner is substantially free of impurities. The sulfonic acid is ideal for overbasing to high Total Base Number (TBN) sulfonate.
    Type: Grant
    Filed: January 17, 1977
    Date of Patent: March 23, 1982
    Assignee: Standard Oil Company (Indiana)
    Inventor: Charles F. Nicolet
  • Patent number: 4321215
    Abstract: A method for producing ammonium hydrocarbon sulfonate which comprises (1) contacting a sulfonation liquor comprising a hydrocarbon sulfonic acid, unreacted hydrocarbon, and SO.sub.3 with an alcoholic extraction medium in which the unreacted hydrocarbon is insoluble, (2) separating the insoluble hydrocarbon raffinate from the extraction medium, (3) removing a substantial portion of the extraction medium in a stripping tower to produce a hydrocarbon sulfonic acid having a residual amount of extraction medium, (4) neutralizing the hydrocarbon sulfonic acid with an excess of ammonia to produce an ammonia hydrocarbon sulfonate and heating the ammonium hydrocarbon sulfonate to remove residual volatile material. To conserve ammonia and solvent, this volatile material is returned to the stripping tower.
    Type: Grant
    Filed: June 1, 1978
    Date of Patent: March 23, 1982
    Assignee: Standard Oil Company (Indiana)
    Inventor: James W. McAbery
  • Patent number: 4298353
    Abstract: An amino methylenesulfonic acid comprising the reaction product of an amine compound (eg) a substituted succinimide containing free primary or secondary nitrogen atoms or a compound of the formula R.sub.1 NH-CH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2 or RNH.sub.2 wherein R and R.sub.1 have 1 to 25 carbon atoms; a compound of the formula ##STR1## wherein R.sub.2 is a hydrogen or a methyl group and R.sub.3 is a hydrogen or an alkyl group having from about 1 to 7 carbon atoms and sulfur dioxide; which can be alternatively reacted with a polyfunctional crosslinking agent; and mixtures of the amino-methylene sulfonic acid with a nitrogen compound adduct of a maleic anhydride olefin copolymer.
    Type: Grant
    Filed: February 25, 1980
    Date of Patent: November 3, 1981
    Assignee: Standard Oil Company (Indiana)
    Inventor: James R. Spence
  • Patent number: 4252542
    Abstract: An amino methylenesulfonic acid comprising the reaction product of an amine compound (eg) a substituted succinimide containing free primary or secondary nitrogen atoms or a compound of the formula R.sub.1 NH-CH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2 or RNH.sub.2 wherein R and R.sub.1 have 1 to 25 carbon atoms; a compound of the formula ##STR1## wherein R.sub.2 is a hydrogen or a methyl group and R.sub.3 is a hydrogen or an alkyl group having from about 1 to 7 carbon atoms and sulfur dioxide; which can be alternatively reacted with a polyfunctional crosslinking agent; and mixtures of the amino-methylene sulfonic acid with a nitrogen compound adduct of a maleic anhydride olefin copolymer.
    Type: Grant
    Filed: April 26, 1978
    Date of Patent: February 24, 1981
    Assignee: Standard Oil Company (Indiana)
    Inventor: James R. Spence
  • Patent number: 4188299
    Abstract: Compounds having the structures: ##STR1## wherein B is A or a hydrogen and A is R--X; wherein X is ##STR2## M is a Group II metal cation and R is a hydrocarbyl group having about 1 to 100 carbon atoms.
    Type: Grant
    Filed: May 17, 1978
    Date of Patent: February 12, 1980
    Assignee: Standard Oil Company (Indiana)
    Inventor: Gunter Caspari
  • Patent number: 4170562
    Abstract: The invention provides a process for the Mannich condensation reaction of oxidized olefinic polymers. The condensation reaction is carried out in the presence of about 0.01 to 25.0 weight percent of an oil soluble phenol based on the neat polymer. The phenols improve the processing and properties of the oxidized oil soluble Mannich reaction product.
    Type: Grant
    Filed: February 15, 1978
    Date of Patent: October 9, 1979
    Assignee: Standard Oil Company
    Inventor: C. Thomas West
  • Patent number: 4137186
    Abstract: Process for preparing overbased magnesium sulfonate dispersions by hydrating at an elevated temperature a magnesium compound in the presence of an inert diluent, an alkanol, a sulfonic acid comprising a neutral ammonium sulfonate, and water, removing the alkanol and the displaced ammonia, and contacting the resulting mixture with an acidic material at a temperature of about 80.degree. F to 155.degree. F.
    Type: Grant
    Filed: November 22, 1977
    Date of Patent: January 30, 1979
    Assignee: Standard Oil Company (Indiana)
    Inventor: Albert R. Sabol
  • Patent number: 4137183
    Abstract: A compound having the structure ##STR1## WHEREIN X+Y=4 AND X RANGES FROM 1 TO 3 AND Y RANGES FROM 1 TO 3 AND R.sub.1 comprises a hydrocarbyl group of about 1 to about 18 carbon atoms and R.sub.2 is a hydrocarbyl group of about 1 to 24 carbon atoms.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: January 30, 1979
    Assignee: Standard Oil Company (Indiana)
    Inventor: Guntar Caspari
  • Patent number: 4131551
    Abstract: An improved lubricant composition comprises (A) a lubricant mineral oil base, (B) a Mannich condensation reaction product comprising the reaction product of an alkyl phenol, a polyamine and formaldehyde, (C) an alkaline earth metal salt of a Mannich condensation reaction product comprising the reaction product of alkyl phenol, formaldehyde and a polyamine, (D) an alkylbenzene alkaline earth metal sulfonate of low total base number, and (E) the alkaline earth metal salts of a bis-alkylphenol sulfide, (F) chlorinated paraffin, and (G) dimethyl siloxane polymer.
    Type: Grant
    Filed: August 15, 1977
    Date of Patent: December 26, 1978
    Assignee: Standard Oil Company
    Inventors: Jerry L. Thompson, Sigmund S. Deluga, James W. Harnach, Eliahu Shamah
  • Patent number: 4131553
    Abstract: This invention provides a process for and products of the Mannich condensation reaction of oxidized olefinic polymers. The Mannich reaction is carried out in the presence of about 0.01 to 40.0% by weight of an oil soluble sulfonic acid based on the neat polymer. The sulfonic acid improves the properties of the oxidized oil soluble Mannich reaction product and catalyzes the Mannich condensation reaction.
    Type: Grant
    Filed: February 15, 1978
    Date of Patent: December 26, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventor: C. Thomas West
  • Patent number: 4125471
    Abstract: A stable free sulfur containing mineral oil is produced in a two-step process. The first step of the process comprises producing a sulfurized solubilizing oil by reacting a lubricant oil with elemental sulfur until the uncombined sulfur content is less than about 0.5%. The second step comprising dissolving in the oil a quantity of sulfur such that the final concentration of uncombined sulfur is less than 2.0%.
    Type: Grant
    Filed: August 3, 1977
    Date of Patent: November 14, 1978
    Assignee: Standard Oil Company a corporation of Indiana
    Inventors: Paul C. Vienna, Marvin J. Den Herder, Alex Zletz
  • Patent number: 4122020
    Abstract: A method is disclosed for moving and eventually recovering oil from a subterranean oil-bearing formation which comprises injecting into the formation an aqueous fluid containing a succinamate surface-active agent and method for mobility control (imparting viscosity) to a surfactant system used for recovery or moving of oil in an oil-bearing formation.
    Type: Grant
    Filed: August 25, 1977
    Date of Patent: October 24, 1978
    Assignee: Standard Oil Company
    Inventors: Joseph J. Valcho, Robert E. Karll
  • Patent number: 4120344
    Abstract: Tellurium steel may be cast with a white mineral oil lubricant preventing dangerous explosive reactions.
    Type: Grant
    Filed: July 20, 1977
    Date of Patent: October 17, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventors: Arthur C. Borg, Alex Zletz
  • Patent number: 4120800
    Abstract: A method is disclosed for moving and eventually recovering oil from a subterranean oil-bearing formation which comprises injecting into the formation an aqueous fluid containing a succinamate surface-active agent and method for mobility control (imparting viscosity) to a surfactant system used for recovery or moving of oil in an oil-bearing formation.
    Type: Grant
    Filed: August 25, 1977
    Date of Patent: October 17, 1978
    Assignee: Standard Oil Company
    Inventors: Joseph J. Valcho, Robert E. Karll
  • Patent number: 4113443
    Abstract: The product of the reaction of an amine, an olefin and sulfur trioxide, or sulfur trioxide complex, is an effective ashless antistatic agent for hydrocarbons. A small amount of the antistatic agent, when added to hydrocarbons, increases the conductivity of the hydrocarbon. The increased conductivity of the hydrocarbon conducts away any static charges that may be generated on the hydrocarbon and thus prevents the buildup of the static charges. The antistatic additive is represented by the general formula ##STR1## where R.sub.1 is a hydrocarbon group of less than 24 carbon atoms and R.sub.2 is hydrocarbon group with less than 18 carbons, or ammonia.
    Type: Grant
    Filed: June 27, 1977
    Date of Patent: September 12, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventor: J. Ronald Spence
  • Patent number: 4097387
    Abstract: Disclosed are a composition of matter, a process for making said composition, and a lubricating oil composition having improved anti-wear properties containing an effective amount of said composition of matter.The composition of matter comprises olefin-dimercapto-thiadiazole compositions, especially an oil soluble reaction product of an olefin; lithium, sodium or potassium 2,5-dimercapto-1,3,4-thiadiazole or mixtures thereof; and a member selected from the group consisting of S.sub.2 Cl.sub.2, SCl.sub.2, S.sub.2 Br.sub.2, SBr.sub.2, R-S-Cl, R-S-Br, and mixtures thereof, wherein R comprises C.sub.1 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl.Some of these compositions can be represented as follows: ##STR1## wherein X comprises R.sub.1 -SS-R.sub.2, wherein R.sub.1 comprises a C.sub.6 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl, and R.sub.2 comprises R.sub.1 or ##STR2## and wherein Y comprises H or X. Preferably R.sub.1 comprises C.sub.6 -C.sub.
    Type: Grant
    Filed: September 3, 1976
    Date of Patent: June 27, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventor: Gunter Caspari
  • Patent number: 4094800
    Abstract: Disclosed are lubricating oil compositions having improved anti-wear properties, comprising a major portion of a lubricating oil and an effective amount of an oil soluble additive combination comprising a basic zinc alkyl dithiophosphate having alkyl groups made from primary alcohols containing from about 6 to about 20 carbon atoms and a non-acidic lubricating oil anti-rust compound comprising a succinic anhydride substituted with an alkenyl group which has about 8 to about 50 carbon atoms reacted with an alcohol, an amine, or mixtures thereof.The zinc dithiophosphate is generally made from primary alcohol containing about 7 to about 12 carbon atoms and generally has a zinc to phosphorous ratio of about 1.15-1.5:1.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: June 13, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventor: Thomas M. Warne