Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.

Abstract: Autodeposited coatings useful for protecting metal surfaces and in production of rubber-to-metal composites are obtained by curing adducts based on epoxy resins which are adhered to the metal surface. One or more epoxy resins, such as for example, the combination of a diglycidyl ether of bisphenol A and a flexibilizing epoxy resin, may be prereacted to form an adduct of higher average molecular weight than the starting epoxy resins. Said adduct may then be dispersed in water, with the resulting dispersion being used in an autodeposition bath composition.

Abstract: A film of a polymer or polymer precursor such as an epoxy resin is autodeposited on an active metal surface and then used to form an adhesive bond directly between the metal surface and the surface of a rubber substrate. Excellent adhesion of the metal to the rubber is obtained without the need to either phosphate the metal surface or use a primer or adhesive other than the autodeposited coating.

Abstract: A multipurpose treatment composition for metal surfaces comprises phosphate ions, fluorometallate ions, water soluble polymers containing substituted aminomethylene moieties bonded to benzene rings which also have an oxygen atom bonded to another carbon atom in the same ring, and a distinct kind of film-forming polymer. The compositions are free from chromium and other heavy metals that cause serious pollution problems in some prior art treatment compositions.

Abstract: Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments may be stabilized to decrease the rate of hydrogen peroxide decomposition by the use of an aryl sulfonic acid such as phenol sulfonic acid in combination with a triazole such as tolyltriazole.

Abstract: Using aqueous electrolytes containing complex fluorides or oxyfluorides such as fluorozirconates, fluorotitanates, and fluorosilicates, articles containing light metals such as magnesium and aluminum may be rapidly anodized to form protective surface coatings. White coatings may be formed on aluminum articles using pulsed direct current or alternating current. When the article to be anodized is comprised of magnesium, pulsed direct current having a relatively low average voltage is preferably used.

Abstract: A water-based metal surface treatment composition for forming a lubricating film with excellent marring resistance, characterized in that it comprises (a) a water-compatible urethane resin which contains bisphenol skeletons and carboxyl groups in the resin backbone and has an average molecular weight of 3,000 or higher and which has been synthesized through reaction of an isocyanate in which the content of nitrogen atoms participating in the isocyanate reaction is 2 to 13 wt. % and the ratio of nitrogen atoms participating in urea bond formation to the nitrogen atoms participating in the isocyanate reaction is 10/100 to 90/100, (b) a hardener, (c) silica, and (d) a polyolefin wax, and that the sum of the ingredients (a) and (b) is 50 to 95 wt. % based on the whole composition (e) on a solid basis, the amount of functional groups contained in the ingredient (b) is 0.10 to 1.00 equivalent to the carboxyl groups contained in the backbone of the ingredient (a), the amount of the ingredient (c) is 3 to 40 wt.

Abstract: Corrosion resistant, hydrophilic coatings on the surface of aluminum and aluminum alloys may be formed using aqueous compositions containing fluorometallates such as H2TiF6 or H2ZrF6 and vanadium compounds such as decavanadates. To minimize the odor evolved from the conversion coatings it is preferred for a specified oxide, hydroxide, carbonate, or alkoxide to also be present in or added to the aqueous composition.

Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid that preferably has a pH value between 0.5 and 5.

Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.

Abstract: A metal treating composition comprising at least a specific type of dissolved and/or dispersed organic resin, a dissolved vanadium compound in which the valence of vanadium is from 3 to 5, and a dissolved compound that contains at least one of the metals Zr, Ti, Mo, W, Mn, and Ce can provide metal surfaces with superior corrosion resistance, alkali resistance, and fingerprint resistance. The composition contains no chromium to cause pollution problems and/or require pollution abatement.

Abstract: A process of cleaning very sparingly water soluble soaps off workpieces after cold forming them is made considerably more economical by using a cleaning solution that causes the removed soap anions to form a separate floating solid phase that can easily be skimmed from the surface of the cleaning solution. When such a separation is made, much longer intervals between replacement of the cleaning solution are possible while still obtaining satisfactory results. A preferred cleaning solution for such a process comprises hydroxides, neutral salts, polymeric quaternary ammonium cations, and a sequestering agent for the counterions of the soap anions to be cleaned.

Abstract: Autodeposition compositions for polymeric coatings of reduced gloss are prepared using resins having at least one hydroxy group and at least one epoxy group per molecule, a low temperature crosslinker and a high temperature crosslinker. The low temperature crosslinker forms a reactive prepolymer that may be subsequently mixed or emulsified with a high temperature crosslinker to form an autodeposition composition. Alternatively, a hybrid crosslinking agent may be utilized which contains both free isocyanate groups reactive at a relatively low temperature with the resin and at least one functional group capable of reacting with the resin only at a relatively elevated temperature. When deposited and cured, the resulting coating has a matte finish that is resistant to surface defects.

Abstract: A metal surface on which a phosphate conversion coating is to be formed and which has been surface conditioned by contact with a liquid surface conditioner composition that contains dispersed fine particles of solid phosphate of at least one divalent or trivalent cations type and an adhesion promoting agent. After such conditioning, a very high quality conversion coating can be formed on the surface by contact with a nickel-free liquid phosphating composition that contains at least acid, zinc cations, and phosphate anions and optionally and preferably also contains other materials.

Abstract: In a process for the chemical pretreatment before painting of composite metal structures that contain aluminum or aluminum alloy portions together with steel, galvanized steel and/or alloy-galvanized steel portions, in a first step the metal structure is treated with a zinc phosphating solution that forms a surface-covering crystalline zinc phosphate layer on steel and on galvanized or alloy-galvanized steel, but without forming a zinc phosphate layer on the aluminum portions, and then in a second step the metal structure is brought into contact with a treatment solution that does not excessively dissolve the crystalline zinc phosphate layer on steel, galvanized and/or alloy-galvanized steel, but forms a conversion layer on the aluminum portions.

Abstract: Polyols initiated with a first initiator having a relatively high functionality averaging greater than eight and comprising a range of species of different functionality, and optionally a second initiator, having low functionality, i.e. a two to eight nominal functionality initiator molecule. Another aspect of the invention is a process for making the polyol. The invention is also directed to a process for producing polyurethane foam by reacting the polyol of the invention with isocyanates, and the foam produced thereby.

Abstract: A metal article whose surface is coated with a coating composition composed of (A) a silane coupling agent component, (B) a polymer component having a specific chemical structure, and (C) a wax component provides a chromium-free surface treated metal material with superior corrosion resistance, paintability, fingerprint resistance, and workability.

Abstract: A liquid iron phosphating concentrate is provided which contains dispersed aromatic carboxylic acid. The aromatic carboxylic acid remains dispersed in the concentrate by incorporation of a thickener in the composition.

Abstract: A water-based liquid treatment composition for metal surfaces comprises water, (A) dissolved, dispersed, or both dissolved and dispersed urethane resin, acrylic resin; or both urethane and acrylic resins; (B) dissolved, dispersed, or both dissolved and dispersed curing agent molecules; (C) dispersed silica powder; (D) dispersed oxidized polyethylene wax with an average particle size of 0.01 to 0.

Abstract: A composition and method for coating and touching up a metal surface is provided. The composition contains from about 0.5 to about 240 millimoles per kilogram of a fluorometallate ion, from about 0.5 grams/liters to about 10 grams/liter of phosphorous-containing inorganic oxy anions calculated at their stoichiometric equivalent as H3PO4; from about 0.05 g/l to about 3.5 g/l of hexavalent chromium and from about 0.10 g/l to about 2.20 g/l of trivalent chromium ions and a surfactant.