Abstract: A process for forming a shaped laminate for use in a safety glazing such as a vehicle window or the like which comprises lightly bonding at least one flexible, transparent, thermoplastic carrier layer having one or more adherent functional performance layers or coatings on its surface to at least one layer of ptasticized polyvinyl butyral to form a premolding composite, stretching the composite to impart compound curvature thereto and form a shaped, shrinkable laminate, subjecting the shaped laminate to elevated temperature while constraining its edges to relieve stresses in the carrier layer, and cooling the shaped laminate while maintaining its edges constrained.

Abstract: Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.

Abstract: Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.

Abstract: Paper surface sizing properties of aqueous solutions of high molecular weight (at least 100,000 Daltons weight average) styrene-maleate half ester polymers are improved by forming the maleate half ester using oxyalkylene-alkyl alcohol, preferably 2-(n-butoxy) ethyl alcohol.

Abstract: A light-transmitting laminated panel having increased resistance to impact-induced rupture sequentially includes: a) a glass layer, b) an optically clear layer of a plasticized polyvinyl butyral matrix containing discrete particles of crosslinked polyvinyl butyral integrally randomly dispersed throughout the matrix which enhance the impact-resistance of the panel and are visually indistinguishable from the matrix polyvinyl butyral, and c) another glass layer, the laminated panel at a specific pummel adhesion having greater mean break height than that of a laminated panel containing layers a), b) and c) but without the impact-resistance-enhancing particles of crosslinked polyvinyl butyral in layer b). An amount up to 40 weight % of the particles is incorporated into the matrix polyvinyl butyral before preparing the laminated panel.

Abstract: A plastic sheet, preferably of plasticized partial polyvinyl butyral, for a laminated safety glazing, having means dispersed on its surface, preferably comprising a multiplicity of spaced projections, capable of resisting adhesion to a rigid panel, such as glass, of such a glazing when the sheet is laminated to the panel, the area of the sheet surface without such dispersed means having high affinity for adhesion. The projections physically block adhesion of a dispersed area of the sheet to the panel in that the means on the sheet surface have no or weak interfacial adhesion. The multiplicity of space projections also have low or no affinity for adhesion when in blocking contact with each other or with another plasticized partial polyvinyl butyral surface and thereby increase blocking resistance.

Abstract: A thermoplastic interlayer, such as of polyvinyl butyral, has a regular pattern of deairing channels formed in each side which are angularly arranged with respect to each other wherein, to avoid moire, the angle of intersection is at least 25 degrees, preferably 90 degrees.

Abstract: A mixed bisimide having the formula: ##STR1## wherein D, A and Z are as defined in the specification, produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid anhydride and a halogenated compound containing an anhydride group and aromatic or bicyclo groups to form a bisamic acid composition and then dehydrating such composition to ring close the end groups. The halogenated end groups (Z) of the mixed bisimide component render the bisimide reaction product of the ring closing reaction flame retardant.

Abstract: A laminated glazing panel having improved resistance to light exposure comprising: A) a glass sheet; B) an IR reflective or electrically conductive multi-layered coating on the glass sheet which includes a cap layer of Cr.sub.x O.sub.y where X.ltoreq.2 and y.ltoreq.5; and C) a plasticized sheet containing polyvinyl butyral in interfacial contact with the cap layer, such sheet containing one or more carboxylic acid metal salts wherein the metal is predominantly divalent, in amount effective to control the potential level of adhesion of said plasticized sheet to another glass sheet to which it is eventually laminated; such glazing panel when laminated with said another glass sheet exhibiting pummel adhesion, measured on the side of the plasticized sheet contacting component B), of at least 3 after at least 2000 hours exposure in a Fadeometer or Weatherometer.

Abstract: A thermoplastic interlayer having a first air removal surface which includes a multiplicity of microscopic embossments of substantially identical shape integrally projecting from the plane of one side of the interlayer in a regular pattern and a second air removal surface on the other side of the interlayer which is different from the first air removal surface and includes a multiplicity of microscopic peaks and valleys of varying heights and depths arranged in an irregular, non-linear pattern; the height, R.sub.z, of the embossments and peaks being less than about 75 microns and the distance, S.sub.m, between embossments and peaks being less than about 650 microns. During deairing in forming a safety glazing, the first air removal surface is partially transferred to and imposed on the second air removal surface to provide deair paths of reduced obstruction.

Abstract: A mixed bisimide having the formula: ##STR1## wherein D, A and Z are as defined in the specification, produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid anhydride and a halogenated compound containing an anhydride group and aromatic or bicyclo groups to form a bisamic acid composition and then dehydrating such composition to ring close the end groups. The halogenated end groups (Z) of the mixed bisimide component render the bisimide reaction product of the ring closing reaction flame retardant.

Abstract: The adhesion between layers of polyester and plasticized polyvinyl butyral is improved by the presence of a surface film of plasma-polymerized chlorosilane (e.g. dichlorosilane) at the interface between the layers.

Abstract: A process for deairing an interface region by applying on the surface of a plastic sheet a multitude of spaced plastic projections formed of a plastic material different from that of the sheet, assembling the sheet with the spaced projections in face to face contact with at least one rigid panel such as glass, and evacuating air from the interface region between the rigid panel and the plastic sheet through spaces between the projections.

Abstract: A method of producing plasticized partial polyvinyl butyral sheet having a desired level of potential adhesion to glass which comprises: i) providing partial polyvinyl butyral resin having a high affinity for adhesion to glass when in sheet form under laminating conditions of elevated temperature and pressure, ii) mixing the resin with plasticizer to form a heat-shapable formulation, iii) extruding the formulation to form a sheet, and iv) applying a multiplicity of spaced anti-adhesion projections to the surface of the sheet to an extent effective to counteract the high adhesion of the sheet to glass between projections.

Abstract: A method of protecting a metal layer of a solar reflecting coating on a heat-shrinkable substrate, which are components of a prelaminate for a laminated window, from atmospheric corrosion. The prelaminate is cut partially through its thickness adjacent the edge and when the region of the cut is later exposed to elevated temperature, preferably during the laminating process forming the window, the substrate shrinks to create a channel into which flows plasticized polyvinyl butyral (PVB) to block the edge wall of the coating inward of the channel from the surrounding atmosphere.

Abstract: A process for preparing a flame retardant bisimide composition which comprises reacting i) diamine with ii) a mixture of ethylenically unsaturated dicarboxylic acid anhydride and a halogenated compound containing aromatic or bicyclo groups and an anhydride groups to form an intermediate bisamic acid composition, the molar ratio of the halogenated compound to the ethylenically unsaturated dicarboxylic acid anhydride being no more than 1:1; and dehydrating the bisamic acid composition to ring close the end groups and form a flame retardant bisimide composition having end groups which contain ethylenically unsaturated carbon-carbon bonds and end groups free of non-benzenoid unsaturation containing halogen atoms and aromatic or bicyclo groups.

Abstract: The ammonium salt of a polymer of styrene and maleic anhydride includes 0.02 to 0.20 weight fraction copolymerized C.sub.1 -C.sub.3 alkyl methacrylate to improve paper signing properties.

Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.

Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.

Abstract: A process for forming a shaped prelaminate of glass and plastic by a) drawing an assembly of plastic layers against a hot, contoured, e.g. of compound curvature, mold surface to provide a shaped plastic preform at elevated temperature; b) transferring the shaped preform without cooling to an adjacent unheated glass layer of substantially matching surface contour to heat bond the shaped plastic preform to the glass layer; and then c) removing heat from the shaped plastic preform via conductive heat transfer to the glass layer to form the shaped prelaminate of glass and plastic layers. A bilayer glazing panel is formed in a conventional unmodified autoclave bonding system by exposing the prelaminate to elevated temperature and pressure to firmly bond the plastic to the glass.