Abstract: A composition comprising an admixture ofa. a major quantity of an aromatic polycarbonate andb. a minor quantity ofi. a polycarbonate polysiloxane block copolymer; andii. a hydrogenated alkylidene vinyl aromatic block copolymer graft modified with an unsaturated dicarboxylic acid or unsaturated dicarboxylic acid anhydride,wherein the quantities of b are such that the 1/4 inch impact resistance of a molded part and the organic solvent resistance is improved over polycarbonate alone while maintaining the compatibility of the composition of a and b.
Abstract: A die block component for use in a punch and die assembly is described, having a plurality of grooves in the die face. The block and assembly are useful for cutting articles from sheets and film of synthetic polymeric resins while avoiding the contamination of the article with severed particles and slivers.
Type:
Grant
Filed:
March 14, 1990
Date of Patent:
April 16, 1991
Assignee:
General Electric Company
Inventors:
Stephen O. Ketcham, Paul W. Ortiz, Jamie S. Jarvis, Clyde S. McCray
Abstract: A composition comprising an admixture of (a) polybutylene terephthalate, (b) an impact modifying effective amount of an ABS or ABS type resin, and (c) a mold release and/or impact resistance improving effective amount of a fluid hydrogenated or non hydrogenated oligomer of an alpha olefin.
Abstract: Apparatus for the thermoplastic shaping of polymeric resins is improved by the use of thin-film resistance heaters as the means of applying thermal energy to the resin. The heaters are mounted on the resin molding surfaces.
Abstract: Block copolymers which include polyisobutylene chain moieties of the formula: ##STR1## wherein n is an integer such that the moiety has a molecular weight contribution of from 5,000 to 30,000 Daltons as determined by gel permeation chromatography are obtained by block copolymerization of appropriate compounds of the formula: ##STR2## wherein n is as defined above and X represents hydroxyl, halogen or alkoxy, with polycarbonates, polyesters, polyamides, poly(ester-amides), polyarylates, polyetherimides or monomer precursors thereof. The block copolymers are useful thermoplastic molding compositions.
Abstract: Carboxylic acid functionalized polydimethylsiloxane fluids react with polycarbonate in the melt to form polydimethylsiloxane/polycarbonate block copolymers. The resultant copolymers are transparent and show improved flow and thick section impact relative to the polycarbonate.
Type:
Grant
Filed:
June 16, 1989
Date of Patent:
February 19, 1991
Assignee:
General Electric Company
Inventors:
Christopher M. Hawkins, Robert R. Gallucci
Abstract: A process which comprises reacting interfacially a dihydric phenol, a carbonate precursor and a prior prepared salt of an aliphatic alpha omega dicarboxylic acid having from 8 to about 20 carbon atoms thereby producing a copolyestercarbonate.
Type:
Grant
Filed:
January 30, 1990
Date of Patent:
January 8, 1991
Assignee:
General Electric Company
Inventors:
Luca P. Fontana, Paul W. Buckley, Denise Y. Harris, Eugene P. Boden
Abstract: A composition comprising an aromatic polycarbonate in admixture with an anti-yellowing effective amount of a compound of the formula ##STR1##
Type:
Grant
Filed:
December 30, 1988
Date of Patent:
October 9, 1990
Assignee:
General Electric Company
Inventors:
Robert C. Babillis, Stanley V. Martin, Randall A. Reed
Abstract: Polycarbonate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group consisting of hydrogen, halogen, hydrocarbyl of from 1 to 12 carbon atoms, inclusive; and halogen-substituted hydrocarbyl of 1 to 12 carbon atoms, inclusive; R.sub.1 is attached to a ring carbon atom at one of the 4, 5 or 6 positions; and R.sub.2 and R.sub.3 when taken together represent the divalent moiety of formula: --CH.dbd.CH.sub.2 --CH.sub.2 .dbd.CH--which effectively creates an additional fused aromatic ring structure. The resins exhibit a low plate-out when processed thermally.
Type:
Grant
Filed:
December 20, 1988
Date of Patent:
August 21, 1990
Assignee:
General Electric Company
Inventors:
Daniel W. Fox, Edward N. Peters, Paul D. Sybert
Abstract: A composition comprising a modified polyester, said modification being in the additional presence in the backbone of the polyester unsaturated aliphatic diester repeating units, the said modified polyester being covalently bonded to a polyolefin.
Type:
Grant
Filed:
September 12, 1988
Date of Patent:
August 14, 1990
Assignee:
General Electric Company
Inventors:
Christopher M. Hawkins, Robert R. Gallucci
Abstract: A plastic container for use in receiving product in a hot state the sealing of which creates a negative pressure therein after the product cools, an ovalized portion of the container disposed between a bottom and shoulder having circular cross sections wherein the negative pressure causes a uniform deformation of the ovalized portion allowing the container to remain aesthetically pleasing in appearance.
Abstract: Polycarbonate and polyarylate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein each R independently represents one of hydrogen or lower alkyl. The resins are reactive polycarbonates, poly(ester carbonates) and polyarylates, useful as intermediates in the preparation of block and graft copolymers, with other polymers having functional, reactive groups.
Abstract: Apparatus and method for the impregnation of a continuous length of multifilament or multifiber yarns with a molten thermoplastic polymeric resin includes a member for spreading the multifilaments or multifibers apart during their immersion in a bath of the molten resin. The shape, configuration and location of the member facilitates the homogeneous impregnation, particularly with highly viscous melts, to produce a uniform and thorough encapsulation of the filaments or fibers.
Abstract: A composition comprising an admixture of(a) an aromatic polycarbonate of intrinsic viscosity of from about 0.35 to about 0.41 dl/g, measured in methylene chloride at about 25.degree. C., said aromatic polycarbonate chain terminated with an endcapping agent which provides the polycarbonate with improved ductility and higher Tg when compared to a paratertiary butyl phenol encapped polycarbonate of the same intrinsic viscosity;(b) a core/shell copolymer comprising a conjugated diene with a Tg of less than or equal to -10.degree. C. as the core, said core being about 50 to 90 wt.
Type:
Grant
Filed:
December 28, 1988
Date of Patent:
June 5, 1990
Assignee:
General Electric Company
Inventors:
Omar M. Boutni, Linda H. Nelson, Dwight J. Patterson, Charles F. Pratt, Herman B. Savenije
Abstract: Polycarbonate resins containing at least one divalent chain unit of the formula: ##STR1## are transitory cross-linkers prepared by thermal degradation of the corresponding acid esters (the ester group being removable under conditions of the degradation by a beta-elimination mechanism). Cross-linked polycarbonate resins exhibit enhanced fire-resistance, especially non-dripping. The cross-linkers are useful to cross-link any resin having a group reactive with a carboxyl group.
Abstract: Polycarbonate blends with a VO rating by underwriters laboratory Bulletin 94 (UL-94), together with good strength and processing characteristics are obtained by blending an aromatic carbonate polymer, an ABS copolymer, a tetrabromobisphenol A polycarbonate and a flame retardant sulfonate salt.
Abstract: A polycarbonate resin, containing in the polymer chain at least one divalent moiety of the formula: ##STR1## wherein E is selected from the group consisting of alkylene containing from 1 to 15 carbon atoms, inclusive, and halogen-substituted alkylene containing from 1 to 15 carbon atoms, inclusive, a is an integer of 0 or 1 and R' is hydrogen or hydrocarbyl or halogen substituted hydrocarbyl amenable to beta elimination upon thermal degradation.