Abstract: A polyurethane composition is disclosed that comprises an isocyanate-terminated polyurethane prepolymer, and a curative agent including a polyaspartic ester. Desirably, the curative agent includes a co-curative selected from the group consisting aromatic diamines and diols. This composition is useful for rotationally casting cylindrical parts. The invention includes the method for coating a cylindrical object.
Abstract: The invention concerns a method for making a polyurethane foam by reacting at least a polyester polyol with at least a polyisocyanate in the presence of a foaming agent and a catalytic agent, such a polyester polyol having been previously obtained by reacting a reactive acid A comprising at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least a polyol P3 with functionality not less than 3, being thereafter called AP2P3, wherein the catalytic agent at least partly consists of at least one amine polyester polyol AP2P3, wherein at least part of polyol P3 consists of at least a polyoxyalkylene polyalkanolamine having at least a tertiary amine function, the alkanol radicals of said polyalkanolamine being C1-C6, the alkylene oxide units being C2-C4 and the statistical mean of the number N o
Abstract: The present invention relates to a process for preparing alkali metal tetraalkylaluminates, in particular potassium tetraethylaluminate, and also to the use of such an aluminate complex in aluminum deposition by electroplating-electrolysis.
Type:
Grant
Filed:
May 27, 2003
Date of Patent:
May 11, 2004
Assignee:
Crompton GmbH
Inventors:
Peter Heitmann, Thomas Wanke, Mario Hüttenhofer
Abstract: A composition is disclosed that comprises lubricating oil and at least a first antioxidant and a second antioxidant, the first antioxidant being a secondary diarylamine and the second antioxidant being a 2,2,4-trialkyl-1,2-dihydroquinoline or a polymer thereof. Also disclosed is a method of increasing the oxidation stability of a lubricating oil comprising adding thereto at least a first antioxidant and a second antioxidant, the first antioxidant being a secondary diarylamine and the second antioxidant being a 2,2,4-trialkyl-1,2-dihydroquinoline or a polymer thereof.
Abstract: A composition of matter is disclosed wherein the composition comprises a polyurethane elastomer prepared by mixing
A) a polyurethane prepolymer,
B) a curative, and
C) a liquid, non-reactive polydimethylsiloxane,
wherein C) is present in a concentration of about 0.5 to about 25% based on the combined weight of A) plus B),
and curing the mixture to form the elastomer.
Abstract: A process for removing saturated fatty acids from a primarily unsaturated fatty acid mixture is disclosed wherein the process comprises fractionally distilling off saturated C16 and other minor fatty acid components in the mixture to a level less than or equal to 4% by weight, adding a lower polyglycerol ester as a crystallization aid, then cooling and fractionally crystallizing out remaining saturated fatty acids to yield a product comprising less than 3.3% saturated fatty acids by weight.
Type:
Grant
Filed:
October 7, 2002
Date of Patent:
March 16, 2004
Assignee:
Crompton Corporation
Inventors:
Guy Hendree, Shannon Martin, Thomas E. Breuer, Kyle Walker
Abstract: A process is disclosed for the preparation of a poly(&agr;-olefin) polymer wherein the process comprises polymerizing at least one &agr;-olefin in the presence of hydrogen and a catalytically effective amount of catalyst comprising the product obtained by combining a metallocene catalyst with a cocatalyst, the metallocene catalyst being at least one meso compound of general formula:
wherein:
A1 and A2 are independently selected from the group consisting of mononuclear and polynuclear hydrocarbons;
M1 is a metal from group IVb, Vb, or VIb of the Periodic Table;
R1 and R2 are independently selected from the group consisting of hydrogen, C1-C10 alkyl, C1-C10-alkoxy, C6-C10 aryl, C6-C10 aryloxy, C2-C10 alkenyl, C7-C40 arylalkyl, C7-C40 alkylaryl, C8-C40 arylalkenyl and halogen;
R7 is selected from the group consisting of:
═BR11, ═AlR11, —Ge—, —Sn—, —O—, —S—, ═SO, ═SO2, ═NR11, ═CO, ═PR11 and &
Abstract: Disclosed herein is a composition comprising:
(A) a lubricant, and
(B) at least one alkyl succinhydrazide compound of the formula:
wherein:
R1 is selected from the group consisting of linear or branched alkyl, alkenyl, alkaryl, alkyl ether, alkyl ester, and alkylene ester groups;
R2 is selected from the group consisting of hydrogen, linear or branched alkyl, alkenyl, alkyl ether, and alkyl ester groups; and
R3 and R4 are independently selected from the group consisting of hydrogen, linear or branched alkyl and alkenyl groups, aryl groups, and alkaryl groups.
Abstract: Disclosed herein is a polyurethane elastomer comprising the reaction product of:
A) at least one aliphatic diisocyanate monomer;
B) at least one high molecular weight polyol;
C) at least one low molecular weight diol comprising an aromatic moiety; and
D) at least one saturated diol curing agent.
These elastomers are useful as components of golf ball covers.
Abstract: A process for preparing fatty acid zinc salts comprising the steps of:
stirring a slurry mixture comprising zinc oxide, at least one catalyst, and water at a temperature in the range of from about 55° C. to about 65° C.; adding at least one fatty acid in its liquid state to said stirred slurry mixture; and reacting the fatty acid with the zinc oxide in the presence of the catalyst in the water at a temperature of from about 60° C. to about 75° C. until substantially all of the fatty acid has reacted. The final product mixture can then be filtered and dried to give a fatty acid zinc salt in high yield.
Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds. Also disclosed is a composition of matter comprising:
A) an ethylenically unsaturated monomer and
B) an effective inhibiting amount, sufficient to prevent premature polymerization during distillation or purification of said ethylenically unsaturated monomer, of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds used together with an effective amount of oxygen or air to enhance the inhibiting activity of said inhibitor.
Type:
Grant
Filed:
January 16, 2002
Date of Patent:
February 3, 2004
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Brigitte Benage, Gerald J. Abruscato, Andrew J. Eisenstein
Abstract: Disclosed herein is a rubber composition comprising:
a) a blocked mercaptosilane of a defined structure, wherein the blocking group contains an unsaturated heteroatom or carbon chemically bound directly to sulfur via a single bond and, optionally, may be substituted with one or more carboxylate ester or carboxylic acid functional groups;
b) an organic polymer;
c) a filler; and
d) a deblocking agent.
Type:
Grant
Filed:
November 9, 2001
Date of Patent:
January 27, 2004
Inventors:
Richard W. Cruse, Robert J. Pickwell, Keith J. Weller, Eric R Pohl
Abstract: The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known henceforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.
Abstract: The invention pertains to the use of a white oil having a select viscosity as an extrusion lubricant for PVC, including PVC potable water pipe.
Abstract: A method is disclosed for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers a polymerization inhibiting amount of a mixture comprising
A) a first inhibitor comprising 4-amino-2,2,6,6-tetramethylpiperidinyloxy, wherein said amino group is a primary, secondary, or tertiary amino group; and
B) at least one other inhibitor having the structural formula:
wherein:
R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl;
R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl;
X1 and X2 (1) are independently selected alkyl groups of 1 to 15 carbon atoms or (2) taken together, form a ring structure with the nitrogen.
Type:
Grant
Filed:
July 12, 2002
Date of Patent:
December 9, 2003
Assignee:
Crompton Corporation
Inventors:
Brigitte Benage, Angela M. Edwards, Vilen Kosover, Gan Wang, Anthony Gentile, Jesus R. Fabian, Gerald J. Abruscato
Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of a mixture comprising:
A) at least one stable hindered nitroxyl compound having the structural formula:
wherein R1 and R4 are independently selected from the group consisting of hydrogen, alkyl, and heteroatom-substituted alkyl and R2 and R3 are independently selected from the group consisting of alkyl and heteroatom-substituted alkyl; and X1 and X2 (1) are independently selected from the group consisting of halogen, cyano, COOR7, —S—COR7, —OCOR7, (wherein R7 is alkyl or aryl), amido, —S—C6H5, carbonyl, alkenyl, or alkyl of 1 to 15 carbon atoms, or (2) taken together, form a ring structure with the nitrogen; and
B) at least one inhibitor selected from the group consisting of ortho-quinone, ortho-hydroquinone, para-quinone, para-hydroquinone, and derivatives of the foregoing.
Type:
Grant
Filed:
July 30, 2001
Date of Patent:
November 25, 2003
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Brigitte Benage, Brendan J. Geelan, Gerald J. Abruscato, Leo Bonnell
Abstract: Silicone surfactants for use in inert gas blown polyurethane foams comprise low to moderate molecular weight comb-type flame-retardant silicone copolymers possessing no high ethylene oxide content branches. The silicone surfactants yield Dissolved Gas Technology foams having improved consistency as compared to other surfactant compositions.
Type:
Grant
Filed:
April 26, 2002
Date of Patent:
November 25, 2003
Inventors:
Brian L. Hilker, Lee F. Lawler, Susan B. McVey
Abstract: An organopolysiloxane composition which comprises:
a) organopolysiloxane I of the general formula:
A(Si(R1)2O)a(SiR1O)bSi(R1)2A
R2(NH2CH2CH2)cNHR3;
b) organopolysiloxane II of the general formula:
(AB)nA
where A is a polysiloxane unit of the general formula:
(X(CaH2aO)bR2(Si(R1)2OcR2(OCaH2a)bX)
and B is a polyalkyleneoxide unit of the general formula (YO(CaH2aO)dY);
c) organopolysiloxane III of the general formula:
A(Si(R1)2O)x(Si(R1)(E)O)y(Si(R1)(G)O)zSi(R1)2A
G is —(R2)bO(C2H4O)c(C3H6O)dR3 group; and
d) organopolysiloxane IV of the general formula:
A(Si(R1)2O)x(Si(R1)(G)ySi(R1)2A
where G is —(R2)bO(C2H4O)c(C3H6O)dR3 group.
Abstract: A composition of matter is disclosed wherein the composition comprises:
A) at least one latent mercaptosilane coupling agent; and
B) at least one additional mercaptan.
Preferably, the composition comprises:
A) at least one sulfur vulcanizable rubber;
B) at least one latent mercaptosilane coupling agent;
C) at least one latent mercaptosilane activator;
D) at least one filler; and, optionally,
E) at least one additional mercaptosilane.
A two pass process for preparing cured articles, such as tires and/or tire treads, which employs the composition is also disclosed.
Type:
Grant
Filed:
December 15, 2000
Date of Patent:
October 21, 2003
Assignee:
Crompton Corporation
Inventors:
Richard W. Cruse, Martin J. Hannon, Prashant G. Joshi, Frederick D. Osterholtz, Robert J. Pickwell
Abstract: The present invention is directed to fast reacting epoxy compositions employing select unidentate and chelated Ti(IV) and Sn(II) curing catalysts.
Type:
Grant
Filed:
August 29, 2000
Date of Patent:
September 30, 2003
Assignee:
Crompton Corporation
Inventors:
Antonio Chaves, Eric R. Pohl, Frederick D. Osterholtz