Abstract: Copolymers comprising, in polymerized form, a 1,1-substituted arylethylene comonomer and at least one polymaleimide comonomer, are prepared using a system that provides a reduced onset of polymerization temperature thereby allowing removal of the copolymer from the mold after a preliminary curing period followed by transfer to an oven, a less expensive piece of equipment, for additional curing; thus making the mold, a more expensive piece of equipment, available for the next polymerization run.

Abstract: A high tonnage reaction injection molding (RIM) press has fixed and movable platens for clamping a composite mold therebetween at a closed mold position. A plurality of high pressure hydraulic cylinders are mounted on a carrier for the movable platen, and a locking mechanism having a plurality of incrementally spaced locking positions is effective to lock the carrier selectively at said positions. A pair of low power hydraulic piston-cylinder assemblies connected with the carrier adjacent to its opposite ends move the carrier and movable platen to the closed position. Short stroke connecting rods operated by the high pressure cylinders are forced independently of each other into high tonnage engagement with the movable platen at a plurality of locations within the area of the composite mold to clamp the latter between the platens and positively seal its junctions, whereupon a RIM mix head injects the high pressure reactive chemicals into the sealed mold.

Abstract: A process for preparing linearly-extended polyalkylenepolyamines, such as linear and branched polyethylenepolyamines, comprising contacting a difunctional aliphatic alcohol, such as monoethanolamine, with a reactant amine, such as ethylenediamine, in the presence of a catalyst containing tungsten oxide essentially free of the metals of Groups VIII, IB, and IIB of the Periodic Table. Included among the linearly-extended polyalkylenepolyamines are alcohol-extended piperazines, such as N-(2-hydroxyethyl)-piperazine, and amine-extended piperazines, such as N-(2-aminoethyl)piperazine.

Abstract: Corrosion of metal surfaces in contact with an aqueous medium is inhibited by incorporating a N-(hydrophobe aromatic)pyridinium compound such as N-(p-dodecylphenyl-2,4,6-trimethylpyridinium sulfoacetate into the aqueous medium.

Abstract: Fatty acid ester derivatives of 1,3,5-tris(2-hydroxyalkyl)perhydro-s-triazine or mixed ester/ether derivatives thereof are corrosion inhibitors for acid-containing fluids. The compounds are also useful as emulsifiers, lubricants and hydraulic fluids.

Abstract: This invention is a process for cyclizing an ortho-alkenyl arenol, wherein the double bond of the alkenyl moiety is one or two carbons removed from the aromatic ring, with carbon monoxide, wherein the process comprises contacting an ortho-alkenyl arenol with carbon monoxide in the presence of a catalytic amount of a catalyst comprising (1) a rhodium-carbonyl complex and (2) an amine with a pK.sub.a of 6 or greater, arsine, phosphine, stibine or mixture thereof, under conditions such that a lactone-fused aromatic compound is prepared.

Abstract: Dense star polymers having terminal group densities greater than conventional star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, amine-terminated polyamidoamine dense star polymer prepared from ammonia, methyl acrylate and ethylenediamine has 1.24.times.10.sup.-4 amine moieties per unit volume (cubic Angstrom units) in contrast to the 1.58.times.10.sup.-6 amine moieties per unit volume contained by a conventional star polymer. Such dense star polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, and agents for modifying viscosity in aqueous formulations such as paints.

Abstract: Polyamide-polyurea containing polymers are disclosed that are derived from the reaction of (A) an organic polyisocyanate; (B) an organic compound having at least two active hydrogen containing groups; and (C) about 15 to about 160 parts per 100 parts of said (B) of a chain extender combination comprising (i) a particular enamine and (ii) an aromatic diamine and optionally (iii) an extender diol wherein the ratio of equivalents of (A) to total equivalents of (B) and (C) is within the range of about 0.90:1 to 1.10:1.The polymers find particular utility in the preparation of RIM parts having excellent physical properties. At the same time, the polymers are characterized by slower gel times than prior art aromatic diamine extended polymers thereby allowing the filling of larger molded parts.

Abstract: Novel polyamide block copolymers are provided which comprise a central block of a soft segment derived from the residue of a polymeric polyol or polyamine joined to terminal hard segment polyamide blocks. The linkages which join the blocks are of a novel type and are the opened form of certain bis azetidine-2,4-dione rings.The block copolymers can be prepared very rapidly via anionically polymerizing lactams on to prepolymer soft segments containing terminal azetidine-2,4-dione rings.The speed with which the polymerizations can be carried out make the block copolymers particularly useful for the RIM preparation of molded parts.

Abstract: Disclosed is an improved process for the preparation of carbamates by heating an organic carbonate and an aromatic amine in the presence of aluminum as catalyst and a promoter comprising a combination of iodine and a mercury salt.High reaction temperatures are avoided by the process and conversions to carbamate products are high. Additionally, the process is economically attractive because even the common aluminum foil can be used as the catalyst.The products prepared by the process can be used in the production of insecticides, and, particularly, as intermediates in the preparation of organic mono- and polyisocyanates.

Abstract: The impact resistance and crystallization velocity of polyalkylene terephthalates (polyethylene and polybutylene terephthalates in particular) are improved significantly by blending said polyesters with a minor amount of a segmented polyesteramide.

Abstract: Allyl derivatives of phenols, thiophenols and arylamines are prepared by contacting such aromatic reactant with an allyl lower alkyl carbonate in the presence of a molybdenum, tungsten or Group VIII metal.

Abstract: Reaction injection moldings (RIM) having increased heat resistance are provided by employing a thiapolycyclic polyahl such as dimethyl-9-thiabicyclononane diamine as a chain extender in an otherwise conventional RIM formulation.

Abstract: The reaction of an isocyanate such as toluene diisocyanate with itself to form an isocyanurate or with an active hydrogen compound such as diethylene glycol to form a urethane is catalyzed by the presence of an ar-ammonium areneoxide such as 4-dodecyl-2-trimethylammonium phenoxide.

Abstract: Ordered copolyestercarbonate resins having repeating units of the formula: ##STR1## wherein a portion of R.sup.1 is meta-phenylene and a portion of R.sub.1 is para-phenylene and R is independently an aromatic hydrocarbylene or inertly substituted aromatic hydrocarbylene, e.g., ##STR2## exhibit physical properties such as heat resistance, clarity and impact strength that are superior to the comparable properties of corresponding random copolymers. They exhibit melt processability that is superior to the melt processability of corresponding copolyestercarbonates wherein R.sup.1 is entirely para-phenylene. They exhibit heat resistance, notch sensitivity and low temperature impact resistance that are superior to comparable properties of corresponding copolyestercarbonates wherein R.sup.1 is entirely meta-phenylene. Such resins are useful for making transparent tough films and molded articles having high heat resistance.

Abstract: A low viscosity hydrocarbon solution of a dihydrocarbyl magnesium compound such as di(n-butyl) magnesium is provided by combining the dihydrocarbyl magnesium with a solubilizing amount of an organozinc or organoboron compound, a hydrocarbon liquid and a viscosity reducing agent such as an ether, alcohol, or an organo aluminum compound. Such solution is very useful in the preparation of high efficiency catalysts for the polymerization of ethylene and other alpha alkylenes at polymerization temperatures above 150.degree. C.

Abstract: A multilayer, metal/organic polymer composite exhibiting high specular reflectivity even after substantial elongation is provided by metallizing a layer of thermoplastic organic polymer such as polystyrene or polycarbonate film with a normally solid soft metal such as indium or an alloy of tin and cadmium. Subsequently the multilayer composite or at least a portion thereof can be stretched or elongated by more than 10 percent in both the longitudinal and traverse directions without losing its initial specular reflectivity. Articles fabricated of the multilayer composite may be structurally reinforced by casting an elastomeric or rigid foam polymer such as polyurethane into a cavity defined by the composite. The multilayer composites are useful in the manufacture of reflective and decorative parts for automobiles and other vehicles of transportation, as well as high barrier packages for foods and electroconductive elements.

Abstract: Aqueous solutions of amide polymers, such as polyacrylamide when treated with small amounts of a water-soluble polyaldehyde and a hypohalite salt at an alkaline pH, react to form firm gels within a short time at ambient temperature. Such gels, which are stable under alkaline as well as acidic conditions, are usefully employed to plug porous subterranean formations, for grouting of leaking soil pipes or wells, and to otherwise render porous structures impermeable to the passage of liquids such as water.

Abstract: Ar-halo-ar(t-alkyl)styrenes, e.g., 2-chloro-4-(t-butyl)styrene, polymerize to form materials having unusually high temperature resistance. Additionally, compositions of such monomers, unsaturated polyesters and free-radical generating catalysts cure at lower temperatures and in less time than similar compositions containing conventional styrene monomers.

Abstract: N-(aminomethyl)-.alpha.,.beta.-ethylenically unsaturated carboxamides such as N-(dimethylaminomethyl)acrylamide are readily prepared without coincident production of saturated impurities by reacting an .alpha.,.beta.-ethylenically unsaturated carboxamide such as acrylamide with a lower aldehyde such as formaldehyde and a secondary amine such as dimethylamine at a pH below 7. The resulting aminomethyl carboxamides are polymerized at a pH of 7 or less to form polymers containing essentially no gelled product.